HIGHER SECONDARY MODEL EXAMINATION 2010 PART.

III CHEMISTRY Maximum : 60 Scores

HSE(I) Time : 2hours Cool off time : 15 minutes

1. Molarity of solution is the number of moles of solute in 1 litre of solution a) Calculate the molarity of NaOH in the solution prepared by dissolving its 4g in enough water to form 250ml of the solution? b) Define molality? 2. Dual nature of matter was proposed by de-Broglie a) Calculate the de-Broglie wavelength of a ball of mass 0.1kg moving with a velocity of 10m/s? b) Two students wrote the quantum number of 4s electrom as follows Student I n=4 l=1 m=0 s=+1/2 Student II n=4 l=0 m=0 s=+1/2 Whose representation is correct? Justify? c) State Paulis exclusion principle and Hunds rule of maximum multiplicity? 3. Ionization enthalpy is the energy required to remove the most loosely bound electron from an atom. a) First ionization enthalpy of Boron is slightly less than that of Be. Why? b) who introduced the periodic law of elements for the first time? State the law? 4. The geometry and bond angles of molecules are obtained by hybridisation. a) Fill in the blanks Molecule PCl5 BF3 BeF2 Hybridisation --SP Shape -Trigonal Planar -Bond angle 1200, 900 ---

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b) Compare the relative stability of the following O2- , O2 + 5. a) The boiling point of a liquid is not a constant but it varies with the external pressure. Due you agree with this? Justify? b) Mercury drops are spherical in shape which property is responsible for the spherical shape of drops? c) In liquid H2 there will be some weak interaction between H molecules. 2 Name the type of interaction?

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6. a) r G = rr H - T S. Name the equation and write down the parameters? b) The entropy change when 1mole of solid AB melts at its normal melting point is 36.6J/K/mol. The enthalpy of fusion of AB is 7.32KJ/mol. Calculate the melting point of AB? 7. The equilibrium constant of a reversible reaction in terms of concentration and pressure are called Kc & Kp respectively. a) Give an example for an equilibrium where Kp = Kc b) Define common ion effect and solubility product? c) The value of r G0 for the phosphorylation of glucose in glycolysis is 13.8KJ/mol. Find the value of Kc at 298K?

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8. a) HNO3 acts only as oxidant where as acts both as an oxidant and reductant. Why? (2) 2 HNO b) Fe + CuSO FeSO4 + Cu 4 Which one is oxidised and which one is reduced? (1) 9. a) H2O2 is stored in wax lined glass or plastic vessels in dark. Why it is not stored in glass vessels? b) What is calgon? What is its use? c) Name one compound each in which hydrogen exists in i) Positive oxidation state ii) Negative oxidation state 10. a) How will you prepare slaked lime and Calcium Carbonate from quick lime? b) What is the purpose of adding gypsum in the manufacture of cement? c) Complete the following reactions i) CaCO3 + H2 SO4 r ii) 2NaHCO3 11. a) Match the following 1. Silicon Carbide Gold 2. Haber process paramagnetic 3. Ozone Fullerenes 4. Aquaregia Diamond structure 5. Carbon Diamagnetic 6. Oxygen Ammonia b) Diborane react wth ammonia to form inorganic benzene. Write the balanced chemical equation? 12. a) Write the type of hybridisation of each carbon in the compound CH3-CH=CH-CN b) Explain the chemistry of Lassaignes test for the detection of nitrogen in an organic compoud?

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c) Write the IUPAC names of the following compounds i)CH3-CH(CH3 )-CH2 -CH(C2H5)-CH2-CH3 ii) CH3 CH(OH)CH2 CH2 CH2 COOH 13. a) Sodium metal react with bromoethane in dry ether to form higher alkane. Name the reaction and write the product? b) Complete the reaction CH -CH=CH + HBr C H (CO) O6 5 2 2 3 2 c) Identify cis and trans isomer H C=C CH3 H (a) CH CH3 C=C H (b) CH3 H

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d) How would you carryout the following conversions i) CH3-CH2 -CH=CH2 CH3-CH2-CH(OH)-CH2(OH) ii) CH3-CH CH CH3COCH3 14. a) Write a short note on i) Global warming ii) Greenhouse Effect b) Explain the formation of photochemical smog?

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