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CHE_Physical and Chemical Changes_CBS
CHE_Physical and Chemical Changes_CBS
No.
UNIT - 2
Page
No.
1.0 INTRODUCTION
2.0 PHYSICAL CHANGES
2.1 Introduction to Physical changes
2.2 Examples of physical changes
2.3 Characteristics of a physical change
3.0 REVERSIBLE AND NON-REVERSIBLE CHANGES
4.0 CHEMICAL CHANGES
4.1 Introduction to chemical changes
4.2 Examples of chemical changes
4.3 Determining whether a change is Physical or Chemical
5.0 RUSTING
5.1 Introduction to rusting
5.2 Conditions necessary for rusting
5.3 Prevention of Rusting
5.4 How Galvanised Iron is protected from rust?
6.0 CRYSTALLISATION
EXERCISE-1
EXERCISE-2
EXERCISE-3
DFGGFGF
Physical and Chemcial changes
1.0 INTRODUCTION
We know that nothing on this earth ever really disappears. It may be seen like snow disappears in
the sun, or the flames that wood makes vanish in a fire, but that is not what is happening. Snow
melts and becomes liquid which on evaporation turns into gas that rises into the atmosphere, and
burnt wood turns into ash and smoke.
Matter is never created or destroyed. It just changes form. All matter is made up of tiny molecules,
and when these molecules are changed or moved around, the matter changes its form.
When a change occurs in an object there may be some alteration in it. The alterations can be in the
form of shape, size, colour, physical state, position, chemical composition of the substances etc.,
For example changes in-
1. Shape- You can change the shape of a rubber ball by squeezing it.
2. Size- Increase in the number of cells which causes our body to grow.
3. Position- When you kick a football, it moves from its position.
4. Colour- If you heat a piece of iron, it becomes red hot.
5. Internal structure- When we cook food, the structure of the molecules change. Even burning
brings about changes in the molecules of fuel.
We classify these changes into two categories
Changes
Physical Chemical
So, a physical change is a temporary change in which the physical appearance of a substance
may change but its chemical composition remains unchanged.
In a physical change, the particles of a substance may move closer together or farther apart, or
they may mix with particles of other substances. However, no new kinds of particles are produced.
2.2 Examples of physical changes
a . Kicking a football- When you kick a football its position changes but remains a football. No
new substance is formed. The molecules that make up the football remain same.
b. Tearing of paper- On tearing, a paper changes its shape and size but it remains paper. No
new substance is formed. The molecules of paper remains the same. We can demonstrate it by
the following activity:-
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Class VII : Chemistr y
ACTIVE CHEMISTRY
Take a piece of paper and cut it into four pieces. Lay these pieces on the table so as to get the same
shape as they had it originally.
Same properties
are retained by
the paper
ACTIVE CHEMISTRY
Take few cubes of ice in a glass and keep it at room temperature. You will find that, the cubes of ice
melts to form water.
ACTIVE CHEMISTRY
Take some water in a porecelain dish and dissolve some common salt in it. The salt disappears in
water and forms a salt solution. So a change has taken place. Now, pour this solution in a china
dish and heat it for a long time till all the water evaporates. A white powder is left behind in the
porcelain dish. This is sodium chloride. This means that no new chemical substance has been
formed by dissolving common salt in water to make salt solution. Thus making of a solution is a
physical change.
e. Glowing up electric bulb and heating of heater is a physical change
When a electric current is passed through a bulb or a heater, the filament glows.
Filament of an electric bulb and heater glows when electric current is passed.
But once the electric supply is cut off the bulb glow and filament of heater stops to emit heat and
light. Thus, emitting of light by bulb is temporary and reversible.
f. Heating of metallic knife is a physical change
ACTIVE CHEMISTRY
Take an ordinary knife and heat the metallic part of the knife in flame till it becomes red hot.
ACTIVE CHEMISTRY
Take a pinch of zinc oxide in a flask and heat it. Zinc oxide is white in colour but when you heat it
white colour will get converted into yellow. On cooling, it will again converted into white colour.
Thus, we see that heating of zinc oxide is temporary and reversible.
+
Pass
Put in magnet
carbon
Iron Sulphur Mixture of iron
disulphide
and sulphur
When a stretched band is released, it regains its original shape, hence the change is physical
change.
