1

DRONA NEET
Chemical Kinetics Practice Sheet - 1

1 6. In the reaction:
1. A gaseous reaction, A2(g) → B(g) + C(g), shows
2 BrO3− (aq) + 5Br–(aq) + 6H+ → 3Br2(I) + 3H2O(I)
increase in pressure from 100 mm to 120 mm in 5 The rate of appearance of bromine (Br2) is related
minutes. The rate of disappearance of A2 is to rate of disappearance of bromide ions as
(1) 4 mm min–1 (2) 8 mm min–1 following
(3) 16 mm min–1 (4) 2 mm min–1 d(Br2 ) 5 d(Br − )
(1) =−
dt 3 dt
2. In a reaction, 2X + Y → X2Y, the X disappears at d(Br2 ) 5 d(Br − )
(1) Half the rate as that of disappearance of Y (2) =
dt 3 dt
(2) The same rate as that of disappearance of Y d(Br2 ) 3 d(Br − )
(3) The same rate as that of appearance of X2Y (3) =
dt 5 dt
(4) Twice the rate as that of appearance of X2Y
d(Br2 ) 3 d(Br − )
(4) =−
dt 5 dt
3. For the reaction N2 + 3H2 → 2NH3, the rate of
change of concentration for hydrogen is
7. For the reaction A + B → Products, it is observed
–0.3 × 10–4 Ms–1. The rate of change of
that
concentration of ammonia is
(I) On doubling the initial concentration of A
(1) –0.2 × 104 (2) 0.2 × 10–4
only, the rate of reaction is also doubled and
(3) 0.1 × 10–4 (4) 0.3 × 10–4
(II) On doubling the initial concentration of both
A and B, there is a change by a factor of 8 in
4. The graph plotted between concentration versus the rate of the reaction.
time The rate of this reaction is given by
(1) Rate = k [A] [B]2
(2) Rate = k [A]2 [B]2
(3) Rate = k [A] [B]
(4) Rate = k [A]2 [B]

8. The rate of a reaction is expressed as

(1) It gives rate of disappearance of reactant 1 [C] 1 [D] 1  [A]   [B] 
+ = = − = −
[C − C1 ] 2 t 3 t 4  t   t 
(2) Rate = − 2
t 2 − t1 Then reaction is
(3) Both (1) & (2) (1) 4A + B → 2C + 3D
(4) It predicts the order of reaction (2) B + 3D → 4A + 2C
(3) A + B → C + D
5. For the given reaction: (4) B + D → A + C
N2 + 3H2 → 2NH3
Rate of formation of ammonia is 2 × 10–4 mol. L–1 9. For a reaction A + B → products, the rate of
s–1 then find rate of disappearance of hydrogen? reaction was doubled when concentration of A was
(1) 3 × 10–4 mol. L–1 s–1 doubled, rate was doubled. When concentration of
(2) 2 × 10–4 mol. L–1 s–1 A and B both was doubled, the rate was again
(3) 4 × 10–4 mol. L–1 s–1 doubled, order of reaction w.r.t. A and B are
(4) 6 × 10–4 mol. L–1 s–1 (1) 1, 1 (2) 2, 0
(3) 1, 0 (4) 0, 1
 2

