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fy;tpg; nghJj;juhju ( caHju) khjpupg; guPl;ir – 2025
General Certificate of Education (Adv. Level) model Examination -2025
,urhadtpay; - II
Chemistry - II SERIAL - 03 1 -HOUR

DIAS BSc(Hons)Spl in Chem – New Science World , Brown Road , Jaffna

Istructiones :
 This paper consist of 8 pages
 Answer all the questions
 Use of calculators is not allowed

01. Consider the statements I and II given below.

i) α,β and γ rays are emitted by radioactive materials.
ii) Electrons travel keeping the distance from the nucleus constant
The two scientists who discovered the above respectively are,
1) Henry Becquerel, Niels Bohr 2) Henry Becquerel, Rutherford
3) Rutherford, Niels Bohr 4) Henry Becquerel, Jeffrey Moseley
5) Rutherford;> J.J. Thomson

02. Which element has 3 unpaired electrons in its ground state?

1)Ni 2) Sc 3) Co 4) Cr 5) Fe

03. The maximum number of electrons having quantum numbers n=3 ms=+1/2in an atom is
1) 3 2) 18 3) 5 4) 9 5) 10

04. e; /m value of an electron is

1) 1.602 x10-18Cg-1 2) 1.76x 10-28Cg-1 3) 1.76x1011Cg-1 4) 9.1 x1011Cg-1 5)1.76x1011Ckg-1

05. The maximum valency and electronic configuration of Vanadium are,

1) 3,[Ar] 3d34s2 2) 5, [Ar]3d54s2 3) 3, [Ar] 3d104s1 4) 2, [Ar] 3d94s1 5) 5,[Ar] 3d34s2

06. The electronic configuration of the element which can not form a diatomic molecule is.
1) ns1 2) ns2 3) ns2np3 4) ns2np4 5) ns2np5

07. Which electronic configuration of the element have higher number of valencies
1) 2s22p3 2) 3s23p4 3) 3s23p2 4) 3s23p5 5) 3s23p5

08. The element X can forms two oxides such as XO2 and XO3. The atomic number of X is
1) 32 2) 16 3) 37 4) 17 5) 15

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09. The structure of thiosulphate ion (S2O32-) is given below.

The valencies of the atoms X,Y,Z and W respectively are,

1) 2> 6> 2> 2 2) 2> 6> 1> 2 3) 2> 4> 2> 2
4) 2> 6> 1> 6 5) 2> 2> 2> 2
10. The correct statement about proton is
1) The number of protons may change among atoms of the element.
2) Proton was discovered by Eugen Goldstein.
3) The number of protons in cations is higher than its atoms.
4) Proton is a nucleon.
5) The charge of proton is 1F.

11. Consider the electron transissions between different principal energy levels.
A) n= n=1 B) n=5 2 C) n=6 n=3 D) n=4 n=1
In ; which order the wavelength of the emitted radiation increases?
1) C<B<A<D 2) D<B < A<C 3) D<A<B<C 4) C<B<D<A 5) D<A<C<B

12. The elements X,Y are belong to same period > They form compounds XF3, YF4 respectively. X and Y are,
(1) S,Cl (2) O,N (3) B,N (4) N,O (5) Cl,S

13. Which is correct regarding quantum numbers ?

(1) Azimuthal quantum numbers ;(l) shows the orbital where electron is located (shows the orbital of
electron)
(2) Principal quantum number always changes during to the movement of electrons in an atom.
(3) For a particular azimuthal quantum (l) number ,the direction of the orbital changes with magnetic quantum
number(ml)
(4) The highest number of electrons in the principal energy level n is n2
(5) The energy of an atom is minimized by filling completely the principal energy levels in succession.

