DATE: 17-04-2016

JEE-Advanced Test-2 [CC]

PAP ER - 1 PAPER - 2
T E ST C O D E 10530 T EST C O D E 10531
PHYSICS MATHEMATICS CHEMISTRY PHYSICS MATHEMATICS CHEMISTRY
PART-A Ans. PART-A Ans. PART-A Ans. PART-A Ans. PART-A Ans. PART-A Ans.
1 A 1 B 1 D 1 ABD 1 ABC 1 AB
2 A 2 B 2 B 2 ABC 2 AD 2 ACD
3 C 3 B 3 A
3 AC 3 AD 3 AB
4 D 4 A 4 A
4 ABCD 4 ABC 4 AB
5 B 5 C 5 B
5 ABC 5 BC 5 AC
6 B 6 A 6 C
6 AD 6 ABC 6 ABCD
7 D 7 D 7 C
7 C 7 AB 7 ABCD
8 D 8 A 8 A
8 D 8 ABD 8 BC
9 A 9 B 9 C
9 B 9 B 9 D
10 A 10 B 10 B
10 D 10 C 10 A
11 B 11 A 11 A
11 C 11 C 11 D
12 B 12 C 12 D
12 B 12 D 12 C
13 B 13 D 13 B

14 A 14 C 14 A 13 A 13 B 13 C

15 B 15 A 15 C 14 D 14 B 14 C

16 D 16 C 16 C 15 D 15 A 15 C

17 B 17 A 17 D 16 A 16 B 16 C

18 C 18 A 18 C 17 A 17 A 17 A

19 D 19 D 19 A 18 B 18 D 18 B
20 B 20 B 20 D 19 C 19 B 19 C
21 C 21 C 21 B 20 B 20 C 20 B
22 D 22 A 22 C
 HINTS & SOLUTIONS
PAPER-1 k
T2
T2  T3 dT
P H YS I C S Q.3 Cavg =
Q T nCdT = T1
= 1
3

PART-A nT n T2  T1  (T2  T1 )

Wnet
Q.1  1940 1700 50
Sum of  Q only Cavg = 3 × = 1.86
(281) 4
1
Wnet = × 0.3 × 2 × 105 = 3 × 104 J f=10cm
2
5 5cm
QAB = nCPdT = (2.4 – 1.5) × 105 10cm
2 Q.4 5cm 5cm
5 20cm
= × 9 × 104
2
1 dy dp
WCA = – × (4 × 105) × 0.3 = – 0.6 ×
2 d
y

105 = – 6 × 104 J
Q.5  3
r
3 3 2
QCA = n RdT = (1.5 – 0.8) × 105
2 2
3 2 .1  3
  0.7 105  105 = 1.05 × 105 y = r tan  = tan 
2 2 2
= 10.5 × 104 q
dq = dy
QCA = WCA + UCA = (10.5 – 6) × 104 
= 4.5 × 104
 3
3 10 4 3 1 dp =  sec   dq
 = = 2
22.5 10  4.5 10
4 4
27 9
py = 0
Q.2 Using phasor diagram 30
isource & VR are always in phase. p = px =  dp cos 
X L  XC 4 30
tan  = 
R 3 Q.6 When we displaced the block x verticallydown
 = 53° ward then liquid level comes up y such that
 XL > XC
Vsource is ahead in phase with i and VR. 2 = (42 – 2) y
x
(V y
& 3
)

R
ing

VSource i(
e as

VR=3 Work done by external force = work done

e cr

i nc
re a
ed

s in
)
u rc

g
against extra buoyance
so
(V

VL
3
8
= w    2 ( x  y) dx  w g
0
VC For upper limit
x + y = x + x/3 = /2.
at t

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 1 2 1 10 pi
Q.7 Li = CV 2 Q.13 Attenuation = L log p
2 2 f
2
1  20  1 10 p 
20 10 3   =  2 10 6 V 2 1.25  log  i 
2  5  2 16  0 .3 

0.20 10 3 16 p 

V 20.00  10 log  i 
2 10 6  0 .3 
pi = 10 × 0.3 = 30 W
2

1610 2 = 40 volt
10 pi
Q.8 Think event like elastic collision. Q.14 Attenuation = L log p
f
Hence velocity interchange.
10 pi
Q.9 Work done by conservation force 5= log p
2 f

 Fx Fy  pi
   on closed path will be zero. 10 = 10 log p
 y x  f

pi
Q.10 Retardation of a car When brakes car applied 1 = log p
to front wheel only f

