ISOMERISM

1. CH3CH2CH(CHO)CH2CH3 and CH3CH(CHO) 7. How many alkenes (only structural isomers) are
CH2CH 2CH3 are :- possible with the molecular formula C4H8
(1) Chain isomer (2) Positon isomer
(1) 4 (2) 3 (3) 5 (4) 6
(3) Metamerism (4) Functional isomer
2. Find out relation between the following 8. Which of the following is correct :-
compounds: O O
O COOH (1) ,
H
(1) O and Functional group isomers

O (2) ; Position isomers

O C–Cl
Cl
(2) and O
O
(3) ;
NH2 H2N H
(3) CH3CH2CH2CHCH3 and CH3CH2CHCH2CH3
COOH COOH Position and functional group isomers
(4) All of these
O O
9. Which of the following compounds can show
(4) O and geometrical isomerism :
O
(i) Pent-1-ene
3. How many amines are possible with the (ii) 1-chloropropene
molecular formula C4H11N (structural isomers (iii) 2-Methylbut-2-ene
only) :-
(iv) CH3–CH=CH–CH3
(1) 6 (2) 7 (3) 8 (4) 9
4. How many benzenoid isomers are possible for H H
molecular formula C7H8O :- Cl Cl
(1) 3 (2) 4 (3) 5 (4) 6 (v) C C (vi)
5. The relation between given compound is :- H H COOH COOH

H CH3
N CH3 N
(vii)

(1) Chain isomerism 10. Assign the configuration E/Z to the following
(2) Position isomerism compounds.
(3) Functional isomerism
(4) Metamerism H2N CH3 H2N OCH3
6. The structure below are :- C C
(i) (ii)
H C C
CH 3
H H H H Cl NO2 HS-CH2 F

H CH3 H CH3
H CH3 F Cl
C
(1) Not isomers (iii) (iv)
(2) Conformational isomers C
H D
(3) Cis-trans isomers
(4) Structural isomers

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11. Which of the following compounds have non zero 13. Which is true for the following isomeric forms
dipole moment. I & II respectively :

(1) CCl4 CH3 CH3 CH3

H
C=C C=C
H CH3 H H
CH3 H
(2) C=C (I) (II)
H C2 H 5
Dipole Boiling Melting Stability
Cl H moment point point
(3) C=C
H Cl (1) I > II I > II II > I I > II
(2) II > I II > I II > I II > I
(3) I > II I > II I > II I > II
(4) Cl Cl
(4) II > I II > I I > II I > II
14. In which compound cis-trans nomenclature
12. Which one of the following is a Z isomer ? cannot be used :
CH3 Br (1) CH3–CH=CH–COOH
(1) C=C
(2) C6H5–CH=CH–C6H5
H Cl
(3) C6H5–CH=CHD
CH3 Cl
(2) C=C CH3
H Br (4) C6H5–CH=C
Cl

Cl 15. Compare dipole moment of the following

CH3
(3) C=C
Br H Cl Cl H Cl
(A) C=C ; C=C
H H Cl H
CH3 H
(4) C=C
H CH3 F CH3 F H
(B) C=C ; C=C
H H H CH3
(C) CH3–CH2–CCH ; CH3–CC–CH3

ANSWER KEY
Q ue. 1 3 4 5 6 7 8 11 12 13 14
Ans . 1 3 3 3 4 2 2 2 1 4 4

2. (i) Functional Group Isomerism 9. (ii), (iv), (v), (vi), (vii)

(ii) Functional Group Isomerism 10. (i) Z (ii) Z (iii) Z (iv) 2Z, 4E
(iii)Chain Isomerism 15. (A) i > ii (B) ii > i (C) i > ii
(iv)Functional Isomerism

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