JEE

Lakshya JEE 2.0 2025

Chemistry
DPP: 1
Chemical Kinetics

Q1 For the reaction, N2 + 3H2 → 2 NH3 , rate is Q6 For the reaction: H2 ( g) + I2 ( g) → 2HI(g),
expressed as the rate of disappearance of H2 , is
(A) d[N2 ] d[H ] d[NH ]
= − 2dt2 = 3 dt 3 1.0 × 10−4 mol L−1 s−1 . The rate of
3dt
(B) − d[N2 ] = − 1 d[H2 ] = 1 d[NH3 ] appearance of HI will be
dt 3 dt 2 dt
(A) 1.0 × 10−4 mol L−1 s−1
(C) − d[N2 ] = − 3 d[H2 ] = 2 d[NH3 ]
dt dt dt (B) 0.50 × 10−4 mol L−1 s−1
(D) − d[N2 ] = − d[H2 ] = d[NH3 ] (C) 2.0 × 10−4 mol L−1 s−1
dt dt dt
(D) 4.0 × 10−4 mol L−1 s−1
Q2 The rate of reaction that does not involve gases,
is not dependent on Q7 In a reaction, the concentration of a reactant
(A) pressure (B) temperature changes from 0. 2 mol L−1 to
(C) concentration (D) catalyst −1
0. 15 mol L in 10 min . Avg. rate of reaction
(A) 0.05 (B) 0.0005
Q3 For the reaction, A + B → 2C + D , which one
(C) 0.5 (D) 0.005
is the incorrect statement?
(A) Rate of disappearance of A = Rate of Q8 For the reaction, 2NO → N2 + O2 , the
disappearance of B 1 d[NO]
expression − 2 dt represents
(B) Rate of disappearance of A = Rate of (A) The rate of formation of NO.
appearance of D (B) The average rate of the reaction.
(C) Rate of disappearance of B = 2× rate of (C) The instantaneous rate of reaction.
appearance of C
(D) All of these
(D) Rate of disappearance of B = 12 × rate of
appearance of C Q9 For the reaction

Q4 The term − dx in the rate expression refers to 1

dt N2 O5 ( g) ⟶ 2NO2 ( g) + O2 ( g)
the: 2
(A) instantaneous rate of reaction the value of rate of disappearance of N2 O5 is
(B) average rate of reaction −3 −1 −1
given as6.25 × 10 mol L s . The rate of
(C) increase in the concentration of reactants formation of NO2 and O2 is given respectively
(D) concentration of reactants as:
(A) 1.25 × 10−2 mol L−1 s−1 and
Q5 For the reaction, 3 A → 2 B, rate of reaction
+d[ B] 6.25 × 10−3 mol L−1 s−1
is equal to
dt (B) 6.25 × 10−3 mol L−1 s−1 and
(A) − d[A]
3
6.25 × 10−3 mol L−1 s−1
2 dt
(B) − 2 d[A] (C) 1.25 × 10−2 mol L−1 s−1 and
3 dt
(C) − 1 d[A] 3.125 × 10−3 mol L−1 s−1
3 dt
(D) 6.25 × 10−3 mol L−1 s−1 and
(D) +2 d[A]
dt 3.125 × 10−3 mol L−1 s−1

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Q10 In the following reaction, xA → yB

d[A] d[B]
log10 [− ] = log10 [ ] + 0.3010
dt dt

A and B respectively can be:

(A) n-butane and iso-butane
(B) C2 H2 and C6 H6
(C) C2 H4 and C4 H8
(D) N2 O4 and NO2

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Answer Key
Q1 (B) Q6 (C)

Q2 (A) Q7 (D)

Q3 (C) Q8 (C)

Q4 (A) Q9 (C)

Q5 (B) Q10 (C)

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