Materials_MSDSGold_MSDSVendors_2024_May_07_11-22-33-826_AM2

UNICOOL R-449A
Wilhelmsen Ships Service AS

Part Number: 905748 Issue Date: 29/03/2023
Version No: 3.5 Print Date: 07/05/2024
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) L.REACH.NOR.EN
SECTION 1 Identification of the substance / mixture and of the company / undertaking
1.1. Product Identifier

Product name UNICOOL R-449A
Chemical Name Not Applicable
Synonyms 905744; 905748; R-449A

REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 (contains pentafluoroethane, difluoromethane,
Proper shipping name
1,1,1,2-tetrafluoroethane and 2,3,3,3-tetrafluoropropene)
Chemical formula Not Applicable

Other means of
905748, 905744, 905784, 905794
identification
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Refrigeration
Uses advised against No specific uses advised against are identified.
1.3. Details of the manufacturer or supplier of the safety data sheet

Outback (M)SDS portal:
Wilhelmsen Ships Service AS*
Registered company name Wilhelmsen Ships Service AS http://jr.chemwatch.net/outb/account/autologin?
Central Warehouse
login=wilhelmsen
--------Use our Outback portal to obtain our

(M)SDSs in other languages and/or format.---------
Strandveien 20 Lysaker 1366 Willem Barentszstraat 50
Address For questions relating to our SDSs please use
Norway Rotterdam Netherlands
Email: WSS.GLOBAL.SDSINFO@wilhelmsen.com
--------- Norway
Telephone +47 67 58 40 00 Not Available +31 10 4877 777

Fax Not Available Not Available Not Available
Website http://www.wilhelmsen.com/ http://www.wilhelmsen.com http://www.wilhelmsen.com
Email wss.norway.cs@wilhelmsen.com wss.global.sdsinfo@wilhelmsen.com wss.rotterdam@wilhelmsen.com
1.4. Emergency telephone number

Association / Organisation Giftinformasjonssentralen - 24 timer 24hrs - Chemwatch Dutch nat. poison centre
Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers
Association / Organisation CHEMWATCH EMERGENCY RESPONSE (24/7)
Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
Part Number: 905748 Page 2 of 17 Issue Date: 29/03/2023
UNICOOL R-449A
Once connected and if the message is not in your preferred language then please dial 01
SECTION 2 Hazards identification
2.1. Classification of the substance or mixture
Considered a hazardous mixture according to Reg. (EC) No 1272/2008 and their amendments. Classified as Dangerous Goods for transport
purposes.
Classification according to
regulation (EC) No
1272/2008 [CLP] and H280 - Gases Under Pressure (Liquefied Gas), H315 - Skin Corrosion/Irritation Category 2
amendments [1]
Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI
2.2. Label elements
Hazard pictogram(s)
Signal word Warning
Hazard statement(s)
H280 Contains gas under pressure; may explode if heated.
H315 Causes skin irritation.
Supplementary statement(s)
EUH019 May form explosive peroxides.
EUH044 Risk of explosion if heated under confinement.
CLP classification (additional)

Not Applicable
Precautionary statement(s) Prevention

P280 Wear protective gloves and protective clothing.
P264 Wash all exposed external body areas thoroughly after handling.
Precautionary statement(s) Response

P302+P352 IF ON SKIN: Wash with plenty of water.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
Precautionary statement(s) Storage

P410+P403 Protect from sunlight. Store in a well-ventilated place.
Precautionary statement(s) Disposal

Not Applicable
Material does not contain any CLP Article 18 substances.
2.3. Other hazards

Inhalation may produce health damage*.
Cumulative effects may result following exposure*.
May produce discomfort of the respiratory system*.
Limited evidence of a carcinogenic effect*.
Repeated exposure potentially causes skin dryness and cracking*.
Vapours potentially cause drowsiness and dizziness*.
Continued...
UNICOOL R-449A
REACH - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date.
SECTION 3 Composition / information on ingredients
3.1.Substances
See 'Composition on ingredients' in Section 3.2
3.2.Mixtures
1. CAS No
Classification according to regulation
2.EC No % Nanoform Particle
Name (EC) No 1272/2008 [CLP] and SCL / M-Factor
3.Index No [weight] Characteristics
amendments
4.REACH No
Not Available
1. 811-97-2 Acute M factor:
2.212-377-0 1,1,1,2- Gases Under Pressure (Liquefied Gas); Not Available
26 Not Available
3.Not Available tetrafluoroethane H280, EUH044 [1] Chronic M
4.Not Available factor: Not
Available
Not Available
1. 754-12-1 Flammable Gases Category 1A, Gases Acute M factor:
2.468-710-7 2,3,3,3- Not Available
25 Under Pressure (Liquefied Gas); H220, Not Available
3.Not Available tetrafluoropropene Chronic M
4.Not Available H280, EUH019, EUH044 [1] factor: Not
Available
Not Available
2.206-557-8 Gases Under Pressure (Liquefied Gas); Not Available
25 pentafluoroethane Not Available
3.Not Available H280, EUH044 [1] Chronic M
Available
Not Available
2.200-839-4 Flammable Gases Category 1A; H220, Not Available
24 difluoromethane Not Available
3.Not Available EUH044 [1] Chronic M
Available
Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from
C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties
SECTION 4 First aid measures
4.1. Description of first aid measures

If product comes in contact with eyes remove the patient from gas source or contaminated area.
Take the patient to the nearest eye wash, shower or other source of clean water.
Open the eyelid(s) wide to allow the material to evaporate.
Gently rinse the affected eye(s) with clean, cool water for at least 15 minutes. Have the patient lie or sit down and tilt the
head back. Hold the eyelid(s) open and pour water slowly over the eyeball(s) at the inner corners, letting the water run out of
the outer corners.
The patient may be in great pain and wish to keep the eyes closed. It is important that the material is rinsed from the eyes to
prevent further damage.
Eye Contact Ensure that the patient looks up, and side to side as the eye is rinsed in order to better reach all parts of the eye(s)
Transport to hospital or doctor.
Even when no pain persists and vision is good, a doctor should examine the eye as delayed damage may occur.
If the patient cannot tolerate light, protect the eyes with a clean, loosely tied bandage.
Ensure verbal communication and physical contact with the patient.
DO NOT allow the patient to rub the eyes
DO NOT allow the patient to tightly shut the eyes
DO NOT introduce oil or ointment into the eye(s) without medical advice
DO NOT use hot or tepid water.
Skin Contact If skin contact occurs:

Immediately remove all contaminated clothing, including footwear.
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
In case of cold burns (frost-bite):
Move casualty into warmth before thawing the affected part; if feet are affected carry if possible
Bathe the affected area immediately in luke-warm water (not more than 35 deg C) for 10 to 15 minutes, immersing if possible
and without rubbing
DO NOT apply hot water or radiant heat.
Apply a clean, dry, light dressing of "fluffed-up" dry gauze bandage
If a limb is involved, raise and support this to reduce swelling
Continued...
UNICOOL R-449A
If an adult is involved and where intense pain occurs provide pain killers such as paracetomol
Transport to hospital, or doctor
Subsequent blackening of the exposed tissue indicates potential of necrosis, which may require amputation.
Following exposure to gas, remove the patient from the gas source or contaminated area.
NOTE: Personal Protective Equipment (PPE), including positive pressure self-contained breathing apparatus may be
required to assure the safety of the rescuer.
Prostheses such as false teeth, which may block the airway, should be removed, where possible, prior to initiating first aid
procedures.
If the patient is not breathing spontaneously, administer rescue breathing.
If the patient does not have a pulse, administer CPR.
Inhalation
If medical oxygen and appropriately trained personnel are available, administer 100% oxygen.
Summon an emergency ambulance. If an ambulance is not available, contact a physician, hospital, or Poison Control Centre
for further instruction.
Keep the patient warm, comfortable and at rest while awaiting medical care.
MONITOR THE BREATHING AND PULSE, CONTINUOUSLY.
Administer rescue breathing (preferably with a demand-valve resuscitator, bag-valve mask-device, or pocket mask as
trained) or CPR if necessary.
Not considered a normal route of entry.
Avoid giving milk or oils.
Ingestion
Avoid giving alcohol.
For advice, contact a Poisons Information Centre or a doctor.
4.2 Most important symptoms and effects, both acute and delayed
See Section 11
4.3. Indication of any immediate medical attention and special treatment needed
for intoxication due to Freons/ Halons;
A: Emergency and Supportive Measures
Maintain an open airway and assist ventilation if necessary
Treat coma and arrhythmias if they occur. Avoid (adrenaline) epinephrine or other sympathomimetic amines that may precipitate ventricular arrhythmias.
Tachyarrhythmias caused by increased myocardial sensitisation may be treated with propranolol, 1-2 mg IV or esmolol 25-100 microgm/kg/min IV.
Monitor the ECG for 4-6 hours
B: Specific drugs and antidotes:
There is no specific antidote
C: Decontamination
Inhalation; remove victim from exposure, and give supplemental oxygen if available.
Ingestion; (a) Prehospital: Administer activated charcoal, if available. DO NOT induce vomiting because of rapid absorption and the risk of abrupt onset CNS
depression. (b) Hospital: Administer activated charcoal, although the efficacy of charcoal is unknown. Perform gastric lavage only if the ingestion was very
large and recent (less than 30 minutes)
D: Enhanced elimination:
There is no documented efficacy for diuresis, haemodialysis, haemoperfusion, or repeat-dose charcoal.
POISONING and DRUG OVERDOSE, Californian Poison Control System Ed. Kent R Olson; 3rd Edition
Do not administer sympathomimetic drugs unless absolutely necessary as material may increase myocardial irritability.
No specific antidote.
Because rapid absorption may occur through lungs if aspirated and cause systematic effects, the decision of whether to induce vomiting or not should be
made by an attending physician.
If lavage is performed, suggest endotracheal and/or esophageal control.
Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach.
Treatment based on judgment of the physician in response to reactions of the patient
For frost-bite caused by liquefied petroleum gas:
If part has not thawed, place in warm water bath (41-46 C) for 15-20 minutes, until the skin turns pink or red.
Analgesia may be necessary while thawing.
If there has been a massive exposure, the general body temperature must be depressed, and the patient must be immediately rewarmed by whole-body
immersion, in a bath at the above temperature.
Shock may occur during rewarming.
Administer tetanus toxoid booster after hospitalization.
Prophylactic antibiotics may be useful.
The patient may require anticoagulants and oxygen.
[Shell Australia 22/12/87]
For gas exposures:
--------------------------------------------------------------
BASIC TREATMENT
--------------------------------------------------------------
Establish a patent airway with suction where necessary.
Watch for signs of respiratory insufficiency and assist ventilation as necessary.
Administer oxygen by non-rebreather mask at 10 to 15 l/min.
Monitor and treat, where necessary, for pulmonary oedema .
Monitor and treat, where necessary, for shock.
Anticipate seizures.
--------------------------------------------------------------
ADVANCED TREATMENT
--------------------------------------------------------------
Continued...
UNICOOL R-449A
Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred.
Positive-pressure ventilation using a bag-valve mask might be of use.
Monitor and treat, where necessary, for arrhythmias.
Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload might create complications.
Drug therapy should be considered for pulmonary oedema.
Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Fluid overload might create complications.
Treat seizures with diazepam.
Proparacaine hydrochloride should be used to assist eye irrigation.
BRONSTEIN, A.C. and CURRANCE, P.L.
EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994
SECTION 5 Firefighting measures
5.1. Extinguishing media

SMALL FIRE: Use extinguishing agent suitable for type of surrounding fire.
LARGE FIRE: Cool cylinder.
DO NOT direct water at source of leak or venting safety devices as icing may occur.
5.2. Special hazards arising from the substrate or mixture

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may
Fire Incompatibility
result
5.3. Advice for firefighters

--------------------------------------------------------------
GENERAL
--------------------------------------------------------------
Fire Fighting
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus and protective gloves.
Fight fire from a safe distance, with adequate cover.
Containers may explode when heated - Ruptured cylinders may rocket

Fire exposed containers may vent contents through pressure relief devices.
High concentrations of gas may cause asphyxiation without warning.
May decompose explosively when heated or involved in fire.
Decomposition may produce toxic fumes of:
,
carbon monoxide (CO)
Fire/Explosion Hazard ,
carbon dioxide (CO2)
,
hydrogen fluoride
,
other pyrolysis products typical of burning organic material.
Contains low boiling substance: Closed containers may rupture due to pressure buildup under fire conditions.
Vented gas is more dense than air and may collect in pits, basements.
SECTION 6 Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

See section 8
6.2. Environmental precautions

See section 12
6.3. Methods and material for containment and cleaning up

Avoid breathing vapour and any contact with liquid or gas. Protective equipment including respirator should be used.
Minor Spills
DO NOT enter confined spaces where gas may have accumulated.
Clear area of all unprotected personnel and move upwind.
Alert Emergency Authority and advise them of the location and nature of hazard.
Major Spills Remove leaking cylinders to a safe place.
Fit vent pipes. Release pressure under safe, controlled conditions
Burn issuing gas at vent pipes.
DO NOT exert excessive pressure on valve; DO NOTattempt to operate damaged valve.
6.4. Reference to other sections

Personal Protective Equipment advice is contained in Section 8 of the SDS.
Continued...
UNICOOL R-449A
SECTION 7 Handling and storage
7.1. Precautions for safe handling

· Consider use in closed pressurised systems, fitted with temperature, pressure and safety relief valves which are vented for safe
dispersal. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature
· The tubing network design connecting gas cylinders to the delivery system should include appropriate pressure indicators and
Safe handling vacuum or suction lines.
· Fully-welded types of pressure gauges, where the bourdon tube sensing element is welded to the gauge body, are
recommended.
DO NOT transfer gas from one cylinder to another.
Fire and explosion
See section 5
protection
· Do NOT store halogenated aliphatics in areas containing alkali or alkaline earth metals such as powdered
aluminum, zinc, or beryllium
Other information Cylinders should be stored in a purpose-built compound with good ventilation, preferably in the open.
Such compounds should be sited and built in accordance with statutory requirements.
The storage compound should be kept clear and access restricted to authorised personnel only.
7.2. Conditions for safe storage, including any incompatibilities

DO NOT use aluminium or galvanised containers
Cylinder:
Suitable container Ensure the use of equipment rated for cylinder pressure.
Ensure the use of compatible materials of construction.
Valve protection cap to be in place until cylinder is secured, connected.
As a general rule, hydrofluorocarbons tend to be flammable unless they contain more fluorine atoms than hydrogen atoms.
Haloalkanes:
are highly reactive:some of the more lightly substituted lower members are highly flammable; the more highly substituted
may be used as fire suppressants, not always with the anticipated results.
may react with the lighter divalent metals to produce more reactive compounds analogous to Grignard reagents.
may produce explosive compounds following prolonged contact with metallic or other azides
may react on contact with potassium or its alloys - although apparently stable on contact with a wide rage of halocarbons,
reaction products may be shock-sensitive and may explode with great violence on light impact; severity generally increases
Storage incompatibility
with the degree of halocarbon substitution and potassium-sodium alloys give extremely sensitive mixtures .
Haloalkenes are highly reactive.
Some of the more lightly substituted lower members are highly flammable; many members of the group are peroxidisable
and polymerisable.
Avoid reaction or contact with potassium or its alloys - although apparently stable on contact with a wide rage of halocarbons,
reaction products may be shock-sensitive and may explode with great violence on light impact.
Compressed gases may contain a large amount of kinetic energy over and above that potentially available from the energy of
reaction produced by the gas in chemical reaction with other substances
Hazard categories in
accordance with
Not Available
Regulation (EC) No
2012/18/EU (Seveso III)
Qualifying quantity
(tonnes) of dangerous
substances as referred to Not Available
in Article 3(10) for the
application of
+ x + o + + +
X — Must not be stored together

0 — May be stored together with specific preventions
+ — May be stored together
Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes
of dangerous goods are stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly.
7.3. Specific end use(s)

See section 1.2
SECTION 8 Exposure controls / personal protection
8.1. Control parameters
Continued...
UNICOOL R-449A
DNELs PNECs
Ingredient
Exposure Pattern Worker Compartment
0.1 mg/L (Water (Fresh))

1 mg/L (Water - Intermittent release)
Inhalation 13 936 mg/m³ (Systemic, Chronic)
1,1,1,2-tetrafluoroethane 0.01 mg/L (Water (Marine))
Inhalation 2 476 mg/m³ (Systemic, Chronic) *
0.75 mg/kg sediment dw (Sediment (Fresh Water))
73 mg/L (STP)

Inhalation 950 mg/m³ (Systemic, Chronic) 1 mg/L (Water - Intermittent release)
Inhalation 186 400 mg/m³ (Systemic, Acute) 0.01 mg/L (Water (Marine))
2,3,3,3-tetrafluoropropene
Inhalation 113.1 mg/m³ (Systemic, Chronic) * 1.51 mg/kg sediment dw (Sediment (Fresh Water))
Inhalation 186 400 mg/m³ (Systemic, Acute) * 0.151 mg/kg sediment dw (Sediment (Marine))
1.49 mg/kg soil dw (Soil)

pentafluoroethane 1 mg/L (Water - Intermittent release)

difluoromethane 1.42 mg/L (Water - Intermittent release)
Inhalation 750 mg/m³ (Systemic, Chronic) *
* Values for General Population
Occupational Exposure Limits (OEL)
INGREDIENT DATA
Source Ingredient Material name TWA STEL Peak Notes
Not Available Not Available Not Available Not Available Not Available Not Available Not Available
Not Applicable
Emergency Limits
Ingredient TEEL-1 TEEL-2 TEEL-3
1,1,1,2-tetrafluoroethane Not Available Not Available Not Available
2,3,3,3-tetrafluoropropene 2,200 ppm Not Available 1.40E+05 ppm

difluoromethane 3,000 ppm 6,500 ppm 39,000 ppm
Ingredient Original IDLH Revised IDLH

1,1,1,2-tetrafluoroethane Not Available Not Available
2,3,3,3-tetrafluoropropene Not Available Not Available
pentafluoroethane Not Available Not Available
difluoromethane Not Available Not Available
MATERIAL DATA
Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically occupational exposure standards for
these irritants have been based on observation of workers' responses to various airborne concentrations. Present day expectations require that nearly every
individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or
more.
May act as a simple asphyxiants; these are gases which, when present in high concentrations, reduce the oxygen content in air below that required to support
breathing, consciousness and life; loss of consciousness, with death by suffocation may rapidly occur in an oxygen deficient atmosphere.
CARE: Most simple asphyxiants are odourless or possess low odour and there is no warning on entry into an oxygen deficient atmosphere. If there is any doubt,
oxygen content can be checked simply and quickly.
8.2. Exposure controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
8.2.1. Appropriate
provide this high level of protection.
engineering controls
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
8.2.2. Individual protection

measures, such as
personal protective
equipment
Chemical goggles.
Eye and face protection Full face shield may be required for supplementary but never for primary protection of eyes.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants.
Skin protection See Hand protection below

Hands/feet protection Butyl rubber gloves
Continued...
UNICOOL R-449A
· Butyl rubber gloves should be used when handling halogenated aliphatics .

