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Ye_IJHE_2023
Ye_IJHE_2023
ScienceDirect
Jianjun Ye a, Junxu Cui a, Zhengli Hua b, Junlong Xie a,*, Wenzhu Peng c,
Wei Wang a
a
School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China
b
Institute of Process Equipment, Zhejiang University, Hangzhou, 310027, China
c
Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Foshan,
528200, China
highlights
A large pressure gradient of hydrogen flow will be generated at the valve spool.
The valve with arc cone spool has a larger flow rate and a smaller pressure drop.
The arc cone spool can reduce the high-speed zone and the eddy current in the valve.
Article history: The needle valve is a critical control unit for high-pressure hydrogen systems such as
Received 10 January 2022 hydrogen refueling stations, which is the infrastructure of hydrogen energy. As an
Received in revised form important part of the needle valve, the valve spool affects the flow characteristics of
5 March 2022 hydrogen in the valve and then affects the working performance and safety of the high-
Accepted 8 April 2022 pressure hydrogen valve. In this paper, based on the real hydrogen gas model and the
Available online 11 June 2022 finite volume method, a CFD model of the high-pressure hydrogen needle valve is con-
structed to find out the influence of the valve spool shape on the performance and flow
Keywords: characteristics of the high-pressure hydrogen needle valve. The results show that high-
High-pressure hydrogen pressure hydrogen will produce a sudden change in pressure around the valve spool and
Spool shape there will be a local high-speed area, and the turbulent intensity will also increase. The arc
Needle valve cone spool can increase the flow by 2%e8% at different openings of the valve, and reduce
Throttling characteristic the maximum speed at the spool by 15% at small openings. In addition, the sudden change
Pressure distribution of pressure and the eddy current have also been improved. Flat-bottomed cone spool re-
duces turbulence intensity and energy consumption. Therefore, it can be concluded that
changing the shape of the valve spool to have a larger flow area at a small opening can
make the high-pressure hydrogen valve have a better flow field distribution. Flattening the
cone angle of the spool can improve the turbulent flow in the valve. The research in this
paper can provide research accumulation and theoretical support for the optimization
design of the needle valve of the high-pressure hydrogen system.
© 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
* Corresponding author.
E-mail address: jlxie@hust.edu.cn (J. Xie).
https://doi.org/10.1016/j.ijhydene.2022.04.073
0360-3199/© 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 8 ( 2 0 2 3 ) 1 1 3 7 0 e1 1 3 8 1 11371
flow turbulence. This work can provide a reference for spool threaded to limit the lateral displacement and rotation of the
erosion quantification and prediction. Adeyemi et al. [25] valve stem. When working, apply torque and turn the handle
developed a mathematical model using a purely analytical to make the valve stem drive the valve spool upward. The gap
approach to quantify the effect of turbulent flow on pressure at the spool gradually increases, and high-pressure gas cir-
transients in porous media. And the exact analytical solution culates. Through the up and down movement of the valve
of the dimensionless equation is obtained by the method of spool, the flow adjustment function of the valve is realized.
Boltzmann transformation. The obtained results demonstrate The maximum stroke distance of the spool is 4.5 mm. Use
the efficiency and accuracy of the Boltzmann transform valve opening (%) to indicate the position of the spool. Fig. 1(b)
method in solving such complex problems. shows the relationship between the valve opening and the
According to the literature, it can be observed that there are stroke distance. The specific calculation formula is as follows:
not many researches on high-pressure hydrogen system
ð4:5 yÞ
valves, and most of them focus on the types of check valves, valve opening ¼ 100% (1)
4:5
safety valves, and pressure reducing valves. In addition, the
researches on the valve spool structure mainly used water or A three-dimensional model was established for the flow
air as the medium, which cannot reflect the flow character- channel in the valve, as shown in Fig. 1(c). The diameter of the
istics of the hydrogen flow inside the valve. It can also be pipeline connected with the inlet and outlet of the needle
found that many weaknesses have been exposed in the study valve is 2.5 mm, and extend the inlet and outlet pipes to
with water and air as the medium, such as the high-pressure 60 mm to eliminate the influence of unstable hydrogen flow.
