Topicwise Questions

ASSIFICATION AND NOMENCLATURE 7. The IUPAC name of CH,COCH, is:

(a) Acetone
corectIUPAC name of the organic compound (b) 2-propanone
CH-CH-ÇH-CH-CH,OH
The is: (c) di-methyl ketone
1. (d) Propanal
8. IUPAC name of the given compond is:
CH, CH,
ÇH, H
a )4-chloro-2, 3 dimethyl pentan-1-ol
(6)
2-chloro-3-4-dimethyl pentan-5-ol
i 2.3-dimethyl-4-chlorpentan-|-ol
CH,C=C-COOH
(a) 2-methyl but-2-enoic acid
(b) 3-methyl but-2-enoic acid
2-chloro-3, 4-dimethyln-pentyl alcohol
nane of:
(c) 3-methyl but-3-enoic acid
ThelUPAC
2 CH,=CH-CH-CH, -CH, (d) 2-methyl but-3-enoic acid

H,-CH, -CH,
9. IUPACname of (CH,), CCl is:
(a) 3-chloro butane (b) 2-chloro-2-methyl propane
(a) 3-propyl pent-l-ene (b) 3-ethyl pent-]-ene (c) t-butyl chloride
(c) 4-ethylhex-1-ene (d) 3-ethyl hex-1-ene (d) n-butyl chloride
10. The correct structure of
(a) Br- CH =C(CH,), 4-bromo-3-methyl but-1-ene is:
alkane.
3. For the given
(b) CH, =CH-CH (CH) CH,Br
The IUPAC name is: (c) CH, = C(CH,) CH, CH, Br
(a) 1, 1-dimethyl-5-ethyl octane (d) CH, -C(CH,) = CHCH,-Br
(6) 6-ethyl-2-methyl nonane 11. Which is the incorrect name of
CH,NC?
(c) 4-ethyl-8- methyl nonane (a) Aceto isonitrile(b) Methyl isocyanide
(d) 2-methyl-6-propyl octane (c) Methyl carbylamine
(d) Methyl isonitrile
4. The IUPAC name of: 12. The IUPAC name of the molecule:

ÇH,
CH,-CH,-C-C-CH, is: CH,--ç=--OH is:
CH, CH, CH, CH,
(a) 3,4, 4-trimethyl heptane (a)
(b) 3,4, 4-trimethyloctane
4-oxo-2,3-dimethylpent-2-en-1 oic acid
(b) 2-carboxy-3-methylpent-2-en-3-one
(c) 2-butyl-2-methyl-3-ethyl butane (c) 4-carboxy-3-methylpent-3 en-2-one
(d) 2-ethyl
-3,3-dimethyl heptane
5. The IUPAC name of the
(d) 2,3-dimethyl-4 -0x0 pent-2-en-1-oic acid
13. The IUPACname of the compound:
CH, =C= CH-CH, following compound is: CH,-C-CH,0H is:
(a) but -2,3 diene
(b) buta-1, 2-diene
(c) but-1-ene-2-yne CH,
6. () Conjugated butadiene
IUPAC name is: (a) 2-ethylprop-2-en-1-ol
(6) 2-hydroxymethyl butan-1-ol
CH-CH,f-p=CH,
-ÇH-Ç CH, CH,
is: (c) 2-methylenebutan-1-ol
(d) 2-ethyl-3-hydroxy prop-l-ene
14. The IUPAC name of:
CH,
la) 2-methyl-3-ethyl pent-1-ene
is:
0) 3-ethyl-4-methyl-4-pent-4-ene OH
e) 3-ethyl-2-methyl-1-pentene (a) but-3-enoic acid (b) but-l-enoic acid
) 3-methyl-2-ethyl-]-pentene (c) pent-4-enoic acid (d) prop-2-enoic acid