· Nitrile, PVC-coated nitrile, and PVC protective equipment are not recommended
When handling sealed and suitably insulated cylinders wear cloth or leather gloves.
Insulated gloves:
NOTE: Insulated gloves should be loose fitting so that may be removed quickly if liquid is spilled upon them. Insulated gloves
are not made to permit hands to be placed in the liquid; they provide only short-term protection from accidental contact with
the liquid.
Body protection See Other protection below
· Halogen-selective detectors use a specialized sensor that allows the monitor to detect compounds containing
fluorine, chlorine, bromine, and iodine with-out interference from other species.These detectors are typically easy to
use, feature higher sensitivity than the nonselective detectors (detection limits are typically <5 ppm when used as an
area monitor and <1.4 gm/yr [<0.05 oz/yr] when used as a leak pinpointer).
Other protection · Compound-Specific Detectors are typically capable of detecting the presence of a single compound without
interference from other compounds.
Protective overalls, closely fitted at neck and wrist.
Eye-wash unit.
Ensure availability of lifeline in confined spaces.
Respiratory protection
Type AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)
Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Protection
Factors (defined as the ratio of contaminant outside and inside the mask) may also be important.
Required minimum protection Maximum gas/vapour concentration present in air p.p.m. (by Half-face Full-Face
factor volume) Respirator Respirator
up to 10 1000 AX-AUS / Class1 -

up to 50 1000 - AX-AUS / Class 1
up to 50 5000 Airline * -
up to 100 5000 - AX-2
up to 100 10000 - AX-3

100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand

A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic
compounds(below 65 degC)
Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content.
The wearer must be warned to leave the contaminated area immediately on detecting any odours through the respirator. The odour may indicate that the mask
is not functioning properly, that the vapour concentration is too high, or that the mask is not properly fitted. Because of these limitations, only restricted use of
cartridge respirators is considered appropriate.
Cartridge performance is affected by humidity. Cartridges should be changed after 2 hr of continuous use unless it is determined that the humidity is less than
75%, in which case, cartridges can be used for 4 hr. Used cartridges should be discarded daily, regardless of the length of time used
Positive pressure, full face, air-supplied breathing apparatus should be used for work in enclosed spaces if a leak is suspected or the primary containment is to
be opened (e.g. for a cylinder change)
Air-supplied breathing apparatus is required where release of gas from primary containment is either suspected or demonstrated.
up to 10 1000 AX-AUS / Class 1 -

up to 100 5000 - AX-2
up to 100 10000 - AX-3

100+ - Airline**
** - Continuous-flow or positive pressure demand.

A(All classes) = Organic vapours, B AUS or B1 = Acid gases, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
compounds(below 65 deg C)
8.2.3. Environmental exposure controls

See section 12
SECTION 9 Physical and chemical properties
Continued...
UNICOOL R-449A
9.1. Information on basic physical and chemical properties

Appearance Colourless
Relative density (Water =

Physical state Liquified Gas Not Available
1)
Partition coefficient n-
Odour Not Available Not Available
octanol / water
Auto-ignition temperature
Odour threshold Not Available Not Applicable
(°C)
Decomposition
pH (as supplied) Not Applicable Not Applicable
temperature (°C)
Melting point / freezing

Not Applicable Viscosity (cSt) Not Applicable
point (°C)
Initial boiling point and

-46 Molecular weight (g/mol) Not Applicable
boiling range (°C)
Flash point (°C) Not Applicable Taste Not Available
Evaporation rate >1 Ether = 1 Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Surface Tension (dyn/cm

Upper Explosive Limit (%) Not Applicable Not Available
or mN/m)
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) Not Applicable
Vapour pressure (kPa) 12748 Gas group Not Available
Solubility in water Not Applicable pH as a solution (1%) Not Available
Vapour density (Air = 1) 3.07 VOC g/L Not Applicable
Nanoform Particle
Nanoform Solubility Not Available Not Available
Characteristics
Particle Size Not Available
9.2. Other information

Not Available
SECTION 10 Stability and reactivity
10.1.Reactivity See section 7.2
Unstable in the presence of incompatible materials.

10.2. Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.
10.3. Possibility of
See section 7.2
hazardous reactions
10.4. Conditions to avoid See section 7.2
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3
decomposition products
SECTION 11 Toxicological information
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Inhaled The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives
using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by narcosis, reduced alertness, loss of
reflexes, lack of coordination and vertigo.
Exposure to high concentrations of fluorocarbons may produce cardiac arrhythmias or cardiac arrest due sensitisation of the
heart to adrenalin or noradrenalin. Deaths associated with exposures to fluorocarbons (specifically halogenated aliphatics) have
occurred in occupational settings and in inhalation of bronchodilator drugs.
Bronchospasm consistently occurs in human subjects inhaling fluorocarbons.
Acute intoxication by halogenated aliphatic hydrocarbons appears to take place over two stages. Signs of a reversible narcosis
are evident in the first stage and in the second stage signs of injury to organs may become evident, a single organ alone is
(almost) never involved.
Depression of the central nervous system is the most outstanding effect of most halogenated aliphatic hydrocarbons. Inebriation
and excitation, passing into narcosis, is a typical reaction. In severe acute exposures there is always a danger of death from
respiratory failure or cardiac arrest due to a tendency to make the heart more susceptible to catecholamines (adrenalin)
Continued...
UNICOOL R-449A
Material is highly volatile and may quickly form a concentrated atmosphere in confined or unventilated areas. The vapour may
displace and replace air in breathing zone, acting as a simple asphyxiant. This may happen with little warning of overexposure.
Symptoms of asphyxia (suffocation) may include headache, dizziness, shortness of breath, muscular weakness, drowsiness and
ringing in the ears. If the asphyxia is allowed to progress, there may be nausea and vomiting, further physical weakness and
unconsciousness and, finally, convulsions, coma and death. Significant concentrations of the non-toxic gas reduce the oxygen
level in the air.
The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritating
atmosphere developing. Before starting consider control of exposure by mechanical ventilation.
Not normally a hazard due to physical form of product.

Ingestion
Considered an unlikely route of entry in commercial/industrial environments
Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a substantial
number of individuals following direct contact, and/or produces significant inflammation when applied to the healthy intact skin of
animals, for up to four hours, such inflammation being present twenty-four hours or more after the end of the exposure period.
Skin irritation may also be present after prolonged or repeated exposure; this may result in a form of contact dermatitis
(nonallergic). The dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which may progress to
blistering (vesiculation), scaling and thickening of the epidermis.
The material may accentuate any pre-existing dermatitis condition
Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce
health damage following entry through wounds, lesions or abrasions.
Skin Contact
In common with other halogenated aliphatics, fluorocarbons may cause dermal problems due to a tendency to remove natural
oils from the skin causing irritation and the development of dry, sensitive skin. They do not appear to be appreciably absorbed.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with
harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Vapourising liquid causes rapid cooling and contact may cause cold burns, frostbite, even through normal gloves. Frozen skin
tissues are painless and appear waxy and yellow. Signs and symptoms of frost-bite may include "pins and needles", paleness
followed by numbness, a hardening an stiffening of the skin, a progression of colour changes in the affected area, (first white,
then mottled and blue and eventually black; on recovery, red, hot, painful and blistered).
Although the material is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce
Eye transient discomfort characterised by tearing or conjunctival redness (as with windburn).
Direct contact with the eye may not cause irritation because of the extreme volatility of the gas; however concentrated
atmospheres may produce irritation after brief exposures..
Long-term exposure to the product is not thought to produce chronic effects adverse to health (as classified by EC Directives
using animal models); nevertheless exposure by all routes should be minimised as a matter of course.
Halogenated oxiranes may arise following epoxidation of haloalkenes.
The metabolism of haloethylenes by microsomal oxidation leading to epoxide formation across the double bond has been
proposed. The resulting oxiranes are highly reactive and may covalently bind to nucleic acids leading to mutations and possible
Chronic
cancers A measure of such potential carcinogenicity is the development of significant preneoplastic foci in livers of treated rats.
Principal route of occupational exposure to the gas is by inhalation.
On the basis, primarily, of animal experiments, concern has been expressed by at least one classification body that the material
may produce carcinogenic or mutagenic effects; in respect of the available information, however, there presently exists
inadequate data for making a satisfactory assessment.
TOXICITY IRRITATION
UNICOOL R-449A
Inhalation (Rat) LC50: >567000 ppm/4h[2] Not Available
TOXICITY IRRITATION
1,1,1,2-tetrafluoroethane
Inhalation (Rat) LC50: 359453.102 ppm4h[2] Not Available
TOXICITY IRRITATION
[2] Not Available
Inhalation (Rat) LC50: >86.831 ppm4h
TOXICITY IRRITATION
pentafluoroethane
Inhalation (Rat) LC50: >709000 ppm4h[2] Not Available
TOXICITY IRRITATION
difluoromethane Inhalation (Rat) LC50: >760000 ppm4h[2] Not Available
[2]
Oral (Mouse) LD50; 1810 mg/kg
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
1,1,1,2- * with added oxygen - ZhongHao New Chemical Materials MSDS Excessive concentration can have a narcotic effect; inhalation
TETRAFLUOROETHANE of high concentrations of decomposition products can cause lung oedema.
Continued...
UNICOOL R-449A
Mutagenicity : Did not cause genetic damage in animals. Did not cause genetic damage in cultured mammalian cells.
Experiments showed mutagenic effects in cultured bacterial cells. Reproductive toxicity : Animal testing showed no reproductive
toxicity. Teratogenicity : Animal testing showed effects on embryo-fetal development at levels equal to or above those causing
2,3,3,3- maternal toxicity. * Vendor For similar product, 1,3,3,3-tetrafluoropropene HFO-1234ze is not likely to accumulate in the bodies of
TETRAFLUOROPROPENE humans or animals HFO-1234ze is practically non-toxic. Short-term exposures at levels higher than 10% have not induced
cardiac sensitization to adrenalin nor induced serious toxic effects. Rats and rabbits did not exhibit any serious toxic,
developmental or reproductive effects even with exposures to high levels of HFO-1234ze. Based on a series of mutagenicity and
genomics studies, the cancer risk for HFO-1234ze is LOW
PENTAFLUOROETHANE Cardiac sensitisation threshold limit >245400 mg/m3 Anaesthetic effects threshold limit 490800 mg/m3 * DuPont SDS
The fluoroalkenes vary widely in acute inhalation toxicity. Those, such as perfluoroisobutylene, PFIB, the most highly toxic
UNICOOL R-449A & 2,3,3,3- member, attacks the pulmonary epithelium of rats eventuating in edema and death after a delay of about one day. Other
TETRAFLUOROPROPENE fluoroalkenes, such as hexafluoropropylene (HFP) or chlorotrifluoroethylene (CTFE), also cause pulmonary injury but at lower
concentrations produce concentration dependent changes in the renal concentrating mechanism of the rat.
Disinfection by products (DBPs) re formed when disinfectants such as chlorine, chloramine, and ozone react with organic and
UNICOOL R-449A & 1,1,1,2-
inorganic matter in water. The observations that some DBPs such as trihalomethanes (THMs), di-/trichloroacetic acids, and 3-
TETRAFLUOROETHANE &
chloro-4-(dichloromethyl)-5-hydroxy-2(5H)-furanone (MX) are carcinogenic in animal studies have raised public concern over the
2,3,3,3-
possible adverse health effects of DBPs. To date, several hundred DBPs have been identified.
TETRAFLUOROPROPENE
Numerous haloalkanes and haloalkenes have been tested for carcinogenic and mutagenic activities.
Acute Toxicity Carcinogenicity
Skin Irritation/Corrosion Reproductivity

Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard
Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification
11.2 Information on other hazards
11.2.1. Endocrine disrupting properties

No evidence of endocrine disrupting properties were found in the current literature.
11.2.2. Other information

See Section 11.1
SECTION 12 Ecological information
12.1. Toxicity
Endpoint Test Duration (hr) Species Value Source

UNICOOL R-449A Not Not Not
Not Available Not Available
Available Available Available

Not
NOEC(ECx) 96h Fish 300mg/l
Available
EC50 96h Algae or other aquatic plants 142mg/l 2

1,1,1,2-tetrafluoroethane EC50 72h Algae or other aquatic plants >114mg/l 2
Not
EC50 48h Crustacea 980mg/l
Available
Not
LC50 96h Fish 450mg/l
Available

ErC50 72h Algae or other aquatic plants >100mg/l 2
Not
NOEC(ECx) 72h Algae or other aquatic plants >100mg/l
Available
EC50 72h Algae or other aquatic plants >2.5mg/l 2
EC50 48h Crustacea 65mg/l 2

Not
LC50 96h Fish >197mg/l
Available
pentafluoroethane
Continued...
UNICOOL R-449A
EC50 72h Algae or other aquatic plants >114mg/l 2

LC50 96h Fish >81.8mg/l 2
NOEC(ECx) 96h Fish 10mg/l 2
EC50 48h Crustacea >97.9mg/l 2


difluoromethane
Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
Substances containing unsaturated carbons are ubiquitous in indoor environments. They result from many sources (see below). Most are reactive with
environmental ozone and many produce stable products which are thought to adversely affect human health.The potential for surfaces in an enclosed space to
facilitate reactions should be considered.
In addition to carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O), the greenhouse gases mentioned in the Kyoto Protocol include synthetic substances
that share the common feature of being highly persistent in the atmosphere and exhibiting very high specific radiative forcing (radiative forcing is the change in the
balance between radiation coming into the atmosphere and radiation out; a positive radiative forcing tends on average to warm the surface of the earth). These
synthetic substances include hydrocarbons that are partially fluorinated (HCFs) or totally fluorinated (PFCs) as well as sulfur hexafluoride (SF6).
The greenhouse potential of these substances, expressed as multiples of that of CO2, are within the range of 140 to 11,700 for HFCs, from 6500 to 9,200 for
PFCs and 23,900 for SF6.
DO NOT discharge into sewer or waterways.
12.2. Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
1,1,1,2-tetrafluoroethane HIGH HIGH
2,3,3,3-tetrafluoropropene HIGH HIGH
pentafluoroethane HIGH HIGH

difluoromethane LOW LOW
12.3. Bioaccumulative potential

Ingredient Bioaccumulation
1,1,1,2-tetrafluoroethane LOW (LogKOW = 1.68)
2,3,3,3-tetrafluoropropene LOW (LogKOW = 2.1485)
pentafluoroethane LOW (LogKOW = 1.5472)
difluoromethane LOW (LogKOW = 0.2)
12.4. Mobility in soil

Ingredient Mobility
1,1,1,2-tetrafluoroethane LOW (Log KOC = 96.63)
2,3,3,3-tetrafluoropropene LOW (Log KOC = 154.4)
pentafluoroethane LOW (Log KOC = 154.4)
difluoromethane LOW (Log KOC = 23.74)
12.5. Results of PBT and vPvB assessment

P B T
Relevant available data Not Available Not Available Not Available
PBT
vPvB
PBT Criteria fulfilled? No
vPvB No
12.6. Endocrine disrupting properties
Continued...
UNICOOL R-449A
12.7. Other adverse effects

No evidence of ozone depleting properties were found in the current literature.
SECTION 13 Disposal considerations
13.1. Waste treatment methods

Evaporate residue at an approved site.
Product / Packaging
Return empty containers to supplier. If containers are marked non-returnable establish means of disposal with manufacturer
disposal
prior to purchase.
Waste treatment options Not Available
Sewage disposal options Not Available
SECTION 14 Transport information
Labels Required
Marine Pollutant NO
Land transport (ADR-RID)

14.1. UN number or ID
1078
number
14.2. UN proper shipping REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 (contains pentafluoroethane, difluoromethane,
name 1,1,1,2-tetrafluoroethane and 2,3,3,3-tetrafluoropropene)
14.3. Transport hazard Class 2.2

class(es) Subsidiary Hazard Not Applicable
14.4. Packing group Not Applicable
14.5. Environmental
Not Applicable
hazard
Hazard identification (Kemler) 20

Classification code 2A
14.6. Special precautions Hazard Label 2.2

for user Special provisions 274 582 662
Limited quantity 120 ml
Tunnel Restriction Code C/E
Air transport (ICAO-IATA / DGR)

14.1. UN number 1078
14.2. UN proper shipping

Refrigerant gas, n.o.s. * (contains pentafluoroethane, difluoromethane, 1,1,1,2-tetrafluoroethane and 2,3,3,3-tetrafluoropropene)
name
ICAO/IATA Class 2.2

14.3. Transport hazard
ICAO / IATA Subsidiary Hazard Not Applicable
class(es)
ERG Code 2L
14.5. Environmental
Not Applicable
hazard
14.6. Special precautions

Special provisions Not Applicable
for user
Cargo Only Packing Instructions 200
Cargo Only Maximum Qty / Pack 150 kg
Passenger and Cargo Packing Instructions 200
Passenger and Cargo Maximum Qty / Pack 75 kg
Continued...
UNICOOL R-449A
Passenger and Cargo Limited Quantity Packing Instructions Forbidden

Passenger and Cargo Limited Maximum Qty / Pack Forbidden
Sea transport (IMDG-Code / GGVSee)

14.2. UN proper shipping REFRIGERANT GAS, N.O.S. (contains pentafluoroethane, difluoromethane, 1,1,1,2-tetrafluoroethane and 2,3,3,3-
name tetrafluoropropene)
14.3. Transport hazard IMDG Class 2.2

class(es) IMDG Subsidiary Hazard Not Applicable
14.5 Environmental hazard Not Applicable
EMS Number F-C , S-V

Special provisions 274
for user
Limited Quantities 120 mL
Inland waterways transport (ADN)

14.2. UN proper shipping REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 (contains pentafluoroethane, difluoromethane,
name 1,1,1,2-tetrafluoroethane and 2,3,3,3-tetrafluoropropene)

2.2 Not Applicable
class(es)
14.5. Environmental
Not Applicable
hazard
Special provisions 274; 582; 662

for user
Equipment required PP
Fire cones number 0
14.7. Maritime transport in bulk according to IMO instruments
14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable
14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
1,1,1,2-tetrafluoroethane Not Available
2,3,3,3-tetrafluoropropene Not Available
pentafluoroethane Not Available
difluoromethane Not Available
14.7.3. Transport in bulk in accordance with the IGC Code

Product name Ship Type
SECTION 15 Regulatory information
15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture
1,1,1,2-tetrafluoroethane is found on the following regulatory lists
Europe EC Inventory
European Union - European Inventory of Existing Commercial Chemical Substances (EINECS)
Continued...
UNICOOL R-449A
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs - Not Classified as Carcinogenic
2,3,3,3-tetrafluoropropene is found on the following regulatory lists
EU European Chemicals Agency (ECHA) Community Rolling Action Plan (CoRAP) List of Substances
Europe EC Inventory
pentafluoroethane is found on the following regulatory lists

Europe EC Inventory
difluoromethane is found on the following regulatory lists
Europe EC Inventory
Additional Regulatory Information

Not Applicable
This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : Directives 98/24/EC, - 92/85/EEC, - 94/33/EC,
- 2008/98/EC, - 2010/75/EU; Commission Regulation (EU) 2020/878; Regulation (EC) No 1272/2008 as updated through ATPs.
Information according to 2012/18/EU (Seveso III):

Seveso Category Not Available
15.2. Chemical safety assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
National Inventory Status

Australia - AIIC / Australia
Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (1,1,1,2-tetrafluoroethane; 2,3,3,3-tetrafluoropropene; pentafluoroethane; difluoromethane)
China - IECSC No (2,3,3,3-tetrafluoropropene; difluoromethane)
Europe - EINEC / ELINCS /

Yes
NLP
Japan - ENCS Yes
Korea - KECI Yes
New Zealand - NZIoC Yes
Philippines - PICCS Yes
USA - TSCA Yes
Taiwan - TCSI Yes

Mexico - INSQ No (2,3,3,3-tetrafluoropropene)
Vietnam - NCI Yes
Russia - FBEPH No (2,3,3,3-tetrafluoropropene)
Yes = All CAS declared ingredients are on the inventory

Legend: No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require
registration.
SECTION 16 Other information
Revision Date 29/03/2023
Initial Date 23/04/2020
CONTACT POINT
- For quotations contact your local Customer Services - http://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheet Wilhelmsen
Ships Service AS - Prepared by: Compliance Manager, - Email: Email: wss.global.sdsinfo@wilhelmsen.com - Telephone: Tel.: +47 67584000
Full text Risk and Hazard codes

H220 Extremely flammable gas.
SDS Version Summary
Continued...
UNICOOL R-449A
Date of
Version Sections Updated
Update
Toxicological information - Acute Health (inhaled), Ecological Information - Environmental, Exposure controls /
2.5 29/03/2023
personal protection - Personal Protection (Respirator), Toxicological information - Toxicity and Irritation (Other)
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios.
For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:
EN 166 Personal eye-protection
EN 340 Protective clothing
EN 374 Protective gloves against chemicals and micro-organisms
EN 13832 Footwear protecting against chemicals
EN 133 Respiratory protective devices
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]
regulation (EC) No
Classification Procedure
1272/2008 [CLP] and
amendments
Gases Under Pressure

On basis of test data
(Liquefied Gas), H280
Skin Corrosion/Irritation
Expert judgement
Category 2, H315
, EUH019 Calculation method
, EUH044 On basis of test data
Powered by AuthorITe, from Chemwatch.
Continued...
UNICOOL R-449A
end of SDS
UNICOOL R-452A

Synonyms R-452A; 905732; 905728

REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 (contains pentafluoroethane, difluoromethane and
2,3,3,3-tetrafluoropropene)

Other means of
905728, 905732, 905787, 905797
identification
Chemical Product
PC16 Heat transfer fluids
Category
Sectors of Use SU3 Industrial uses

Central Warehouse
login=wilhelmsen
--------- Norway

Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Page 1 continued...
UNICOOL R-452A
Other emergency
+61 3 9573 3188
telephone numbers
purposes.
regulation (EC) No
H280 - Gases Under Pressure (Liquefied Gas), H315 - Skin Corrosion/Irritation Category 2
1272/2008 [CLP] and
[1]
amendments
2.2. Label elements
Hazard pictogram(s)
Signal word Warning
Hazard statement(s)
EUH019 May form explosive peroxides.