N2 pi
N1 10 = p
ma(Pseudo) f
mg h v pf = 0.1 pi

(rear wheel) x f (front wheel) Q.15 Total loss 1.5 × 10 + 0.8 × 9

l = 15 + 7.2 = 22.2
At equilibrium in car frame
Q.20 For curve 1 and curve 2 frequency same
f = ma
because stopping potentials are same but
...(i)
intensity of 2 is greater then 1 because
N1 + N2 = mg
saturation current is high in 2.
...(ii)
Net torque of about c.m. = 0 N
15a
N1 × (l – x) = f × h + N2 x
...(iii)
b
gxµ 
15kg
a=
(l – µh )
Q.21
37° fs
Q.11 a = µg
150
u2 N + 9a = 150 ... (1)
Q.12 s=
2a 12a – fs = 15b ... (2)
2
fs × R = × 15 × R2 ×  ... (3)
5
b = R ... (4)
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 Q.2  cos 5 = cos (3 + 2)
N'
= cos 3 cos 2 – sin 3 sin 2
fs = (4 cos3 – 3 cos ) (2 cos2 – 1)
5kg – (3 sin  – 4 sin3) · 2 sin  cos 
a = 8 cos5 – 10 cos3 + 3 cos 
50

N
 
– 2 3  4(1  cos 2 ) (1 – cos2) cos 
= 8 cos5 – 10 cos3 + 3 cos 
(N + 50) sin 37° – fs cos 37° = 5a ... (5) – 2 cos  (– 4 cos4 + 5 cos2 – 1)
solving eq. (i), (ii), (iii), (iv) & (v) = 5 cos  – 20 cos3 + 16 cos5
we get a = 9.1 ms–2, b = 5.2 ms–2,  a = 5, b = – 20, c = 16 and d = 0
 = .6 rad/sec2, fs = 31.2  log(d – b)(5ac) = log20 (400) = 2 Ans.
Q.22 Think about real and virtual objects.
Q.3 Clearly 3x + 4y – 11 =0 must be directrix and
(2, 5) must be focus of P.B.
M AT H E M AT I C S  Length of LR
PART-A = 2 × (distance between focus of directrix)
Q.1 Given integral | 3.2  4.5  11 |
=2× = 2·3 = 6
5
( x  1) ( x  1) Q.4 Let
2
dx
= 2 x g(x) = x3 + bx2 + cx in [1, 2]
 x  1 g(1) = g(2)  1 + b + c = 8 + 4b + 2c
 3  (x 6  x 4  x 2 )
 x   3b + c = –7 ……(i)
g'(x) = 3x2 + 2bx + c
 4  16 8
 1   g'   =  b+c=0
1  2  dx 3 3 3
 x 
=  2 8b 16
( x  1) 2 1  +c=– ……(ii)
3
· x x2 1 2 3 3
x x
(i) – (ii),
b 5
=  b = –5
 1  3 3
1  2  dx
 x  and c=8
=  2
 1  1  5x  x 3  (a 2  6a  30), 0x3
 x    x   1 f (x) = 
 x  x  x  8, x 3
 f has local minimum at x = 3
 L.H.L at x = 3  f (3)
 1
= sec 1 x   + C –15 – 27 + (a2 + 6a + 30)  –5
 x  (a2 + 6a + 30)  37
 a2 + 6a – 7  0
1  (a + 7)(a – 1)  0
 f(x) = x + , x>0
x  a  –7 or a  1
 Minimum value of f(x) is 2. Ans.  minimum natural value of a = 1.

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Q.5 4a2 – 12a + b2 + 2b + c2 – 12c + 46 = 0 6
 (2a – 3)2 + (b + 1)2 + (c – 6)2 = 0 =
(n  1)(n  2)
3
 a= , b = –1, c = 6 6
2  Prob. that A wins = 1 –
(n  1)(n  2)
3  3 
mid points of sides =  , 0  ,  , 6  Lim P(n) = 1
2  2  n 
and (–1, 6)
A(x1, y1) 
3
(1  3 tan 2 x ) (1  tan 2 x ) (3  4 sin 2 x )
Q.8 I=  (3 tan x  tan 3 x ) (1  tan 2 x )
dx

6
B(x2, y2) C(x3, y3)

Let vertices be A(x1, y1), B(x2, y2) 3
(3 sin x  4 sin 3 x )
and C(x3, y3) then
x2 + x3 = 3 y2 + y3 = 0
=  tan 3x · sin x · cos 2x
dx

x3 + x1 = 3 y3 + y1 = 12 6
x1 + x2 = –2 y1 + y2 = 12

x1 + x2 + x3 = 2 y1 + y2 + y3 = 12 3
sin 3x
=  tan 3x · sin x · cos 2x
dx
 x1 = – 1, x2 = –1, x3 = 4
y1 = 12, y2 = 0, y3 = 0 6

 A (–1, 12), B(–1, 0) and C( 4, 0)


 side AB = C = 12; BC = a = 5 3
and AC = b = 13 cos 3x
Incentre is required point
=  sin x cos 2x dx
 Incentre 6

 5(1)  13( 1)  12  4 5(12)  13(0)  12(0) 

=  ,  
 5  13  12 5  13  12  3
cos 2x cos x  sin 2x sin x
 30 60  =  sin x cos 2x
dx
= , 
 30 30  6
 Sum = 1 + 2 = 3 Ans.