10. Which of the following statement is not correct? 16. For the reaction A + B → products, it is observed
(1) Molecularity of a reaction cannot be fractional that
(2) Molecularity of a reaction cannot be more than
(i) on doubling the initial concentration of A only,
three
(3) Molecularity of a reaction may or may not be the rate of reaction is also doubled and
equal to the order of reaction (ii) on doubling the initial concentration of
(4) Molecularity of a reaction can be obtained both A and B, there is a change by a
from balanced chemical equation factor of 8 in the rate of the reaction.
The rate of this reaction is given by
11. The overall order of reaction between X & Y is 3.
Which of the following rate equation must be (1) rate = k[A] [B]2 (2) rate = k[A]2 [B]2
correct, if on doubling the concentration of X, the (3) rate = k[A] [B] (4) rate = k[A]2 [B]
rate of reaction gets doubled?
(1) r = K[X]2 [Y]0 (2) r = K[X]1[Y]2
1 3 17. The data for the reaction: A + B → C is
(3) r = K[X] [Y] (4) r = K[X]2[Y]1
Exp. [A]0 [B]0 Initial rate
12. For a reaction between A and B the order with 1 0.012 0.035 0.10
respect to A is 2 and the other with respect to B is
2 0.024 0.070 0.80
3. The concentrations of both A and B are doubled,
the rate will increase by a factor of 3 0.024 0.035 0.10
(1) 12 (2) 16 4 0.012 0.070 0.80
(3) 32 (4) 10
The rate law corresponds to the above data is
13. Which one of the following statements for the order (1) Rate = k [A][B]3 (2) Rate = k [A]2 [B]2
of a reaction is incorrect? (3) Rate = k [B]3 (4) Rate = k[B]4
(1) Order can be determined only experimentally.
(2) Order is not influenced by stoichiometric 18. During the kinetic study of the reaction,
coefficient of the reactants.
2A + B → C + D, following results were obtained
(3) Order of a reaction is sum of power to the
concentration terms of reactants to express the
rate of reaction. Initial rate of formation
(4) Order of reaction is always whole number. Run [A]/mol L–1 [B]/mol L–1
of D/mol L–1 min–1
14. The rate of reaction between two reactants A and B I. 0.1 0.1 6.0 × 10–3
decreases by a factor of 4 if the conc. of reactant B
is doubled. The order of this reaction with respect II. 0.3 0.2 7.2 × 10–2
to reactant B is III. 0.3 0.4 2.88 × 10–1
(1) 2 (2) –2 IV. 0.4 0.1 2.40 × 10–2
(3) 1 (4) –1
Based on the above data which one of the following
15. The rate of reaction A + B + C → P is given by is correct?
−d[A] (1) Rate = K [A]2 [B]
r= = k[A]1/2 [B]1/2 [C]1/4.
dt (2) Rate = K [A] [B]
The order of reaction is (3) Rate = K [A]2 [B]2
(1) 1 (2) 2
(4) Rate = K [A][B]2
1 5
(3) (4)
2 4
 3

Answer Key
1. (2) 4. (3) 7. (1) 10. (4) 13. (4) 16. (1)
2. (4) 5. (1) 8. (1) 11. (2) 14. (2) 17. (3)
3. (2) 6. (4) 9. (3) 12. (3) 15. (4) 18. (4)
 4

Solutions
1. (2) 5. (1)
1
A2(g) → B(g) + C(g) +1 d[NH3 ] −1 d[H2 ]
2 r= =
t=0 100 mm 0 0 2 dt 3 dt
t = 5 min 100 – x x x/2 2 10 −4
−d[H2 ]
(Pinitial = 100, let x pressure dissociated) 3 =
2 dt
At equilibrium 100 – x + x + x/2 = 120
−d[H2 ]
x = 40 = 3 10−4 mol L−1 s−1
 −d  A2   dt
rate of disappearance of A 2  = r
 dt 
6. (4)
−d[A2 ] (−)[final conc. − initial conc.]
r  −d[BrO3 ]− −1 d[Br − ] −1 d[H+ ]
dt Time taken r = = = =
dt 5 dt 6 dt
−(100 – x) − 100
 1 d[Br2 ]
5 +
3 dt
−(100 – 40) − 100
 d[Br2 ] 3 d[Br − ]
5 =−
−(60 –100) dt 5 dt
r
5
40 7. (1)
r  = 8 mm min −1 r1 = k[A]x[B]y
5
2r1 = k[2A]x[B]y → i.e.,
2. (4) order w.r.t. (1) → (1) (x = 1)
1 d X −d Y d X2 Y 8r1 = k[2A]1[2B]y → i.e.,
r=− = =+
2 dt dt dt order w.r.t. (2) → 2 y = (2)
Rate of disappearance of (X) = k[2A]2[2B]2
d  X 2d Y = 8r1
= − =−
dt dt R = k[A][B]2
2d X2 Y

dt 8. (1)
⇒ Twice the rate as that of appearance of X2Y.  
1  C 1  D 1   A    B 
+ = = − = − 
2 t 3 t t   t 
 
