Not To Be Discussed in Class

CHO COOH
(CHOH)4 
Br2 / H 2 O
 (CHOH)4 (Gluconic acid)
CH2OH CH2OH

CHO CH2OH
(CHOH)4 
NaBH 4
 (CHOH)4 (Sorbitol)
CH2OH CH2OH

CHO OH
H OCH3
(CHOH)4
CH2OH 
 (CHOH)4
Glucose CH2OH
(Methyl glycoside)

1
 CHO
CH2
CHOH

HIO4

CHOH excess

CH2OH

O
H—C—CH2—CHO

CHO
CH2
CHO
CHOH
CH2

2HIO 4

CHOH
CHO
CH2OH

2
 
 


OH H OH
OH
O O O O O
O O
HO HO
OH OH H OH
H
Cellulose

CH2OH

H H HOH2C O H
H 1 2
OH H H HO
OH CH2OH
O
H OH OH H
D-Glucose D-Fructose



 

 
 
 
 

3
 



 
 

CH2SH
CH2CH2COOH
NH3—CH—C—NH—CH—C—O
O O
Glu-Cys

CH2SH
NH3—CH—C—NH—CH2—C—O
O O
Cys-Gly

4
 
H



5
 z

 


 

forms i.e., a form in which the OH at C

  

 







  

6
  


 






CH 3 C C CH3 CH 3 CH C C CH3
CH3
CH 3 CH2 CH CH2

Na metal
Positive

FeCl3 (neutral)
A(C7H8O) Negative

Lucas reagent
Positive
Anhydrous ZnCl2/HCl

OH
CH2 – OH OCH3 OH
CH3

CH3





7
 NO3

aq. NaHCO 3 aq. NaOH aq. HCl H2 O aq. NaHCO 3 aq. HCl
               
aq. HCl aq. NaHCO aq. NaOH aq. NaOH aq. NaHCO aq. HCl
     
3
          
3
  

8
 O
C Cl NMe2

COOH
COOH

CH3




9
 



10
C C C
C C  C O  CH3—C—ONa + CHI3
C C C O
(A) (B) (C)

(CH 2  C  CH  CH 2 
)n
|
Cl
H H O O
| | || ||
( N  (CH 2 ) 6  N  C  (CH 2 ) 4  C)n
Cl
|
(CH 2  CH ) n
OH OH

11
 




CaC 2  2H 2 O 
 Ca(OH) 2  C 2 H 2
Pd  BaSO 4
HC  CH  H 2   CH 2  CH 2
nCH 2  CH 2 
 —(CH 2  CH 2 )—
n
Polythene


   

12
If neither NH

  

 
 
 
        

13
  

 

14
On electrolysis in acidic solution, 

  

15
 

16
 









17
 NOH


 




O
O

18
 

 




19