3
Q.6 Clearly, locus of | z – 4 | + | z + 4 | = 16 is
ellipse with foci (4, 0) and (–4, 0) and =  cot x  tan 2x  dx
1 6
eccentricity = .
2

A conic with foci (4, 0) and (–4, 0) and  1 3
=  ln sin x  ln cos 2 x 
eccentricity 2 will be a hyperbola and its  2 
6
equation will be | z – 4 | – | z + 4 | = ± 4.Ans.
 3 1 1 1 1 1
Q.7 Probability that B wins =  ln  ln  ln  ln 
 2 2 2 2 2 2
2 1 2 n 1 n 2 1
= ·  · ·  · ·
n  2 n 1 n  2 n 1 n n  2 n 1 n = ln 3 . Ans.

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 (3n  2) 9
Q.9  Tn = m=
n (n  1)2 (n  2)
2
2 3
 b1, b2, b3 are in G.P..
(n 2  3n  2)  n 2  ln b1, ln b2, ln b3 are in A.P.
= 2
n (n  1) 2 (n  2)  f(1) + ln b1, f(2) + ln b2,
f(3) + ln b3 are in A.P.
1 1
= 2
 2  f(sin x) = 3  y = 3x2
n (n  1) (n  1) (n  2)
 dy  y 0
  = 6x0 = 0
 1 1   1 1   dx ( x 0 , y0 ) x0  2
 S =  2  2  +  2  2 
 1 · 2 2 ·3   2 ·3 3 · 4   y0 = 6x0 (x0 – 2)
 1 1 
+  2  2  ……  terms × (x0, y0)
 3 · 4 4 ·5 
1
= Ans.
2
(0, 0) (2, 0)

Paragraph for question nos. 10 to 12  (x0, y0) is on curve

Solving inequalities, we get common value as
 y0 = 3x 02
f(x) = 3 (a constant and continuous function)
3x 02 = 6x0 (x0 – 2)
 
3
1 3 3
 Area OABO =  x 2 dx = x 0 = 3.  x0 = 0 or x0 = 4
3
0  y0 = 0 or y0 = 48
Tangent y = 0 or y = 24 (x – 2).
Area OABDO = 3 3 .
Paragraph for question nos. 13 to 15
  
(i) Let O be origin & p.vs of A, B, C be a , b, c
D C B( 3 , 3)
y=3 respectively
  
 OA · BC = a · ( c  b)
mx
y=

2     1 1
y=
x = a·c  a·b =  = 0
2 2
O A

 OA  BC  =
 Area of OBDO = 2 3 2
O ( o)
 Area of OCD = 3
( y = mx bisects area)
3
y
  m dy = 3
0 A (a ) C (c )

3
 y2 
   =
 3
 2m  0 B ( b)


2 3m=9 similarly OB  CA  =
2

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  2
& OC  AB  =  ON =
2 3
 sin  + sin  + sin2  = 3
2 2
 AON is right angled triangle
     
a · a a · b a · c 2 1
  OA 2  ON 2 = 1
    AN = =
(ii)  a b c 2 = b · a b · b b · c 3 3
    
c ·a c ·b c ·c Ans.

1 1 Q.16  z1, z2, z3 are the roots of

1 x3 + 3ax2 + 3 bx + c = 0
2 2
1 1 We have
= 1 z1 + z2 + z3 = – 3a
2 2
1 1 and z1z2 + z2z3 + z3z1 = 3b
1
2 2 z1  z 2  z 3
Centroid = =–a
3
 1 11 1 11 1 Trianlge will be equilateral triangle if
= 1 1          
 4 22 4 24 2
z12  z 22  z32 = z1z2 + z2z3 + z3z1
3 1 1 1  (z1 + z2 + z3)2 = 3(z1z2 + z2z3 + z3z1)
=   =
4 8 8 2

  a b c  = 1
2
x ;
 e
1 x  e
Q.17 g(x) =  ; xe
1 
 Volume of tetrahedron = a b c =
6
1
6 2
 2
0 ; xe

2e e 2e  e2  1 
3 2 3   g ( x ) dx =  x dx   0 dx =  2 
(iii) Area of ABC = ·1 = 1 1 e  
4 4
Ans.
O
Q.18 Any point on hyperbola can be taken as
(3 sec , 2 tan )
Reflection of point will be = (2 tan , 3 sec )
x 2 y2
A C  Locus is  = –1
4 9
N
4 13
 Eccentricity = 1 = Ans.
9 3
B
    
Q.19  c = x a + y b + z (a  b)

1
3
× Area of ABC × ON

   
 x a  y b  z(a  b)  b


= Volume of tetrahedron
 
  
= a – x a  y b  z (a  b ) 

