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Lakshya NEET (2024)

Electrochemistry DPP-07

1. The rates of a certain reaction at different times are 7. Silver is monovalent and has atomic mass of 108.
as follows: Copper is divalent and has an atomic mass of 63.6.
Time(s) : 0 10 20 30 The same electric current is passed for the same
Rate : 2.8  10−2 2.78  10−2 2.81 10−2 2.79  10−2 length of time through a silver coulometer and a
copper coulometer. If 27.0 g of silver is deposited,
(mol L−1 s −1 )
then the corresponding amount of copper deposited
The reaction is of is
(1) third order (2) second order (1) 63.60 g (2) 31.80 g
(3) first order (4) zero order (3) 15.90 g (4) 7.95 g

2. Time required to decompose half of the substance 8. By passing 0.1 Faraday of electricity through fused
for nth order reaction is inversely proportional to sodium chloride, the amount of chlorine liberated is
(1) an+1 (2) an–1 (1) 35.45 g (2) 70.9 g
(3) an–2 (4) an (3) 3.545 g (4) 17.77 g

3. What is the order of the reaction which obeys the 9. What is the amount of chlorine evolved when 2
1 amperes of current is passed for 30 minutes in an
expression t1/ 2 = ?
ka aqueous solution of NaCl?
(1) Zero (2) Third (1) 66 g (2) 1.32 g
(3) First (4) Second (3) 33 g (4) 99 g

4. 96500 C of electricity liberates Cu from CuSO4 10. Total charge on 1 mole of a monovalent metal ion is
solution equal to
(1) 63.5g of Cu (1) 9.65 × 104 coulomb
(2) 31.75 g of Cu (2) 6.28 × 1018 coulomb
(3) 96500 g of Cu (3) 1.6 × 10−19 coulomb
(4) 100 g of Cu (4) none of these

5. A current of 2.0 A passed for 5 hours through a 11. If 0.5 amp current is passed through acidified silver
molten metal salt deposits 22.2 g of metal nitrate solution for 10 minutes. The mass of silver
(At wt. = 177 g/mol). The oxidation state of the deposited on cathode is : (Eq. mass of silver nitrate
metal in the metal salt is = 108 )
(1) + 1 (2) + 2 (1) 0.235 g (2) 0.336 g
(3) + 3 (4) + 4 (3) 0.536 g (4) 0.636 g

6. In a solution of CuSO4 how much time will be 12. 2.5F of electricity are passed through a CuSO4
required to precipitate 2 g copper by 0.5 ampere solution. The number of gram-equivalent of Cu
current? deposited on cathode is
(1) 12157.48 sec (2) 102 sec (1) zero (2) 1.25
(3) 510 sec (4) 642 sec (3) 2.5 (4) 5.0
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13. The current in a given wire is 1.8 A. The number of 17. After electrolysis of a sodium chloride solution with
coulombs that flow in 1.36 minutes will be inert electrodes for a certain period of time, 600 mL
(1) 100 C of the solution was left. Which was found to be 1 N
(2) 147 C in NaOH. During the same period 31.75 g of copper
(3) 247 C was deposited in the copper voltameter in series with
(4) 347 C the electrolytic cell. Calculate the percentage yield
of NaOH obtained (in %).
14. During the electrolysis of an electrolyte, the number (1) 60 (2) 20
of ions produced is directly proportional to the (3) 40 (4) 80
(1) time consumed
18. Calculate the electricity that would be required to
(2) electrochemical equivalent of electrolysis
reduce 12.3 g of nitrobenzene to aniline, if the
(3) quantity of electricity passed
current efficiency for the process is 50 percent. If the
(4) mass of electrons
potential drop across the cell is 3.0 volt, how much
energy will be consumed?
15. Electrolysis of water with 1 Faraday electricity gives
(1) 252 kJ, 0.6F (2) 380.5 kJ, 1.2F
(1) 1 mole of oxygen (3) 347.4 kJ, 1.2F (4) 351.2 kJ, 0.6F
(2) 1 gram equivalent of oxygen
(3) 1 molecule of oxygen 19. What current strength in ampere will be required to
(4) 1 atom of oxygen liberate 10 g of chlorine from sodium chloride
solution in one hour?
16. A current of strength 2.5 amp was passed through (1) 7.55 ampere (2) 7.15 ampere
CuSO4 solution for 6 minutes 26 seconds. The (3) 7.50 ampere (4) 7.45 ampere
amount of copper deposited is (Atomic weight of
Cu = 63.5) 20. An electric current of 100 amperes is passed through
(1 faraday = 96500 coulomb) a molten liquid of sodium chloride for 5 hours.
(1) 0.3175 g Calculate the volume of chlorine gas liberated at the
(2) 3.175 g electrode at NTP.
(3) 0.635 g (1) 210.5 L (2) 200 L
(4) 6.35 g (3) 211 L (4) 208.91 L
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (4) 11. (2)
2. (2) 12. (3)
3. (4) 13. (2)
4. (2) 14. (3)
5. (3) 15. (2)
6. (1) 16. (1)
7. (4) 17. (1)
8. (3) 18. (3)
9. (2) 19. (1)
10. (1) 20. (4)

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