and high-speed fluid at the throttling element will wash the In order to compare the influence of spool shapes on the
valve core, and the vortex around the valve core will affect the flow characteristics of the needle valve in the high-pressure
stability of the valve, etc. Due to the simple nature of water hydrogen system, three types of spool shape models have
and air, the effects of these weaknesses on the valve are not been constructed based on the current common spool forms,
obvious. However, when the medium is hydrogen, due to its as shown in Fig. 2: (a) is a straight-sided cone spool. The shape
special physical properties under high-pressure conditions is simple, and it is commonly used for high-pressure needle
and the reverse Joule-Thomson effect during throttling, the valves [26]. It is often used in high-pressure fuel injectors to
flow field in the valve is more severe and complex. Coupled control the spray process [27]. (b) is a valve spool with an arc
with the corrosiveness of hydrogen, it is prone to hydrogen edge. This shape changes the cone angle of the spool, so that
embrittlement leakage and other phenomena. Generally, the the valve has a large flow area at a small opening, and the
hydrogen will have a greater impact on the working charac- changes in different openings are more gradual [28]. (c) is a
teristics and safety and stability of the valve. Therefore, flat-bottomed cone valve spool, which is used in different
studying the real flow state of high-pressure hydrogen in the types of valves such as gate valves and one-way valves, which
valve and quantifying the complex flow field changes is a key can effectively slow down the erosion of gas [29,30].
step in the research of high-pressure hydrogen needle valves.
A CFD model of the needle valve in the high-pressure Governing equation
hydrogen system is constructed based on the real hydrogen
state equation, which can simulate the real flow state of the In this paper, the finite volume method is used to simulate the
high-pressure hydrogen flow in the valve in the actual appli- hydrogen flow in the needle valve of the high-pressure
cation process. Based on this model, the working performance hydrogen system. The continuity equation, momentum
and the internal hydrogen flow characteristics of the high- equation, and energy equation must be solved to obtain the
pressure hydrogen needle valve are studied in detail. Firstly, high-pressure hydrogen flow process inside the valve. The
the throttling characteristics of the high-pressure hydrogen equations are as follows:
needle valve with different spool shapes are analyzed. Sec-
vr v
ondly, the variation law of pressure, velocity and eddy current þ ðrui Þ ¼ 0 (2)
vt vxi
distribution of valve spool under different opening degrees are
studied. Finally, the influence of different spool structures on Here, r is the density of hydrogen, ui is the velocity tensor,
the turbulence intensity is analyzed. This research can pro- and xi refers to the coordinate direction. The subscript i ¼ 1, 2,
vide a reference for the structural optimization and applica- 3 refers to the x, y, and z directions, respectively.
tion of the high-pressure hydrogen needle valve. vr v vp v
ðrui Þ þ rui uj ¼ þ tij ru0i u0j þ rFi (3)
vt vxj vxi vxj
Physical and mathematical model of high- Here, p is the static pressure, Fi is the volume force in the i
pressure needle valve direction, tij is the stress tensor, and ru0i u0j is the Reynold
stress.
3D model of high-pressure needle valve
vui vuj 2 vui
tij ¼ m þ dij (4)
vxj vxi 3 vxj
The object studied in this paper is the high-pressure manual
needle valve commonly used in hydrogen storage systems, 0 1
and the specific structure is shown in Fig. 1(a). It is composed v v v @ vT X
ðrEÞ þ ½ui ðrE þ pÞ ¼ keff hj jj þ uj tij A þ Sh (5)
of the gasket, handle, valve body, valve stem, valve spool, and vt vxi vxi vxi j
so on. The valve stem, the locking cap, and the valve body are
i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 8 ( 2 0 2 3 ) 1 1 3 7 0 e1 1 3 8 1 11373
Fig. 1 e High-pressure hydrogen needle valve. (a) The components of the valve. (b) The relationship between valve opening
and stroke distance. (c) Flow-channel model of the valve.