1
×
3
× ON =
1  
  
     
 x a  b + 0 + z (a · b ) b  ( b · b ) a 
3 4 6 2  
  
= a – x a  y b  z (a  b ) 
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     Maximum distance = diameter = 5
 – z a + x (a  b )
    A
= (1 – x) a – y b – z (a  b)
 1 – x = –z , y = 0 and – z = x  3
C  2, 
P  2
1 1 (– 4, –3)
 1–x=x  x= and z =
2 2
    B
 a , b and a × b
are mutuallyperpendicular unit vectors 5 5
Radius of director circle = 2=
2 2 2 2
 1 1 1
 |c| =   0  = Length of tangent = 42  32  42  32
2 2 2
Ans. =5 2
f (x  h)  f (x) Circumcircle of PAB will be circle with PC
Q.20  f '(x) = Lim as diameter
h 0 h
2
2 3  2
  h   Diameter = (2  4)    3 
f (x)  f     f (x) 2 
= Lim   2 
h 0 h 81 15
= 36  = Ans.
4 2
 h   h 
 f    1  f    1
 2   2  Q.22  f (x) = 7 + 2x ln 25 – 5x–1 – 52–x
= f (x) Lim
h 0 h  f '(x) = 2 ln 25 – 5x–1 ln 5 + 52–x ln 5
( f (0) = 1) 
 5x 25 
f ' (x) = ln 5  4   x
 5 5 
= f (x) f '(0)  = f '(0)
f (x )
ln f (x) = f '(0) x + c  ln 5 2x
= (5 – 20 · 5x – 125)
Putting x = 0 5 · 5x
0=0+c  c=0
 ln 5 x
 ln f (x) = x ln 2  f (x) = 2x = (5 – 25) (5x + 5)
 f (x) + f (2x) + f (3x) + ……+ f (nx) 5x 1
= 2x + 22x + 23x + …… + 2nx sign of f '(x) 

2 x (2nx  1) f ( x ) f (nx )  1
= = 2
2x  1 f (x )  1
 f (x) is maximum when x = 2
 A = 1, B = –1, C = –1 Ans.  a=2
Q.21  AB is fixed with A = (4, 0) and B = (0, 3) x

t
2
for all positions of R and ARB = 90º. dt
x2 1
 Locus of R is a circle withAB as diameter r = Lim 0
2 = Lim 3 =
x 0 x tan x x 0 3x 3
 Required locus is :
x (x – 4) + y(y – 3) = 0 1
 x2 + y2 – 4x – 3y = 0  r=
3
2
3 5 a 2
radius = 22    =  S= = = 3 Ans.
2 2 1 r 1 1
 Circle passes through origin 3
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 C H E M I S T RY
PART-A
Q.1 For residue solution at its normal boiling point : Ps = 1 atm = 760 torr
Ps = Xb × 900 + Xt × 600
760 = 900 Xb + (1–Xb) × 600 = 600 + 300 Xb
160
Xb = = 0.53
300

O H O
C CH2–OH
C–O

Q.3 K
OH
 +
Cl Cl
Cl

Q.4 A2 = t + 
2AdA

dt
dA 
 
dt 2(A)

dA  1
 A
dt 2
 order = –1

O
CHCl
Q.6 Ph – C – NH2 KOH
/ Br
 2
 Ph–NH2 KOH
3  Ph–N C
(Hoffmann bromide) (Carbyl amine)

Q.10 Volume of system increases so entropy also increases

Ssystem > 0,
Ssurroundings < 0

 Vf 
Q.11 S = 2.303 nR log  V 
 i 
 30 
= 2.303 ×3 × 8.314 log   = 27.4 JK–1
 10 

Q.12 For reversible process :

Ssystem + Ssurroundings = 0
Suniverse = 0

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Q.13 A  (NH4)2SO4. Cr2(SO4)3. 24H2O
B  NH3
C  HgO . HgI . NH2
D  [Cu(NH3)4]2+
E  CrO5
F  Cr2O3

Q.17 ST-1 : False : Because electrolysis of aq. solution of magnesium chloride gives H2 gas at cathode and
Cl2 gas at anode.

ST-2 : True : 
MgCl2 . 6H2O dry HCl MgCl2 (anhydrous) + 6H2O 

Q.18 Ethylene accepts electron pair from filled d-orbital of Pt2+ into its vaccant antibonding M.O.

Q.21 (i) BF3 + H2O Partial

 B(OH)3 + H+[BF4]¯
Hydrolysis

Partial
(ii) SiF4 + H2O  Si(OH)4 + H2[SiF6]
Hydrolysis

(iii) PCl3 + H2O  H3PO3 + HCl

(iv) SF4 + H2O  H2SO3 + HF

PAPER-2
P H YS I C S Now at Q along PQ
PART-A dB
  d EQ × 2 2 R =   5R 
2
dt
Q.1  E nc . d A 
dt
at P along PQ
E
dB
P  2R  R 2 2R
dt Q

R

P Enc EQ

R M
3R
O
B=B0t

5 R dB
EQ =
2 dt
R dB
Ep =
2 dt 5 R dB
(EQ)along QM = cos 
which is dircted along PQ 2 dt
Now at any point on side PQ have same
electric field elong PQ 5 R dB 2R ( 2R ) dB
  
