Atkynes

-CEc
Greneral formula - Cnt2n-2
es alknes a.Nou tanmnna alKgnL
I. Tenwiual alkyw
CH-ChCEl- CH2
CH-H,-Cec-H
SAuehune 130
thape, b smd anale
-

, inean
rdsatian-
hepanahan ot aUKyneb
.
Faa alk halide
Na- Cel-Na
H-CEC-H N a H-t=C- Na
(satiun aehyide) R-x

R-CE C-R
o o dehalogqenahism t vie-dhalda
Nar
CH-C=c-H
keHy CHa - =e H
-

-Hale - HX
CH- H
X

3. Fram trihalides

aCHCl + bA CHECH +6Aget

canbides
4. From hydrelyais metal
CaC2+ 4,o CH = CH + CaloH),
Ma,3 t H,0 CA-CECH
Prapeulies
. Atdie narua; Teminal alknes anl aidie in naBe
H- CHC H
+H

5o,s chanacten)
Move electronegative

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 companus on & audie natwr

Ch CH= CH= CH

(25), s) (33-37 s) (5o s)

awion
Aeidic nolune d Abiuly
CH EC
CH CH Most eleehonzakivn)
Least ele ehvanizaBiv
Na
CH-CECNa 4H
aNHz H-ECNa t NH
CH-CEH Tellen's Yeazer CHa-C EC-Ar
White ppt)
Cu CH-C=C Cu
H40H
(Red ppt tmmua A
Al hes2 rRauhowo cam lbe ked todisiguish

Adlition neashion
Hdrra22nahianM
PtlH2 Ch-Cta-4t-H
H2/ Pa
H2 Pd >ChaCH= CH-CH
CA-CEt-H- BasO4
Ni-8 CH-CH=CH-CH
(is)
NaNH CHa-CHCH=CH-CH2
Thans)
Unes ane mene nearhve han alKenes todando tataktie
hdrogenotion.
Halogenation He=e- 4-l_
CI C
H-EC-4-
H-¢= (lage size ofT sBaps the furRe
I adsion)
2
 AAAian nSMmmetueal neagow
X
'Electophilie additi0n Jr0acion
CHg=CH CH-¢ CH
CH-CECH X
(oH)
elaHO- CH- HC4
OH

--CHCd
Nuelepkilic asdtion neaeion
16Ms
achions tke place m presente o{ heay metad
2
-CC Ha NP

thene is posibily
Koaetion întoiwMeliat eahouion. so 1
two AHfvjent paducrs, maion produeh ill be T6tA
OM dnL Slble carlbani gw
H20
d-HsogH-¢ =c -H TALomeu gm> CMa-
TauBbmeu'sm

Ha2 OH H

H-C=C-H vinyf alcohol)

HCN
2
H-
N

R-OH H-=-H,
OR H (vinmgf athw)
--C
A -e-Ha
CHCOOH
CHCOOH -i =e-a AaCooA H -e-H
A H 0--4
3. Oxidation (AXacut
using aye's ya2on
OH
H-CEC-HCold alkatine H- e - H H--ë
J honal)
KMnO4 OH 0
CoOH

Oxalit auid)
aA)
 MnDA
CH-C
C-H
CAl, G-H

a Ougat Conceunhrotod kMnDA

C-H O4 HCo0H + HCOOH Ma, CD + Ho
CAC-CHaMay
C Cta CoDH + CHCoo4
02analysis
R-CEc-R R R
H0R-- -R
DKekone

(0 2enide)
H,o -CoOH + R-CoOH
4. Polameusahon
CuC +NHaC
CHECH
uel +NH4C Hc =
C-C=CH H CH
A
HCH-tat- ¢ =Ct2
inglaaen
Red haEE
(Divinaehylenu)
3HLEA Totn tbe
3He Ee4

3 CH-CECH Red hat

CAMetylen
A CH CH NC4 eleochtetrame
CH CH+ AsCa CH= C4
C AsC
(Leuiste)
N a ganPeisonus

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