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1. Which of the following statements is not true regarding the laws of thermodynamics?
(A) It deals with energy changes of macroscopic systems.
(B) It deals with energy changes of macroscopic systems.
(C) It does not depends on the rate at which these energy transformations are carried out.
(D) It depends on initial and final states of a system undergoing the change.
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2. Which of the following is closed system?
(A) Jet engine (B) Tea placed in a steel kettle
(C) Pressure cooker (D) Rocket engine during propulsion
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3. The state of a thermodynamic system is described by its measurable or macroscopic (bulk)
properties. These are
(A) Pressure and volume
(B) Pressure, volume, temperature and amount
(C) Volume, temperature and amount
(D) Pressure and temperature
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4. Enthalpy change of a system depends upon its
(A) Initial state (B) Final state
(C) Both on initial and final state (D) None of these
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5. Which of the following factors affect the internal energy of the system?
(A) Heat passes into or out of the system. (B) Work is done on or by the system.
(C) Matter enters or leaves the system. (D) All of the above.
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6. Adiabatic expansions of an ideal gas is accompanied by
(A) decrease in
(B) increase in temperature
(C) decrease in
(D) no change in any one of the above properties
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7. Among the following, the state function (s) is (are)
(i) Internal energy
(ii) Irreversible expansion work
(iii) Reversible expansion work
(iv) Molar enthalpy
 (A) (ii) and (iii) (B) (i), (ii) and (iii) (C) (i) and (iv) (D) (i) only
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8. According to the first law of thermodynamics which of the following quantities represents change
in a state function?
(A) (B) (C) (D)
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9. According to the first law of thermodynamics, . In special cases the statement can be
expressed in different ways. Which of the following is not a correct expression ?
(A) At constant temperature
(B) When no work is done
(C) In gaseous system
(D) When work is done by the system
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10. A
(A) (B) (C) (D)
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11. When 1 mol of a gas is heated at constant volume, temperature is raised from 298 to 308 K. If
heat supplied to the gas is 500 J, then which statement is correct?
(A) (B)
(C) (D)
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12. Which of the following statements/relationships is not correct in thermodynamic changes?
(A) (isothermal reversible expansion of a gas)

(B) (isothermal reversible expansion of an ideal gas)

(C) (isothermal reversible expansion of an ideal gas)

(D) For a system of constant volume, heat involved directly changes to internal energy.
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13. An ideal gas expands in volume from to at 300 K against a constant pressure
of . The work done is
(A) (B) (C) (D)
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14. The difference between and is usually significant for systems consisting of
(A) only solids (B) only liquids
(C) both solids and liquids (D) only gases
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15. Assume each reaction is carried out in an open container. For which reaction will ?
(A) (B)
(C) (D)
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16. For
(A) (B) (C) (D)
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17. A
(A) (B) (C) (D)
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18. A
(A) (B) (C) (D)
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19. A
(A) (B) (C) (D)
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20. A
(A) (B) (C) (D)
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21. A
(A) (B) (C) (D)
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22. A
(A) (B) (C) (D)
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23. A
(A) (B) (C) (D)
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24. A
(A) (B) (C) (D)
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25. A
(A) (B) (C) (D)
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26. A
(A) (B) (C) (D)
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27. A
(A) (B) (C) (D)
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28. A
(A) (B) (C) (D)
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29. A
(A) (B) (C) (D)
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30. A
(A) (B) (C) (D)
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31. A
(A) (B) (C) (D)
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