Not Applicable




Not Applicable
2.3. Other hazards

Continued...
UNICOOL R-452A
3.1.Substances
3.2.Mixtures
1. CAS No
amendments
4.REACH No
Not Available
2.206-557-8 Gases Under Pressure (Liquefied Gas); Not Available
59 pentafluoroethane Not Available
3.Not Available H280, EUH044 [1] Chronic M
Available
Not Available
Flammable Gases Category 1A, Gases
2.468-710-7 2,3,3,3- Not Available
H280, EUH019, EUH044 [1]
Available
Not Available
2.200-839-4 Flammable Gases Category 1A; H220, Not Available
11 difluoromethane Not Available
3.Not Available EUH044 [1] Chronic M
Available

the outer corners.
If skin contact occurs:
Skin Contact
and without rubbing
Continued...
UNICOOL R-452A
procedures.
Inhalation
Ingestion
See Section 11
C: Decontamination
For gas exposures:
--------------------------------------------------------------
BASIC TREATMENT
--------------------------------------------------------------
--------------------------------------------------------------
ADVANCED TREATMENT
--------------------------------------------------------------
Continued...
UNICOOL R-452A


result

--------------------------------------------------------------
GENERAL
--------------------------------------------------------------
Fire Fighting

,
Fire/Explosion Hazard ,
,
hydrogen fluoride
,

See section 8

See section 12

Minor Spills

Continued...
UNICOOL R-452A

recommended.
Fire and explosion
See section 5
protection

Cylinder:
Haloalkanes:
and polymerisable.
accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ x + o + + +


See section 1.2

DNELs PNECs
Ingredient
pentafluoroethane Inhalation 16 444 mg/m³ (Systemic, Chronic) 0.1 mg/L (Water (Fresh))
Inhalation 1 753 mg/m³ (Systemic, Chronic) * 1 mg/L (Water - Intermittent release)
Continued...
UNICOOL R-452A
DNELs PNECs
Ingredient

difluoromethane 1.42 mg/L (Water - Intermittent release)
INGREDIENT DATA
Not Applicable
Emergency Limits

difluoromethane 3,000 ppm 6,500 ppm 39,000 ppm

difluoromethane Not Available Not Available
MATERIAL DATA
more.

8.2.1. Appropriate

measures, such as
personal protective
equipment
Chemical goggles.
Butyl rubber gloves

Hands/feet protection
Insulated gloves:
the liquid.
Continued...
UNICOOL R-452A
Eye-wash unit.
up to 100 5000 - AX-2
up to 100 10000 - AX-3
100+ Airline**

up to 100 5000 - AX-2
up to 100 10000 - AX-3
100+ - Airline**


See section 12


Physical state Liquified Gas 1.13
1)
octanol / water
Continued...
UNICOOL R-452A
(°C)
Decomposition
pH (as supplied) Not Applicable Not Available
temperature (°C)

Not Available Viscosity (cSt) Not Applicable
point (°C)

< 47 Molecular weight (g/mol) Not Available
boiling range (°C)
Evaporation rate Not Available Explosive properties Not Available


or mN/m)
Solubility in water Not Available pH as a solution (1%) Not Applicable

Vapour density (Air = 1) 3.64 VOC g/L Not Available
Nanoform Particle
Characteristics

Not Available

Product is considered stable.
10.2. Chemical stability
Extremely high temperatures.
See section 7.2
hazardous reactions
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives
(almost) never involved.
Inhaled Depression of the central nervous system is the most outstanding effect of most halogenated aliphatic hydrocarbons. Inebriation
level in the air.
Ingestion
Continued...
UNICOOL R-452A
Skin Contact
Chronic
TOXICITY IRRITATION
UNICOOL R-452A
TOXICITY IRRITATION
pentafluoroethane
TOXICITY IRRITATION
Inhalation (Rat) LC50: >86.831 ppm4h[2] Not Available
TOXICITY IRRITATION
difluoromethane Inhalation (Rat) LC50: >760000 ppm4h[2] Not Available
Oral (Mouse) LD50; 1810 mg/kg[2]
UNICOOL R-452A & 2,3,3,3- The fluoroalkenes vary widely in acute inhalation toxicity. Those, such as perfluoroisobutylene, PFIB, the most highly toxic
TETRAFLUOROPROPENE member, attacks the pulmonary epithelium of rats eventuating in edema and death after a delay of about one day. Other
fluoroalkenes, such as hexafluoropropylene (HFP) or chlorotrifluoroethylene (CTFE), also cause pulmonary injury but at lower
Continued...
UNICOOL R-452A
Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity



pentafluoroethane

Not
Available
Not
Available


difluoromethane

Continued...
UNICOOL R-452A

difluoromethane LOW LOW


difluoromethane LOW (LogKOW = 0.2)

Ingredient Mobility
difluoromethane LOW (Log KOC = 23.74)

P B T
PBT
vPvB
vPvB No



Product / Packaging
disposal
prior to purchase.
Labels Required
Marine Pollutant NO

1078
number
14.2. UN proper shipping REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 (contains pentafluoroethane, difluoromethane and
name 2,3,3,3-tetrafluoropropene)
Continued...
UNICOOL R-452A

14.5. Environmental
Not Applicable
hazard



Refrigerant gas, n.o.s. * (contains pentafluoroethane, difluoromethane and 2,3,3,3-tetrafluoropropene)
name
ICAO/IATA Class 2.2

class(es)
ERG Code 2L
14.5. Environmental
Not Applicable
hazard

for user


REFRIGERANT GAS, N.O.S. (contains pentafluoroethane, difluoromethane and 2,3,3,3-tetrafluoropropene)
name


for user

14.2. UN proper shipping REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 (contains pentafluoroethane, difluoromethane and
name 2,3,3,3-tetrafluoropropene)

2.2 Not Applicable
class(es)
14.5. Environmental
Not Applicable
hazard

for user
Continued...
UNICOOL R-452A

Fire cones number 0
Not Applicable
Product name Group


Europe EC Inventory
Europe EC Inventory
difluoromethane is found on the following regulatory lists

Europe EC Inventory

Not Applicable



Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (pentafluoroethane; 2,3,3,3-tetrafluoropropene; difluoromethane)
China - IECSC No (2,3,3,3-tetrafluoropropene; difluoromethane)

Yes
NLP
Japan - ENCS Yes
Korea - KECI Yes
Continued...
UNICOOL R-452A

USA - TSCA Yes
Taiwan - TCSI Yes
Vietnam - NCI Yes

registration.
CONTACT POINT

SDS Version Summary

Version Date of Update Sections Updated
2.12 29/03/2023 Exposure controls / personal protection - Personal Protection (Respirator)
Other information
regulation (EC) No
1272/2008 [CLP] and
amendments

Expert judgement
Category 2, H315
, EUH019 Calculation method
Continued...
UNICOOL R-452A
end of SDS
UNICOOL R-507

Product name UNICOOL R-507
Synonyms Product Part Number: 905628 (9.5 kg), 905610 (45 kg)
REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 (contains pentafluoroethane and 1,1,1-
trifluoroethane)

Other means of
905628, 905610, 905810, 905828
identification
Relevant identified uses

Central Warehouse
login=wilhelmsen

--------- Norway


Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
UNICOOL R-507
purposes.
regulation (EC) No
H280 - Gases Under Pressure (Liquefied Gas), H315 - Skin Corrosion/Irritation Category 2
1272/2008 [CLP] and
amendments [1]
2.2. Label elements
Hazard pictogram(s)
Signal word Warning
Hazard statement(s)

Not Applicable


P302+P352 IF ON SKIN: Wash with plenty of water and soap.


Not Applicable
2.3. Other hazards

Continued...
UNICOOL R-507
3.1.Substances
3.2.Mixtures
1. CAS No
amendments
4.REACH No
Not Available
1. 420-46-2
Acute M factor:
2.206-996-5 1,1,1- Flammable Gases Category 1A; H220,
50 Not Available Not Available
3.Not Available trifluoroethane EUH044 [1]
Chronic M factor:
4.Not Available
Not Available
Not Available
1. 354-33-6
Acute M factor:
2.206-557-8 Gases Under Pressure (Liquefied Gas);
50 pentafluoroethane Not Available Not Available
3.Not Available H280, EUH044 [1]
Chronic M factor:
4.Not Available
Not Available

the outer corners.
Skin Contact
and without rubbing
procedures.
Inhalation
Continued...
UNICOOL R-507

Ingestion
See Section 11
C: Decontamination
For gas exposures:
--------------------------------------------------------------
BASIC TREATMENT
--------------------------------------------------------------
--------------------------------------------------------------
ADVANCED TREATMENT
--------------------------------------------------------------

Continued...
UNICOOL R-507


result

--------------------------------------------------------------
GENERAL
--------------------------------------------------------------
Fire Fighting

,
Combustion products include:
Fire/Explosion Hazard
,
,
hydrogen fluoride
,

See section 8

See section 12

Environmental hazard - contain spillage.
Minor Spills Avoid breathing vapour and any contact with liquid or gas. Protective equipment including respirator should be used.
Major Spills
Remove leaking cylinders to a safe place.


recommended.
Fire and explosion

See section 5
protection
Continued...
UNICOOL R-507

Cylinder:
Haloalkanes:
Storage incompatibility may produce explosive compounds following prolonged contact with metallic or other azides
accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ x + o + + +


See section 1.2

DNELs PNECs
Ingredient
Inhalation 438.61 mg/m³ (Systemic, Chronic)
1,1,1-trifluoroethane 350 µg/L (Water (Fresh))
Inhalation 219.3 mg/m³ (Systemic, Chronic) *
pentafluoroethane 1 mg/L (Water - Intermittent release)
INGREDIENT DATA
Not Applicable
Emergency Limits
Continued...
UNICOOL R-507
UNICOOL R-507 Not Available Not Available Not Available

1,1,1-trifluoroethane Not Available Not Available
MATERIAL DATA
more.

8.2.1. Appropriate

measures, such as
personal protective
equipment
Chemical goggles.
Butyl rubber gloves

Insulated gloves:
the liquid.
Eye-wash unit.
up to 100 5000 - AX-2

up to 100 10000 - AX-3
100+ Airline**

Continued...
UNICOOL R-507

See section 12

Appearance Liquefied pressure gas

Physical state Liquified Gas 1319
1)
octanol / water
Odour threshold Not Available 728
(°C)
Decomposition
temperature (°C)

-116-760 Viscosity (cSt) Not Available
point (°C)

-47.1-760 Molecular weight (g/mol) Not Available
boiling range (°C)
Flash point (°C) Not Available Taste Not Available
Evaporation rate Not Available BuAC = 1 Explosive properties Not Available
Flammability Not Available Oxidising properties Not Available

Upper Explosive Limit (%) Not Available Not Available
or mN/m)
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Solubility in water Immiscible pH as a solution (1%) Not Available

Nanoform Particle
Characteristics

Not Available

Product is considered stable.
10.2. Chemical stability
Extremely high temperatures.
See section 7.2
hazardous reactions
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3
Continued...
UNICOOL R-507

Inhaled (almost) never involved.
Depression of the central nervous system is the most outstanding effect of most halogenated aliphatic hydrocarbons. Inebriation
level in the air.

Ingestion
Skin Contact
Chronic using animal models); nevertheless exposure by all routes should be minimised as a matter of course.
TOXICITY IRRITATION
UNICOOL R-507
TOXICITY IRRITATION
1,1,1-trifluoroethane
TOXICITY IRRITATION
pentafluoroethane
[2] Not Available
Inhalation (Rat) LC50: >709000 ppm4h
UNICOOL R-507 chloro-4-(dichloromethyl)-5-hydroxy-2(5H)-furanone (MX) are carcinogenic in animal studies have raised public concern over the
Continued...
UNICOOL R-507
NOTE: Substance has been shown to be mutagenic in at least one assay, or belongs to a family of chemicals producing damage
1,1,1-TRIFLUOROETHANE
or change to cellular DNA.
Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity

UNICOOL R-507 Not Not Not

1,1,1-trifluoroethane EC0(ECx) 96h Algae or other aquatic plants >44mg/l 2
EC50 72h Algae or other aquatic plants ~71mg/l 2


pentafluoroethane
On the basis of the available evidence concerning properties and predicted or observed environmental fate and behavior, the material may present a danger to the
structure and/ or functioning of the stratospheric ozone layer.

1,1,1-trifluoroethane HIGH HIGH

1,1,1-trifluoroethane LOW (LogKOW = 1.7393)
Continued...
UNICOOL R-507

Ingredient Mobility
1,1,1-trifluoroethane LOW (Log KOC = 48.64)

P B T

PBT
vPvB
vPvB No



Product / Packaging
disposal
prior to purchase.
Labels Required
Marine Pollutant NO

1078
number
14.2. UN proper shipping REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 (contains pentafluoroethane and 1,1,1-
name trifluoroethane)

14.5. Environmental
Not Applicable
hazard

Continued...
UNICOOL R-507


Refrigerant gas, n.o.s. * (contains pentafluoroethane and 1,1,1-trifluoroethane)
name
ICAO/IATA Class 2.2

class(es)
ERG Code 2L
14.5. Environmental
Not Applicable
hazard


for user


REFRIGERANT GAS, N.O.S. (contains pentafluoroethane and 1,1,1-trifluoroethane)
name


for user

14.2. UN proper shipping REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 (contains pentafluoroethane and 1,1,1-
name trifluoroethane)
2.2 Not Applicable
class(es)
14.5. Environmental
Not Applicable
hazard

for user
Fire cones number 0
Not Applicable
Product name Group
1,1,1-trifluoroethane Not Available
Continued...
UNICOOL R-507

1,1,1-trifluoroethane Not Available
1,1,1-trifluoroethane is found on the following regulatory lists
Europe EC Inventory
Europe EC Inventory

Not Applicable




Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (1,1,1-trifluoroethane; pentafluoroethane)
China - IECSC Yes

Yes
NLP
Japan - ENCS Yes

Korea - KECI Yes
USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ Yes
Vietnam - NCI Yes
Russia - FBEPH Yes

registration.
CONTACT POINT
Continued...
UNICOOL R-507
Other information
regulation (EC) No
1272/2008 [CLP] and
amendments

Expert judgement
Category 2, H315
Continued...
UNICOOL R-507
end of SDS
UNICOOL R-513A

Synonyms R-513A, 905770, 905771

Proper shipping name REFRIGERANT GAS, N.O.S. (contains 1,1,1,2-tetrafluoroethane and 2,3,3,3-tetrafluoropropene)
Other means of
905770, 905771, 905785, 905795
identification

Central Warehouse
login=wilhelmsen
--------- Norway
Registered company name Wilhelmsen Ships Service AS* Central Warehouse

Address Willem Barentszstraat 50 Rotterdam Netherlands
Telephone +31 10 4877 777
Fax Not Available

Website http://www.wilhelmsen.com
Email wss.rotterdam@wilhelmsen.com

Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers
Association / Organisation Dutch nat poison centre CHEMWATCH EMERGENCY RESPONSE (24/7)
Page 1 continued...
UNICOOL R-513A
Association / Organisation Dutch nat. poison centre CHEMWATCH EMERGENCY RESPONSE (24/7)
Emergency telephone
+ 31 88 7558561 +47 23 25 25 84
numbers
Other emergency
+ 31 10 4877700 +61 3 9573 3188
telephone numbers
purposes.
regulation (EC) No
1272/2008 [CLP] and H280 - Gases Under Pressure (Liquefied Gas)
amendments [1]
2.2. Label elements
Hazard pictogram(s)
Signal word Warning
Hazard statement(s)

Not Applicable

Not Applicable

Not Applicable


Not Applicable
2.3. Other hazards

May produce discomfort of the respiratory system and skin*.
Continued...
UNICOOL R-513A
3.1.Substances
3.2.Mixtures
1. CAS No
amendments
4.REACH No
Not Available
Flammable Gases Category 1A, Gases
2.468-710-7 2,3,3,3- Not Available
H280, EUH019, EUH044 [1]
Available
Not Available
2.212-377-0 1,1,1,2- Gases Under Pressure (Liquefied Gas); Not Available
44 Not Available
3.Not Available tetrafluoroethane H280, EUH044 [1] Chronic M
Available

the outer corners.
Skin Contact
and without rubbing
Inhalation Following exposure to gas, remove the patient from the gas source or contaminated area.
procedures.
Continued...
UNICOOL R-513A

Ingestion Avoid giving alcohol.
If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible
aspiration of vomitus.
See Section 11
C: Decontamination
For gas exposures:
--------------------------------------------------------------
BASIC TREATMENT
--------------------------------------------------------------
--------------------------------------------------------------
ADVANCED TREATMENT
--------------------------------------------------------------
Continued...
UNICOOL R-513A


result

--------------------------------------------------------------
GENERAL
--------------------------------------------------------------
Fire Fighting

,
,
,
hydrogen fluoride
,

See section 8

See section 12

Minor Spills



recommended.
Fire and explosion
See section 5
protection
Continued...
UNICOOL R-513A
Cylinders should be stored in a purpose-built compound with good ventilation, preferably in the open.
Other information Such compounds should be sited and built in accordance with statutory requirements.

Cylinder:
Haloalkanes:
and polymerisable.
accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ + + + + + +


See section 1.2

DNELs PNECs
Ingredient

1,1,1,2-tetrafluoroethane 0.01 mg/L (Water (Marine))
73 mg/L (STP)

Continued...
UNICOOL R-513A
INGREDIENT DATA
Not Applicable
Emergency Limits
1,1,1,2-tetrafluoroethane Not Available Not Available Not Available

1,1,1,2-tetrafluoroethane Not Available Not Available
MATERIAL DATA
more.

8.2.1. Appropriate

measures, such as
personal protective
equipment
Chemical goggles.
Insulated gloves:
Hands/feet protection NOTE: Insulated gloves should be loose fitting so that may be removed quickly if liquid is spilled upon them. Insulated gloves
the liquid.