Here, jj is the diffusion flux of the component, keff is the predict the characteristics of high-pressure hydrogen flow.
effective thermal conductivity. The first three teams on the The real hydrogen gas model can be expressed as follows:
right-hand side of the equation describe the energy conver-
Mp
sion which is brought by heat conduction, component diffu- r¼ (7)
ZRT
sion and viscous dissipation correspondingly. Sh refers to
chemical reaction heat and other defined volume heat source Here, r is the density of hydrogen, R is the molar gas con-
terms. stant, 8.3145, T is the absolute temperature, p is the pressure,
The energy E per unit mass fluid is: MPa, M is the molar mass, 2.016 g/mol, and the compressibility
factor Z can be described as a function as follows:
p ui 2
E¼h þ (6) 6 X
X 4 j1
r 2 100
Z¼ vij pi1 (8)
i¼1 j¼1
T
Real hydrogen gas model
Here, vij is the coefficients [31].
The real flow behavior of hydrogen in the high-pressure nee- Johnson et al. [32] used the NIST real hydrogen gas model to
dle valve is complex and changeable. This study uses a real simulate the temperature change during the hydrogen storage
gas model to describe the compressibility of high-pressure filling process, and the numerical results have passed the
hydrogen. Zheng [31] proposed a standardized hydrogen experimental verification, which is also suitable for the study
compression coefficient equation, which can accurately of the flow characteristics of the needle valve we studied.
11374 i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 8 ( 2 0 2 3 ) 1 1 3 7 0 e1 1 3 8 1
Aiming at the complex flow of high-pressure hydrogen in the To avoid the influence of the number of grids on the simula-
needle valve, the Fluent software is used to calculate. The tion results, this paper sets 8 grid densities of 0.2 million, 0.45
density-based solver is used, and the standard k-ε turbulence million, 0.8 million, 1 million, 1.3 million, 1.6 million, 2 million,
model is selected. The study by Yu et al. [33] shows that for and 3 million for grid independence verification. Monitoring
tapered spools, the flow resistance coefficient calculated by the change of the valve outlet flow rate with the number of
the standard kee turbulence model is closer to the actual re- grids, which is shown in Table 1. It can be seen that when the
sults than other turbulence models. The fluid medium inside number of grids is 1.6 million, the outlet flow has stabilized.
the high-pressure needle valve is hydrogen with initial pres- The number of grids is finally determined to be 2 million to
sure 10 MPa. Pressure inlet and outlet are chosen as the ensure the quality of the grid and the optimal configuration of
boundary conditions respectively. This study focuses on the computing resources.
Analysis of results after 60% opening, the flow rate drops slightly. This is because
the flow area at the valve spool is already greater than the flow
Throttling characteristic area of the pipeline at this opening, and the main factor that
determines the flow rate changes from the flow area to the
The high-pressure needle valve mainly plays the role of flow hydrogen flow velocity. The flow velocity at a large opening is
adjustment, so the flow characteristics are very important to slightly lower than that at 60% opening, so the flow rate is
it. This article compares the changes in the outlet flow of the slightly reduced.
valve under different spool shapes and different openings. As From the perspective of structural influence, the mass flow
shown in Fig. 5, it can be seen that the flow of the valve in- rate of the valve with arc cone spool is larger than the other
creases with a logarithmic function as the opening increases. two shapes at each opening. Below 60% opening, the mass
The mass flow rate increases rapidly with the upward move- flow rate of the valve with arc cone spool is about 8% larger
ment of the valve spool under the small opening. This is than that of the other two structures, and the maximum flow
because the flow area of the valve suddenly increases from rate is about 2% larger than that of the others. This is because
closed to open, and the valve spool is tapered. At a small the arc cone spool maximizes the flow area at each opening.
opening degree, the flow area increases as the valve spool For the flat-bottomed and straight cone spool, the tapered
moves upward, which is also very fast, so the rapid increase in angle is the same, so the flow area is basically the same at a
the circulation area leads to a sharp rise in flow. After that, the small opening. When the opening is small, the flow area at the
flow rate slowly increases and finally stabilizes. When the spool is the most critical factor affecting the flow rate, so the
valve opening degree reaches about 40%, the valve flow rate flow rate of the flat-bottom and the straight-sided cone is
has basically reached a stable state and reached the basically the same. At a larger opening, the flat bottom has a
maximum flow rate. This is because the flow area of the valve larger flow velocity relative to the straight-sided cone spool, so
changes slowly at a larger opening degree. When the opening the flow rate is slightly larger than that of the straight cone
is more than 40%, the valve spool has passed the outlet posi- shape.