14. The correct order of filling of electrons in 6th period is

1) 6s , 6p, 6d, 6f 2) 6s, 6p, 5d, 4f 3) 6s, 5d, 4f, 6p 4) 6s, 4f, 5d, 6p 5) 6s, 6f, 6d, 6p

15. (A) The Aufbau principle

(B) The Pauli exclusion principle
(C) Hund’s rule

I. There can’t be more than two electrons in any single orbit. Those electrons must have opposite spins.
II. In the orbitals, most electrons with equal energy are arranged without pairs. ;.
III.The filling of electrons occurs according to the increasing order of energy in orbitals.
Which statements reveal the above principals/ rules correctly?
(1) B,A,C (2) B,C,A (3) C,B,A (4) C,A,B (5) A,C,B

16. Element M forms a stable cation M3+ Both of them have equal number of unpaired electrons .in its
groundstate. What is M?
(1) V (2) Cr (3) Fe (4) Mn (5) Sc

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17. Which is correct regarding Hydrogen emission spectrum.

1) The radiation formed by the electron transmission from n = 2 to n = 1,has highest wavelength
2) H  line is formed by the electron transission from n=3 to n=2
3) The first series formed by lines (Lyman’sseries) is observed in Infrared region
4) The separation between the successive lines of a series increases in the direction of increasing frequency
5) The emission of radiation occurs when electron transmissed from lower to higher energy level.

18. Element X forms an anion X3-.Which of the following statement is correct about element X?
(1) It may belongs to d-block
(2) There is a sudden increase in fourth ionization energy than third ionization energy in X
(3) There are 3 electrons in the outer most sub energy levels of X and X3- has 6 electrons in its outer most
energy levels.
(4) It can be a metal
(5) X3- may not attain noble gas state.

19. Which is incorrect about the acidity of the oxides.

(1) SO2 < SiO2 (2) BeO > Li2O (3) SO3>SO2 (4) MgO < Al2O3 (5) Na2O > K2O

20. The wave length of a proton having 3.313 x10-22kJ energy is

(1) 3x10-4nm (2) 6x10-9m (3) 3x102nm (4) 6 x102nm (5) 6x102m

 For each of the questions from 16 to 20 four responses (a), (b), (c), (d) is given. One or more out
of the is correct. Choose the correct response/responses.
(1) if only (a), (b) are correct
(2) if Only (b), (c) are correct
(3) if only (c), (d) are correct
(4) if only (a) , (d) are correct
(5) if any other number or combination of responses is correct
summary of above instructions.
1 2 3 4 5
Only (a), (b) are Only (b), (c) are Only (c), (d) are Only (a) , (d) Any other number or
correct correct correct are correct combination of
responses is correct

21. Which quantum number/s determine/s on the energy of electrons in an atom

a) n b) l c) ml d) ms

22. Which is/are correct regarding valency?

a) All 3d elements have more than one valency
b) Most of the elements belongs to 2nd period have more than one valency
c) Cl atom ;shows 1> 3> 5 and 7 valencies in compounds
d) Xenon (Xe) atom ;shows 2> 4> 6 and 8 valencies in compounds

23. Which of the following shows the energy difference between 3rd and 4th lines of Lyman’s series;;?
a) 1st and 2nd lines of Bamer’s series
b) 2nd and 3rd lines of Bamer’s series
c) ;1st and 2nd lines of Pashen series
d) 2nd and 3rd lines of Pashen series

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24. Which of the following element consists two unpaired electrons in its ground state?
a) C b) S c) Ti d) Ni
25. Which is /are correct regarding electron which has n=3 , ml=-1 quantum numbers?
a) It belongs to 3rd principal energy level.
b) This electron must belong to d- orbital
c) Spin quantum number of electron should be ms = +1/2
d) IT may belongs to either p- orbital or d- orbital

 Follow given instructions for question 21 to question 25.

response statement I statement II

1 true True and correctly explains statement I
2 true True and does not explains statement I
correctly
3 true false
4 false true
5 false; false

26. Nitrogen ;form two types of chlorides such as Nitrogen is a group 15 element
NCl3 and NCl5
27. The valence electron of K must have K should have a valance electron
ms=+1/2 quantum number which spins in clockwise direction
28. The space between two adjacent lines of Bamer The energy of successive energy levels
series in hydrogen emission spectrum decreases of Hydrogen increases, when they are
in the direction of increasing frequency considered far from nucleus
29. An orbital can’t have electrons more than two Any of two electrons of an atom can
have same quantum number value for
all four quantum numbers
30. When wave length of a moving neutron The wave length of the moving particle
becomes half, its kinetic energy will be 4 times is directly proporational to its velocity
than before.

