SET -I DELHI PUBLIC SCHOOL RUBY PARK, KOLKATA PRACTICE TEST (2022-23) CLASS XII Time: 3Hi SUBJECT- CHEMISTRY um Marks: 70 General Instructions: Read the following instructions carefully. 4) There are 35 questions in this question paper with internal choice. b) SECTION A consists of 18 multiple-choice questions carrying 1 mark each. ©) SECTION B consists of 7 very short answer questions carrying 2 marks each. 4d) SECTION C consists of 5 short answer questions carrying 3 marks each, ©) SECTION D consists of 2 case- based questions carrying 4 marks each. 1) SECTION E consists of 3 long answer questions carrying 5 marks each. 8) All questions are compulsory. h) Use of log tables and calculator is not allowed SECTION A[18x1=18] The following questions are multiple-choice questions with one correct answer. Each question carries | mark. There is no internal choice in this section. 1. Which colligative property is used to determine molecular weight of biomolecules such as protein ? (a) Osmotic pressure (b)Depression of freezing point (©) Elevation of boiling point (@) Relative lowering of vapour pressure 2. The rate law of a reaction is rate = k{A}*[B] . On doubling the concentration of both A and B the rate ‘x’ will become (a x° (b) 8x (©) 4x” (@) 9x 3. The strong oxidizing agents has (a) high value of reduction potential (b) high value of oxidation potential. (©) low value of reduction potential (@) high tendency to lose electron. 4. The plot between concentration vs time for a zero order reaction is represented by : ‘CL-XI/ PRACTICE TEST Chemistry/Set-I/Page 1 of 9@ - © Tae Concentration Concentration Time (b) @ In which of the following pairs, are both the ions coloured in aqueous solutions? a) Ni?", Cu" b) Ni, TH Senay d) Se Co The oxidation state of Fe in Fe(CO)s is : @-1 2 (+3 @o Which of the following is the most reactive towards nucleophilic substitution reaction ? c ca a a NO; No, ON NO; () (b) © @ NO, NO; CEXIV PRACTIC — 2-23/ Chemistry/Set-VPage 2 of 910. ul. 12, 13. 14, @) n-Butylbromide (©) tert- Butylbromide (©) Isobutylbromide (@) sec- Butylbromide (@) Ti (Z=22) ) V (Z=23) (©) Cr (Z=24) (@) Mn (Z=25) The compound that reacts fastest With Lucas reagent at room temperature is (@) Butan -1-o] (b) Butan- 2-01 (©) 2-Methylpropan-2-o1 (@) 2-Methyipropan-1-o1 (@) Pentan-2-one (©) Benzophenone (©) Acetone (@) Acetophenone @) o-nitrophenol () m-nitrophenol (©) 2,4,6-trinitrophenol @) p-nitrophenol The order of basicity of © p-Methyl aniline (11) m-Methylaniline (IN) Aniline (IV) o-Methylaniline (@) (> a) > am > avy) () (> a > av) > I) (© Vv)>()>an> (1) @ a) > @>av)> ny Nucleotides are composed of a : (2) pentose sugar and phosphoric acid (©) nitrogenous base and phosphoric acid (©) nitrogenous base and pentose sugar @ nitrogenous base , pentose sugar and Phosphoric acid ‘CLXI PRACTICE TEST Chemistry/Set-UPage 3 of 9‘Two statements each labelled as Assertion (A) and Reason (R) are given in question numbers 15 to 18, For each of these questions select the most appropriate answer from the options gi (a). Both A and R are true and R is the correct explanation of A (b). Both A and R are true but R is not the correct explanation of A. (0). A is true but R is false. (@). A is false but R is true. ven below: 15. Assertion (A):Conductivity of CHsCOOH decreases on diution. Reason (R):The number of ions per unit volume decreases on dilution. 16. Assertion(A): Aryl halides are extremely less reactive towards nucleophilic substitution reaction. Reason (R): Halogen atom shows +1 effect in Aryl halides. is slightly more than the tetrahedral angle. 17. Assertion (A): Bond angle in ether ‘0 bulky (-R) groups: Reason (R):In ethers, there is a repulsion between the tw« 18. Assertion (A): Glucose does not give 2,4-DNP test Reason (R): Glucose contains aldehyde group. ‘ SECTION B [7x2=14] ‘This section contains 7 questions with internal choice in two questions. questions are very short answer type and carry 2 marks each. The following 19. Give reason : (@ Aquatic species are more comfortable in cold water than wan water. shows a negative deviation from Rao (b) Mixture of chloroform and acetone sk yult’s law. decomposition. Calculate tvz, 20. A first order reaction takes 30 minutes for 75% [Given log? = 0.3] 21. = 400 = 5 ee aim ve BE 0.2 04 CAR mol Ly LXE pRACTICE TEST Chemistry/Set-/Page 4 of 9(a) Predict the nature of electrolytes A and B. (b) What happens on extrapolation of Aq, to the concentration approaching zero for electrolytes A and B ? 