 Ea = Eb 2 dt 5R 2 dt
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 and now along QM at each point electric field
h
will be same Q.9 ' –  = m 1  cos  
EC = EN and Eb < Ed c

h
Q.3 Angular frequencyofAC =Angular frequency ' =  + m   = 180°
of proton circular motion. e

V u qB h h
 = 
r mn m p' = =
' 2h
qB 
me

1.6 10 19 1.5 rad hc hc 12420 12420

= 
1.44 108 
1.67 10 27 sec Q.10 Ke = – =
 ' 1 .1 1.132
mv max = 319.16 eV
rman = R =
qB
Paragraph for question nos. 11 to 12
p2 (qBR ) 2 In ground frame in x-y horizontal plane
kman = man = = 4.3 × 10–12 J
2m 2m vx = v0 = constant (unknown)
vy = 0
V  Vf In rotation frame
Q.4 ' = VT – VsT = In x-yhorizontal plane
f
340  40 v0' sin 
= = 0.3 m
1000 v0' wrt table

v0' cos v0
 V  V0 
f '   f = 420 × 1000 = 1400 R
 V  Vs  300
v0' sin  = R
340  80
'' = VT' – VsT = = 0.18 m v0' cos  = v0
1400
R R
Q2 1 Q'2 sin  = v '  2R  = 30°
0
Q.5 = Li 2 =
2C1 2 2C 2
Now v0 = v0' sin 
= 2 R cos 30
C2 8
Q' = Q C  20 = 40 2R
1 2  3
2
 32 rv
Q.7 i
R0  Re = 5R 4R 4R 4
R0  t= v = =
11 0 (R  3 ) 3
Q.8 At resonance
XL = XC.

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Q.14 Very check dimesionally
 conduction plane

–q +q
Q.15 x x (object charge)
image
Vt
when charge is at distance x using image charge
(S vt)
Fth = UrRt = v cos 45° × 2 cos 45° method
t
Method I :
v 2s
a F kq 2
M a =
m m( 2 x ) 2
v t
du  s
 v 2   M dt vdu

kq 2
v 0
0
 dx 4m x 2
v
 1 s
 v    M t
v 
kq 2  dx
  v0  v dv 
4m  x2
0 2
1 1 s
  t
v0 u M v2 kq 2  1  1  kq 2
=  =
2 4m   2  8m
1 1 s
  t
v v0 M q
kq
 v =
1 1 s 4m 16  0 m
  t
v v0 M Method II:
By COE for interaction of two charged
1  M  v 0 st 
  particles:
v  v 0 M 
ui + ki = vf + kf
Mv 0  kq 2  kq 2 1
v +0=  mv 2 x 2
M  v 0st u 2 2
Mv
s = vdt  M  v00st dt mv2 =
kq 2
u
v0M q2
 n M  v 0st 0t v2 
v 0s 16  0m

M  M  v 0st  q2
 n   v
s  M  16  0m

 t 
 x 0n 1  
 0 

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 360 M AT H E M AT I C S
Q.16 No. of image   1  3 now using three
90 PART-A
imaginarycharges in which two image is direct Q.1 Let there be n raw in triangle
image hence – q while third image is image of
n ( n  1)
image hence +q now we can see that four  Number of ball =
2
charge system makes potential zero at each
point on the conducting plane. Now we can n ( n  1)
 + 669 = (n – 8)2
find net force on object +q. 2
 n2 + n + 1338 = 2(n2 – 16n + 64)
kq 2 kq 2  n2 – 33n – 1210 = 0
F 2 –
(2) 2 (2 2 ) 2  n2 – 55n + 22n – 1210 = 0
 (n – 55) (n + 22) = 0
q
–q  n = 55
n ( n  1)
 Number of initial balls =
2
+q = 55 × 28 = 1540 Ans.
–q

kq 2  1
 2  2  Q.2
(2)  2 (A) & (B)
Q.19 (P) Vrms  P(x) = x for x = 1, 2, 3, 4, 5
T
and degree of P(x)  4
nC P (TA  TD )  P(x) = x should be an identity
(Q) QDA / QCD = n C (T  T )  P(6) = 6
V D C
(C) & (D)
W P(x) = x for x = 1, 2, 3, 4
(R) = Q Q P(x) – x = a(x – 1) (x – 2) (x – 3) (x – 4)
AB BC
 P(5) = 24a + 5
 a0
3
n RT0  P(5)  5 Ans.
U AB 2
(S) =
WBC 2nRT0
Q.3 a + b = 20 and c + a = 21
Q.20 For maximum range.
b 2  c2  a 2
 cos A = = b2 + c2 – a2 = – bc
H6 H6 2bc
If  6 then h 
2 2  (20 – a)2 + (21 – a)2 – a2
= – (20 – a) (21 – a)
H6
If > 6 then h = 6  400 – 40a + a2 + 441 – 42a + a2 – a2
2
= – (420 – 41a + a2)
 2a2 – 123a + 1261 = 0
 (a – 13)(2a – 97) = 0
 97 
 a = 13  a  
 2 
 b = 7 and c = 8