Some other examples of physical change are:-
1. Formation of dew 2. Drying of wet clothes
3. Bending of glass tube 4. Crushing of iron
5. Melting of wax 6. Crystallisation of sugar
7. Beating aluminium to make aluminium foil 8. Cutting of nails
9. Condensation of steam 10. Making of soda water by dissolving carbon
dioxide
11. Rotation of fan 12. Breaking of a wooden stick
13. Cutting of log of wood into pieces 14. Formation of clouds
15. Conversion of chalk stick into chalk dust 16. Hammering of metals to form sheets
17. Stretching of metals to form wires 18. Change of seasons
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Physical and Chemcial changes
2.3 Characteristics of a physical change
1. A physical change is a temporary change and is generally reversible. For example
a. When water is heated, it converts into steam, if we condense the steam, it will again convert
into water.
b. Common salt can be easily recovered from its solution by evaporating the water.
2. In a physical change, no new substance is formed and the chemical composition
of the substance remains the same. For example:-
a. The conversion of chalk stick into small chalk particles is a physical change because both,
chalk stick and chalk dust are just the same substances, only their size is different.
b. When iodine is heated, it sublimes and changes directly from solid to gaseous state. During
this change, the physical state of iodine has changed but its chemical composition in both
the state is the same. Thus no new substance has formed.
3. Very little energy is either absorbed or evolved in physical changes. For example:-
a. When common salt is dissolved in water, the heat changes involved during the process are
not very large.
b. The addition of washing soda into water is a physical change. But the test tube in which it
takes place becomes slightly hot. Means it involves the evolution of energy but only to some
extent.
4. There is no change in the mass of the substance during a physical change. For
example:-
a. If 10 gm common salt is dissolved in water to form a salt solution then on evaporation of
water, 10 gm common salt will be left behind.
b. When a platinum wire is heated in a bunsen flame, it glows and becomes white hot. If it is
removed from the flame and cooled, it regains its original appearance. During this change,
the mass of platinum wire does not change.
c. The solid wax on heating melts to form the same amount of molten wax.
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Class VII : Chemistr y
2. In a physical change,
(A) State of matter can change (B) Colour of matter can change
(C) Both (A) and (B) (D) Composition of molecule can change
4. Shredding of paper is :
(A) reversible chemical change (B) reversible physical change
(C) irreversible chemical change (D) irreversible physical change
This is more than a change in shape or state. Most of the time, an entirely new kind of matter is
created.
Burning a piece of paper is also a chemical change. The basic substance of the paper is changed
into something new: smoke and ashes. These new substances have very different molecules than
the original piece of paper.
Chemical changes always involve the production of new substances. Most chemical changes are
difficult to reverse.
A chemical change is a permanent change in which the composition of the substance
changes giving rise to one or more new substances with different properties.
We all have seen our mother setting curd from milk in night and by the early morning we obtain
curd. This is a pure chemical change. Let us all try to understand chemical change through this
example :
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Physical and Chemcial changes
Conversion of milk into acid
to (Change
Milk Curd in state)
(Liquid) (Solid)
Thus, conversion of milk to curd is an example of chemical change because new substances are
formed which have different composition and properties. The change is permanent and irrevers-
ible. The products formed are entirely different from the initial substance.
Another example, which can be studied to understand the nature of chemical change is rusting of
iron.
Rusting of iron
Thus, we see that iron gets a coating of oxide on its surface due to which it lose its lusture, change
in compositon is observed and the change is permanent and irreversible.
1. Burning of fuels
a. Coal burns to produce ash and smoke, entirely new substances whose properties are quite
different from those of coal. Let us demonstrate it with the help of following activity:-
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Class VII : Chemistr y
ACTIVE CHEMISTRY
Take a small piece of coal and ignite it. You will see that coal burns with golden yellow flame leaving
behind some ash.
C + O2 CO 2
Coal Oxygen Carbon dioxide
(solid) (from air) (gas)
We observe that the change is permanent and irreversible. At the end the mass of coal decreases. It
is accompanied by heat and light. From coal (C) which is a solid we obtain a new gaseous product
(CO2) which have entirely different properties and hence, burning of coal is a chemical change.
b. LPG (Liquified Petroleum Gas) is commonly used as a fuel for cooking. It burns with a blue
flame to produce carbon dioxide and water vapour which are entirely new substances. LPG
cannot be obtained back from carbon dioxide and water vapour.
c. Natural gas consists of mainly methane. It is used as a fuel for cooking, for running automo-
biles and in industry. It burns with a blue flame to form carbon dioxide and water vapour.