2 (a) Predict the geometry of [CuCli]”. (b) Calculate the spin only magnetic moment of [Fe(H20).)*. OR Give the IUPAC name of : (a) Ks[Fe(C204)s] (b) [Co(NHs)sCO;]CL. 23. Give reason : (a) Chloroacetic acid is stronger acid than acetic acid, (b)Ethanal is more reactive than propanone towards nucleophilic addition reaction, 24. Write chemical reactions for the following: (a) Carbylamine reaction (b) Hoffmann bromamide reaction . oR Arrange the following compounds as directed : (a) In the increasing order of solubility in water (CHs):NH , CHsNHo , CeHsNHo. (b) In the decreasing order of basic strength in aqueous solution : (CHs)3N , (CHs)2NH , CHsNH) . 25, (a) What is Peptide linkage? (b) Why must Vitamin C be supplied regularly in diet? SECTION C [3x5=15] This section contains 5 questions with internal choice in one question. The following questions are short answer type and carry 3 marks each. 26. (a) State a condition under which a bimolecular reaction is kinetically first order reaction . (b) Differentiate between average rate and instantenousrate . (©) What is the effect of adding a catalyst on (i) Activation energy(E,) and (ii) Gibbs energy (AG) of a reaction? OR (CL-XII/PRACTICE TEST ' Chemistry/Set-W/Page 5 of 9‘The following results were obtained for the reaction between NO and Ch. The reaction is = Chg) + 2NO(g) + 2NOCI(g) Expne : Concentration initial rate a {NOL mole! Mole!" {Cl mole} i 0.01 0.01 1.20 x 107 le, zi 0.02 0.01 24x 10" 3 0.02 0.02 9.6 x10" Determine (i) the overall order, (ii)the rate law, and (jii)the rate constant of the reaction 27. (a)Compare the following pairs with reasons as per the instructions given in the bracket : ial cl and (Sx2 reactivity) cl cl 3) Ab aa J (Syl reactivity) (b)How do you prepare benzyl alcohol from toluene? 28. (a) Identify the following : ()CH;CHO () CH;MgBr, THF | A _PCCinCH.Ch _, B Gi) HO" (ii) CHSOH NaOH, C (i) COp, (ii) Hs0" D (b)Giv: the mechanism of the acid catalyzed dehydration of ethanol. CLXIV PRACTICE TEST.’ Chemistry/Set-U/Page 6 of 929. (a) Give one chemical test to distinguish between : (i) Ethyl amine and aniline Gi) Aniline and N,N-dimethyl aniline. (b) Give reaction for the preparation of ethyl amine by Gabriel Phthalimide Synthesis. 30. (a) Name the products obtained when :Glucose is (i) treated with Red P and HI, Gii) Bry — water. (b) What is denaturation of protein? SECTION D [4x28] The following questions are case-based questions. Each question has an internal choice and carries 4 (1+1+2) marks, Read the passage carefully and answer the questions that follow. 31. Colligative property is a property of a solution that is dependent on the ratio between the total number of solute particles (in the solution) to the total number of solvent particles and independent on the chemical nature of the solution’s components. Thus, colligative properties can be linked to several quantities that express the concentration of a solution, such as molarity, normality, and molality. The four colligative properties that can be exhibited by a solution are Boiling point elevation, Freezing point depression, Relative lowering of vapour pressure, Osmotic pressure which has many applications in everyday life. Osmosis is a physicochemical process,in which the concentration difference between two solutions creates a difference in pressure across a separating semipermeable membrane. Solvent transport takes place from a dilute solution to a concentrated solution until equilibrium is reached. Van’t Hoff proposed the formula for the osmotic pressure as 1 = CRT. For electrolyte solutionsVan’t Hoff factor * i’ has to be taken into consideration, From the value of ‘i’ degree of dissociation can be determined. 