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DRONA NEET
Chemical Kinetics Practice Sheet - 2

1. Consider the following in respect of zero order 7. A sample of a radioactive substance undergoes 80%
reaction. decomposition in 345 minutes. Its half-life is
I. t1/2 is directly proportional to the initial ______ minutes.
concentration. ln 2 ln 5
II. Time taken for the completion of the reaction (1)  345 (2)  345
ln 5 ln 2
is twice its t1/2 ln 5 ln 4
III. Concentration of the reactant decreases (3)  345 (4)  345
linearly with time ln 4 ln 5
Which of the statements given above are correct? 8. The graph of t1/2 versus initial concentration ‘a’ is
(1) I & II only (2) I & III only for
(3) II & III only (4) I, II & III
2. If initial concentration is reduced to 1/4th in a zero
order reaction, the time taken for half the reaction
to complete
(1) Remains same (1) First order (2) Second order
(2) Becomes 4 times (3) Zero order (4) Can’t predict
(3) Becomes one-fourth 9. 99% of a first order reaction, was completed in 32
(4) Doubles minute. When will 99.9% of the reaction complete?
3. If initial concentration of the reactants is doubled, (1) 50 minute (2) 46 minute
the time for half reaction is also doubled, the order (3) 49 minute (4) 48 minute
of the reaction is
10. A first order reaction completes 60% in 20 minutes.
(1) Zero (2) One
The time required for the completion of 90% of the
(3) Two (4) Three
reaction is approx…
4. For a 1st order reaction, a straight line is obtained if (1) 30 minutes (2) 40 minutes
you plot (3) 50 minutes (4) 60 minutes
(1) Log conc. Vs. time
11. The half-life of a second order process,
(2) Conc. vs. time
(3) 1/conc. vs. time 2A → products, is
(4) Log conc. vs. 1/time (1) Independent of initial concentration
(2) Directly proportional to initial concentration
5. A substance (initial concentration ‘a’) reacts of A
according to zero order kinetics. The time it takes (3) Inversely proportional to initial concentration
for the completion of the reaction is of A
a a (4) Inversely proportional to square of initial
(1) (2) concentration
k 2k
k 2k 12. The half-life period of a substance is 50 minutes at
(3) (4)
a a a certain initial concentration. When concentration
is reduced to one-half, half-life is found to 25
6. For a reaction, A → B, it has been found that the minutes. Order of reaction is
order of the reaction is zero with respect to A. (1) Zero (2) First
Which of the following expressions correctly (3) Second (4) Third
describes the
reaction? 13. For a first order reaction, the time taken to reduce
2.303 [A0 ] 1
(1) K = log the initial concentration to a factor is 10 minutes
t [A] 4
(2) [A]0 – [A] = Kt if the reduction in concentration is carried out to a
0.693 1
(3) t1/2 = factor of , then time required will be
K 16
1 (1) 10 minute (2) 20 minute
(4) t1/2  (3) 40 minute (4) 60 minute
[A]0
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Answer Key
1. (4) 4. (1) 7. (1) 10. (3)
2. (3) 5. (1) 8. (1) 11. (3)
3. (1) 6. (2) 9. (4) 12. (1)
13. (2)
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Solutions
1. (4) 6. (2)
For zero order For zero order reaction [A]0 – [A]t = Kt
a
t1/2 = t1/2  a 7. (1)
(i) 2K Radioactive decomposition is first order reaction.
(ii) x = Kt
2.303 a 2.303 100
x a K= log = log
K =  t1/2 = So, t a−x t 100 − x
t x
2 0.693
t  t1/2 =
at K
t1/2  0.693 2.303 100
2x = log
2t t1/2 345 100 − 80
 t  1/2  x
a 0.693 2.303 100 0.693 2.303
= log = log5
(iii) Concentration decreases with time. t1/2 345 20 ⇒ t1/2 345
2. (3) [0.693 = 2.303 × log2]
r = K[A]0 2.303  log 2 2.303
= log5
a a So, t1/2 345
t1/2 = 
2K 2K ln 2
⇒ becomes one fourth of initial half-life. t1/2  345 
ln5
1
a '  a
4
'
8. (1)
a / 4 t1/2 1 Graph shows that t1/2 does not depend on initial
'
t1/2 =  =
2K t1/2 4 concentration which is properly of first order
reaction.
3. (1) t1/2 ∝ a0
Initial concentration → doubled → t1/2 also
doubled when t1/2 ∝ a and it is in zero
order reaction. 9. (4)
2.303 100
4. (1) K= log
t 100 − x
2.303 100
K= log
32 100 − 99 …(i)
2.303 100
K= log
t 100 − 99.9 …(ii)
2.303 100
K= log
 K  32 1
log(A)t = log(A)0 −  t 2.303 100
 2.303  K= log
(i)/(ii) 32 0.1
5. (1)
1 1
[R]0 – [R]t = Kt (log1000) = (log100)
One completion [R]0 = 0 t 32
⇒ (R)t = (R)0 = [a = x] 1 1
(log103 ) = (log102 )
∴ (R)0 – (R)t = Kt t 32
a – a + x = Kt 1 1
 3log10 = 2  log10
x = Kt t 32
x a ∴ log10 = 1
t = =
K K on completion 3  32
t  48 minute
or 2
r = K[A]0
d(A) a
− =k
dt t
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10. (3) 12. (1)

2.303 100 t1/2 ∝ a1–n
K= log 1− n
t 100 − x 1− n
 
2.303 100 (t1/2 )1  a1   
50  a 
K= log =  →  = 
20 100 − 60 ….(i) (t1/2 )2  a 2   25   1 a 
2.303 100 2 
K= log (2) ⇒ (2)1–n
t 100 − 90 ….(ii)
∴n=0
2.303 100
K= log (2) = (2)1–0
20 40 → 1 log10 = 1 [log10 − log 4]
2.303 100 t 20
K= log
t 10 13. (2)
1 1 2.303 a
1  [1 − 0.6020] K= log ....(i)
t 20 10 1
a
t ⇒ 50 4
t = 50 minutes 2.303 a
K= log
11. (3) t 1
a
t1/2 ∝ a1–2 second order (n = 2) 16 …..(ii)
1 1
t1/2 
1 log16 = log 4
a t 10
1 1
log(4)2 = log 4
t 10
1 1
 2log 4 =  log 4
t 10
t = 20 minute

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