These are entirely new substances and cannot be converted back into natural gas.
2. Burning of magnesium ribbon
ACTIVE CHEMISTRY
Take a thin strip of magnesium ribbon. Clean its tip with sand paper and ignite it with the help of
candle flame. Magnesium ribbon burns with dazzling white light. When it is completely burnt, it
leaves a white coloured solid residue behind, which is also known as ash.
2Mg + O2 ¾® 2MgO
Magnesium Oxygen Magnesium oxide
(Metal) (from air) (ash)
As we see that burning of magnesium ribbon results in the formation of a compound whose
composition and properties are entirely different from the magnesium metal, along with heat and
light. This change is permanent and irreversible and hence, a chemical change.
ACTIVE CHEMISTRY
Take magnesium ribbon and burn it some white coloured ash is produced
2Mg + O2 ¾® 2MgO
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Burning of magnesium
Now, collect the ash and mix it with small amount of water. Stir the mixture well.
MgO + H2O ¾® Mg(OH)2
Magnesium oxide Water Magnesium hydroxide
The nature of the above solution can be tested by using litmus as an indicator. When litmus
solution is added to magnesium hydroxide solution
8
Physical and Chemcial changes
Mg(OH)2 + litmus solution ¾® Solution turns blue
Thus, it is observed that a new substance is formed with evolution of energy. On dissolving it in
water we get another compound with entirely different properties. The change is permanent and
irreversible and hence, we conclude that, burning of magnesium is a chemical change.
3. Reaction of Iron and Sulphur
ACTIVE CHEMISTRY
Take some iron filings and small amount of sulphur powder. Mix it thoroughly so that we get a
mixture of iron and sulphur. It represents a physical change. Now heat this mixture strongly over the
flame. Iron and sulphur combine chemically in fixed proportion to form iron sulphide. At the high
temperature, iron reacts with sulphur to form iron sulphide.(FeS)
Reaction
Fe + S ¾® FeS
Iron Sulphur Iron sulphide
This reaction results in the formation of new compound that is iron sulphide. It is entirely different
from original substances. This compound is not attracted by magnet nor it dissolves in sulphur. The
change is irreversible and permanent.
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5. Mixture of vinegar and baking soda
ACTIVE CHEMISTRY
Take small volume of vinegar in test tube and add a pinch of baking soda to it. Brisk effervescence
will be observed with evolution of a gas. When this gas is passed through lime water, it turns milky.
Green colour
water and carbon dioxide, which react to form sugar and oxygen. When we eat these
plants and inhale oxygen from the air, the sugar and oxygen react in our cells to produce
water, carbon dioxide, and energy. From this reaction the energy generated is used for
our daily activities.
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Physical and Chemcial changes
A new colour Heat, light or sound Bubbles of gas A solid material The change is
appears is given off are formed. A (called as precipitate) difficult or impossible
(or absorbed) new odour may forms in a liquid. to reverse
be noticed.
Evidences of a chemical change.
Illustration 3. Look at the following figures and classify them as physical and chemical changes.
(i) (ii)
(iii) (iv)
(v) (vi)
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Class VII : Chemistr y
5.0 RUSTING
5.1 Introduction
As we all know that the eating up of metals by the action of air, moisture or a chemical (such as an
acid) on their surface is called corrosion. So when most of the metals corrode, it is called corrosion
but when iron corrode, it is called rusting.
Iron is one metal which is used extensively in making buildings, bridges, rails, machinery and host
of other articles. However, the problem with iron is that, when it comes in contact with moist air, it
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slowly reacts with oxygen to form ferric oxide and ferric hydroxide, a brown powdery substance,
commonly called rust. The rust is flaky, non-sticky in nature and hence, easily crumbles from the
surface of metal. Thus, fresh iron is exposed for attack of moist air to form more rust. The rust not
only corrodes iron, but weakens the iron structures, thereby causing great economic loss. So rusting
can be defined as-
Rusting — The slow conversion of iron into its hydrated ferric oxide in the presence of moisture
and air is called rusting.