3. (2) 4
N2 + 3H2 → 2NH3  
d  N2  1 d  H2  1 d  NH3  +ve sign –ve sign
r=− =− =+
dt 3 dt 2 dt indicates product indicates
d H2  reactants
Given, − = −0.3 10−4 Ms−1
dt
1 1 d  NH3  9. (3)
So, r  −  0.3 10−4 = + 𝑟1 = 𝐾[𝐴]𝑥 [𝐵]𝑦 𝑟2 = 2𝑟1 𝐴′ = 2𝐴 2𝑟1
3 2 dt
d[NH3 ] 2 = 𝐾[2𝐴]𝑥 [𝐵]𝑦 … 1 2𝑟1
  × 0.3 × 10–4 ⇒ 0.2 × 10–4 = 𝐾[2𝐴]𝑥 [2𝐵]𝑦 …2
dt 3
It means (𝑟) ∝ conc. of (𝐴)
4. (3)
So order w.r.t. [𝐴] = 1 and rate of reaction does not
In given graph concentration decreases with time
which shows that it is the graph of reactant because change on concentration of (𝐵) . So, w.r.t. (𝐵)
concentration of reactant decreases as time increases order = 0.
So,
10. (4)
Molecularity of a reaction can't be obtained from
balanced chemical equation.
 5

11. (2) 17. (3)

If concentration of (𝑋) doubles rate of reaction also 𝐴+𝐵 →𝐶
doubles means (𝑟) ∝ concentration of (𝑋). Let rate = 𝑘(𝐴)𝑥 (𝐵)𝑦
So, order w.r.t. (𝑥) = 1. where order of reaction is (𝑥 + 𝑦).
Hence, over all order = 3 so, w.r.t. (Y) order = 2 Putting the values of exp. 1, 2 and 3, we get
𝑟 = 𝐾[𝑋]1 [𝑌]2 following, equations

12. (3) 0.10 = 𝑘[0.012]𝑥 [0.035]𝑦 … . . (𝑖) 0.80 =

𝑥 𝑦
Rate 1 = 𝑘[𝐴]2 [𝐵]3 𝑘[0.024] [0.070] … . . (𝑖𝑖) 0.10 =
Rate 2 = 𝑘[2𝐴]2 [2𝐵]3 𝑘[0.024]𝑥 [0.035]𝑦 … . . (𝑖𝑖𝑖) 0.80 =
𝑥 𝑦
Rate 2 = 32𝑘[𝐴]2 [𝐵]3 𝑘[0.012] [0.070] … … … (𝑖𝑣)𝐷𝑖𝑣𝑖𝑑𝑖𝑛𝑔 (𝑖𝑣) 𝑏𝑦
∴ Rate 2 = 32(𝑅𝑎𝑡𝑒1 ) 0.80 0.070 𝑦
(𝑖), 𝑤𝑒 𝑔𝑒𝑡 =( )
0.10 0.035
⇒ 2y = 8 ⇒ y = 3
13. (4)
Keeping [𝐴] constant, [𝐵] is doubled, rate
Order of a reaction is not always whole number. It
becomes 8 times.
can be zero, or fractional also.
Dividing eq. (iii) by eq. (i), we get
0.10 0.024 𝑥
14. (2) =( ) ⇒ 2𝑥 = 1 𝑥 = 0
0.10 0.012
Rate of reaction = 𝑘[𝐴0 ]𝛼 [𝐵0 ]𝛽
Keeping [𝐵] constant, [𝐴] is doubled, rate remains
𝛼→ order of reaction w.r.t. 𝐴
unaffected. Hence rate is independent of [𝐴]. rate ∝
𝛽→ order of reaction w.r.t. 𝐵
[𝐵]3 .
𝑟1 𝑘[𝐴0 ]𝛼 [𝐵0 ]𝛽 1 𝛽
[𝐵] = [2𝐵 0 ] = ; 4=( ) =𝛽
𝑟2 𝑘[𝐴0 ]𝛼 [2𝐵0 ]𝛽 2 18. (4)
= −2 According to table:
when concentration of (1) = constant (II, III)
15. (4) then (2) = doubles, r = four times.
1 1 1
Order = + +
2 2 4 i.e., order w.r.t. (2) = 2
2 + 2 +1 5 when concentration of (2) = constant (I & IV)
= =
4 4 (A) = four times, r = four times.
i.e., order w.r.t. (1) = 1
16. (1) r = k[A]1[B]2
R = k[A]m [B]n …..(i)
2R = k[2A]m [B]n …..(ii)
m
8R = k[2A] [2B] n
…..(iii)
From (i), (ii) and (iii), m = 1, n = 2
So, rate = k[A] [B]2

For more questions, kindly visit the library section: Link for app: https://links.physicswallah.live/vyJw

For more questions, kindly visit the library section: Link for web: https://physicswallah.live/tabs/tabs/library-tab

PW Mobile APP: https://physicswala.page.link/?type=contact-us&data=open

For PW Website: https://www.physicswallah.live/contact-us