1, Calculate the percentage degree of dissociation of an electrolyte XY2 (Normal molar mass = 164) in water if the observed molar mass by measuring elevation in boiling point is 65.6 2. Equimolal solutions of FeCls, K,[Fe(CN),], CaCl, and NaCl were taken , arrange them in the increasing order of osmotic pressure of liquids. 3. Determine the amount of CaCl; (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27°C. OR ‘A1.2% solution of NaC1 is isotonic with7.2% solution of glucose. Calculate the Van’t Hoff factor of NaCl. [Na=23 , CI=35.5 , Ca=40 , C=12 , O=16 , H=1] 32. In 1893 Werner produced a theory to explain the structures bonding and reactivity of several coordination compounds. In this theory it was proposed that transition, metal posses two types of valencies , primary valency which is ionisble and secondary valency which is non CLXIV/ PRACTICE TEST Chemistry/Set-/Page 7 of 933. ionisable, primary valency is satisfied by radicals which are located out of the coordination sphere whereas the secondary valency is satisfied by the ligands within the coordination sphere with the metals, One such compound was studied with molecular formulae CrCls.6NHs It exists in several isomeric forms A,B,C,D and E. When treated with excess of AgNOs the no. of moles of AgCl precipitated are 3,2,1,0 andl respectively. One mole of C when treated with a chelating ligand. like ethylene diamine (en) followed by subsequent treatment with AgNOs gives two moles of AgCI whereas E does not give such reactions. Such compounds exhibit different colours, more the number of strong field ligands more the crystal field splitting and lesser the wavelength of light absorbed for electronic transition. Answer the following questions pertaining to the above passage. 1. Give IUPAC nomenclature of the compound B. 2. State the hybridisation of Cr and calculate the magnetic moment in compound A. 3. Arrange the following A, B,C in the decreasing order of wavelength of light absorbed. 4.Jdentify the compound which exhibit stereoisomerism and draw it’s enantiomeric forms. SECTION E [5x3=15] ‘The following questions are long answer type and carry 5 marks each. Two questions have an internal choice. (a) Three iron sheets have been coated separately with three metals (A, B and C) whose standard electrode potentials are given below: Metal A B ic Iron E" -0.46V, -0.66V_ -0.20V 0.44V Identify in which case rusting is faster and why? (b)Predict the product of electrolysis of an aqueous solution of AgNOs using Pt electrode. (©) A solution of Ni(NO3), is electrolysed between platinum electrodes using a current of 5 Amp for 20 minutes. What mass of Ni is deposited at the cathode? [At wt of Ni=58.9] OR (a) State Faraday’s 2" law of electrolysis. (b) Write the relationship between specific conductance and molar conductance. CEXIL practice TEST Chemistry/Set-UPage 8 of 934, 35. (©) Calculate the emf of the following cell : Zn(s)| Zn?*(0.1 M) 11 Ag’(0.01M)I Ag(s) Given : E°( Zn**/Zn) = -0.76 V , E° (Ag’/Ag) = +.0.80 V (a) Give reason : (i)Value for Mn?*/Mn?" couple is much more positive than that of Fe™/Fe". (ii)La(OH); is more basic than Lu(OH); (b) Draw the structure of permanganate ion. (©) Give balanced chemical equation : (i)Acidified potassium permanganate is reacted with oxalic acid. (ii)Hydrogen sulphide is passed over acidified potassium dichromate solution. (a) Give one chemical test to distinguish between : (Ethanal and propanone (ii) Acetophenone and benzophenone (a) Carry out the following conversions : (Ethanol to But-2-enal (ii) Toluene to m-Nitro benzaldehyde (b) What happens when propanoic acid is treated with chlorine and Red P(Write chemical equation) OR (a) Give the IUPAC name of : (CHs):C = CHCOCHs (b) Give the IUPAC name of the product obtained on reductive ozonolysis of2,3- Dimethylbut-2-ene. ()Draw the various structures of compound A having molecular formula CsHio0 on the basis of the following characteristics : (i) If (A) is produced from Pentan-2-ol. (ii) If (A) reduces Tollen’s reagent and has a chiral carbon. (Gii)If (A) neither reduces Tollen’s reagent nor gives iodoform test but produces orange precipitate with 2,4-DNP reagent. 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