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Based on

CF + OYM AIATS-05

Corporate Office: Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.011-47623456

CONCEPT STRENGTHENING SHEET


CSS-05
CHEMISTRY
AIATS-05 (CF + OYM)-Q.80 (3) A qualitative measure of the stability of an
ionic compound is provided by its enthalpy
Topic: Covalent Character in Ionic Bond - Fajan’s
of lattice formation
Rule
(4) Lattice enthalpy can be calculated from the
Which of the following compound has maximum interaction of forces of attraction and
lattice energy? repulsion only
(1) MgF2 (2) CaF2 AIATS-05 (CF + OYM)-Q.54
(3) SrF2 (4) BaF2 Topic: Molar Mass
Total number of valence electrons present in
3.2 g of O2– ion is (NA is the Avogadro’s number)
(1) 1.6 NA (2) 16 NA
(3) 2 NA (4) 0.8 NA

Practice Questions:
1. Consider the following statements
Statement-I: Lattice enthalpy of an ionic solid is
the energy required to completely separate its
one gram into gaseous constituents. Practice Questions
Statement II: As the size of ions increases, the 1. Total number of nucleons in 1.6 g of oxygen gas
lattice energy decreases. is
In the light of above statements, select the (1) 1.6 NA
correct option.
(2) 3.2 NA
(1) Both the statements are correct
(3) 8 NA
(2) Both the statements are incorrect
(4) 4 NA
(3) Only statement I is correct
2. Total number of protons present in 1.8 g of
(4) Only statement II is correct water molecules is
2. Which of the given compounds has the highest (1) 0.1 NA
value of lattice enthalpy? (2) NA
(1) NaI (3) 2 NA
(2) NaBr (4) 10 NA
(3) NaCl 3. Volume of 3.01 × 1023 molecules of methane at
(4) NaF STP will be
3. Choose the incorrect statement. (1) 22.4 L
(1) Arrangement of cation and anion in the (2) 11.2 L
crystalline solid forms the crystal lattice (3) 33.6 L
(2) Crystal structure gets stablilized due to the (4) 2.25 L
energy released in the formation of crystal
lattice

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CSS-05 Chemistry

AIATS-05 (CF + OYM)-Q.76


Topic: Bond Length
In the given species the correct order of C – O
bond length is
2
(1) CO  CO2  CO3
2
(2) CO3  CO  CO2
2
(3) CO3  CO2  CO Practice Questions
2 1. Identify the number p-p and p-d bonds
(4) CO2  CO  CO3
respectively in SO3
(1) 2 and 1
(2) 1 and 2
(3) 3 and 0
(4) 2 and 0
2. Which among the following species consists of
only  bond(s)?
Practice Questions C2, N2, CO2 and B2
1. The compound with longest H-X bond (1) N2 and B2
(1) HI (2) HCl (2) C2 and CO2
(3) HBr (4) HF (3) CO2 and N2
2. Choose the incorrect statement. (4) C2 and B2
(1) Less the bond order, longer would be the 3. Given below are two statements.
bond length Statement I: XeF4 and [Ni(CN)4]2- are
(2) Average bond order of P-O bond in PO is 3– isostructural.
4

1.25 Statement II: The 'd' orbital involved in sp3d


hybridisation is dz2.
(3) Average bond order of S-O bond in SO2–
4 is
In the light of above statements, select the
more than that in SO2
correct option.
(4) C-O bond length is more in CO2 molecule
(1) Both the statements are correct
as compared to CO molecule
(2) Both the statements are incorrect
3. The correct order of bond length is
(3) Only statement I is correct
(1) C=O > N=O > C=C
(4) Only statement II is correct
(2) C=O > C=C > N=O
(3) N=O > C=C > C=O AIATS-05 (CF + OYM)-Q.84

(4) C=C > N=O > C=O Topic: Bond length


AIATS-05 (CF + OYM)-Q.82 Arrange the following bonds according to their
average bond length in increasing order.
Topic: The Valence Shell Electron Pair Repulsion
(1) C–O < N–O < C–H < O–H
(VSEPR) Theory
(2) O–H < C–H < C–O < N–O
Consider the following statements.
(3) O–H < C–H < N–O < C–O
a. The total number of p-d bonds in SO3 is
2. (4) C–H < O–H < N–O < C–O
b. XeF2 and C2H2 are isostructural.
c. B2 has only  bond.
d. In sp3d2 hybridisation, the d-orbitals involved
in hybridization are d z2 and d x 2  y 2 .

The correct statements are


(1) a and b only (2) b and d only
(3) a, c and d only (4) a, b, c and d

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CSS-05 Chemistry

Practice Questions AIATS-05 (CF + OYM)-Q.56


1. Arrange the following bonds according to their Topic: Mole Fraction
average bond length in increasing order Mole fraction of solvent in a 5 molal aqueous
(1) O–H < C–H < C–C < C–N solution of urea is nearly
(2) C–C < C–N < C–H < O–H (1) 0.01 (2) 0.09
(3) O–H < C–H < C–N < C–C (3) 0.1 (4) 0.9
(4) C–H < O–H < C–N < C–C
2. The correct order of bond angles in the following
species is

(1) C2H2 < NH4 < NH3 < H2O

(2) H2O < NH3 < NH4 < C2H2

(3) NH3 < H2O < NH4 < C2H2
Practice Questions

(4) NH3 < H2O < C2H2 < NH4 1. Mole fraction of solvent in a 7 molal aqueous
solution of urea is nearly
3. Which of the following molecules has the
(1) 0.01 (2) 0.1
maximum dipole moment?
(3) 0.09 (4) 0.9
(1) CO2
2 Mole fraction of solute in aqueous solution of
(2) BF3 40%. NaOH is
(3) NF3 (1) 0.23 (2) 0.65
(4) NH3 (3) 0.43 (4) 0.09
3. The molarity of NaNO3 is 2M. The density of
solution is 1.25 g/ml. Calculate molality of
solution. (Molar mass of NaNO3 = 85 g)
(1) 0.85 (2) 1.85
(3) 0.4 (4) 0.04

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CSS-05 Chemistry

Based on
AIATS-05 (CF + OYM)

Corporate Office: Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.011-47623456

CONCEPT STRENGTHENING SHEET


CSS-05 (CHEMISTRY)
Answer Key

AIATS-05 (CF + OYM)-Q.80 Topic: The Valence Shell Electron Pair Repulsion
Topic: Covalent Character in Ionic Bond - Fajan’s (VSEPR) Theory
Rule 1. (2)
1. (4) 2. (4)
2. (4) 3. (1)
3. (4) AIATS-05 (CF + OYM)-Q.84
AIATS-05 (CF + OYM)-Q.54 Topic: Bond Length
Topic: Molar Mass 1. (3)
1. (1) 2. (2)
2. (2) 3. (4)
3. (2) AIATS-05 (CF + OYM)-Q.56
AIATS-05 (CF + OYM)-Q.76 Topic: Mole Fraction
Topic: Bond Length 1. (4)
1. (1) 2. (1)
2. (3) 3. (2)
3. (4)
AIATS-05 (CF + OYM)-Q.82

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