Other protection Eye-wash unit.

up to 100 5000 - AX-2
up to 100 10000 - AX-3

100+ Airline**
Continued...
UNICOOL R-513A

up to 100 5000 - AX-2
up to 100 10000 - AX-3
100+ - Airline**


See section 12


Physical state Liquified Gas 1.17
1)
octanol / water
Odour threshold Not Available Not Available
(°C)
Decomposition
pH (as supplied) Not Available Not Available
temperature (°C)
Not Available Viscosity (cSt) Not Available
point (°C)
-29.6 Molecular weight (g/mol) Not Available
boiling range (°C)

or mN/m)

Nanoform Particle
Characteristics
Continued...
UNICOOL R-513A
Not Available

See section 7.2
hazardous reactions
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

Inhaled Bronchospasm consistently occurs in human subjects inhaling fluorocarbons.
level in the air.
Overexposure is unlikely in this form.
Ingestion Not normally a hazard due to physical form of product.
Limited evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a
substantial number of individuals following direct contact, and/or produces significant inflammation when applied to the healthy
intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or more after the end of the
exposure period. Skin irritation may also be present after prolonged or repeated exposure; this may result in a form of contact
dermatitis (nonallergic). The dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which may
progress to blistering (vesiculation), scaling and thickening of the epidermis.
Skin Contact
Chronic Long-term exposure to the product is not thought to produce chronic effects adverse to health (as classified by EC Directives
Continued...
UNICOOL R-513A
TOXICITY IRRITATION
UNICOOL R-513A
TOXICITY IRRITATION
Inhalation (Rat) LC50: >86.831 ppm4h[2] Not Available
TOXICITY IRRITATION
1,1,1,2-tetrafluoroethane
Inhalation (Rat) LC50: 359453.102 ppm4h[2] Not Available
1,1,1,2- * with added oxygen - ZhongHao New Chemical Materials MSDS Excessive concentration can have a narcotic effect; inhalation
TETRAFLUOROETHANE of high concentrations of decomposition products can cause lung oedema.
The fluoroalkenes vary widely in acute inhalation toxicity. Those, such as perfluoroisobutylene, PFIB, the most highly toxic
UNICOOL R-513A & 2,3,3,3- member, attacks the pulmonary epithelium of rats eventuating in edema and death after a delay of about one day. Other
TETRAFLUOROPROPENE fluoroalkenes, such as hexafluoropropylene (HFP) or chlorotrifluoroethylene (CTFE), also cause pulmonary injury but at lower
UNICOOL R-513A & 2,3,3,3-
TETRAFLUOROPROPENE
& 1,1,1,2-
TETRAFLUOROETHANE

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity

Continued...
UNICOOL R-513A
Not
Available
Not
Available

Not
NOEC(ECx) 96h Fish 300mg/l
Available

1,1,1,2-tetrafluoroethane EC50 72h Algae or other aquatic plants >114mg/l 2
Not
EC50 48h Crustacea 980mg/l
Available
Not
Available


1,1,1,2-tetrafluoroethane HIGH HIGH

1,1,1,2-tetrafluoroethane LOW (LogKOW = 1.68)

Ingredient Mobility
1,1,1,2-tetrafluoroethane LOW (Log KOC = 96.63)

P B T
PBT
vPvB
vPvB No


Continued...
UNICOOL R-513A

Product / Packaging
disposal
prior to purchase.
Labels Required
Marine Pollutant NO

1078
number
14.2. UN proper shipping REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 (contains 1,1,1,2-tetrafluoroethane and 2,3,3,3-

14.5. Environmental
Not Applicable
hazard



Refrigerant gas, n.o.s. * (contains 1,1,1,2-tetrafluoroethane and 2,3,3,3-tetrafluoropropene)
name
ICAO/IATA Class 2.2

class(es)
ERG Code 2L
14.5. Environmental
Not Applicable
hazard

for user

Continued...
UNICOOL R-513A

REFRIGERANT GAS, N.O.S. (contains 1,1,1,2-tetrafluoroethane and 2,3,3,3-tetrafluoropropene)
name


for user

14.2. UN proper shipping REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture F3 (contains 1,1,1,2-tetrafluoroethane and 2,3,3,3-

2.2 Not Applicable
class(es)
14.5. Environmental
Not Applicable
hazard

for user
Fire cones number 0
Not Applicable
Product name Group


Europe EC Inventory
1,1,1,2-tetrafluoroethane is found on the following regulatory lists
Europe EC Inventory

Not Applicable
Continued...
UNICOOL R-513A




Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (2,3,3,3-tetrafluoropropene; 1,1,1,2-tetrafluoroethane)

China - IECSC No (2,3,3,3-tetrafluoropropene)

Yes
NLP
Japan - ENCS Yes
Korea - KECI Yes

USA - TSCA Yes
Taiwan - TCSI Yes
Vietnam - NCI Yes

registration.
CONTACT POINT

Other information
regulation (EC) No
1272/2008 [CLP] and
amendments

Continued...
UNICOOL R-513A
Continued...
UNICOOL R-513A
end of SDS
UNIMIX 10

Product name UNIMIX 10
Synonyms 905673; 905681

Proper shipping name COMPRESSED GAS, N.O.S. (contains carbon dioxide and argon)
Other means of
905673, 905681
identification
Relevant identified uses Shielding gas for welding

Central Warehouse
login=wilhelmsen
--------- Norway

Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
UNIMIX 10
purposes.
regulation (EC) No
1272/2008 [CLP] and H280 - Gases Under Pressure (Compressed Gas)
[1]
amendments
2.2. Label elements
Hazard pictogram(s)
Signal word Warning
Hazard statement(s)

Not Applicable

Not Applicable

Not Applicable


Not Applicable
2.3. Other hazards

May affect fertility*.
May be harmful to the foetus/ embryo*.
3.1.Substances
3.2.Mixtures
Continued...
UNIMIX 10
1. CAS No
2.EC No % Classification according to regulation (EC) Nanoform Particle
Name SCL / M-Factor
3.Index No [weight] No 1272/2008 [CLP] and amendments Characteristics
4.REACH No
Not Available
1. 7440-37-1
Acute M factor:
2.231-147-0 Gases Under Pressure (Compressed Gas);
90 argon Not Available Not Available
Chronic M factor:
4.Not Available
Not Available
Not Available
1. 124-38-9
Acute M factor:
2.204-696-9 carbon Gases Under Pressure (Liquefied Gas); H280,
3.Not Available dioxide * EUH044 [1]
Chronic M factor:
4.Not Available
Not Available

the outer corners.
If skin or hair contact occurs:
Skin Contact Flush skin and hair with running water (and soap if available).
procedures.
Inhalation
Ingestion Not considered a normal route of entry.
See Section 11
Continued...
UNIMIX 10
For gas exposures:

--------------------------------------------------------------
BASIC TREATMENT
--------------------------------------------------------------
--------------------------------------------------------------
ADVANCED TREATMENT
--------------------------------------------------------------


Fire Incompatibility None known.

--------------------------------------------------------------
GENERAL
--------------------------------------------------------------
Fire Fighting
Non combustible.
Not considered a significant fire risk, however containers may burn.

See section 8

See section 12

Minor Spills


Continued...
UNIMIX 10

recommended.
Fire and explosion
See section 5
protection

Cylinder:
Ensure the use of equipment rated for cylinder pressure.
Suitable container
Carbon dioxide:
reacts violently with strong bases and alkali metals (especially their dusts)
may ignite or explode when heated or in suspended chemically active metals (and their hydrides) such as aluminium,
chromium, manganese, magnesium (above 775 C), titanium (above 550 C), uranium (above 750 C) or zirconium ,
diethylmagnesium
is incompatible with water, acrolein, acrylaldehyde, amines, anhydrous ammonia, aziridine, metal acetylides (such as lithium
acetylide), caesium monoxide (moist), lithium, potassium, sodium, sodium carbide, sodium-potassium alloy, sodium peroxide,
titanium
may build up static electricity when discharged at high flow rates from storage cylinders or fire extinguishers - this may
produce sparks resulting in ignition of flammables or explosives.
may decompose to toxic carbon monoxide and flammable oxygen when exposed to electrical discharges or very high
temperatures
accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ + + + + + +


See section 1.2

DNELs PNECs
Ingredient
Not Available Not Available Not Available
Continued...
UNIMIX 10
INGREDIENT DATA
EU Consolidated List of
Indicative Occupational
carbon dioxide Carbon dioxide 5000 ppm / 9000 mg/m3 Not Available Not Available Not Available
Exposure Limit Values
(IOELVs)
Norway regulations on action
values and limit values for
physical and chemical
factors in the work carbon dioxide Karbondioksid 5000 ppm / 9000 mg/m3 Not Available Not Available E
environment and infection
risk groups for biological
factors (Norwegian)
Emergency Limits

argon 65,000 ppm 2.30E+05 ppm 4.00E+05 ppm

argon Not Available Not Available
carbon dioxide 40,000 ppm Not Available
MATERIAL DATA
For carbon dioxide:
NOTE: Detector tubes for carbon dioxide, measuring in excess of 0.01 % vol.,are commercially available. Long-term measurements (4 hrs) may be conducted to
detect concentrations exceeding 250 ppm.
Studies using physically fit males in confined spaces indicate the TLV-TWA and STEL provides a wide margin of safety against asphyxiation and from undue
metabolic stress, provided normal amounts of oxygen are present in inhaled air.

8.2.1. Appropriate

measures, such as
personal protective
equipment
"Safety glasses with side shields

Chemical goggles.
Eye and face protection
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy
document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task.
Hands/feet protection When handling sealed and suitably insulated cylinders wear cloth or leather gloves.


See section 12
Continued...
UNIMIX 10

Appearance Not Available

Physical state Compressed Gas Not Available
1)
octanol / water
(°C)
Decomposition
temperature (°C)

Not Applicable Viscosity (cSt) Not Applicable
point (°C)
Not Available Molecular weight (g/mol) Not Applicable
boiling range (°C)

or mN/m)
Vapour pressure (kPa) Not Applicable Gas group Not Available
Solubility in water Immiscible pH as a solution (1%) Not Applicable
Vapour density (Air = 1) 1.4 VOC g/L Not Applicable
Nanoform Particle
Characteristics

Not Available

See section 7.2
hazardous reactions
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

Inert gas narcosis may result following exposure. Inert gas narcosis is directly related to the pressure of the inert gas. The best
known form of this narcosis is is produced by nitrogen and is common amongst divers breathing compressed air..
Carbon dioxide is an odourless gas which gives very poor warning of exposure. The gas can produce rapid unconsciousness
and death from oxygen deficiency at concentrations of 10% in air. Even concentrations of 3% may produce shortness of breath
Inhaled
and headache.
level in the air.
Ingestion Overexposure is unlikely in this form.
Continued...
UNIMIX 10

The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives
using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves
be used in an occupational setting.
Skin Contact
TOXICITY IRRITATION
UNIMIX 10
TOXICITY IRRITATION
argon
TOXICITY IRRITATION
carbon dioxide
No known carcinogenic, mutagenic or specific reproductive effects. [BOC] No significant acute toxicological data identified in
ARGON
literature search.

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity

UNIMIX 10 Not Not Not

argon Not Not Not

carbon dioxide
LC50 96h Fish 35mg/l 1
Continued...
UNIMIX 10
For carbon dioxide:

Environmental fate:
Carbon dioxide in earth's atmosphere is considered a trace gas currently occurring at an average concentration of about 385 parts per million by volume or 582
parts per million by mass. The mass of the Earth atmosphere is 5.14×10+18 kg , so the total mass of atmospheric carbon dioxide is 3.0×10+15 kg (3,000
gigatonnes). Atmospheric concentrations of carbon dioxide fluctuate slightly with the change of the seasons, driven primarily by seasonal plant growth .

carbon dioxide LOW LOW

carbon dioxide LOW (LogKOW = 0.83)

Ingredient Mobility
carbon dioxide HIGH (Log KOC = 1.498)

P B T
PBT
vPvB
vPvB No



Product / Packaging
disposal
prior to purchase.

Labels Required
Marine Pollutant NO

1956
number
COMPRESSED GAS, N.O.S. (contains carbon dioxide and argon)

Continued...
UNIMIX 10

name

14.5. Environmental
Not Applicable
hazard


for user Special provisions 274 378 392 655 662

Tunnel Restriction Code E


Compressed gas, n.o.s. * (contains carbon dioxide and argon)
name
ICAO/IATA Class 2.2

class(es)
ERG Code 2L
14.5. Environmental
Not Applicable
hazard
Special provisions A202


for user



name


Special provisions 274 378 392
for user

name

2.2 Not Applicable
class(es)

14.5. Environmental
Not Applicable
hazard
Continued...
UNIMIX 10
Special provisions 274; 378; 392; 655; 662

for user
Fire cones number 0
Not Applicable
Product name Group
argon Not Available
carbon dioxide Not Available

argon Not Available
argon is found on the following regulatory lists
Europe EC Inventory
FEI Equine Prohibited Substances List - Banned Substances
FEI Equine Prohibited Substances List (EPSL)
carbon dioxide is found on the following regulatory lists
EU Consolidated List of Indicative Occupational Exposure Limit Values (IOELVs)

Europe EC Inventory
FEI Equine Prohibited Substances List - Controlled Medication
Norway regulations on action values and limit values for physical and chemical factors in the work environment and infection risk groups for biological factors
(Norwegian)

Not Applicable




Yes
Non-Industrial Use
Canada - DSL Yes

Canada - NDSL No (argon; carbon dioxide)
China - IECSC Yes

Yes
NLP
Continued...
UNIMIX 10
Japan - ENCS No (argon)
Korea - KECI Yes

USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ Yes
Vietnam - NCI Yes
Russia - FBEPH Yes

registration.

CONTACT POINT
SDS Version Summary

0.2 23/11/2021 Transport Information
Other information
Continued...
UNIMIX 10
end of SDS
UNIMIX 20

Product name UNIMIX 20
Synonyms 905581; 905573

Proper shipping name COMPRESSED GAS, N.O.S. (contains carbon dioxide and argon)
Other means of
905573, 905581
identification
Relevant identified uses Gas welding

Central Warehouse
login=wilhelmsen
--------- Norway

Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
UNIMIX 20
purposes.
regulation (EC) No
1272/2008 [CLP] and H280 - Gases Under Pressure (Compressed Gas)
[1]
amendments
2.2. Label elements
Hazard pictogram(s)
Signal word Warning
Hazard statement(s)

Not Applicable

Not Applicable

Not Applicable


Not Applicable
2.3. Other hazards

May affect fertility*.
May be harmful to the foetus/ embryo*.
3.1.Substances
3.2.Mixtures
Continued...
UNIMIX 20
1. CAS No
Name SCL / M-Factor
4.REACH No
Not Available
1. 7440-37-1
Acute M factor:
2.231-147-0 Gases Under Pressure (Compressed Gas);
80 argon Not Available Not Available
Chronic M factor:
4.Not Available
Not Available
Not Available
1. 124-38-9
Acute M factor:
2.204-696-9 carbon Gases Under Pressure (Liquefied Gas); H280,
3.Not Available dioxide * EUH044 [1]
Chronic M factor:
4.Not Available
Not Available

the outer corners.
procedures.
Inhalation
Ingestion Not considered a normal route of entry.
See Section 11
Continued...
UNIMIX 20
For gas exposures:

--------------------------------------------------------------
BASIC TREATMENT
--------------------------------------------------------------
--------------------------------------------------------------
ADVANCED TREATMENT
--------------------------------------------------------------



--------------------------------------------------------------
GENERAL
--------------------------------------------------------------
Fire Fighting
Non combustible.

See section 8

See section 12

Minor Spills


Continued...
UNIMIX 20

recommended.
Fire and explosion
See section 5
protection

Cylinder:
Ensure the use of equipment rated for cylinder pressure.
Suitable container
Carbon dioxide:
reacts violently with strong bases and alkali metals (especially their dusts)
may ignite or explode when heated or in suspended chemically active metals (and their hydrides) such as aluminium,
chromium, manganese, magnesium (above 775 C), titanium (above 550 C), uranium (above 750 C) or zirconium ,
diethylmagnesium
is incompatible with water, acrolein, acrylaldehyde, amines, anhydrous ammonia, aziridine, metal acetylides (such as lithium
acetylide), caesium monoxide (moist), lithium, potassium, sodium, sodium carbide, sodium-potassium alloy, sodium peroxide,
titanium
may build up static electricity when discharged at high flow rates from storage cylinders or fire extinguishers - this may
produce sparks resulting in ignition of flammables or explosives.
may decompose to toxic carbon monoxide and flammable oxygen when exposed to electrical discharges or very high
temperatures
accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ + + + + + +


See section 1.2

DNELs PNECs
Ingredient
Continued...
UNIMIX 20
INGREDIENT DATA
carbon dioxide Carbon dioxide 5000 ppm / 9000 mg/m3 Not Available Not Available Not Available
(IOELVs)
factors in the work carbon dioxide Karbondioksid 5000 ppm / 9000 mg/m3 Not Available Not Available E
factors (Norwegian)
Emergency Limits

argon 65,000 ppm 2.30E+05 ppm 4.00E+05 ppm

argon Not Available Not Available
carbon dioxide 40,000 ppm Not Available
MATERIAL DATA
For carbon dioxide:
NOTE: Detector tubes for carbon dioxide, measuring in excess of 0.01 % vol.,are commercially available. Long-term measurements (4 hrs) may be conducted to
detect concentrations exceeding 250 ppm.
Studies using physically fit males in confined spaces indicate the TLV-TWA and STEL provides a wide margin of safety against asphyxiation and from undue
metabolic stress, provided normal amounts of oxygen are present in inhaled air.

8.2.1. Appropriate

measures, such as
personal protective
equipment

Chemical goggles.
Hands/feet protection When handling sealed and suitably insulated cylinders wear cloth or leather gloves.


See section 12
Continued...
UNIMIX 20


Physical state Compressed Gas Not Available
1)
octanol / water
(°C)
Decomposition
temperature (°C)

point (°C)
Not Available Molecular weight (g/mol) Not Available
boiling range (°C)

or mN/m)
Vapour pressure (kPa) Not Available Gas group Not Available
Nanoform Particle
Characteristics

Not Available

See section 7.2
hazardous reactions
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

Inert gas narcosis may result following exposure. Inert gas narcosis is directly related to the pressure of the inert gas. The best
known form of this narcosis is is produced by nitrogen and is common amongst divers breathing compressed air..
Carbon dioxide is an odourless gas which gives very poor warning of exposure. The gas can produce rapid unconsciousness
Inhaled
and death from oxygen deficiency at concentrations of 10% in air. Even concentrations of 3% may produce shortness of breath
and headache.
level in the air.
Continued...
UNIMIX 20
Overexposure is unlikely in this form.

Ingestion Not normally a hazard due to physical form of product.
Skin Contact
TOXICITY IRRITATION
UNIMIX 20
TOXICITY IRRITATION
argon
TOXICITY IRRITATION
carbon dioxide
No known carcinogenic, mutagenic or specific reproductive effects. [BOC] No significant acute toxicological data identified in
ARGON
literature search.

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity

UNIMIX 20 Not Not Not

argon Not Not Not

carbon dioxide
Continued...
UNIMIX 20
For carbon dioxide:

Environmental fate:
Carbon dioxide in earth's atmosphere is considered a trace gas currently occurring at an average concentration of about 385 parts per million by volume or 582
parts per million by mass. The mass of the Earth atmosphere is 5.14×10+18 kg , so the total mass of atmospheric carbon dioxide is 3.0×10+15 kg (3,000
gigatonnes). Atmospheric concentrations of carbon dioxide fluctuate slightly with the change of the seasons, driven primarily by seasonal plant growth .

carbon dioxide LOW LOW

carbon dioxide LOW (LogKOW = 0.83)

Ingredient Mobility
carbon dioxide HIGH (Log KOC = 1.498)

P B T
PBT
vPvB

vPvB No



Product / Packaging
disposal
prior to purchase.

