LT-2025(IIT-WORK BOOK) Part-I-CHEMISTRY

CHAPTER - 02
STRUCTURE OF ATOM

hc
1. 3 EN

N  6.626 1034  3108
10 10 
1000 1010

2. 2

hc
Ne
3. 2 E emitted c N  53 4530
  e a    47%
E absorbed hc N a  e 100 5080
Na
a

4. 2

5. 3

6. 4
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7. 2

8. 3

9. 3

10. 3 hv = hv0 + KE
11. 1 Ice energy available for 2 atoms of A = 4.4 × 10–19 – 4×10–19

4  1020
 KE for an atom =  2  10 20
2
12. 2
13. 2
14. 1
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15. 4

16. 4

17. 1

18. 4

19. 1

1 1
20. 3   R H z2  2  2 
 n1 n2 

1 1 
R H 12  2  2 
H  C  1 4   3
 H  H 
21. 4  Li2 Li2 C Li2 1 1 4
R H 32  2  2 
2 3 

22. 4
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 1 1 
23. 2   R Hz2  2  2  ; n1  2
 n1 n 2 
1 1 
  109678 12  2  2  ; n 2  
2  
1



hc 6.626 1034  3 103

24. 3 E= =  8.211019 Js
 242 109
For 1 mole  8.21 × 10–19 × 6 × 1023 = 495 kJ

 1 1 
25. 2   R H Z2  2  2  n1  1, n 2  4, Z  2
 n1 n 2 
 1 1
  RH  4 2  
1 4 
15 4
  RH;  
4 15R H

26. 2
27. 3

28. 2

29. 3
 LT-2025(IIT-WORK BOOK) Part-I-CHEMISTRY

30. 1

31. 3

r0 n 2
32. 2 r  r1 : r2 : r3  1: 4 : 9
z

33. 3
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z2
34. 3 Ionisation energy 
n2

32
IE Li2 2 9
 12 
IE Be3 4 16
2
1

35. 1
36. 1
37. 1

38. 3

n2 12
39. 4 r  0.529  ; r1  0.529   a 0
z 1
Third excited state n  4
42
r4  0.529   16a 0
1
2r  n
2r 216a 0
   8a 0
n 4

40. 4 E  h
E 495.5 103
 
h 6 1023  6.626  1034
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41. 1

42. 1

43. 3
 LT-2025(IIT-WORK BOOK) Part-I-CHEMISTRY

44. 2

45. 3

46. 4

47. 3
48. 3

49. 4

50. 1
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51. 2

52. 4 n, l, m  were the results of solution of schrodinger equation

53. 2
54. 4 For sodium electronic configuration 1s2 2s2 2p6 3s1
55. 2
56. 4 Orientations of subshell refers to orbitals which are denoted by magnetic quantum number (2l
+1)
57. 2
58. 4 Total number of electron in a shell = 2n2 = 2 × 32 = 18
59. 2
60. 4
61. 4
62. 1
63. 4
64. 1
65. 2 Spherical node or radial node = n – l – 1
Angular node or nodal plane = l
66. 3
67. 3
68. 4
69. 1
70. 2
71. 3 If there are three values for s, 1s3 2s3 2p93s33p1 ie; p - block

72. 1

73. 1
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74. 2

75. 1

76. 3

77. 4
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78. 2

79. 1
80. 2
81. 2
82. 3
83. 1
84. 2
85. 3
86. 2
87. 4
88. 4
89. 1
90. 2
91. 2
92. 1
93. 1

94. 1
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95. 1
96. 2
97. 3
98. 3