OrGAN C CHEMISTRY 103

15. The IUPAC name of tertiary butyl iodide is: 26. I.U.P.A.C name of ester is:
(a) 4-iodobutane (a) Alkoxy alkane (b) Alkylalkanoate
(b) 2-iodo butane (c) Alkanoyl halide (d) Alkanoic anhydide
(c) 1-iodo-3-methyl propane 27. 1.U.P.A.C name of methyl cyanide is:
(d) 2-i0do-2- methy propane (a) Cyanomethane (b) Ethanenitrile
16. Corect IUPAC name is: (c) Methanenitrile (d) Methyl-n-butyl armine,
HC CH=C-CH, CH, 28. The suffixes for alcohols, aldehydes and
CH,CHCH,
to IUPAC system are respectively
(a) - ane, - al- keto
ketones, acta
(b) ol, - al, - keto
(a) 3-cthylhex-2-ene (0) 3-ethyipent-2-enc (c) - al, ol, one (d) - ol, al, - one
(c) 3-cthylpent-3-cne (d) 3-propylpent-2-ene 29. The correct IUPACname of
17, The IUPAC name is:
CH-Ç*Ç-CH, is
CH, C,H,
(a) 1,2- Diethylbutene
(a) 3,4-dimethyl pentanoyl chloride (b) 2- Ethyl- 3 - methyl pentene
(b) 1-chloro-1-0xo-2, 3-dimethyl pentane (c) 3, 4 - Dimethylhex - 3- ene
(c) 2-cthyl-3-methyl butanoyl chloride (d) 2, 3 - Dimethylpent - 2- ene
(d) 2. 3-dimethyl pentanoyl chloride 30. IUPAC name of CH,0HCH,OH is:
18. The IUPAC name for the hydrocarbon represented by (a) 1,2-dihydroxy ethane (b)
Ethylene glycol
swastik sign is: (c) Ethane-1, 2-diol (d) Ethane-1, 2-dial
(a) neo-nonane
(b) tetraethylcarbon 31. IUPAC name of CH
(c) 2-ethyl pentane =C-CH=CH, is:
(a) 3,3-diethyl pentane (a) But 3- ene - 1- yne (b)
But-l- ene -3- yne
19. Organic compounds can be formed by: (c) But - 1 yne 3- ene (d) But
-3 - yne - 1-ene
(a) Plants only 32. In IUPAC system of naming of
(b) Animals only of the following functional grouporganic compounds. WE
has more preference
(c) Plants and animals others (in a poly functional compound)?
(d) Plants, animals and can be (a) -OH (b) - CHO
synthesized in laboratory
20. The first carbon compound (c) -Co (a) -CONH,
prepared from its elements is:
(a) Urea (b) Acetic acid OH
(c) Methane (d) Benzene 33. The IUPAC name of
21. According to Huckel's rule a compound is said to be CH-CH-CH,-CH-CHOs
(a) 4-Hydroxy-2-methylpentanal
if it contains: aromatic
(a) 4n bonds
(6) 2-Hydroxy-4-methylpentanal
(b) 4n atoms (c) 4-Hydroxy-2-methylpentanol
(c) (4n+ 2) atoms (d) (4n + 2) T electrons (d) 2-Hydroxy-4-methylpentanol
22. Which of the following is an
aromatic compound? 34. The functional group present in acylchlorides i$:
(a) Phenol (b) Naphthalene
(c) Pyridine (d) All of these (a) -CI (b) - CI
23. Which is a saturated
(a) Alkanes
compound?
(b) Alkenes
(c) Alkynes (c) C-0CI (a) -CH,-0CI
(d) Cyclo alkenes
24. Functional group present in amides is: 35. The structural formula of methyl amino methane IS:
(a) -COOH
(b) - NH, (a) (CH,), CH NH, (b) (CH,), N
(c) -CONH, (d) - CO0 (c) (CH,), NH (d) CH,NH, respectivel;:
36. Formula of phenyl carbinol and chloral are
25. (a) C, H, CH,CH, OH and CHCI, CHO
group is present in:
(b) CçH, CH,OH and CCl, CHO
(a) Ketones only (b) Aldehyds only (c) CHCH, OH and CH,CI.CHO
(c) Carboxylic acid only (d) All the above NEET
(a) C,H,CHO and CHCI,CHO
MATERIAL
104 FULL CoURSE STUDY
 ofo & t bonds present in C,H, respectively are: 47. Which of the folowing pair is heterocyclic aromatic?
The no.
(b) 2, 1 (a) Pyrrole, Oxirane (b) Pyridine, Phenol
(a) 1,2
(d) 3, 2 (c) Thiophene, Furan (d) Napthalene, Benzene
(c) 5.2
number of t electrons present in phenanthrene 48. Select structure of iso-propylidene radical:
The (6) 14
(a) CH,-CH,-CH (b) CH
(a) 10
(c) 12
(d) 16 çH-ÇH,
39. The
percentage of s-character of the hybrid i orbitals in ethane,
respectively:
(c) CH-ÇK () CH-CH-CH;
ethene and ethyne are CH, CH,
(a) 50, 75,
100 (b) 10, 20, 40
25, 33. S0 () 25, 50, 75 49. Propargyl alcohol has sum of no of o, n bonds & lp:
(c)
carbon atoms present in neopentane
40, The number &type of CHEC-CH,-ÖH
are:
(a) 10 (b) 12
) Four 1' carbons, one 4° carbon (c) 11 (d) 13
(b) Two 1' carbons, two 20 carbons
c) One 1' carbon, one 4° carbon
À One l carbon, one 4° carbon 50. C,H,C-C,H, is:
4 Eind the molecule in which all carbons are sp' hybridised:
(a) CH, - CH, - CH= CH, (a) Triphenyl radical (b) Ter-phenyl radical
(b) CH, CH, CH, -CH, (c) Trityl (d) None of these
(c) CH, =CH-CH = CH, 51. Match the given general formula with their respective
(d) CH, C=C-CH, functional
A. CH,0groups: P- Hydroxy Carbonyl
42. In which molecule all carbon atoms lie in the plane: B. CHan -2 Q-Alkenyne
C. CH2n 4 R-Cyclicether
(a (6)
D. C,H,0, S-Alkadiene
(a) A-Q, B-R, C-S, D-P (b) A-R, B-Q, C-S, D-P
(c) (d) None of these (c) A-P, B-S, C-Q, D-R (d) A-R, B-S, C-Q, D-P
52. Structure of Anthranilic & sulfanilic acid are represented by:
43. In the following molecule how many carbon atoms arrange COOH SO,H
linearly:
CH, CH-cæC-CH-ÇHCH, (a)
NH,