Rust — The flaky, non-sticking brown powder formed on the surface of iron, when the iron is
exposed to the moist air is called rust.
Rust is soft and porous, and it gradually falls off from the surface of iron object, and then the iron
below starts corroding.
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Physical and Chemcial changes
During the rusting of iron, iron metal combines with the oxygen of air in the presence of water to
form hydrated iron (III) oxide, Fe2O3.xH2O. This hydrated iron (III) oxide is called rust. So, rust is
mainly hydrated iron (III) oxide, Fe2O3.xH2O (the number of molecules of water x varies, it is not
fixed). Rusting of iron can be shown by the following reaction–
2 Fe (s) + 3 O2 (g) + x H2O (l) Fe2O3 .xH2O- (s)
2
Iron from air Moisture hydrated ferric
oxide (Rust)
5.2 Conditions necessary for rusting
Rusting of iron (or corrosion of iron) needs both, air and water. Thus, two conditions are necessary
for the rusting of iron to takes place :
(i) Presence of air (or oxygen) (ii) Presence of water (or moisture)
We know that iron rusts when placed in water. Now, damp air (or moist air) also contains water
vapour. Thus, damp air alone supplies both the things, air and water, required for the rusting of
iron. Again, ordinary water has always some air dissolved in it. So, ordinary water alone also
supplies both the things, air and water, needed for rusting. We will now describe an experiment to
show that air and water together are necessary for the rusting of iron.
5.3 Prevention of Rusting
The rusting of iron can be prevented, if moist air is not allowed to come in contact with its surface.
Following methods are employed in the prevention of rusting :
(1) By coating with red lead oxide paint (Pb3O4) or Tar : The underside of the ships,
bridges, electric poles, etc., is coated with tar or red lead oxide paint, which does not allow the
moist air to come in contact with iron. Thus, rusting is prevented. It is a fairly inexpensive
method and is widely used.
(2) By painting : Articles, such as iron doors, windows, bodies of buses, cars, motorcycles, etc.,
are first given a coating of red lead oxide, followed by a coat of paint of desired colour. This
effectively cuts out the moist air and prevents rusting.
(3) By enamelling : Enamelling is the process of baking a mixture of silicates on the surface of
iron at high temperature. Articles, such as bodies of cooking stoves, refrigerators, cups, plates,
wash basins, etc., are enamelled.
(4) By oil and grease : Moving parts of machines cannot be given a protective layer, because it
wears off quickly. These moving parts of the machines are protected from rusting by coating
them with a thin layer of oil or grease, which not only prevents them from rusting but also
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lubricates them.
(5) Plastic coating : Iron furniture and fixtures are given a thin coating of plastic, which cuts off
the moist air and prevents rusting.
(6) By galvanising : In this process iron sheets are dipped in the molten zinc and then passed
through heavy rollers, when zinc metal forms a protective layer over iron. The galvanised iron
is extensively used in making roofs of sheds, buckets, tubes, iron trunks and suit cases.
(7) By tinning : In this process iron sheets are dipped in molten tin and then passed through hot
and heavy rollers, when tin forms a protective layer over iron. Tinned iron sheets are extensively
used for making containers for edible substances, such as fruits, vegetables, meat, etc.
(8) By coating with chromium or nickel electrolytically : This method is highly expensive,
but gives a very bright finish. Chromium or nickel are deposited on iron articles by electroplating.
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Class VII : Chemistr y
Articles such as, bicycle handles, rims, bumpers of the cars, etc., are coated with nickel or
chromium.
(9) By converting iron into stainless steel : When 12% to 20% chromium is incorporated in
iron with 0.1% to 0.7% of carbon, it develops a special property due to which it does not rust
in the moist air, Such a sample of iron is called stainless steel. Stainless steel is used for making
surgical instruments, kitchen utensils, cutlery, tools, etc.
(10) Anodising of aluminium : A layer of aluminium oxide is formed on aluminium upon
exposure to air. This prevents corrosion of aluminium. This is done by the process of Anodising.
It consists of passing an electric current through sulphuric acid using aluminium as anode.