Labels Required
Marine Pollutant NO

1956
number
Continued...
UNIMIX 20

name

14.5. Environmental
Not Applicable
hazard


for user Special provisions 274 378 392 655 662

Tunnel Restriction Code E


Compressed gas, n.o.s. * (contains carbon dioxide and argon)
name
ICAO/IATA Class 2.2

class(es)
ERG Code 2L
14.5. Environmental
Not Applicable
hazard
Special provisions A202


for user


name


Special provisions 274 378 392
for user

name

2.2 Not Applicable
class(es)

14.5. Environmental
Not Applicable
hazard
Continued...
UNIMIX 20
Special provisions 274; 378; 392; 655; 662

for user
Fire cones number 0
Not Applicable
Product name Group
argon Not Available

argon Not Available
argon is found on the following regulatory lists
Europe EC Inventory
FEI Equine Prohibited Substances List - Banned Substances
carbon dioxide is found on the following regulatory lists

Europe EC Inventory
FEI Equine Prohibited Substances List - Controlled Medication
(Norwegian)

Not Applicable




Yes
Non-Industrial Use
Canada - DSL Yes

Canada - NDSL No (argon; carbon dioxide)
China - IECSC Yes

Yes
NLP
Continued...
UNIMIX 20
Japan - ENCS No (argon)
Korea - KECI Yes

USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ Yes
Vietnam - NCI Yes
Russia - FBEPH Yes

registration.

CONTACT POINT
SDS Version Summary

3.6 05/03/2021 Toxicological information - Acute Health (inhaled), Toxicological information - Chronic Health
Other information
Continued...
UNIMIX 20
end of SDS
UNIPOL
Part Number: 736975 (25 liter), 736983 (210 liter) Issue Date: 29/09/2023

Product name UNIPOL
Synonyms 736975, 736983 Pr No: 150341

Other means of
736975 (25 liter), 736983 (210 liter), 736975, 736983
identification
Chemical Product
PC35 Washing and cleaning products
Category
SU22 Professional uses

Sectors of Use
SU3 Industrial uses
Relevant identified uses Cleaning agent


Central Warehouse
login=wilhelmsen
--------- Norway


Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Page 1 continued...
Part Number: 736975 (25 liter), 736983 (210 liter) Page 2 of 15 Issue Date: 29/09/2023
UNIPOL
Other emergency
+61 3 9573 3188
telephone numbers
Considered a hazardous mixture according to Reg. (EC) No 1272/2008 and their amendments. Not classified as Dangerous Goods for
transport purposes.
regulation (EC) No
H315 - Skin Corrosion/Irritation Category 2, H318 - Serious Eye Damage/Eye Irritation Category 1
1272/2008 [CLP] and
[1]
amendments
2.2. Label elements
Hazard pictogram(s)
Signal word Danger
Hazard statement(s)
H318 Causes serious eye damage.
Not Applicable

Not Applicable

P280 Wear protective gloves, protective clothing, eye protection and face protection.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/physician/first aider.

Not Applicable

Not Applicable
Material contains sodium dodecylbenzenesulfonate, Fatty alcohol ethoxylates.
2.3. Other hazards

Ingestion may produce health damage*.
2-(2-butoxyethoxy)ethanol Listed in the Europe Regulation (EC) No 1907/2006 - Annex XVII (Restrictions may apply)
3.1.Substances
Continued...
UNIPOL
3.2.Mixtures
1. CAS No
2.EC No % SCL / M- Nanoform Particle
Name regulation (EC) No 1272/2008 [CLP]
3.Index No [weight] Factor Characteristics
and amendments
4.REACH No
Not Available
1. 112-34-5* Acute M factor:
2.203-961-6 Serious Eye Damage/Eye Irritation Not Available
1-5 2-(2-butoxyethoxy)ethanol * Not Available
3.603-096-00-8 Category 2; H319 [1] Chronic M
Available
Not Available
1. 160875-66-1* Acute M factor:
Acute Toxicity (Oral) Category 4,
2.Not Available Serious Eye Damage/Eye Irritation Not Available
1-5 Fatty alcohol ethoxylates Not Available
3.Not Available Chronic M
4.Not Available Category 1; H302, H318 [1] factor: Not
Available
Not Available
1-5 sodium carbonate Not Available
Available
Not Available
Acute Tox. 4, Serious Eye
2.246-680-4 sodium Not Available
5-10 Damage/Eye Irritation Category 2; Not Available
3.Not Available dodecylbenzenesulfonate Chronic M
4.Not Available H302, H312, H319 [3] factor: Not
Available

If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally
Eye Contact
lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Inhalation
Other measures are usually unnecessary.
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and
prevent aspiration.
Ingestion Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
See Section 11
Treat symptomatically.

There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area.
Continued...
UNIPOL
result

Fire Fighting Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
,
May emit poisonous fumes.

See section 8

See section 12

Clean up all spills immediately.
Minor Spills Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Moderate hazard.
Major Spills Clear area of personnel and move upwind.


Avoid all personal contact, including inhalation.
Safe handling Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Fire and explosion

See section 5
protection
Other information

Polyethylene or polypropylene container.
Suitable container Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility Avoid reaction with oxidising agents
accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ x o x + + +

Continued...
UNIPOL

See section 1.2

DNELs PNECs
Ingredient

Inhalation 67.5 mg/m³ (Local, Chronic) 0.11 mg/L (Water (Marine))
2-(2-butoxyethoxy)ethanol Inhalation 101.2 mg/m³ (Local, Acute) 4.4 mg/kg sediment dw (Sediment (Fresh Water))
Oral 6.25 mg/kg bw/day (Systemic, Chronic) * 0.44 mg/kg sediment dw (Sediment (Marine))
56 mg/kg food (Oral)
Inhalation 10 mg/m³ (Local, Chronic)

sodium carbonate Not Available
Inhalation 5 mg/m³ (Local, Chronic) *
Dermal 57.2 mg/kg bw/day (Systemic, Chronic)
Inhalation 52 mg/m³ (Systemic, Chronic)
Dermal 1.57 mg/cm² (Local, Chronic)
Dermal 80 mg/kg bw/day (Systemic, Acute)
Inhalation 52 mg/m³ (Systemic, Acute) 0.693 mg/L (Water (Fresh))
Dermal 1.57 mg/cm² (Local, Acute) 0.654 mg/L (Water - Intermittent release)
Inhalation 52 mg/m³ (Local, Acute) 1 mg/L (Water (Marine))
sodium Dermal 28.6 mg/kg bw/day (Systemic, Chronic) * 27.5 mg/kg sediment dw (Sediment (Fresh Water))
dodecylbenzenesulfonate Inhalation 26 mg/m³ (Systemic, Chronic) * 2.75 mg/kg sediment dw (Sediment (Marine))
Oral 13 mg/kg bw/day (Systemic, Chronic) * 25 mg/kg soil dw (Soil)
Dermal 0.787 mg/cm² (Local, Chronic) * 50 mg/L (STP)
Inhalation 26 mg/m³ (Local, Chronic) * 20 mg/kg food (Oral)
Dermal 40 mg/kg bw/day (Systemic, Acute) *
Inhalation 26 mg/m³ (Systemic, Acute) *
Oral 13 mg/kg bw/day (Systemic, Acute) *
Dermal 0.787 mg/cm² (Local, Acute) *
Inhalation 26 mg/m³ (Local, Acute) *
INGREDIENT DATA

Indicative Occupational 2-(2- 2-(2-Butoxyethoxy) 10 ppm / 67.5 101.2 mg/m3 / 15 Not Not
Exposure Limit Values butoxyethoxy)ethanol ethanol mg/m3 ppm Available Available
(IOELVs)

2-(2- 10 ppm / 68 Not
factors in the work 2-2(butoksyetoksy)etanol Not Available E
butoxyethoxy)ethanol mg/m3 Available
factors (Norwegian)
Emergency Limits
2-(2-butoxyethoxy)ethanol 30 ppm 33 ppm 200 ppm

sodium carbonate 7.6 mg/m3 83 mg/m3 500 mg/m3
sodium
2.1 mg/m3 23 mg/m3 87 mg/m3
dodecylbenzenesulfonate

2-(2-butoxyethoxy)ethanol Not Available Not Available
Fatty alcohol ethoxylates Not Available Not Available

sodium carbonate Not Available Not Available
Continued...
UNIPOL
sodium
Occupational Exposure Banding
Ingredient Occupational Exposure Band Rating Occupational Exposure Band Limit
Fatty alcohol ethoxylates E ≤ 0.1 ppm

sodium carbonate E ≤ 0.01 mg/m³
sodium
E ≤ 0.01 mg/m³
Notes: Occupational exposure banding is a process of assigning chemicals into specific categories or bands based on a chemical's
potency and the adverse health outcomes associated with exposure. The output of this process is an occupational exposure
band (OEB), which corresponds to a range of exposure concentrations that are expected to protect worker health.
MATERIAL DATA

8.2.1. Appropriate

measures, such as
personal protective
equipment

Chemical goggles.

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from
manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material
can not be calculated in advance and has therefore to be checked prior to the application.
Hands/feet protection The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be
observed when making a final choice.
Wear chemical protective gloves, e.g. PVC.
Wear safety footwear or safety gumboots, e.g. Rubber
Overalls.
Other protection P.V.C apron.
Barrier cream.
Recommended material(s) Respiratory protection

GLOVE SELECTION INDEX Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 &
Glove selection is based on a modified presentation of the: 149:2001, ANSI Z88 or national equivalent)
"Forsberg Clothing Performance Index". Where the concentration of gas/particulates in the breathing zone, approaches
The effect(s) of the following substance(s) are taken into account in the or exceeds the "Exposure Standard" (or ES), respiratory protection is required.
computer-generated selection: Degree of protection varies with both face-piece and Class of filter; the nature
UNIPOL of protection varies with Type of filter.
Material CPI Required Minimum Half-Face Full-Face Powered Air

NATURAL RUBBER A Protection Factor Respirator Respirator Respirator
NITRILE A A-PAPR-AUS /
up to 10 x ES A-AUS -
Class 1
* CPI - Chemwatch Performance Index
A-AUS / Class
A: Best Selection up to 50 x ES - -
1
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion up to 100 x ES - A-2 A-PAPR-2 ^
NOTE: As a series of factors will influence the actual performance of the glove,
^ - Full-face
a final selection must be based on detailed observation. -
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or
* Where the glove is to be used on a short term, casual or infrequent basis,
hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
factors such as "feel" or convenience (e.g. disposability), may dictate a choice
dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury,
of gloves which might otherwise be unsuitable following long-term or frequent
NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic
use. A qualified practitioner should be consulted.
Cartridge respirators should never be used for emergency ingress or in

areas of unknown vapour concentrations or oxygen content.
Continued...
UNIPOL
The wearer must be warned to leave the contaminated area immediately

on detecting any odours through the respirator. The odour may indicate that
the mask is not functioning properly, that the vapour concentration is too
high, or that the mask is not properly fitted. Because of these limitations,
only restricted use of cartridge respirators is considered appropriate.
Cartridge performance is affected by humidity. Cartridges should be
changed after 2 hr of continuous use unless it is determined that the
humidity is less than 75%, in which case, cartridges can be used for 4 hr.
Used cartridges should be discarded daily, regardless of the length of time
used

See section 12

Appearance Liquid, pale yellow, soluble in water

Physical state Liquid 1.025 - 1.035
1)
octanol / water
(°C)
Decomposition
pH (as supplied) 8.5 - 9.5 Not Available
temperature (°C)

Not Available Viscosity (cSt) Not Applicable
point (°C)

100 Molecular weight (g/mol) Not Available
boiling range (°C)

or mN/m)
Solubility in water Miscible pH as a solution (1%) Not Available
Vapour density (Air = 1) Not Applicable VOC g/L Not Applicable
Nanoform Particle
Characteristics

Not Available

See section 7.2
hazardous reactions
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3
Continued...
UNIPOL

The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation (as
classified by EC Directives using animal models). Nevertheless, adverse systemic effects have been produced following
Inhaled
exposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimum and that
suitable control measures be used in an occupational setting.
Ingestion Accidental ingestion of the material may be damaging to the health of the individual.
Skin Contact Anionic surfactants/ hydrotropes generally produce skin reactions following the removal of natural oils. The skin may appear red
and may become sore. Papular dermatitis may also develop.
Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce
transient discomfort characterised by tearing or conjunctival redness (as with windburn).
Eye
Direct eye contact with some concentrated anionic surfactants/ hydrotropes produces corneal damage, in some cases severe.
Low concentrations may produce immediate discomfort, conjunctival hyperaemia, and oedema of the corneal epithelium. Healing
may take several days.
Chronic
TOXICITY IRRITATION
UNIPOL
TOXICITY IRRITATION
[2] Eye (rabbit): 20 mg/24h moderate
2-(2-butoxyethoxy)ethanol Dermal (rabbit) LD50: 4120 mg/kg
Oral (Rat) LD50: 5660 mg/kg[2] Eye (rabbit): 5 mg - SEVERE
TOXICITY IRRITATION
Fatty alcohol ethoxylates
TOXICITY IRRITATION
dermal (rat) LD50: >2000 mg/kg[2] Eye (rabbit): 100 mg/24h moderate
Oral (Rat) LD50: 2800 mg/kg[2] Eye (rabbit): 100 mg/30s mild
sodium carbonate Eye (rabbit): 50 mg SEVERE
Eye: adverse effect observed (irritating)[1]
Skin (rabbit): 500 mg/24h mild
Skin: no adverse effect observed (not irritating)[1]
TOXICITY IRRITATION
dermal (rat) LD50: >2000 mg/kg[1] Eye (rabbit): 0.25 mg/24hr-SEVERE
Inhalation (Rat) LC50: 0.31 mg/L4h[1] Eye (rabbit): 1% - SEVERE

sodium [2]
Oral (Rat) LD50: 438 mg/kg Eye: adverse effect observed (irritating)[1]
Skin (rabbit): 20 mg/24 hr-SEVERE
Skin: adverse effect observed (corrosive)[1]
2-(2-butoxyethoxy)ethanol
The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure
to irritants may produce conjunctivitis.
For diethylene glycol monoalkyl ethers and their acetates:
This category includes diethylene glycol ethyl ether (DGEE), diethylene glycol propyl ether (DGPE) diethylene glycol butyl
ether (DGBE) and diethylene glycol hexyl ether (DGHE) and their acetates.
Acute toxicity: There are adequate oral, inhalation and/or dermal toxicity studies on the category members. Oral LD50
values in rats for all category members are all > 3000 mg/kg bw, with values generally decreasing with increasing
Continued...
UNIPOL
molecular weight. Four to eight hour acute inhalation toxicity studies were conducted for all category members except
DGPE in rats at the highest vapour concentrations achievable.
Human beings have regular contact with alcohol ethoxylates through a variety of industrial and consumer products such as
soaps, detergents, and other cleaning products . Exposure to these chemicals can occur through ingestion, inhalation, or
contact with the skin or eyes. Studies of acute toxicity show that volumes well above a reasonable intake level would have
to occur to produce any toxic response.
Alcohol ethoxylates are according to CESIO (2000) classified as Irritant or Harmful depending on the number of EO-units:
EO < 5 gives Irritant (Xi) with R38 (Irritating to skin) and R41 (Risk of serious damage to eyes)
EO > 5-15 gives Harmful (Xn) with R22 (Harmful if swallowed) - R38/41
EO > 15-20 gives Harmful (Xn) with R22-41
Fatty alcohol ethoxylates >20 EO is not classified (CESIO 2000)
Oxo-AE, C13 EO10 and C13 EO15, are Irritating (Xi) with R36/38 (Irritating to eyes and skin) .
AE are not included in Annex 1 of the list of dangerous substances of the Council Directive 67/548/EEC
In general, alcohol ethoxylates (AE) are readily absorbed through the skin of guinea pigs and rats and through the
gastrointestinal mucosa of rats. AE are quickly eliminated from the body through the urine, faeces, and expired air
(CO2).Orally dosed AE was absorbed rapidly and extensively in rats, and more than 75% of the dose was absorbed. When
applied to the skin of humans, the doses were absorbed slowly and incompletely (50% absorbed in 72 hours). No
significant acute toxicological data identified in literature search.
for sodium carbonate:

Sodium carbonate has no or a low skin irritation potential but it is considered irritating to the eyes. Due to the alkaline
properties an irritation of the respiratory tract is also possible.
No valid animal data are available on repeated dose toxicity studies by oral, dermal, inhalation or by other routes for
sodium carbonate. A repeated dose inhalation study, which was not reported in sufficient detail, revealed local effects on
SODIUM CARBONATE
the lungs which could be expected based on the alkaline nature of the compound.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis
(nonallergic). This form of dermatitis is often characterised by skin redness (erythema) and swelling epidermis.
Histologically there may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the
epidermis.
Linear alkylbenzene sulfonates (LAS) are classified as Irritant (Xi) with the risk phrases R38 (Irritating to skin) and R41
(Risk of serious damage to eyes) according to CESIO (CESIO 2000). LAS are not included in Annex 1 of list of dangerous
substances of Council Directive 67/548/EEC.
UNIPOL & SODIUM
Linear alkylbenzene sulfonic acids (LABS) are strong acids (pKa<2) are classified as corrosive (R34)
DODECYLBENZENESULFONATE
Branched materials exhibit comparable toxicity to linear species.
Acute toxicity: The available data indicate minimal to moderate toxicity, with LD50 values ranging from 500 to 2000 mg/kg
body weight (bw).
Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a
SODIUM CARBONATE & non-allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high
SODIUM levels of highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease in
DODECYLBENZENESULFONATE a non-atopic individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documented
exposure to the irritant.

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity

UNIPOL Not Not Not
2-(2-butoxyethoxy)ethanol
Continued...
UNIPOL
EC50 48h Crustacea >100mg/l 1
NOEC(ECx) 96h Algae or other aquatic plants >=100mg/l 1

Fatty alcohol ethoxylates Not Not Not

NOEC(ECx) 48h Fish 0.011mg/L 4
sodium carbonate EC50 96h Algae or other aquatic plants 242mg/L 4
156.6-
EC50 48h Crustacea 4
298.9mg/l

LC50 96h Fish 0.59mg/L 4

sodium 0.065-
EC50(ECx) 48h Crustacea 4
dodecylbenzenesulfonate 0.085mg/L
EC50 96h Algae or other aquatic plants 0.9mg/L 5
0.065-
0.085mg/L
For linear alkylbenzene sulfonic acids (LABS) (and their salts):

Environmental fate:
LABS are generally highly water soluble (miscible) and have a relatively low Kow. The environmental fate data indicate that these chemicals are highly susceptible
to photo-and biodegradation.
LABS are strong acids (pKa <1) that are completely ionised in aqueous solutions.
For Surfactants: Kow cannot be easily determined due to hydrophilic/hydrophobic properties of the molecules in surfactants. BCF value: 1-350.
Aquatic Fate: Surfactants tend to accumulate at the interface of the air with water and are not extracted into one or the other liquid phases.

