h campounda sasme moaculas

ohmsula but dilfoant Jhystal lmd Chemmical prgelus

on accaut o dterentshuctres th spatial
aangemimti anecalled isomers and the
phenamenon s isomerism.

ISoMERISM CooRDINATiON CoMPOUNDS

Athucthal isomeism Sreoisbmehian
Soomeism Saomehism
enisation selnte Codination Lmkage alynghisaien
Shomerim

Cosdnaten peaton
GTRUCTUREL ISOMAERI5M
Oenusatin sewgrisn
his arises chen the
Lompaunda selution
hre e 2 ismes t the Compêumda
haing Co (NH)s By so4 + SO;
gves ht
olet)
Bi
(Red) gves pale
 Pece

2Selvate Saonsehisna
alae

Nhis ahises 2hin diteLnt neabeh

tl aaler moleculesane ohesimt inide
andGutaide the coAhlination shere
heeahe 3 isomehA the

t ha 3onisable hlarieLons.

he salen molaculesesent aetsiole the

coBhdinatia sphere cam liadly dast.

his the Cahdination

Kêmpeasno CATIONIC and
ANION IC COMPY EXona and the
ahe someA

ohaaammine plalinua() Jehaanminecogper (TL)

Jethachlahidecuphate () Aolhack lonideplatinate ()

Btexaamainechhomiwaa (m)
thioaalatocobaltate (m) thionalatochimate (m
 (sCN)
Netnaameninedithuityanatochhemiana (m) calmmineteha
kiotyamatocksoate ()
semehsm
Lasing ambidentate ligands dke NO,
sc CN S,0ele. hse Lgans kane
atoms bt at atame onl aton
dihectly dmked to she senhel malal atan.

fentaaminenibito -N-Cebalt m) Pentaamminentite-0

chlehidle Cobat n) chlobiale
yellau) (red)

Lipghidykdlhutcynato-N
palasi )

stenchuomehc
componitens
 ase
multyoles ef the limpleststnckaomelic.
asanqimlet.

are

Maomehusm
hissomeriom echikited

tnttalattns
hesot the cemplex
72+

NH), Co

Bothte chlohe ligands Are aih

lobalt Ýn
NH,

linked 2sit
aball aonA
 TERE D IGoAERIAM
husaises hen the cohdinatin Cemplana
contain the sane liganda wnthe cotbdinaton
but aiter
gphenes but the hat these
Jpace
iyanda aeahamgcd
Taiaasises due te

anethe
<a) TE TRAHEDRAL and LINEAR
and LiNEAR copleaes e
net ht giorelhical usemehus

<b) SsuARE 4Remplexes hang genehal

fiamula Maaand Ma_b]"
net shen geometucal weomesna

[Magb b
M M

Ma,be 2 b.
CM M

Cis

M.
 Date
fecc

quase glanas censgloxea hasnf tnsgmtiky

cal budedale ganda
CH- NH NH,CH
Pt

Pt
CH, - NH,
c) Oe TAHEDRAL complenes.
fohanuda fMaand Magb do et
qeemetical csomerisna

Mayb]la M
a

b
Cis thans

[Ma, ba' a b M
M

thans
 [M abcolig hae 15

NHa

3+ lo

meh
fac
3 33 bigands ahangcd
all eis faahion die
the
on
fais,ie
theane
ctahedon mesdiam 0ahedhen

[Masbs}
octahedhal emplex ahe Gpicalyiaackine

Ctshdnaton Complund stbck

relatehe plane e palaaud light s called
acive
he mtleculea
which oN- SUPERMPOSABLE ibheh
each oten.
ratades to
palanisud the
dinecton
lasontatay fam)
 Date
Paçe

hetatest

enaieaeh

Enaniomea
anothes
alesent.
Dhtical hbmehisniia CKpected in tete

tpical
folemas Conmsleaesnlacceunt

seneism
Rtahsdral complees. tothhedal compleaes which
2+

24

PE PL

NH, NHSi
NHla NH,

lis l-isemer
 Mabedef]
Bh Br

PE PA
NH¡ H,N

IM (AA),I [olen),]3 3+

en

M(AA), a, +

cisd-isome -isomer
net
aha hticel someism
2+
MAA, ob! 2+

Ce
NH
is d-isomeh
 Date
Fece

ahe
mohe eammples

hlokudal
Dotahuthal conspleas,
edta,
hexedentate
etiylene
diamintethaacetatotobaltate ( ) alse
Bplcaly active.

) plana canplex
a 4 b)
6) 2 e) 3

22 qemetucal
BA Ba
CPd SCN
SCN

2 SCN w
ankideutate
B
NCS SCN Bh