tion, and the flow area has been larger than the cross-
sectional area of the pipe, and basically no longer changes. Pressure analysis of high-pressure hydrogen flow
So the flow rate also tends to be stable. It can also be seen that
In order to compare the flow characteristics of the valve with
different openings and different spool shapes, the pressure
and velocity contours of the middle section of the valve are
Table 1 e Verification of grid independence. analyzed. Fig. 6 presents a pressure distribution of the middle
section of the needle valve in the high-pressure hydrogen
Number of grids (million) Mass flow rate (kg/s)
system with different valve spool shapes. It can be observed
0.2 0.013548
that when the high-pressure gas flows out from the inlet
0.45 0.013989
0.8 0.013888
through the valve spool, the pressure gradually decreases
1 0.013853 from the inlet to the outlet. There are low-pressure areas on
1.3 0.013836 both sides of the valve spool and the inlet and outlet pipes of
1.6 0.01383 the valve. It is caused by sudden changes in the circulation
2 0.013839 area at the pipe connection. And the pressure gradient at the
3 0.013838
valve spool is more obvious at a small opening. The valve
11376 i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 8 ( 2 0 2 3 ) 1 1 3 7 0 e1 1 3 8 1
spool is now near the inlet position, which causes a sudden quantify the pressure drop at this place, a straight line parallel
change in the flow area, so a larger pressure gradient is to the surface of the valve spool at the gap between the valve
generated. With the valve opening increasing, the flow area body and the valve spool was taken as shown in Fig. 7. The
gradually becomes larger and tends to be stable, so the pres- pressure change on the line with the position in the x direction
sure unevenness at the valve spool also gradually decreases, is monitored, and the pressure drop changes under different
but the pressure gradient at the inlet and outlet pipelines opening degrees and different valve spool shapes.
exists at each opening. Fig. 7 shows the pressure change on the monitoring line
From the perspective of the spool shape, at a small open- with the distance in the X-direction when the high-pressure
ing, the pressure gradient at the arc cone spool is lower. This is hydrogen system needle valve with a straight cone valve
because the shape of the arc cone changes the angle of the spool at different openings. The results show that the pres-
valve spool. Moreover, the small opening has a larger flow sure on the line changes at different openings is basically the
area than the other two valve spools, and the transition under same. In the range of 0e1.4 mm, the monitoring line is mainly
different opening degrees is more stable. Lin et al. also found a located in the inlet section of the lower part of the spool. Due
similar rule in the study of the cone angle of the globe valve. to the throttling effect of the spool, part of the hydrogen flow is
As the number of cone angles increases, the throttling area collected here, so the pressure is relatively large and remains
increases, so the pressure drop at the valve core decreases. basically stable. Different opening degrees have different
However, increasing the spool angle does not have a signifi- throttling effects. The hydrogen flow is easy to pass through
cant effect on increasing the flow rate at large openings. And with a large opening degree, and the collection is less, so the
for the high-pressure hydrogen needle valve, increasing the pressure is smaller. On the contrary, the pressure is higher
cone angle of the valve core will make the flow field change when the opening degree is small. After that, in the range of
more violently at the moment of opening and at a small 1.4e1.6 mm, the pressure on the monitoring line has a huge
opening, thus affecting the stability of the valve. As the decrease, and the decrease speed is approximately linear. This
opening degree increases, the difference in internal pressure is because the section is in the gap between the valve spool
distribution of the three valve spool shapes is no longer and the valve body, and the flow area here suddenly de-
obvious. creases, and the flow rate increase rapidly, so the pressure
As mentioned above, the pressure drop of the needle valve decreases rapidly. As the valve gradually opens, the flow area
of the entire high-pressure hydrogen system mainly exists at gradually increases, and the sudden change in pressure is
the position of the spool at a small opening. In order to gradually reduced. Therefore, the overall pressure change at a
Fig. 6 e Pressure distribution of different valve spool shapes at different opening degrees.
i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 8 ( 2 0 2 3 ) 1 1 3 7 0 e1 1 3 8 1 11377
Fig. 8 e The pressure drop on the monitoring line of the three different spool shapes of the high-pressure needle valve.