2-(2-butoxyethoxy)ethanol LOW LOW
sodium carbonate LOW LOW

2-(2-butoxyethoxy)ethanol LOW (BCF = 0.46)
sodium carbonate LOW (LogKOW = -0.4605)

Ingredient Mobility
2-(2-butoxyethoxy)ethanol LOW (Log KOC = 10)
sodium carbonate HIGH (Log KOC = 1)

P B T

PBT
vPvB
Continued...
UNIPOL
vPvB No



Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws
operating in their area. In some areas, certain wastes must be tracked.
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
Product / Packaging In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
disposal Recycle wherever possible.
Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable
treatment or disposal facility can be identified.
Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or incineration in a
licensed apparatus (after admixture with suitable combustible material).
Labels Required
Marine Pollutant NO
Land transport (ADR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Not Applicable
number

Not Applicable
name
14.3. Transport hazard Class Not Applicable

14.5. Environmental
Not Applicable
hazard
Hazard identification (Kemler) Not Applicable
Classification code Not Applicable
14.6. Special precautions Hazard Label Not Applicable

for user Special provisions Not Applicable
Limited quantity Not Applicable
Tunnel Restriction Code Not Applicable
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable

Not Applicable
name
ICAO/IATA Class Not Applicable

class(es)
ERG Code Not Applicable
14.5. Environmental
Not Applicable
hazard
Continued...
UNIPOL
14.6. Special precautions Cargo Only Packing Instructions Not Applicable

for user
Cargo Only Maximum Qty / Pack Not Applicable
Passenger and Cargo Packing Instructions Not Applicable
Passenger and Cargo Maximum Qty / Pack Not Applicable
Passenger and Cargo Limited Quantity Packing Instructions Not Applicable
Passenger and Cargo Limited Maximum Qty / Pack Not Applicable
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Not Applicable
name
14.3. Transport hazard IMDG Class Not Applicable

EMS Number Not Applicable

for user
Limited Quantities Not Applicable
Inland waterways transport (ADN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Not Applicable
name

Not Applicable Not Applicable
class(es)
14.5. Environmental
Not Applicable
hazard

for user
Equipment required Not Applicable
Fire cones number Not Applicable
Not Applicable
Product name Group
2-(2-butoxyethoxy)ethanol Not Available

Fatty alcohol ethoxylates Not Available
sodium
Not Available

2-(2-butoxyethoxy)ethanol Not Available
Fatty alcohol ethoxylates Not Available
sodium
Not Available
Continued...
UNIPOL
2-(2-butoxyethoxy)ethanol is found on the following regulatory lists

EU REACH Regulation (EC) No 1907/2006 - Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances,
mixtures and articles
Europe EC Inventory
European Union (EU) Regulation (EC) No 1272/2008 on Classification, Labelling and Packaging of Substances and Mixtures - Annex VI
(Norwegian)
Fatty alcohol ethoxylates is found on the following regulatory lists
Not Applicable
sodium carbonate is found on the following regulatory lists
Europe EC Inventory
sodium dodecylbenzenesulfonate is found on the following regulatory lists
Europe EC Inventory

Not Applicable




Yes
Non-Industrial Use
Canada - DSL No (Fatty alcohol ethoxylates)
Canada - NDSL No (2-(2-butoxyethoxy)ethanol; Fatty alcohol ethoxylates; sodium carbonate; sodium dodecylbenzenesulfonate)
China - IECSC Yes

No (Fatty alcohol ethoxylates)
NLP
Japan - ENCS Yes
Korea - KECI Yes
USA - TSCA Yes

Taiwan - TCSI Yes
Mexico - INSQ No (Fatty alcohol ethoxylates)
Vietnam - NCI Yes
Russia - FBEPH No (Fatty alcohol ethoxylates)

registration.
Continued...
UNIPOL
CONTACT POINT

H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H319 Causes serious eye irritation.
SDS Version Summary

Date of
Update
Hazards identification - Classification, Firefighting measures - Fire Fighter (fire/explosion hazard), Composition /
6.7 29/09/2023 information on ingredients - Ingredients, Identification of the substance / mixture and of the company /
undertaking - Synonyms
Other information
regulation (EC) No
1272/2008 [CLP] and
amendments
Expert judgement
Category 2, H315
Serious Eye Damage/Eye

Expert judgement
Irritation Category 1, H318
Continued...
UNIPOL
end of SDS
UNITOR MKII CELL CLEANER

Product name UNITOR MKII CELL CLEANER
Synonyms Not Available

Other means of
532335, 632308, 673350, 673354, 673355, 773359
identification
Relevant identified uses Instruments and apparatus for physical or chemical analysis

Central Warehouse
login=wilhelmsen
--------- Norway

Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
Not considered a hazardous mixture according to Reg. (EC) No 1272/2008 and their amendments. Not classified as Dangerous Goods for
transport purposes.
regulation (EC) No
1272/2008 [CLP] and Not Applicable
amendments [1]
2.2. Label elements
Hazard pictogram(s) Not Applicable
Signal word Not Applicable
Hazard statement(s)
Not Applicable
Not Applicable

Not Applicable

Not Applicable

Not Applicable

Not Applicable

Not Applicable
2.3. Other hazards
3.1.Substances
3.2.Mixtures
1. CAS No
Name SCL / M-Factor
4.REACH No
Not Available
1. 68956-68-3
Acute M factor:
2.273-313-5 vegetable
50-100 Not Classified [1] Not Available Not Available
3.Not Available oils
Chronic M factor:
4.Not Available
Not Available
Continued...

If this product comes in contact with eyes:
Wash out immediately with water.
Eye Contact
If irritation continues, seek medical attention.
Inhalation
Immediately give a glass of water.
Ingestion
First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
See Section 11

Foam.
Dry chemical powder.
BCF (where regulations permit).

result

Fire Fighting Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of containers.
,
,
acrolein
,
CARE: Water in contact with hot liquid may cause foaming and a steam explosion with wide scattering of hot oil and possible
severe burns. Foaming may cause overflow of containers and may result in possible fire.

See section 8

See section 12

Slippery when spilt.
Remove all ignition sources.
Minor Spills
Avoid breathing vapours and contact with skin and eyes.
Major Spills Slippery when spilt.

CARE: Absorbent materials wetted with occluded oil must be moistened with water as they may auto-oxidize, become self
heating and ignite.
Some oils slowly oxidise when spread in a film and oil on cloths, mops, absorbents may autoxidise and generate heat, smoulder,
ignite and burn. In the workplace oily rags should be collected and immersed in water.
Moderate hazard.
Continued...
Clear area of personnel and move upwind.



Rags wet / soaked with unsaturated hydrocarbons / drying oils may auto-oxidise; generate heat and, in-time, smoulder and
ignite. This is especially the case where oil-soaked materials are folded, bunched, compressed, or piled together - this allows the
heat to accumulate or even accelerate the reaction
Safe handling Oily cleaning rags should be collected regularly and immersed in water, or spread to dry in safe-place away from direct sunlight
or stored, immersed, in solvents in suitably closed containers.
Wear protective clothing when risk of exposure occurs.
Fire and explosion

See section 5
protection
Consider storage under inert gas.
Store in original containers.
Other information
Keep containers securely sealed.
No smoking, naked lights or ignition sources.

Glass container is suitable for laboratory quantities
Metal can or drum
Suitable container
Packaging as recommended by manufacturer.
Avoid contamination of water, foodstuffs, feed or seed.
Avoid reaction with oxidising agents
accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ + + + + + +


See section 1.2

DNELs PNECs
Ingredient
Continued...
INGREDIENT DATA

Not Applicable
Emergency Limits

UNITOR MKII CELL
CLEANER

vegetable oils Not Available Not Available
MATERIAL DATA

8.2.1. Appropriate Process controls which involve changing the way a job activity or process is done to reduce the risk.
engineering controls Care: Atmospheres in bulk storages and even apparently empty tanks may be hazardous by oxygen depletion. Atmosphere must
be checked before entry.
Requirements of State Authorities concerning conditions for tank entry must be met. Particularly with regard to training of crews
for tank entry; work permits; sampling of atmosphere; provision of rescue harness and protective gear as needed

measures, such as
personal protective
equipment

Chemical goggles.
Wear general protective gloves, eg. light weight rubber gloves.

The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be

No special equipment needed when handling small quantities.
OTHERWISE:
Other protection
Overalls.
Barrier cream.

"Forsberg Clothing Performance Index". Selection of the Class and Type of respirator will depend upon the level of
The effect(s) of the following substance(s) are taken into account in the breathing zone contaminant and the chemical nature of the contaminant.
computer-generated selection: Protection Factors (defined as the ratio of contaminant outside and inside the
UNITOR MKII CELL CLEANER mask) may also be important.
Material CPI Required

Maximum gas/vapour
PVC A minimum Half-face Full-Face
concentration present in
protection Respirator Respirator
air p.p.m. (by volume)
* CPI - Chemwatch Performance Index factor
A: Best Selection A-AUS /
B: Satisfactory; may degrade after 4 hours continuous immersion up to 10 1000 -
Class1
C: Poor to Dangerous Choice for other than short term immersion
A-AUS /
NOTE: As a series of factors will influence the actual performance of the glove, up to 50 1000 -
Class 1
* Where the glove is to be used on a short term, casual or infrequent basis, up to 50 5000 Airline * -
factors such as "feel" or convenience (e.g. disposability), may dictate a choice up to 100 5000 - A-2
up to 100 10000 - A-3
Continued...
of gloves which might otherwise be unsuitable following long-term or frequent 100+ Airline**

used

See section 12

Appearance Yellow to Amber

Physical state Liquid 0.879
1)
octanol / water
(°C)
Decomposition
temperature (°C)

-10 Viscosity (cSt) Not Available
point (°C)

>150 Molecular weight (g/mol) Not Available
boiling range (°C)
Flash point (°C) 180 Taste Not Available


or mN/m)

Vapour density (Air = 1) Not Available VOC g/L Not Available
Nanoform Particle
Characteristics

Not Available

10.2. Chemical stability Product is considered stable and hazardous polymerisation will not occur.
See section 7.2
hazardous reactions
Continued...

10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

Inhaled Not normally a hazard due to non-volatile nature of product
Inhalation of oil droplets/ aerosols may cause discomfort and may produce chemical pneumonitis.
Fine mists generated from plant/ vegetable (or more rarely from animal) oils may be hazardous. Extreme heating for prolonged
periods, at high temperatures, may generate breakdown products which include acrolein and acrolein-like substances.
The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because
Ingestion of the lack of corroborating animal or human evidence. The material may still be damaging to the health of the individual,
following ingestion, especially where pre-existing organ (e.g liver, kidney) damage is evident.
Skin Contact using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves
Eye Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce
Chronic
UNITOR MKII CELL TOXICITY IRRITATION

CLEANER Not Available Not Available
TOXICITY IRRITATION
vegetable oils
VEGETABLE OILS Refined grades are edible. No significant acute toxicological data identified in literature search.

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity

UNITOR MKII CELL
Not Not Not
CLEANER Not Available Not Available
Continued...

vegetable oils Not Not Not
For aliphatic fatty acids and alcohols:

Environmental fate:
Saturated fatty acids are very stable in air, whereas unsaturated (C=C bonds) fatty acids are susceptible to oxidation.
Unsaturation increases the rate of metabolism although the degree of unsaturation and positioning of double bonds is not highly significant.
The available data indicate all fatty acid salt chain lengths up to and including C18 can be metabolised under aerobic conditions and can be considered to be
readily biodegradable
All tests showed that fatty acids and lipids are readily biodegradable
The aliphatic acids are of similar very weak acid strength (approximately pKa 5), i.e., partially dissociate in aqueous solution; the salts of the aliphatic acids are
highly dissociated in water solution such that the anion is the same for homologous salts and acids.
Unsaturated vegetable oils are often used in paints which upon "drying" produce a polymeric network formed of the constituent fatty acids.
During the drying process, a number of compounds are produced that do not contribute to the polymer network. These include unstable hydroperoxide (ROOH)
the major by-product of the reaction of oxygen with unsaturated fatty acids.

No Data available for all ingredients No Data available for all ingredients

No Data available for all ingredients

Ingredient Mobility

P B T
PBT
vPvB

vPvB No



Product / Packaging It may be necessary to collect all wash water for treatment before disposal.
disposal In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Authority for disposal.
Bury or incinerate residue at an approved site.
Continued...
Labels Required
Marine Pollutant NO

Not Applicable
number

Not Applicable
name

14.5. Environmental
Not Applicable
hazard

Not Applicable
name

class(es)

14.5. Environmental
Not Applicable
hazard
Cargo Only Packing Instructions Not Applicable

for user

Not Applicable
name



for user
Continued...
Not Applicable
name
class(es)

14.5. Environmental
Not Applicable
hazard

for user
Not Applicable
Product name Group
vegetable oils Not Available

vegetable oils is found on the following regulatory lists

Europe EC Inventory

Not Applicable




Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (vegetable oils)
China - IECSC Yes

Yes
NLP
Japan - ENCS No (vegetable oils)

Korea - KECI Yes
Continued...

USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ Yes
Vietnam - NCI Yes

Russia - FBEPH No (vegetable oils)

registration.
CONTACT POINT
Other information
end of SDS
UNITOR REAGENT S DIGI
Part Number: 733156 - 733155 Issue Date: 05/12/2022

Product name UNITOR REAGENT S DIGI
Synonyms 733156 (Unitor easyship reagent pack water) -773155 (Unitor easyship water test kit)
Other means of
733156 - 733155, 733156
identification
Relevant identified uses reagent

Central Warehouse
login=wilhelmsen

--------- Norway


Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
Part Number: 733156 - 733155 Page 2 of 12 Issue Date: 05/12/2022
transport purposes.
regulation (EC) No H304 - Aspiration Hazard Category 1, H315 - Skin Corrosion/Irritation Category 2, H336 - Specific Target Organ Toxicity - Single
1272/2008 [CLP] and Exposure (Narcotic Effects) Category 3, H412 - Hazardous to the Aquatic Environment Long-Term Hazard Category 3
amendments [1]
2.2. Label elements
Hazard pictogram(s)
Signal word Danger
Hazard statement(s)
H304 May be fatal if swallowed and enters airways.

H336 May cause drowsiness or dizziness.
H412 Harmful to aquatic life with long lasting effects.
Not Applicable

Not Applicable

P271 Use only outdoors or in a well-ventilated area.
P261 Avoid breathing mist/vapours/spray.
P273 Avoid release to the environment.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/physician/first aider.
P331 Do NOT induce vomiting.
P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.

P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.
Material contains distillates, petroleum, light, hydrotreated.
2.3. Other hazards

3.1.Substances
Continued...
3.2.Mixtures
1. CAS No
2.EC No % Classification according to regulation (EC) No SCL / M- Nanoform Particle
Name
3.Index No [weight] 1272/2008 [CLP] and amendments Factor Characteristics
4.REACH No
Not
Available
Aspiration Hazard Category 1, Skin Corrosion/Irritation
1. 64742-47-8* Acute M
distillates, Category 2, Specific Target Organ Toxicity - Single
2.265-149-8 factor: Not
>90 petroleum, light, Exposure (Narcotic Effects) Category 3, Hazardous to Not Available
3.649-422-00-2 Available
hydrotreated the Aquatic Environment Long-Term Hazard Category
2; H304, H315, H336, H411 [1] factor: Not
Available

Eye Contact
Skin Contact
Inhalation
Ingestion
See Section 11
Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. Mechanical means
should be used if it is considered necessary to evacuate the stomach contents; these include gastric lavage after endotracheal intubation. If spontaneous vomiting
has occurred after ingestion, the patient should be monitored for difficult breathing, as adverse effects of aspiration into the lungs may be delayed up to 48 hours.



Non combustible.
May emit corrosive fumes.

See section 8
Continued...
See section 12

Moderate hazard.


Safe handling
DO NOT allow clothing wet with material to stay in contact with skin
Fire and explosion

See section 5
protection
Other information

Storage incompatibility None known
accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ x + o + + +


See section 1.2

DNELs PNECs
Ingredient
INGREDIENT DATA
Continued...

distillates, petroleum, light, Mineraloljer brukt som Not Not Not
factors in the work HKG24
hydrotreated motorolje Available Available Available
factors (Norwegian)
Emergency Limits
distillates, petroleum, light,

140 mg/m3 1,500 mg/m3 8,900 mg/m3
hydrotreated

2,500 mg/m3 Not Available
hydrotreated
MATERIAL DATA
more.

8.2.1. Appropriate

measures, such as
personal protective
equipment
Safety glasses with side shields.

Eye and face protection Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent]

Hands/feet protection manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material
Overalls.
Barrier cream.

See section 12

Appearance Blue liquid with characteristic odour; insoluble in water.

1)
octanol / water
(°C)
Continued...
Decomposition
temperature (°C)
point (°C)

192-256 Molecular weight (g/mol) Not Available
boiling range (°C)


or mN/m)
Vapour pressure (kPa) 0.04 Gas group Not Available


Nanoform Particle
Characteristics

Not Available

See section 7.2
hazardous reactions
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

Inhaled control measures be used in an occupational setting.
Swallowing of the liquid may cause aspiration of vomit into the lungs with the risk of haemorrhaging, pulmonary oedema,
progressing to chemical pneumonitis; serious consequences may result.
Signs and symptoms of chemical (aspiration) pneumonitis may include coughing, gasping, choking, burning of the mouth, difficult
Ingestion breathing, and bluish coloured skin (cyanosis).
of the lack of corroborating animal or human evidence. The material may still be damaging to the health of the individual,
Skin Contact blistering (vesiculation), scaling and thickening of the epidermis.
Eye
Continued...
Chronic
TOXICITY IRRITATION
TOXICITY IRRITATION
Dermal (rabbit) LD50: >2000 mg/kg[2] Eye: no adverse effect observed (not irritating)[1]
hydrotreated Inhalation (Rat) LC50: >4.3 mg/l4h[1] Skin: adverse effect observed (irritating)[1]
Oral (Rat) LD50: >5000 mg/kg[2]
For "kerosenes"
Acute toxicity: Oral LD50s for three kerosenes (Jet A, CAS No. 8008-20-6 and CAS No. 64742-81-0) ranged from > 2 to >20
distillates, petroleum, light, g/kg The dermal LD50s of the same three kerosenes were all >2.0 g//kg. Inhalation LC50 values in Sprague-Dawley rats for
hydrotreated straight run kerosene (CAS No. 8008-20-6) and hydrodesulfurised kerosene (CAS No. 64742-81-0) were reported to be > 5 and
> 5.2 mg/l, respectively. No mortalities in rats were reported in rats when exposed for eight hours to saturated vapor of
deodorised kerosene (probably a desulfurised kerosene). No significant acute toxicological data identified in literature search.

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity

UNITOR REAGENT S DIGI Not Not Not

hydrotreated
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning
equipment or disposing of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
Continued...

LOW (BCF = 159)
hydrotreated

Ingredient Mobility

P B T
PBT
vPvB
vPvB No




Labels Required
Marine Pollutant NO

Not Applicable
number

Not Applicable
name

14.5. Environmental
Not Applicable
hazard
Continued...


Not Applicable
name

class(es)
14.5. Environmental
Not Applicable
hazard


for user
Not Applicable
name


for user

Not Applicable
name
class(es)
14.5. Environmental
Not Applicable
hazard

for user
Continued...
Not Applicable
Product name Group

Not Available
hydrotreated


Not Available
hydrotreated
distillates, petroleum, light, hydrotreated is found on the following regulatory lists
Chemical Footprint Project - Chemicals of High Concern List

Europe EC Inventory
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs - Group 1: Carcinogenic to humans
(Norwegian)

Not Applicable




Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (distillates, petroleum, light, hydrotreated)
China - IECSC Yes

Yes
NLP
Japan - ENCS Yes

Korea - KECI Yes
USA - TSCA Yes

Taiwan - TCSI Yes
Mexico - INSQ Yes
Vietnam - NCI Yes
Russia - FBEPH Yes

Legend: Yes = All CAS declared ingredients are on the inventory
Continued...

No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require
registration.

