San REPORT DOCUMENTATION PAGE Form Approved OMB No. 0704-0188 STS Es Tana ST SET awa TN pt apt, Hausa Dene arg aco ain wir aa Swen, ea a7 Targang es ese td spo vena ccd Toran Soren worargtbe ramos ete ce oa. (ait Bean nest tours Copan of ee, Wash smarts Sevows, Ors roman Osean na Rear oa 1s rn Ons (ite ns hinge hf 0 Pomona rl wae Punting sy ahaa am oper shal oe et ay pray ry oso Wh fe ary ou coe' aunt’ BLEAGE DO NOT NETUNN YOUN FONT TE ABOVE ADDRESS. 1. REPORT DATE (DD-AW-YYYY) 2. REPORT TYPE ‘Technical Paper '3, DATES COVERED (From To] “TTITLE AND SUBTITLE ‘Sa, CONTRACT NUMBER Poutcil= 48-¢= 6010 3b, GRANT NUMBER ‘6. PROGRAM ELENENT NUMBER 6 RUTHORS) ‘6d. PROJECT NUWBER ‘Se, TASK NUMBER ‘BE WORK UNIT NUMBER 7- PERFORHING ORGANIZATION NAME(S) AND ADDRESS(ES) Thiel ‘5 PERFORNING ORGANIZATION REPORT AFRL/PRS 5 Pollux Drive '9, SPONSORING / MONITORING AGENCY NAME(S) AND ADDRESS(ES) Air Force Research Laboratory (FMC) Edwards AFB CA 93524-7048 70. SPONSORMMONITOR’S ACRONYMS) Ti. SPONSORMONITOR'S NUMBER(S) ¥2. DISTRIBUTION 7 AVAILABILITY STATEMENT Approved for public release; distribution unlimited, 75. SUPPLEMENTARY NOTES Ta ABSTRACT Te SUBJECT TERNS 16. SECURITY CLASSIFICATION OF: 7 LIMITATION NUMBER] 19a, NAME OF RESPONSIBLE OF ABSTRACT PAGES | PERSON Leilani Richardson B.ABSTRACT 6: THIS PAGE "9b, TELEPHONE NUMBER A (indo are cose) Unclassified Unclassified (661) 275-5015 ( ler enclose ohFEN 48 -C-0d10 Foe l| -44= MEMORANDUM FOR PRS (Contractor Publication) FROM: PROI (TD (STINFO) 9 September 1999 SUBJECT: Authorization for Release of Technical Information, Control Number: AFRL-PR-ED-TP-FY99-0176 ‘Velarde, S.P., et al., (Thiokol) "Synthetic Directions in New Energetic Materials for Advanced Solid Rocket Propellants" Seventeenth Working Group Mig, of HEDM. (Statement A)p(t +t7e AEEL ~ PR ED TP #71999 — ié Supt als Synthetic Directions in New Energetic Materials for Advanced Solid Rocket Propellants S. P. Velarde, L. F. Cannizzo, T. K. Highsmith, R. S. Hamilton, W. W. Edwards, R. M. Hajik, M. A. Dewey, B. A. Zentner, L. R. Huntsman Submitted in consideration for the Department of the Army Seventeenth Working Group Meeting on Synthesis of High Energy Density Materials Several programs are currently underway at Thiokol Propulsion which strive to ‘meet or exceed the goals of the Integrated High Performance Rocket Propulsion Technology (IHPRPT) Program. The three major program efforts are: the completed Advanced Oxidizers and Fuels Program, in which was synthesized and evaluated a series of new ingredients for solid rocket propellants; the current Hybrid Fuel Program, which will produce fuels that complement the Tactical Hybrid Rocket Engine Applied Technology (THREAT) Program design and proposed advanced oxidizer; and the current Phase III Ingredient Program, which strives to identify novel, high performance, solid propellant ingredients for boost and orbit transfer applications. All three programs have already undergone down-selection from myriad of possible compounds to a much more workable number of candidates for synthetic consideration. Based on several factors including: 1) predicted performance of propellant; 2) expected safety properties, thermal stability, and ingredient compatibility; and 3)ease/cost of synthesis; several furazan based candidates were synthesized for the Alternate Oxidizers and Fuels Program. Five candidates have been targeted for route development in the Hybrid Fuel Program, and at least seven candidates are under investigation in the Phase III Ingredient Program. In the Alternate Oxidizers and Fuels Program aminonitrofurazan (ANF), diaminoazofurazan (DAAF), diaminoazoxyfurazan (DAAOF), dinitroazoxyfurazan, and dinitrobisfurazanopyrazine (PIPER) have all been synthesized from the common precursor diaminofurazan (DAF). The candidates for the Hybrid Fuels are: 4-amino-3,5-dihyrazino-1,2,4-triazole dinitramide (ADHTDN); 1- amino-3,5-dinitro-1,2,4-triazole (ADNT); octahydro-2,5-bis(nitroimino)imidazo[4,s- dlimidazole (BNNID); 2,6-dinitraminospiro[3,3]heptane (SPIRO); and tetraazotetrafurazan oxide (TATFO). The Phase III Ingredient candidates include neutral compounds such as: 1,3,3,5,7,7-hexanitro-1,5-diazacyclooctane (HCO); 1,7-diazido- 2,4,6-trinitrazaheptane (DAHT); bis[1,1-(3,5-dinitro-1, triazolo)methyl] nitramine (NBDNT); 1,9-diazido-2,8-dinitraza-5-methylazanonane (DATNN). In addition, several energetic salts remain as possible Phase III Ingredients, including: hydroxyguanidinium and some bis(oxyammonium)nitramine species. 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