ALLEM

® WORKSHEET AEP-03
■PINI @t@IHHD
� CAREER INSTITUTE
for
� .u.u
JEE (MAIN+ADVANCED)
ENTHUSIAST COURSE
CHEMISTRY CLASS-XII

ALCOHOL, ETHER & PHENOL

SECTION - I : SINGLE CORRECT TYPE QUESTIONS

1. (P); Product (P) is :

(A)o (Bio

�OH
( A) (B)
2. OH
�

Total number of stereoisomers of product (B)will be:

(A)2 (8)3 (C)4 (0)5

3.
0 ---+

KMnO4 (cold di!.)

(2)
For the above conversion the correct order of reagents used is:
(A)1➔2➔3➔4 (B)1➔4➔3➔2 (C)1➔4➔2➔3 (0)2➔3➔4➔1

4. Which are not cleaved by HIO/

I : glycerol II. glycol
III: I, 3-propanediol IV. 1-methoxy-2-propanol
(A)I, II, III and IV (B)I, II (C)II, III (0)III and IV

CH2 OH

4HI04 ( H OH)
5. Pr oduct (ii) I - 4 5HI04 Product
CH2 - OH

Ratio of moles of formic acid obtained in reaction (i)and reaction (ii)is :

3 4 5
(A ) - (B)- (C)1 (0)-
4 5 4
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 SECTION - II: ONE OR MORE THAN ONE CORRECT TYPE QUESTIONS
6. Which of the following reaction will give ether as major product.

(A) � +Et-Cl-----> (B) � +Et - ONa----->

ONa Cl

(C) Ph - Cl + EtONa -------+ (D) PhONa + EtCl -------+

7. Which of the following can oxidise 2 ° alcohol to give ketone.

(A) PCC (B) PDC (C) Cu/300°C (D) LiAlH4

8. Which of the following test can differentiate 1 ° , 2 ° , 3° alcohol.

(A) Victor meyer test (B) Lucas test (C) Haloform test (D) Tollen's test

9. Which of the following represent Wiiliamson's synthesis ?

CH3
I
(B) CH3-C-Cl + CH30Na ---
1
CH3
CH3
I
(D) CH3-y-ONa + CH3I
CH3

10. Victor Meyer's test can be used to distinguish between 1 ° , 2 ° and 3° :

(A) Alkyl halides (B) Nitroalkanes (C) Alcohols (D) Amines

SECTION - Ill: MATRIX MATCH TYPE

11. Match the following:
Column I Column II

(A) O�CH2----+ Ho--C)=-<2H2 (P) N2 H4, OH-

(B) O�CH2----+ o-O-CH2 OH (Q) B2H/fHF and then Hp/OH

(C) O�CH2----+ (rcH2 (R) NaBH4

(D) O�CH2----+ HO-o-CH3 (S) HiPd

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12. Match the following:
Column I (Reaction) Column II (Reagent)

(A) \____.._ --+. \_ COOH

//
'\..OH //
H
OH
(B)� -�

OH 0

(C) (R) PCC

(S) Cu/300°C

*****

ANSWER KEY
1. (B) 2. (B) 3. (C) 4. (D) 5. (C)

6. (AD) 7. (ABC) 8. (AB) 9. (ACD) 10. (ABC)

11. (A) - (R), (B) - (Q), (C) - (P), (D) - (S) 12. (A) - (Q), (B) - (RS), (C) - (QRS), (D) - (S)

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