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 perimeter = 28
Q.5 Points at a distance 2 from origin an line
1
Area = bc sin A x + y = 0 are (–1, 1) and (1, –1).
2
(i) If vertex is (–1, 1) and focus is (1, –1),
1 3 then equation of tangent at vertex
= ·7·8· = 14 3 Ans.
2 2 will be x – y = 
y (–1, 1) is on it
 x–y=–2
|x – 3|

Q.4 x y
(3, 0)
(–1,1)
(i) y = |x – 3| – a if a < 0
x
y
(1,–1)
–a
x

Distance between focus and vertex is 2 2 .

| x  3 | a – 4
Equation of parabola will be
will have no intercept if – a > 4
 a < – 4,  a = –5 2
xy  x y2
   4 2 2  0
| x  3 | a – 4  2   2 
will have one intercept if
{Only one sign is possible}
–a=4 a=–4
but (0, 0) lies inside the parabola
If a>0
y  – sign must be taken
y = |x – 3| – a  required equation of parabola will be
x 2
xy xy2
   4· 2 2  0
 2   2 
y  (x + y)2 = 16 (x – y + 2) Ans.
a (ii) If vertex is (1, –1) and focus is (–1, 1)
Then equation of tangent at vertex
x
y = | |x – 3| – a | x–y=k
 (1, –1) is on it
k=2
 | x  3 | a – 4
Equation of parabola will be
will have exactly three intercept if a = 4
2
 | x  3 | a – 4 xy  xy2
   4·2 2  0
will have exactly four intercept if 0 < a < 4  2   2 
a = 1, 2, 3 (Only one sign is possible)
 sum = 6 Ans. but (0, 0) lies inside the parabola

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  + sign must be taken
x3 p 2
2 Q.7  f (x) =  x + qx + 10
x y  xy2 3 2
    4·2 2  0
 2   2   f '(x) = x2 + px + q
For f to be one one
(x + y)2 = – 16(x – y – 2) Ans.
f '(x)  0  x  R
 p2 – 4q  0
Q.6  | (n – a)! – t | + | t – (b – a)! |
p q
+ | a + b – K1n – K2 |  0,
1 1, 2, 3, 4, 5
 (n – a)! – t = 0
2 1, 2, 3, 4, 5
 t = (n – a)!
3 3, 4, 5
t – (b – a)! = 0
4 4, 5
 t = (b – a)!
 number of ordered pairs n = 15 Ans.
 (n – a)! = (b – a) !
 n–a=0 & b–a=1
Q.8 If both line intersect then intersection of line
 n=a & b = a + 1 = n +1
x = y = z from both planes should be same
 a + b – K1n – k2 = 0
 n + n + 1 – K1n – K2 = 0 1 1
 = 2
 K1 = 2, K2 = 1 2
b  (2  4a )  1 a  (1  2b)  1
Let R be (h, K)
 Diagonal bisect each other   
– a 2  (1  2b)  1 = b2 + 2 – 4a + 1
 x coordinate of P is – h  a2 – 4a + b2 – 2b + 5 = 0
1  2  (a – 2)2 + (b – 1)2 = 0
Slope of PQ = =m  a = 2, b = 1
1 h
 1 = m (1 + h) + 2 Paragraph for question nos. 9 & 10
 Slope of PQ x slope of QR = –1 (i) P(ui) = ki2 ( k = proportionality constant)
K  ( m(1  h )  2)  P(u1) + P(u2) + ...... + P(un) = 1
 mx = –1
h 1  k·12 + k·22 + k · 32 + .....+ k · n2 = 1
 mK – m2 (1 + h) – 2 m = 1 – h n ( n  1)( 2n  1)
k· =1
6
y R(h,K)
6
Q(1,1) k=
S(–1,2) n ( n  1)(2n  1)
y=mx       
P(–h,2) lim P(G ) = nlim  P(u1 )P G   Pu 2 P G   .....  P(u n )P G  
x x       u 
n  
  u1   u2   n 

n
i 2 (i  1)
= lim  k
n 
i 1 (3n  1)
y
 n 2 (n  1) 2 n (n  1)(2n  1) 
6  
 Locus is  4 6 
= lim
(m2 – 1) x – my + m2 + 2m + 1 = 0 n  n (n  1)(2n  1)(3n  1)
On comparing
m2 – 1 = 24, m = 5 , 6 1
= 4 · 2 · 3 = Ans
m2 + 2m + 1 = 36 4
 1 + m + m2 = 31 Ans.