Oxygen is evolved at the anode which reacts with aluminium to form a protective layer of
aluminium oxide.
5.4 How Galvanised Iron is protected from rust ?
Zinc is more active metal than iron in electrochemical series. Thus, in case of oxidation, the zinc
will get oxidised first. The rusting of iron is prevented because.
(i) Zinc will get oxidised first. Thus, as long as zinc is present, rusting of iron is not possible.
(ii) The zinc combines with oxygen to from zinc oxide, which is highly sticky in nature. Thus it
forms impervious layer over the zinc metal and prevents its corrosion and in turn the rusting of
iron.
6.0 CRYSTALLISATION
Sea water contains large amount of dissolved salts. Since, the concentration of these salts is very
high, the sea water can simply be evaporated to produce crystals of sodium chloride (i.e., common
salt). But the crystals obtained in this manner are not pure, small in size and cannot be seen clearly.
In order to obtain large crystals of pure substances, the solution has to be concentrated and then
cooled. This type of crystallisation will yield prominent crystals.
"The process of obtaining large crystals of pure substance from a concentrated solu-
tion is known as crystallisation."
Amorphous substance : Those substances which are powdery and possess no definite geo-
metrical shape are known as amorphous substances.
Example : Talcum powder.
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Cystalline substance : Substances which possess definite geometrical shape are known as
crystalline substances.
Example : Sodium chloride crystals.
ACTIVE CHEMISTRY
Aim-To obtain crystals of copper sulphate
Take 100 mL of water in a beaker and add few drops of dilute sulphuric acid to it. Heat the beaker.
When the water starts to boil, add copper sulphate powder. Keep on adding copper sulphate pow-
der until no more salt (CuSO4) dissolves in it. Filter the warm solution to remove any unwanted
impurity present. Now, keep the filtered solution in a water bath containing ice. Do not disturb the
solution. Beautiful blue crystals will be formed at the base of beaker.
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Physical and Chemcial changes
3. The process that takes place when a supersaturated solution of urea is cooled is called –
(A) Evaporation (B) Crystallisation (C) Condensation (D) None
4. The formula of blue crystals of Copper sulphate (Blue vitriol or neela thotha)
(A) CuSO4.7H2O (B) CuSO4.5H2O (C) CuSO4.3H2O (D) CuSO4
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l "Water changes to crystals of varying shapes and sizes depending on the temperature."
l Crystals are the purest solid form of a substance having a definite geometrical shape.
l A chemical change occurs when two chemical substances interact to produce a new substance (or
substances) with a different set of properties.
l The clues may suggest that a new substance has been produced, but any one of them could also
accompany a physical change. So it is always better to consider several clues in order to determine
what type of change has taken place.
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Class VII : Chemistr y
8. When carbon dioxide is passed through lime water, then lime water becomes :
(A) Milky (B) Shiny (C) Silvery (D) Golden yellow
9. Photosynthesis is
(A) Chemical change (B) Physical change
(C) Both physical and chemical (D) None of the above
10. Anaerobic bacteria digest animal waste and produce biogas (change A). The biogas is then burnt
as fuel (change B). The following statements certain to these changes. Choose the correct one.
(A) Process B is a chemical change. (B) Process A is a chemical change.
(C) Both A and B are chemical changes. (D) Both A and B are physical changes.
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Physical and Chemcial changes
3. What method will you use to get a pure liquid if it has dissolved impurities present in it?
6. When water is frozen, it forms ice that has different properties. Why then do we say that freezing
is a physical change?
7. Define crystallization. How can the crystals of sodium chloride be prepared from table salt?
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Class VII : Chemistr y
5. Burning of paper.
True or false
1. Chemical changes are usually irreversible
3. During a physical change, only the physical properties of the substance undergo a change.
18
Physical and Chemcial changes
ANSWERS
CHECK POST-1
1. (A) 2. (C) 3. (A) 4. (D) 5.(D)
CHECK POST-2
1. (B) 2. (A) 3. (B) 4. (D) 5.(A)
CHECK POST-3
1. (C) 2. (D) 3.(B) 4.(B)
EXERCISE - 1
Que. 1 2 3 4 5 6 7 8 9 10
Ans. D A A C B C A A A C
EXERCISE - 3
*****
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IMPORTANT NOTES
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