Fig. 9 e Velocity distribution of different valve spool shapes at different opening degrees.
i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 8 ( 2 0 2 3 ) 1 1 3 7 0 e1 1 3 8 1 11379
opening, the speed distribution of the three shapes no longer sudden changes in speed and pressure, and the turbulent flow
has a significant difference. In addition, the arc cone and flat- here is also the most severe. The hydrogen flow can flow more
bottomed valve spool shape will make the flow line in the smoothly through the orifice and the turbulence is reduced.
valve more uniform and the vortex will be smaller. In order to When the opening is greater than 60%, the flow area is large
more accurately analyze the influence of the three valve spool enough, and the throttling effect is no longer obvious, so the
shapes on the velocity of high-pressure hydrogen, a moni- turbulence degree at the valve spool decreases. However, the
toring line is set up along the route of the hydrogen flow, as high-velocity area where the outlet line connects to the valve
shown in Fig. 10. The curve shows the velocity on the moni- body still exists, so the most turbulent places are also shifted
toring line of the three different spool shapes of the high- here. And because the flow area at the valve spool is already
pressure needle valve. It can be seen that there are two larger than the area at the outlet pipeline, the degree of tur-
peaks in the curve, which correspond to the high-speed area bulence here is more severe than when the opening degree is
in the velocity distribution in Fig. 9. Besides, the maximum small, so the turbulent kinetic energy in the valve above 60%
speed of the straight cone and flat-bottomed cone spool can opening is on the rise. From the influence of the valve spool
reach 1150 m/s, and the arc cone spool is around 970 m/s. structure, the maximum difference of the turbulent kinetic
Therefore, the valve with arc cone spool reduces the energy of the high-pressure hydrogen needle valve with a
maximum hydrogen velocity in the valve at a small opening, straight cone and a flat-bottomed cone spool is smaller. In
and reduces the vortex at each opening degree, which is more order to better understand the influence of different valve
conducive to the long-term stable operation of the valve spool. spool structures on the turbulence, the turbulent flow distri-
bution in the valve of the three spool structures is analyzed
Turbulence analysis of high-pressure hydrogen flow below.
Fig. 12 shows the turbulence intensity on the internal
A better understanding of the turbulent flow inside the high- monitoring line of the high-pressure hydrogen needle valve
pressure hydrogen needle valve can provide more references with three spool structures at 5% opening (the monitoring line
for the structural optimization of the needle valve. As setting is consistent with the speed monitoring line, Fig. 10). It
mentioned above, it can be seen from Fig. 9 that there is al- can be seen that the turbulent flow changes in the needle
ways a high velocity and a high degree of turbulence near the valves with three spool structures are similar. The inlet
spool and at the outlet line connections. The turbulent kinetic pipeline section from x ¼ 4 mm to x ¼ 1mm is very small, the
energy K is a physical quantity that characterizes the severity turbulent flow is not severe, and it basically flows into the
of turbulence. The larger its value is, the larger the length and valve in the form of laminar flow. After that, it increases
time scale of turbulent pulsation will be. Likewise, a greater rapidly around x ¼ 1.6 mm, resulting in the first wave peak.
degree of turbulence means a greater degree of energy con- At this time, the hydrogen flows through the valve spool, and
sumption. Fig. 11 shows the maximum difference of turbulent due to the throttling effect, the hydrogen forms a severe tur-
kinetic energy in the valve under different opening degrees of bulent flow here, resulting in a rapid increase in the turbu-
high-pressure hydrogen needle valves with different valve lence intensity. As the hydrogen moves away from the orifice,
spool structures. It can be seen that the turbulence variation the turbulence intensity also decreases slowly, which is
laws of the three structures under different opening degrees consistent with the curve from x ¼ 2mm to x ¼ 3mm in the
are roughly similar, and they all decrease first and then in- figure. The second peak appears at x ¼ 3mm. This is because
crease with the increase of the opening degree. Below 60% the hydrogen flows through the connection between the valve
opening, the throttling effect of the spool orifice leads to body and the outlet pipeline, and the flow area suddenly
Fig. 10 e The velocity on the monitoring line of the high- Fig. 11 e Turbulence parameter maximum difference with
pressure needle valve with three different spool shapes. different spool shapes.
11380 i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 8 ( 2 0 2 3 ) 1 1 3 7 0 e1 1 3 8 1
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