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 Paragraph for question nos. 13 & 14
(ii)  P(u i )  k  nk = 1
Consider a point (, f() ) on the curve
1  Equation of tangent is
k=
n y – f() = f '() (x – )
 (2, 0) is on it 0 – f() = f '() (2 – )
1  1  1 2 1 n
P(W) = n ·  3n  1   n · 3n  1  .....  n · 3n  1 f ' ( ) 1
 
 =–
f ( ) 
1  n (n  1)  n 1
=   = Ans  ln f() = – ln  + ln c
n (3n  1)  2  23n  1
c
Paragraph for question nos. 11 & 12  f() =

(i)  h(x) is a rational function
g(x) must be a polynomial function.  curve passes through (1, 1)
 c=1
 Lim h ( x )  
x  1 1
 degree of g(x) < degree of h(x)  f() =  f(x) =
 x
 degree of g(x)  2
 f(x) = x3 + x2 – 16x + 20 1 dy 1
(i) Curve y = f(x)  y =  =– 2
= (x – 2)2 (x + 5) x dx x
and  slope of normal > 0
 g(2) = 0
 (2  a ) a2
 one roots of g(x) is equal to 2.  >0 >0
a a
and
 a < 0 or a > 2
2
( x  2) ( x  5)  a does not lie in (0, 2)
Lim h ( x ) = Lim = – 1,
x 5 x  5 g( x )
ex
exists and finite therefore g(x) should have one (ii)  g(x) =
x
root as – 5.
 g(x) = a (x – 2) (x + 5) xe x  e x ( x  1) e x
 g '(x) = =
2 x2 x2
( x  2) ( x  5)
 Lim =–1  g(x) decreases in (0, 1) and increases in (1, )
x  5 a ( x  2) ( x  5)
 minimum value at x = 1
( x  2) 7  minimum value = g(1) = e. Ans.
 Lim =–1  =–1
x  5 a a
 a=7 Paragraph for question nos. 15 & 16
 g(x) = 7 (x – 2) (x + 5) Given equation is written as
 Number of points ofremovablediscontinuity 3(x4 – y4) – 8x3y – 8xy3 + 8xy
of h(x) = 2. – 3x2 + 3y2 = 0
(ii)  (x) will be continuous where f(x) = g(x)  3(x2 – y2) (x2 + y2) – 3(x2 – y2)
 (x – 2)2 (x + 5) = 7 (x – 2) (x + 5) – 8xy (x2 + y2 – 1) = 0
 x = 2, – 5, 9  3(x2 – y2) (x2 + y2 – 1)
 Sum = 2 + (–5) + 9 = 6. Ans. – 8xy (x2 + y2 – 1) = 0

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  (x2 + y2 – 1) (3x2 – 3y2 – 8xy) = 0 Q.17
 x2 + y2 – 1 = 0 or 3x2 – 8xy – 3y2 = 0 (P) a2 + b2 + c2 = ab + bc + ca
 S : x2 + y2 = 1  (a – b)2 + (b – c)2 + (c – a)2 = 0
and P : (x – 3y) (3x + y) = 0  a=b=c
 ABC is equilateral
x
 y = and y = 3x (Q) a + 2b + c2 – 2bc – 2ab = 0
2 2
3
 (a – b)2 + (b – c)2 = 0
 lines are perpendicular
 a=b=c
 They will divide the circle into four equal
 ABC is equilateral
parts and ABCD will be a square
(R) a2 + b2 + c2 – 2 ab – 2ac = 0
1 
Area of square = 4 ×   11 = 2  2a2 + 2b2 + 2c2 – 2 2 ab – 2 2ac = 0
2 
 (a2 – 2 2ab + 2b2)

+ (a2 – 2 2ac + 2c2) = 0

B
 (a – 2 b )2 + (a – 2c )2 = 0
A
 a= 2b = 2c
90°

b2  c2  a 2
 cos A = =0
2bc
C
 A = 90° & B = C
D  B = C = 45°
(S) a2 + b2 + c2 – ca – ab 3 = 0

 4a2 + 4b2 + 4c2 – 4ca – 4ab 3 = 0

L  (3a2 – 4ab 3 + 4b2)
A
+ (a2 – 4ca + 4c2) = 0
K
D
 ( 3 a – 2b)2 + (a – 2c)2 = 0

2b
B  a= = 2c
3
M
C
3 a
N  b= a&c=
2 2

Tangents at A, B, C, D will intersect at right b2  c2  a 2

cos A = =0
angle therefore circumcircle of KLMN will be 2bc
director circle.  A = 90° then C = 30° & B = 60°
Area of circumcircle =   2 2
= 2 Ans.