CONTACT POINT

H411 Toxic to aquatic life with long lasting effects.
SDS Version Summary

Date of
Update
Composition / information on ingredients - Ingredients, Accidental release measures - Spills (major),
2.5 05/12/2022
Accidental release measures - Spills (minor)
Other information
Continued...
end of SDS
UNITOR TBN + REAGENT

Product name UNITOR TBN + REAGENT
Synonyms Reagent to determine base number of engine oils

Other means of
632306, 632307, 632308, 673354, 673355
identification

Central Warehouse
login=wilhelmsen
--------- Norway

Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
transport purposes.
regulation (EC) No
amendments [1]
2.2. Label elements
Hazard statement(s)
Not Applicable
Not Applicable

Not Applicable

Not Applicable

Not Applicable

Not Applicable

Not Applicable
Material contains hydrocarbons, C10-13- n-alkanes, isoalkanes, cyclics, < 2% aromatics, phosphoric acid, sodium linear-(C12-14)alkyl ether sulfate, triisobutyl
phosphate.
2.3. Other hazards

Possible skin sensitizer*.
hydrocarbons, C10-13- n-
Determined to have endocrine-disrupting properties according to Europe Regulation (EU) 528/2012, Europe Regulation (EU)
alkanes, isoalkanes,
2017/2100, and Europe Regulation (EU) 2018/605
cyclics, < 2% aromatics
3.1.Substances
3.2.Mixtures
Continued...
1. CAS No
Classification according to regulation Nanoform
2.EC No %
Name (EC) No 1272/2008 [CLP] and SCL / M-Factor Particle
3.Index No [weight]
amendments Characteristics
4.REACH No
Not Available
1. 68891-38-3 Acute Toxicity (Oral) Category 4, Skin
Acute M factor: Not
2.500-234-8 sodium linear-(C12- Corrosion/Irritation Category 2, Serious
0.8 Eye Damage/Eye Irritation Category 2; Available Not Available
3.Not Available 14)alkyl ether sulfate
Chronic M factor:
4.Not Available H302, H315, H319 [1]
Not Available
Not Available
1. Not Available hydrocarbons, C10- Flammable Liquids Category 3, Aspiration
Acute M factor: Not
2.Not Available 13- n-alkanes, Hazard Category 1, Specific Target Organ
8 Available Not Available
3.Not Available isoalkanes, cyclics, < Toxicity - Single Exposure (Narcotic
Chronic M factor:
4.Not Available 2% aromatics [e] Effects) Category 3; H226, H304, H336 [1] Not Available
Skin Corr. 1B; H314:
C ≥ 25 % | Skin Irrit.
2; H315: 10 % ≤ C <
1. 7664-38-2 25 % | Eye Irrit. 2;
2.231-633-2 Skin Corrosion/Irritation Category 1B; H319: 10 % ≤ C < 25
4 phosphoric acid * Not Available
3.015-011-00-6 H314 [2] %
4.Not Available Acute M factor: Not
Available
Chronic M factor:
Not Available
Acute Toxicity (Oral) Category 4, Skin
Corrosion/Irritation Category 2, Not Available
1. 126-71-6
Acute M factor: Not
2.204-798-3 Sensitisation (Skin) Category 1, Serious
0.8 triisobutyl phosphate Available Not Available
3.Not Available Eye Damage/Eye Irritation Category 2,
Carcinogenicity Category 2; H302, H315, Chronic M factor:
4.Not Available
Not Available
H317, H319, H351 [1]

Immediately hold eyelids apart and flush the eye continuously with running water.
Eye Contact lifting the upper and lower lids.
Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
Transport to hospital or doctor without delay.
Skin Contact
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid
Inhalation procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket
mask as trained. Perform CPR if necessary.
Transport to hospital, or doctor, without delay.

Ingestion
See Section 11

Continued...

result

,
Fire/Explosion Hazard other pyrolysis products typical of burning organic material.

See section 8

See section 12

Minor Spills
Chemical Class: aliphatic hydrocarbons
For release onto land: recommended sorbents listed in order of priority.
SORBENT
RANK APPLICATION COLLECTION LIMITATIONS
TYPE
LAND SPILL - SMALL
cross-linked polymer - particulate 1 shovel shovel R, W, SS

cross-linked polymer - pillow 1 throw pitchfork R, DGC, RT
wood fiber - pillow 2 throw pitchfork R, P, DGC, RT

treated wood
2 throw pitchfork DGC, RT
fibre- pillow
sorbent clay - particulate 3 shovel shovel R, I, P
foamed glass - pillow 3 throw pitchfork R, P, DGC, RT
LAND SPILL - MEDIUM
cross-linked polymer - particulate 1 blower skiploader R,W, SS

Major Spills cross-linked polymer - pillow 2 throw skiploader R, DGC, RT
sorbent clay - particulate 3 blower skiploader R, I, P

polypropylene - particulate 3 blower skiploader W, SS, DGC
expanded mineral - particulate 4 blower skiploader R, I, W, P, DGC
polypropylene - mat 4 throw skiploader DGC, RT
Legend
DGC: Not effective where ground cover is dense
R; Not reusable
I: Not incinerable
P: Effectiveness reduced when rainy
RT:Not effective where terrain is rugged
SS: Not for use within environmentally sensitive sites
W: Effectiveness reduced when windy
Reference: Sorbents for Liquid Hazardous Substance Cleanup and Control;
R.W Melvold et al: Pollution Technology Review No. 150: Noyes Data Corporation 1988
Moderate hazard.

Continued...

The conductivity of this material may make it a static accumulator., A liquid is typically considered nonconductive if its
conductivity is below 100 pS/m and is considered semi-conductive if its conductivity is below 10 000 pS/m., Whether a liquid is
nonconductive or semi-conductive, the precautions are the same., A number of factors, for example liquid temperature, presence
of contaminants, and anti-static additives can greatly influence the conductivity of a liquid.
Containers, even those that have been emptied, may contain explosive vapours.
Do NOT cut, drill, grind, weld or perform similar operations on or near containers.
· Electrostatic discharge may be generated during pumping - this may result in fire.
Safe handling
· Ensure electrical continuity by bonding and grounding (earthing) all equipment.
· Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<=1 m/sec until fill pipe submerged
to twice its diameter, then <= 7 m/sec).
Fire and explosion

See section 5
protection
Other information

Low molecular weight alkanes:
May react violently with strong oxidisers, chlorine, chlorine dioxide, dioxygenyl tetrafluoroborate.
May react with oxidising materials, nickel carbonyl in the presence of oxygen, heat.
Are incompatible with nitronium tetrafluoroborate(1-), halogens and interhalogens
may generate electrostatic charges, due to low conductivity, on flow or agitation.
accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ + + + + + +


See section 1.2

DNELs PNECs
Ingredient
sodium linear-(C12-14)alkyl Dermal 2 750 mg/kg bw/day (Systemic, Chronic) 0.052 mg/L (Water (Fresh))
ether sulfate Inhalation 7.9 mg/m³ (Systemic, Chronic) 0.071 mg/L (Water - Intermittent release)
Dermal 132 µg/cm² (Local, Chronic) 0.024 mg/L (Water (Marine))
Dermal 1 650 mg/kg bw/day (Systemic, Chronic) * 0.2 mg/kg sediment dw (Sediment (Fresh Water))
Inhalation 1.4 mg/m³ (Systemic, Chronic) * 0.02 mg/kg sediment dw (Sediment (Marine))
Continued...
DNELs PNECs
Ingredient
Oral 1.125 mg/kg bw/day (Systemic, Chronic) * 7.5 mg/kg soil dw (Soil)
Dermal 79 µg/cm² (Local, Chronic) * 1 g/L (STP)

Dermal 134.5 mg/kg bw/day (Systemic, Acute)
Inhalation 948.6 mg/m³ (Systemic, Acute)
Inhalation 1 mg/m³ (Local, Acute)
Dermal 1.9 mg/kg bw/day (Systemic, Chronic) *
phosphoric acid Not Available
Inhalation 3.3 mg/m³ (Systemic, Chronic) *
Oral 0.1 mg/kg bw/day (Systemic, Chronic) *
Inhalation 0.36 mg/m³ (Local, Chronic) *
Dermal 67.3 mg/kg bw/day (Systemic, Acute) *
Inhalation 233.9 mg/m³ (Systemic, Acute) *
Oral 67.3 mg/kg bw/day (Systemic, Acute) *

Dermal 4.25 mg/kg bw/day (Systemic, Chronic) 0.143 mg/L (Water - Intermittent release)
Inhalation 50 mg/m³ (Systemic, Chronic) 0.001 mg/L (Water (Marine))
triisobutyl phosphate Dermal 2.13 mg/kg bw/day (Systemic, Chronic) * 2.05 mg/kg sediment dw (Sediment (Fresh Water))
3.72 mg/L (STP)
INGREDIENT DATA

phosphoric acid Ortophosphoric acid 1 mg/m3 2 mg/m3 Not Available Not Available
(IOELVs)

factors in the work phosphoric acid Fosforsyre 1 mg/m3 Not Available Not Available E
factors (Norwegian)
Emergency Limits
phosphoric acid Not Available Not Available Not Available
sodium linear-(C12-14)alkyl
ether sulfate
alkanes, isoalkanes, cyclics, Not Available Not Available
< 2% aromatics
phosphoric acid 1,000 mg/m3 Not Available
triisobutyl phosphate Not Available Not Available
E ≤ 0.01 mg/m³
ether sulfate
triisobutyl phosphate E ≤ 0.1 ppm
MATERIAL DATA
for tributyl phosphate:
Continued...
An irritant of eyes, skin and mucous membranes in experimental animals, weak cholinesterase inhibitor with narcotic properties. The recommended value for TLV-
TWA is identical to that of triphenyl phosphate measured as ppm. Exposure at or below this limit is thought to protect workers against the significant risk of
anaesthetic effects and skin and eye irritation.
The saturated vapour concentration of phosphoric acid exceeds the TLV. The TLV-TWA is based by analogy from comparable experience and data for sulfuric
acid. Exposure at or below this limit is thought to prevent throat irritation amongst unacclimatised workers.

8.2.1. Appropriate

measures, such as
personal protective
equipment


NOTE:
The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and
other protective equipment, to avoid all possible skin contact.
Hands/feet protection Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
Overalls.
Barrier cream.

GLOVE SELECTION INDEX Type AB-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 &
UNITOR TBN + REAGENT of protection varies with Type of filter.

NAT+NEOPR+NITRILE A Protection Factor Respirator Respirator Respirator
NATURAL RUBBER A AB-PAPR-AUS /

up to 10 x ES AB-AUS P2 -
Class 1 P2
NATURAL+NEOPRENE A
AB-AUS /
NEOPRENE A up to 50 x ES - -
Class 1 P2
NEOPRENE/NATURAL A
up to 100 x ES - AB-2 P2 AB-PAPR-2 P2 ^
NITRILE A
^ - Full-face
NITRILE+PVC A
PE A hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
PVC A dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury,
SARANEX-23 A
A: Best Selection
* Where the glove is to be used on a short term, casual or infrequent basis, only restricted use of cartridge respirators is considered appropriate.
Continued...

used

See section 12


1)
octanol / water
(°C)
Decomposition
temperature (°C)
point (°C)

boiling range (°C)


or mN/m)

Solubility in water Not Available pH as a solution (1%) Not Available
Nanoform Particle
Characteristics

Not Available

See section 7.2
hazardous reactions

10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

Inhaled The material is not thought to produce respiratory irritation (as classified by EC Directives using animal models). Nevertheless
inhalation of vapours, fumes or aerosols, especially for prolonged periods, may produce respiratory discomfort and occasionally,
distress.
Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may produce
severe damage to the health of the individual. Relatively small amounts absorbed through the lungs may prove fatal.
Continued...
Some aliphatic hydrocarbons produce axonal neuropathies. Isoparaffinic hydrocarbons produce injury to the kidneys of male
rats. When albino rats were exposed to isoparaffins at 21.4 mg/l for 4 hours, all animals experienced weakness, tremors,
salivation, mild to moderate convulsions, chromodacryorrhoea and ataxia within the first 24 hours.
Ingestion Many aliphatic hydrocarbons create a burning sensation because they are irritating to the GI mucosa. Vomiting has been
reported in up to one third of all hydrocarbon exposures. While most aliphatic hydrocarbons have little GI absorption, aspiration
frequently occurs, either initially or in a semi-delayed fashion as the patient coughs or vomits, thereby resulting in pulmonary
effects.
Skin Contact Dermally, isoparaffins have produced slight to moderate irritation in animals and humans under occluded patch conditions where
evaporation cannot freely occur. However, they are not irritating in non-occluded tests, which are a more realistic simulation of
human exposure. They have not been found to be sensitisers in guinea pig or human patch testing.
The liquid may be miscible with fats or oils and may degrease the skin, producing a skin reaction described as non-allergic
contact dermatitis. The material is unlikely to produce an irritant dermatitis as described in EC Directives .
When applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty-four hours or more
Eye after instillation.
Instillation of isoparaffins into rabbit eyes produces only slight irritation.
On the basis, primarily, of animal experiments, concern has been expressed that the material may produce carcinogenic or
mutagenic effects; in respect of the available information, however, there presently exists inadequate data for making a
satisfactory assessment.
Practical experience shows that skin contact with the material is capable either of inducing a sensitisation reaction in a
Chronic
substantial number of individuals, and/or of producing a positive response in experimental animals.
Substances that can cause occupational asthma (also known as asthmagens and respiratory sensitisers) can induce a state of
specific airway hyper-responsiveness via an immunological, irritant or other mechanism. Once the airways have become hyper-
responsive, further exposure to the substance, sometimes even to tiny quantities, may cause respiratory symptoms.
TOXICITY IRRITATION
TOXICITY IRRITATION
sodium linear-(C12-
dermal (rat) LD50: >540 mg/kg[1] Eye: adverse effect observed (irritating)[1]
14)alkyl ether sulfate
Oral (Rat) LD50: >540 mg/kg[1] Skin: adverse effect observed (irritating)[1]
hydrocarbons, C10-13- n- TOXICITY IRRITATION

alkanes, isoalkanes,
cyclics, < 2% aromatics
TOXICITY IRRITATION
Dermal (rabbit) LD50: >1260 mg/kg[2] Eye (rabbit): 119 mg - SEVERE [Monsanto]*
phosphoric acid Inhalation (Rat) LC50: 0.026 mg/L4h[2] Eye: adverse effect observed (irritating)[1]
Oral (Rat) LD50: 1530 mg/kg[2] Skin (rabbit):595 mg/24h - SEVERE
TOXICITY IRRITATION
Dermal (rabbit) LD50: >5000 mg/kg[1] Eye : Moderate

triisobutyl phosphate
Inhalation (Rat) LC50: >5.14 mg/l4h[2] Skin : Moderate
UNITOR TBN + REAGENT Chronic inhalation exposures may show indications of peripheral neuropathy, a progressive nerve disorder of extremities.
Continued...
Polyethers, for example, ethoxylated surfactants and polyethylene glycols, are highly susceptible towards air oxidation as the
ether oxygens will stabilize intermediary radicals involved. Investigations of a chemically well-defined alcohol (pentaethylene
glycol mono-n-dodecyl ether) ethoxylate, showed that polyethers form complex mixtures of oxidation products when exposed to
air.
Sensitization studies in guinea pigs revealed that the pure nonoxidized surfactant itself is nonsensitizing but that many of the
investigated oxidation products are sensitizers. Two hydroperoxides were identified in the oxidation mixture, but only one (16-
hydroperoxy-3,6,9,12,15-pentaoxaheptacosan-1-ol ) was stable enough to be isolated.
SODIUM LINEAR-(C12- Alkyl ether sulfates (alcohol or alkyl ethoxysulfates) (AES) (syn: AAASD ,alkyl alcohol alkoxylate sulfates, SLES) are generally
14)ALKYL ETHER classified according to Comité Européen des Agents de Surface et leurs Intermédiaires Organiques (CESIO) as Irritant (Xi) with
SULFATE the risk phrases R38 (Irritating to skin) and R36 (Irritating to eyes). An exception has been made for AES (2-3E0) in a
concentration of 70-75% where R36 is substituted with R41 (Risk of serious damage to eyes).
AES are not included in Annex 1 of the list of dangerous substances of Council Directive 67/548/EEC.
In assessing this family the Cosmetic Ingredient Review (CIR) Expert Panel recognized that most of the acute oral toxicity,
dermal irritation and sensitization, subchronic and chronic oral toxicity, reproductive and developmental toxicity, carcinogenicity,
and photosensitization studies have been conducted on ammonium laureth sulfate and sodium laureth sulfate. Sodium and
ammonium laureth sulfate have not evoked adverse responses in any toxicological testing, including acute oral toxicity, sub-
chronic and chronic oral toxicity, reproductive and develop-mental toxicity, carcinogenicity, and photosensitization studies.
For alkanes:
Exposure to the commercial hexane (a representative of the ECHA group of hydrocarbons, C5-C7, n-alkanes, isoalkanes, n-
HYDROCARBONS, C10-13-
hexane rich) had no effect on the behavior of rats. Rats were tested monthly throughout the exposure for hindlimb splay and grip
N-ALKANES,
strength. The NOAEC for sub-chronic neurological effects is 9000 ppm in rats.
ISOALKANES, CYCLICS, <
In a 13 week subchronic inhalation study, the neurotoxicity of light alkylate naphtha distillate (LAND-2; carbon range C5-C8) was
2% AROMATICS
examined in male and female rats and aside from acute CNS effects, no treatment related neurotoxic effects found in any of the
treatment groups.
phosphoric acid ( 85%)

for acid mists, aerosols, vapours
Data from assays for genotoxic activity in vitro suggest that eukaryotic cells are susceptible to genetic damage when the pH falls
to about 6.5. Cells from the respiratory tract have not been examined in this respect. Mucous secretion may protect the cells of
the airways from direct exposure to inhaled acidic mists, just as mucous plays an important role in protecting the gastric
epithelium from its auto-secreted hydrochloric acid.
The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to
irritants may produce conjunctivitis.
PHOSPHORIC ACID
The material may produce severe skin irritation after prolonged or repeated exposure, and may produce a contact dermatitis
(nonallergic). This form of dermatitis is often characterised by skin redness (erythema) thickening of the epidermis.
Histologically there may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis.
Prolonged contact is unlikely, given the severity of response, but repeated exposures may produce severe ulceration.
Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-
allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of
highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic
individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the
irritant.
The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may
produce conjunctivitis.
for alkyl esters of phosphoric acid:
The chemicals in this category exhibit a low to moderate order of acute toxicity. The rat oral LD50 values ranged from 500-1000
TRIISOBUTYL
mg/kg with 2-ethylhexyl phosphate to >36,800 mg/kg for tris(2-ethylhexyl) phosphate. The dermal LD50 values ranged from 1200
PHOSPHATE
to > 2000 mg/kg (rat) with bis(2-ethylhexyl) hydrogen phosphate to > 20,000 mg/kg (rabbit) with tris(2- ethylhexyl) phosphate.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis. Histologically there may be
intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis.
UNITOR TBN + REAGENT The following information refers to contact allergens as a group and may not be specific to this product.
& TRIISOBUTYL Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The
PHOSPHATE pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type.
Studies indicate that normal, branched and cyclic paraffins are absorbed from the mammalian gastrointestinal tract and that the
absorption of n-paraffins is inversely proportional to the carbon chain length,with little absorption above C30. With respect to the
& HYDROCARBONS, C10-
carbon chain lengths likely to be present in mineral oil, n-paraffins may be absorbed to a greater extent that iso- or cyclo-
13- N-ALKANES,
paraffins.
The major classes of hydrocarbons have been shown to be well absorbed by the gastrointestinal tract in various species. In
2% AROMATICS
many cases, the hydrophobic hydrocarbons are ingested in association with dietary lipids.
SODIUM LINEAR-(C12-
14)ALKYL ETHER
SULFATE &
HYDROCARBONS, C10-13-
N-ALKANES,
No significant acute toxicological data identified in literature search.
2% AROMATICS &
PHOSPHORIC ACID &
TRIISOBUTYL
PHOSPHATE
Continued...
Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation

Many chemicals may mimic or interfere with the body's hormones, known as the endocrine system. Endocrine disruptors are chemicals that can interfere with
endocrine (or hormonal) systems. Endocrine disruptors interfere with the synthesis, secretion, transport, binding, action, or elimination of natural hormones in the
body. Any system in the body controlled by hormones can be derailed by hormone disruptors. Specifically, endocrine disruptors may be associated with the
development of learning disabilities, deformations of the body various cancers and sexual development problems. Endocrine disrupting chemicals cause adverse
effects in animals. But limited scientific information exists on potential health problems in humans. Because people are typically exposed to multiple endocrine
disruptors at the same time, assessing public health effects is difficult.