- Practice makes a perfect man -

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03

Full name ……………………………….…………………….………………………………………..

School …………………………………………………..……………………………………………
Ad number ………………………………………………..…………………………………………….

Part-I……………………………..….

Part-II ………………………………..

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STRUCTURE QUESTIONS
1)
(a) If given statement is true mark; as ( √ ) and if it is wrong mark as ( X )

i. Oxygen can form the compound OF4 . ( )

ii. Salts of Cs give red-violet colour in flame test ( )
iii. The strong acid solution can be obtained when CO2 is dissolved in water ( )
iv. The energy of electro magnetic radiations increases when its frequency increases ( )
v. The highest valency of 3d elements increases uniformly from Sc to Zn ( )
vi. The maximum number of orbitals which are represented by quantum numbers n+d =5 is 9( )

(b) i) Complete . the table about fundamental particles of atoms

Mass (Kg) Molar charge Scientist related to the

(Cmol-1) discovery

Electron
Proton
Neutron

ii) Give an evidence for the properties of cathode rays

(i) The e/m ratio of cathode rays is constant
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ii) Cathode rays have wave nature.

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(c)

i) Complete the passage using most suitable words.

.
In atoms , electrons revolve in a three dimensional space called -------------------------.Sub energy
levels change with the ------------------------ quantum number. If it is ---------------------- , it called
as S sub energy level. If it is ---------------------- , it called P orbital. The shape of s orbital is -------
------------------- The shape of P orbital is -------------------------- . The size of the orbitals increases
when ----------------------- quantum number increases. The way which P orbitals oriented in the
three dimensional space changes with -------------------------- quantum number.

The principal quantum number n=4 has -------------------------- sub energy levels. The number of
orbitals are --------------------- . The maximum number of filling electrons are ---------------------

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ii) a) Write De Broglie’s equation . Identify the terms in it.

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b) Find the mass of a particle moving with10 nm wavelength and ; 1X108ms-1 velocity ?

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2)
(a) I) Write the electronic configuration for the following atoms/ ions?

i) Sc --------------------------------------------------------------------------------------------------------------

ii) N3- --------------------------------------------------------------------------------------------------------------

iii) Cr ---------------------------------------------------------------------------------------------------------------

iv) Fe3+ -------------------------------------------------------------------------------------------------------------

v) Br - --------------------------------------------------------------------------------------------------------------

II) Write the number of electrons present in outer energy level and sub energy level before outer most
energy level for the following species?

Outer energy level Sub energy level before outer outer most sub
energy level

Sc

T3-

Cr

Fe3+

Br-

a) I) Draw the visible region of Hydrogen spectrum and identify the lines using suitable symbols .
(It is enough to draw four lines of the region)

Frequency increases

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II) Write the colour of the lines mentioned above (Write symbols for mentioning the lines)
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III) Mention the electron transissions for the lines (Write symbols for mentioning the lines)
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IV) The first ionization energy of Hydrogen is1312KJmol-1 .Find the highest wave length of
the electro magnetic radiation which can ionize the hydrogen atom.
(h=6.626x10-34Js C=3x108ms-1)
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b)
I) The sets of quantum numbers for four electrons are given in the following order; (n, l, ml, ms).
(3> 2> 0> 1/2)> (3> 0> 0> -1/2) > (4> 0> 0>+1/2)> (4> 2>+1>+1/2)

Arrange them in the increasing order of energy

……………………<………………………<…………………………<…………………………………

II) Complete the chart about quantum numbers.

n l ml Sub energy level

4 0 ------------------------------- -----------------------------

------------------------ --------------------------- -------------------------- 3d

2 ---------------------------- -1, 0, +1 --------------------------------

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