CH,
(a) 2 (b) 3 NH,
(c) 4 (a) 5 COOH SO,H
44. In which of the following molecule the bond strength of CH, CH,
(b)
carbon-carbon bond is maximum?
(a) CH, - CH, (b) HC = CH
(c) CH, = CH, $0,H COOH
(a) CH, -CH, -CH,
3. Select highest electronegative carbon in given molecule: (c) NH, CH,
1 2 3 4

CH,-Ç=CH-H,-C=C-CH,-CH, So,H COOH

CH,
(a) 1 (b) 2
(d CH, CH,
(c) 3 (d) 4
The no of sp- sp- sigma bonds in compound 53. The structure of isobutyl isonitrile is:

CH=CH, (a) CH-ÇH-CH,-CN (6) CH,-ÇH-CH,-NC

CH, CH,
(c) CH,-ÇH-C=N (d) CH,-ÇH-NEC
(a) 3 (6) 5 H, CH,
(c) 4 d) 6
JRGANICCHEMISTRY . 105
54. The common name of the given compound is: 64. In which of following compound
CH,-CH-OH
correct:

(a) (6)
I.0.P.AC
(a) lsopropyl alcohol (b) Dimethyl carbinol
(c) Rubbing alcohol (d) All
55. Which of following are correctly matched:
A. Crotonic acid: CH, -CH -COOH (c) (d)
B. Acrolcin: CH,- CH -CHO
C. Secondary butylalcohol: CH,-ÇH-CH,OH 4

H, 66, Select structure with correct

numbering:
3
D. Cinamaldehyde: C,H,-CH = CH -CHO (a) H,=H-H-=CH
(a) A & B (6) B &C 1 2 4

(c) B& D (d) B,C&D (6) H,H=H-H-H

6 5 4 3
$6. Fomula of wood spirit is:
(a) C,H,OH
(c) CH,CH,CH,OH
(b) CH,0H
() (CH,),CHOH
(c)

(d)
CH.=H-H=CH-H-CH=H
CH,=ÔH -H=CH-CH-H
66. The correct I.U.P.A.C
57. Structural formula is iso-hexane is:-. numbering in compound is.
(a) CH,-ÇH, CH,CH,(6) CH,ÇH-ÇH-CH,
H,-CH, CH, CH,
ÇH,
(c) CH,--CH-CH-ÇH, (d) CH,-Ç
-Ç-CH-CH, (a) (b)
H, CH, 4

58. Select the compound containing more than one methyl

as a substituent: group
(a) Isobutyric acid (6) Isopentyl bromide (c) (d)
(c) Isooctane
(a) Isoamyl alcohol 6
59. Hydrocarbon made by adding neopentyl and 67. In which of following cycle chain is main chain:
would be: isopropyl group
(a) Isopentane (b) Isohexane (b)
(c) Isooctane (a) All the above
60. Common name is 3rd member of ester
homologous series: (c
(a) Propyl formate (b) Methyl propionate (a)
(c) Ethyl acetate (d) All of the above 68. I.U.P.A.C name of Triptane
61. Derived name is 4th member of alkyne
homologous series:
(a) Ethyl methyl acetylene (6) n-propyl acetylene
(a) 2-Methylhexane (b) 2-Methylpentane
(c) 2, 2, 3-Trimethylbutane (d) 2. 2, 4-Trimethylre
(c) Iso-propyl acetylene (d) Allthe above 69. Choose the correct I.U.P.A.C.
62. Derived name of CH, =CH-CH, OH is: name:
(a) 3-Isopropyl-4 methyl pentane
(a) Allyl alcohol (b) Allyl carbinol (b) 4-Methyl-3-isopropyl pentane
(c) Vinyl carbinol (a) Ethyl carbinol (c) 2, 4 Dimethyl-3-ethyl pentane
63. Derived name of the first member of one
branched ketone (a) 3-Ethyl-2, 4-dimethyl pentane
is:
(a) Ethyl methyl acetone 70. I.U.P.A.C name of structure H
(b) Iso propyl methyl acetone (a) 2, 2-dimethyl butane
(c) Unsymmetrical dimethyl acetone (b) Isohexane
(d) Symmetrical dimethyl acetone (c) 2, 3-dimethyl butane
(a) 1, 1, 2, 2-tetramethylethane NEE

106 MATERIAL
FULL CoURSE STUDY