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 Q.20
x2 (P) n {x} = x + [x] (n – 1) {x} = 2[x]
Q.18  g(x) = g(0) + x g'(0) + g"(0)
2 2[ x ]
 {x} =
= – bx2 + cx – 6 n 1
 h(x) = g(x) 2[ x ]
 0  <1
 4x4 – ax3 + bx2 – cx + 6 = 0 n 1
 A.M.  G.M. n 1
 0 [x] <
2
1 2 3 4  n = 10, 11 for five integral values of x
   then [x] = 0, 1, 2, 3, 4
1· 2 · 3 · 4
 x1 x 2 x 3 x 4  4
4 x1x 2 x 3x 4
(Q) (x – a) (x – 10) = –1 = –1 × 1
(i) If x – a = – 1
 24 
1/ 4 then x – 10 = 1  x = 11
 2    22  11 – a = – 1 a = 12
 6/ 4  (ii) If x – a = 1
 A.M. = G.M. then x – 10 = – 1 x = 9
 9 – a = 1 a = 8
1 2 3 4 (R) Probability of occurrence of odd number in
 = = = = k (let)
x1 x 2 x 3 x 4 1
throwing of a die =
2
1 2 3 4 Probability of non occurrence of odd
  
x1 x 2 x 3 x 4 = 4k = 8  k = 2 1
number =
2
1 3
 x1 = , x2 = 1, x3 = , x4 = 2 1
n 1
1 n 1
n
2 2 n
 P(A) = C1     = C1  
(2x – 1) (x – 1) (2x – 3) (x – 2) = 0 2 2 2
(2x2 – 3x + 1) (2x2 – 7x + 6) = 0 n 2 2 n
n 1 1 n 1
4x4 – 20x3 + 35x2 – 25x + 6 = 0 P(B) = C 2     = C2  
2 2 2
 a = 20, c = 25, b = 35 Ans.
n 3 3 n
1 1 1
P(C) = 3     = nC3  
nC
Q.19 2 2 2
(P)  A3 = A  A–1 A · A2 = A–1 A  2P(B) = P(A) + P(C)
 A2 = I 2, nC2 = nC1 + nC3
 A–1 A A = A–1 · I n ( n  1) n ( n  1)( n  2)
2 =n+
 A–1 = A 2 6
6(n – 1) = 6 + (n2 – 3n + 2)
(Q)  A2 = A  A–1 A · A = A–1 A n2 – 9n + 14 = 0
n = 2, 7
 A= I
   
 A–1 = A = I (S)  a bc = –c
  2 2
 abc = c
(R)  AT A = I  A–1 = AT
 
 9 + 9 + 16 + 2  a · b = 16
(S) A2 = I  A = A–1  
  a · b = – 9 Ans.

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 C H E M I S T RY
PART-A

Q.1 A2I2 + MnO4¯ H IO3¯ + AO + Mn+2
+1 –1 +5 +2

 n
xf of A2I2 = 6 × 2 +  2   × 2 = 10 – n and xf of MnO4¯ = 5
 2
e A 2I 2  e MnO 
4

700  0.02  5
5 × 10–3 × (16 – n) =  16 – n = 14
1000
Ans .(A) is correct: n = 2
Ans. (B) is correct: EF of idoide = AI
xf of A2I2 = 16 – n = 16 – 2 = 14

H
A2I2 + K2Cr2O7  IO3¯ + AO + Cr2+
xf = 14 xf = 6
e A 2I2  e K 2Cr2O7

0.15 × 14 = n K 2Cr2O7  6
0.15  14 0.15  7
Ans. (C) is incorrect: n K 2Cr2O 7 used  =
6 3
Ans. (D) is incorrect: "A" is not first group metal as it show variable oxidation state.

Q.6 Theory based

Q.8 NaCl  Na+ + Cl¯

0.4 0 0
0.4(1–0.8) 0.4 ×0.8 0.4 × 0.8
Total ionic conc. = 0.72 M
Glucose = 0.7  Hypotonic
Na3PO4  3Na+ + PO43–
0.3 0 0
0.3(1–0.9) 3 × 0.3 × 0.9 0.3 × 0.9
0.3 0.81 0.27
= 1.11 M  Hypertonic
CH3COOH  (CH3COOH)2
1 0
1 – 0.3 0.15
Total = 0.85  Hypertonic
CaCl2  Ca+ + 2Cl¯
0.5(1–0.2) 0.2 ×0.5 2 × 0.2 × 0.5
0.4 0.1 0.2
Total = 0.7  Hypotonic

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Q.9 X2(g)  2X(g)
t=0 P0
t = 693 sec P0–P 2P Total pressure = P0 + P = 30 mm
t= 0 2P0 2P0 = 40 mm
so P0 = 20 mm
P = 10 mm
0.693
So , K = sec–1 = 10–3 sec–1
693

Q.10 X2(g)  2X(g)

t=0 P0
t = 220 sec P0–P 2P P0 + P = 75 mm
t= 0 2P0 2P0 = 90 mm
so P0 = 45 mm
P = 30 mm
Partial pressure of X2 at 220 sec = P0 – P
= 45 mm – 30 mm
= 15 mm Ans.
Q.13 In osazone formation C1 & C2 both carbon's are involved rest of the skelton is identical.

OH CH = NH
CH = O | |
*CH – CN *CH(OH)
HO H
HO H HO H
H OH H2 / Pd
NaCN H OH H OH
Q.14 (C) H OH BaSO4
HCl
H OH H OH
CH2OH
CH2OH CH2OH

CH = O
|
*CH(OH)

May be D-Glucose or D-Mannose HO H

H OH
H OH
CH2OH

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