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2021 Gr 10 Chem Term II fin answer key
2021 Gr 10 Chem Term II fin answer key
Answer Key
1. 10.0 dm3 of a gas are kept at 27 °C inside a cylinder fitted with a piston. Without changing
the temperature, the piston is slowly moved until the pressure is halved. Find the new
volume of the gas.
Same temperature, same quantity of gas (stated or implied)
P 1 V 1 = P2 V 2
and P2= ½ P1
(Or P α 1/V)
V2 = 2 × V1 = 20.0dm3
V = 0.48 dm3
1520
P= = 2 atm
760
2400
V= = 2.4 dm3
1000
2×2.4
n=
600×0.08
n = 0.10 mol
m= n × M= 0.1×58 = 5.8g
4. 8.0 g of helium gas, He, were placed in a 10–dm3 cylinder at 27 °C. Calculate the pressure
exerted by the gas in mm Hg. [He = 4.0; R= 0.08 atm.dm3.K-1.mol-1]
m
n= = 2.0mol
M
nRT
P=
V
2 ´ 0.08 ´ 300
P=
10
P = 4.8atm
→ P = 4.8 × 760 =3648 mmHg
5. How many oxygen molecules are there in 10 dm3 at 127°C, under a pressure of 912
mmHg?
[R= 0.08 atm.dm3.K-1.mol-1 ; N of Avogadro= 6.1023]
PV = nRT
æ 912 ö
10 ´ ç ÷
n= è 760 ø
0.08 ´ (127 + 273)
n of oxygen = 0.375 mol
6. When 1.0 kg of He gas is filled into an empty balloon at 27ºC the pressure
in the balloon becomes 760 mm Hg.
Find the volume of the inflated balloon.(No calculator allowed)
1000
( )×(0.082)×(300)
nRT 4
V= = = 6150 dm3
P 760
( )
760
7. Calculate the molar volume of an ideal gas at 27°C temperature and 1.0 atm.
[use R = 0.082 dm3.atm.K-1mol-1 ]
nRT 1´ 0.082 ´ 300
V= = = 24.6 dm3
P 1
8. A gas Z travels √2 times as fast as oxygen gas under the same conditions of temperature
and pressure. Given that Z has the formula CHx , find x.
[C=12; H=1; O=16]
Same temperature, average molecular kinetic energy = constant (KE = constant)
v of Z = 2 × v of O2
½ Mv2= ½ Mv2
or v1/v2=√ M2/ M1
1 Mz
=
2 32
M of Z = 16 g/mol
M = 12 + x = 16
x=4
2K+ (aq) + CO3 2-(aq) + Ca2+ (aq) + 2Cl-(aq) ® CaCO3(s) + 2K+ (aq) + 2Cl- (aq)
b) 0.50 liter of 0.400 MCaCl2 is mixed with 1.00 liter of 0.200 MK2CO3. CaCO3 has negligible
solubility.
Calculate the concentrations of all ions present when precipitation stops.
n of CaCl2 = C×V=0.400×0.50= 0.200 mole
n of K2CO3 = C×V=0.200×1.00= 0.200 mole
= 2.5 mol
PV = nRT
12.
V
t (ºC)
13. Gas X has the molecular formula C3Hx.A mass of 2.0g of X occupies a volume of
1.12dm3 at 1 atm and 0 °C. Find the value of x.
[H = 1; C = 12.]
PV = nRT
1.12×1
n=
0.08×273
n ≈ 0.05 mol
m
M= = 40 g/mol
n
M = 3 × 12 + x = 40
x =4
14.. A 10dm3 vessel was filled with some carbon dioxide gas, CO2 , and with 2.5moles of
nitrogen dioxide gas, NO2 at 27°C. The total pressure in the vessel was 9.0atm.
Calculate the number of moles of CO2 that were present in the vessel.
R = 0.080 atm.dm3mol –1.K –1
PV = nRT for NO2
→ PNO2 = 6.0atm
3 ´10
n CO2 =
0.08 ´ 300
.
n CO2 = 1.25 mol
Measure 8.1g of Na2CrO4 and put in a 250 ml volumetric flask. Stir till completely dissolved
then add water up to the etched mark.
17. BQ 7
17.–a- book page 38
-b- If water was allowed to enter from the top, it would soon heat up due to contact with
the vapor and thus would not be an efficient cooling medium. Also, due to the action of
gravity, the condenser jacket might be emptied from the water.
b) If water were allowed to enter from the top, it would soon heat up due to contact with
the vapor and thus would not be an efficient cooling medium. Also, due to the action of
gravity, the condenser jacket might be emptied from the water.
20. The higher temp increases the kinetic energy of the air molecules. Thus they will move faster
and hit against the walls of the tire with more frequency. Also, the collisions will be of a greater
impact.
21..–a- same
!!" "#$" #$
-b-! = !" = !%& = √2
#$" !"
+.&
23.a- X)*% =- = 0.24
%
b-𝑝𝑝."&' = 𝑋."&' x𝑃/'/ = - x 20=12 atm
c- 5 dm3
0 1
24. 0( = 1(
" "
0()" &-2 4 %%%
V2 = 1(
= &5&
= 285.1 ml
25.
7 %&
n6* "+ = 8 = +#2 = 0.2
,
n O2= 3/2 nFe2O3 = 3/2 x 0.2 = 0.3
9:1 2.% 4 2.2< 4 $22
V= == ((%$ = 6.4dm3
;
-'$
6+ = 6+ +
27.6&= (=" )2 r2 =3r1 6&
=9 F2 = 5
F1
(
Ba 2+ (aq) + 2Cl- (aq) + 2 Na+ (aq) + SO42- (aq) → 2Cl- (aq) + 2 Na+ (aq) + BaSO4 (s)
Net ionic:
b. [Na+] = 2x0.2x1/0.4 = 1M
29)E
30)B
31)C
32)A
33D
34.
a- change the liq. to gas ……. Increase the temp
b- It has more PE
$ & 4 +22
c- +<
= 233.33 KJ
d- The molecules that leave the surface take with them a lot of KE
e- The air is already saturated with water vapor and any further evaporation will be balanced by
an equal amount of condensation.
".2"
8
2.236= !&2 M>./".2" = 100+ 2n +2=100