See Section 11.1
12.1. Toxicity

UNITOR TBN + REAGENT Not Not Not

LC50 96h Fish >1<10mg/l 2
sodium linear-(C12-
NOEC(ECx) 672h Fish 0.14mg/l 2
14)alkyl ether sulfate
EC50 72h Algae or other aquatic plants 27.7mg/l 2
EC50 48h Crustacea 7.4mg/l 2
hydrocarbons, C10-13- n- Endpoint Test Duration (hr) Species Value Source

alkanes, isoalkanes, Not Not Not
cyclics, < 2% aromatics Available Available Available

NOEC(ECx) 72h Algae or other aquatic plants <7.5mg/l 2

phosphoric acid
67.94-
LC50 96h Fish 4
113.76mg/L

17.8- Not
LC50 96h Fish
21.5mg/l Available
Not
EC50 72h Algae or other aquatic plants 33mg/l
triisobutyl phosphate Available
Not
EC50(ECx) 72h Algae or other aquatic plants 33mg/l
Available
On the basis of available evidence concerning either toxicity, persistence, potential to accumulate and or observed environmental fate and behaviour, the material
may present a danger, immediate or long-term and /or delayed, to the structure and/ or functioning of natural ecosystems.
When released in the environment, alkanes don't undergo rapid biodegradation, because they have no functional groups (like hydroxyl or carbonyl) that are
needed by most organisms in order to metabolize the compound.
However, some bacteria can metabolise some alkanes (especially those linear and short), by oxidizing the terminal carbon atom. The product is an alcohol, that
could be next oxidised to an aldehyde, and finally to a carboxylic acid.
Continued...
for n-decane:
log Kow : 5.98
Koc : 22200-42700
Half-life (hr) air : 33.6
Half-life (hr) H2O surface water : 84-3120
Henry's atm m3 /mol: 5.15
Log BCF : 3.52-4.31
Environmental fate:
When released into the soil, decane may biodegrade to a moderate extent.and is not expected to leach into groundwater; quick evaporate is expected.
When released into water, decane may biodegrade to a moderate extent but is. expected to quickly evaporate.

phosphoric acid HIGH HIGH
triisobutyl phosphate HIGH HIGH

phosphoric acid LOW (LogKOW = -0.7699)
triisobutyl phosphate LOW (LogKOW = 3.5978)

Ingredient Mobility
phosphoric acid HIGH (Log KOC = 1)
triisobutyl phosphate LOW (Log KOC = 1112)

P B T
PBT
vPvB
vPvB No

The evidence linking adverse effects to endocrine disruptors is more compelling in the environment than it is in humans. Endocrine disruptors profoundly alter
reproductive physiology of ecosystems and ultimately impact entire populations. Some endocrine-disrupting chemicals are slow to break down in the environment.
That characteristic makes them potentially hazardous over long periods of time. Some well established adverse effects of endocrine disruptors in various wildlife
species include eggshell-thinning, displayed of characteristics of the opposite sex and impaired reproductive development. Other adverse changes in wildlife
species that have been suggested, but not proven include reproductive abnormalities, immune dysfunction and skeletal deformaties.


Product / Packaging Containers may still present a chemical hazard/ danger when empty.
disposal Return to supplier for reuse/ recycling if possible.
Otherwise:
If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to
store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Recycle wherever possible.
Continued...
Labels Required
Marine Pollutant NO

Not Applicable
number

Not Applicable
name


14.5. Environmental
Not Applicable
hazard


Not Applicable
name

class(es)
14.5. Environmental
Not Applicable
hazard

for user
Not Applicable
name

Continued...

for user

Not Applicable
name

class(es)
14.5. Environmental
Not Applicable
hazard

for user
Not Applicable
Product name Group
Not Available
ether sulfate
alkanes, isoalkanes, cyclics, Not Available
< 2% aromatics
triisobutyl phosphate Not Available

Not Available
ether sulfate
alkanes, isoalkanes, cyclics, Not Available
< 2% aromatics
triisobutyl phosphate Not Available
sodium linear-(C12-14)alkyl ether sulfate is found on the following regulatory lists
Europe EC Inventory
hydrocarbons, C10-13- n-alkanes, isoalkanes, cyclics, < 2% aromatics is found on the following regulatory lists
Not Applicable
phosphoric acid is found on the following regulatory lists

Europe EC Inventory
Continued...
(Norwegian)
triisobutyl phosphate is found on the following regulatory lists

Europe EC Inventory

Not Applicable




Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (sodium linear-(C12-14)alkyl ether sulfate; phosphoric acid; triisobutyl phosphate)
China - IECSC Yes

Yes
NLP
Japan - ENCS Yes
Korea - KECI Yes
USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ No (sodium linear-(C12-14)alkyl ether sulfate; triisobutyl phosphate)

Vietnam - NCI Yes
Russia - FBEPH Yes

registration.
CONTACT POINT

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
Continued...
SDS Version Summary

Date of
Update
Firefighting measures - Fire Fighter (fire/explosion hazard), Composition / information on ingredients -

3.10 31/10/2023
Ingredients, Name
Other information
Continued...
end of SDS
UNITOR ULTRACIP
Part Number: 770727 (25LTR) Issue Date: 11/08/2021

Product name UNITOR ULTRACIP

Other means of
770727 (25LTR), 770727, 7754015
identification
Relevant identified uses Cleaning agent

Central Warehouse
login=wilhelmsen

--------- Norway


Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
Part Number: 770727 (25LTR) Page 2 of 14 Issue Date: 11/08/2021
UNITOR ULTRACIP
transport purposes.
regulation (EC) No
1272/2008 [CLP] and H314 - Skin Corrosion/Irritation Category 1A, H318 - Serious Eye Damage/Eye Irritation Category 1
[1]
amendments
2.2. Label elements
Hazard pictogram(s)
Signal word Danger
Hazard statement(s)
Not Applicable

Not Applicable

P260 Do not breathe mist/vapours/spray.

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].


Material contains 2-ethylhexanol ethoxilate, Propanoic acid, 2-hydroxy-.
2.3. Other hazards

Eye contact may produce serious damage*.
3.1.Substances
3.2.Mixtures
Continued...
UNITOR ULTRACIP
1. CAS No
Name SCL / M-Factor
4.REACH No
Not Available
2.201-069-1 Serious Eye Damage/Eye Irritation Category Not Available
10-30 citric acid Not Available
3.607-750-00-3 2; H319 [1] Chronic M
Available
Not Available
2.Not Available 2-ethylhexanol Serious Eye Damage/Eye Irritation Category Not Available
1-5 Not Available
3.Not Available ethoxilate 1; H318 [1] Chronic M
Available
Not Available
Skin Corrosion/Irritation Category 2, Serious
2.200-018-0 Propanoic acid, Not Available
1-5 Eye Damage/Eye Irritation Category 1; H315, Not Available
3.Not Available 2-hydroxy- Chronic M
H318 [1]
Available

Immediately flush body and clothes with large amounts of water, using safety shower if available.
Skin Contact Quickly remove all contaminated clothing, including footwear.
Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre.
Transport to hospital, or doctor.
For advice, contact a Poisons Information Centre or a doctor at once.
Urgent hospital treatment is likely to be needed.
Ingestion prevent aspiration.
Observe the patient carefully.
See Section 11

Continued...
UNITOR ULTRACIP


Non combustible.

See section 8

See section 12

Moderate hazard.


Safe handling
Fire and explosion

See section 5
protection
Other information

accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ x o x + + +

Continued...
UNITOR ULTRACIP

See section 1.2

DNELs PNECs
Ingredient
Dermal 2 080 mg/kg bw/day (Systemic, Chronic) 0.014 mg/L (Water - Intermittent release)
Inhalation 294 mg/m³ (Systemic, Chronic) 0.104 mg/L (Water (Marine))
2-ethylhexanol ethoxilate Dermal 1 250 mg/kg bw/day (Systemic, Chronic) * 13.7 mg/kg sediment dw (Sediment (Fresh Water))
Inhalation 87 mg/m³ (Systemic, Chronic) * 13.7 mg/kg sediment dw (Sediment (Marine))
1.4 mg/L (STP)
INGREDIENT DATA
Not Applicable
Emergency Limits
UNITOR ULTRACIP Not Available Not Available Not Available

citric acid Not Available Not Available
2-ethylhexanol ethoxilate Not Available Not Available

Propanoic acid, 2-hydroxy- Not Available Not Available
citric acid E ≤ 0.01 mg/m³

Propanoic acid, 2-hydroxy- E ≤ 0.1 ppm
MATERIAL DATA
more.

8.2.1. Appropriate

measures, such as
personal protective
equipment
Eye and face protection Safety glasses with unperforated side shields may be used where continuous eye protection is desirable, as in laboratories;
spectacles are not sufficient where complete eye protection is needed such as when handling bulk-quantities, where there is
a danger of splashing, or if the material may be under pressure.
Continued...
UNITOR ULTRACIP
Chemical goggles. Whenever there is a danger of the material coming in contact with the eyes; goggles must be properly
fitted.
Elbow length PVC gloves

When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.
Overalls.
Barrier cream.
Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the computer-generated selection:
UNITOR ULTRACIP
Material CPI
NATURAL RUBBER A
NATURAL+NEOPRENE A
NEOPRENE A
NEOPRENE/NATURAL A
NITRILE A
PVA A
PVC A

A: Best Selection
NOTE: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis, factors such as "feel" or convenience (e.g. disposability), may dictate a choice of
gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.

See section 12

Appearance Liquid, colourless to yellow

Physical state Liquid Not Available
1)
octanol / water
Odour threshold Not Available >150
(°C)
Decomposition
pH (as supplied) 2-3 Not Available
temperature (°C)

0 Viscosity (cSt) Not Available
point (°C)
boiling range (°C)

or mN/m)
Continued...
UNITOR ULTRACIP
Nanoform Particle
Characteristics

Not Available

See section 7.2
hazardous reactions
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

The material has NOT been classified by EC Directives or other classification systems as "harmful by inhalation" nor has it been
designated as "irritating to the respiratory system". This is because of the lack of corroborating animal or human evidence. In the
Inhaled
absence of such evidence, care should be taken nevertheless to ensure exposure is kept to a minimum and that suitable control
measures be used, in an occupational setting to control vapours, fumes and aerosols.
The material can produce severe chemical burns within the oral cavity and gastrointestinal tract following ingestion.
Ingestion
The material can produce severe chemical burns following direct contact with the skin.
Skin Contact
The material can produce severe chemical burns to the eye following direct contact. Vapours or mists may be extremely irritating.
Eye When applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty-four hours or more
after instillation.
Repeated or prolonged exposure to corrosives may result in the erosion of teeth, inflammatory and ulcerative changes in the
mouth and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.
Chronic Gastrointestinal disturbances may also occur.
Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving
organs or biochemical systems.
TOXICITY IRRITATION
UNITOR ULTRACIP
TOXICITY IRRITATION
[2] Eye (rabbit): 0.75 mg/24h-SEVERE
citric acid Oral (Rat) LD50: 3000 mg/kg
Skin (rabbit): 500 mg/24h - mild
2-ethylhexanol ethoxilate
TOXICITY IRRITATION
Dermal (rabbit) LD50: >2000 mg/kg[2] Eye (human): SEVERE
Dermal (rabbit) LD50: >5000 mg/kg *[2] Eye: adverse effect observed (irritating)[1]
Oral (Rat) LD50: 1378 mg/kg[2] Skin: no adverse effect observed (not irritating)[1]
Continued...
UNITOR ULTRACIP
Oral (Rat) LD50: 1400 mg/kg *[2] Skin: SEVERE
Oral (Rat) LD50: 2700 mg/kg *[2]
TOXICITY IRRITATION
Propanoic acid, 2-hydroxy- Oral (Rat) LD50: 3730 mg/kg[2] Eye (rabbit): 0.750 mg SEVERE
Skin (rabbit): 5 mg/24h SEVERE
for citric acid (and its inorganic citrate salts)

Based on many experimental data in animals and on human experience, citric acid is of low acute toxicity. The NOAEL for
repeated dose toxicity for rats is 1200 mg/kg/d. The major, reversible (sub)chronic toxic effects seem to be limited to changes in
citric acid blood chemistry and metal absorption/excretion kinetics.
This form of dermatitis is often characterised by skin redness (erythema) and swelling epidermis. Histologically there may be
Human beings have regular contact with alcohol ethoxylates through a variety of industrial and consumer products such as
soaps, detergents, and other cleaning products . Exposure to these chemicals can occur through ingestion, inhalation, or contact
with the skin or eyes. Studies of acute toxicity show that volumes well above a reasonable intake level would have to occur to
produce any toxic response.
2-ethylhexanol ethoxilate >20 EO is not classified (CESIO 2000)
gastrointestinal mucosa of rats. AE are quickly eliminated from the body through the urine, faeces, and expired air (CO2).Orally
dosed AE was absorbed rapidly and extensively in rats, and more than 75% of the dose was absorbed. When applied to the skin
of humans, the doses were absorbed slowly and incompletely (50% absorbed in 72 hours). Dermal (rabbit): 4000 mg/kg *
Somnolence, ataxia, diarrhoea recorded.
Propanoic acid, 2-hydroxy- for simple alpha-hydroxy carboxylic acids and their salts:
The US Food and Drug Administration (FDA) received a total of 114 adverse dermatologic experience reports for alpha-hydroxy
acids (AHA)-containing skin care products between 1992 and February 2004, with the maximum number in 1994. The reported
adverse experiences included burning (45), dermatitis or rash (35), swelling (29), pigmentary changes (15), blisters or welts (14),
skin peeling (13), itching (12), irritation or tenderness (8), chemical burns (6), and increased sunburn (3). The frequency of such
reports for skin exfoliating products that contain AHAs has been considerably lower in subsequent years.
citric acid & Propanoic
acid, 2-hydroxy-
irritant.
2-ethylhexanol ethoxilate &
Propanoic acid, 2-hydroxy-

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation
Continued...
UNITOR ULTRACIP


See Section 11.1
12.1. Toxicity

UNITOR ULTRACIP Not Not Not

EC50(ECx) 48h Crustacea >50mg/l 2
citric acid EC50 72h Algae or other aquatic plants 990mg/l 2

LC50 96h Fish >100mg/l 2

Not
LC50 96h Fish 7mg/l
Available
0.11-
2-ethylhexanol ethoxilate NOEC(ECx) 720h Fish 2
0.28mg/l
2.217-
3.523mg/L

EC50(ECx) 48h Crustacea 130mg/l 2
EC50 72h Algae or other aquatic plants >2800mg/L 2

Propanoic acid, 2-hydroxy-
Not
Available

citric acid LOW LOW

Propanoic acid, 2-hydroxy- LOW LOW

citric acid LOW (LogKOW = -1.64)
Propanoic acid, 2-hydroxy- LOW (LogKOW = -0.649)

Ingredient Mobility
citric acid LOW (Log KOC = 10)
Propanoic acid, 2-hydroxy- HIGH (Log KOC = 1)

P B T
Continued...
UNITOR ULTRACIP
P B T
PBT
vPvB

vPvB No



Labels Required
Marine Pollutant NO

Not Applicable
number

Not Applicable
name

14.5. Environmental
Not Applicable
hazard


Not Applicable
name

class(es)
Continued...
UNITOR ULTRACIP
14.5. Environmental
Not Applicable
hazard

for user


Not Applicable
name


for user

Not Applicable
name

class(es)

14.5. Environmental
Not Applicable
hazard

for user
Not Applicable
Product name Group
citric acid Not Available
2-ethylhexanol ethoxilate Not Available
Propanoic acid, 2-hydroxy- Not Available

2-ethylhexanol ethoxilate Not Available
Continued...
UNITOR ULTRACIP
Propanoic acid, 2-hydroxy- Not Available
citric acid is found on the following regulatory lists
Europe EC Inventory
2-ethylhexanol ethoxilate is found on the following regulatory lists
Not Applicable
Propanoic acid, 2-hydroxy- is found on the following regulatory lists
Europe EC Inventory

Not Applicable



Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (citric acid; 2-ethylhexanol ethoxilate; Propanoic acid, 2-hydroxy-)
China - IECSC Yes

No (2-ethylhexanol ethoxilate)
NLP
Japan - ENCS Yes
Korea - KECI Yes
USA - TSCA Yes
Taiwan - TCSI Yes

Mexico - INSQ Yes
Vietnam - NCI Yes
Russia - FBEPH No (2-ethylhexanol ethoxilate)

registration.
CONTACT POINT
Continued...
UNITOR ULTRACIP

SDS Version Summary

Date of
Update
Toxicological information - Acute Health (eye), Toxicological information - Acute Health (skin), Toxicological
information - Acute Health (swallowed), Hazards identification - Classification, Composition / information on
2.4 11/08/2021
ingredients - Ingredients, Exposure controls / personal protection - Personal Protection (eye), Exposure controls
/ personal protection - Personal Protection (hands/feet)
Other information
Continued...
UNITOR ULTRACIP
end of SDS
UNITOR ULTRACIP

Product name UNITOR ULTRACIP
Synonyms Product Part Number: 770727 (25LTR), 7754015

Other means of
7754015, 770727
identification
Relevant identified uses INTEGRITY CHECK: Product contains BOTH an alcohol and an acid as ingredients.

Central Warehouse
login=wilhelmsen

--------- Norway


Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
UNITOR ULTRACIP
transport purposes.
H314 - Skin Corrosion/Irritation Category 1C, H318 - Serious Eye Damage/Eye Irritation Category 1, H335 - Specific Target
regulation (EC) No
1272/2008 [CLP] and Organ Toxicity - Single Exposure (Respiratory Tract Irritation) Category 3, H412 - Hazardous to the Aquatic Environment Long-
Term Hazard Category 3
amendments [1]
2.2. Label elements
Hazard pictogram(s)
Signal word Danger
Hazard statement(s)
H335 May cause respiratory irritation.

Not Applicable

Not Applicable

P260 Do not breathe mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Material contains citric acid, 2-ethylhexanol ethoxylate, lactic acid.
2.3. Other hazards

Continued...
UNITOR ULTRACIP
3.1.Substances
3.2.Mixtures
1. CAS No
Name
4.REACH No
Not Available
Acute M
1. 77-92-9 Skin Corrosion/Irritation Category 2, Serious Eye
factor: Not
2.201-069-1 Damage/Eye Irritation Category 1, Specific Target
10-30 citric acid Organ Toxicity - Single Exposure (Respiratory Tract Available Not Available
3.607-750-00-3
Chronic M
4.Not Available Irritation) Category 3; H315, H318, H335 [1]
factor: Not
Available
Not Available
Acute Toxicity (Oral) Category 4, Skin Acute M
1. 26468-86-0
Corrosion/Irritation Category 2, Serious Eye factor: Not
2.Not Available 2-ethylhexanol
5-15 Damage/Eye Irritation Category 1, Hazardous to the Available Not Available
3.Not Available ethoxylate Aquatic Environment Long-Term Hazard Category 2; Chronic M
4.Not Available
H302, H315, H318, H411 [1] factor: Not
Available
Not Available
Acute M
1. 79-33-4
factor: Not
2.201-196-2 Skin Corrosion/Irritation Category 1C, Serious Eye
1-5 lactic acid Available Not Available
3.607-743-00-5 Damage/Eye Irritation Category 1; H314, H318 [2]
Chronic M
4.Not Available
factor: Not
Available


See Section 11
Continued...
UNITOR ULTRACIP
For acute or short term repeated exposures to strong acids:
Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially.
Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling
Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise.
Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid on proteins in
specific tissues.
INGESTION:
Immediate dilution (milk or water) within 30 minutes post ingestion is recommended.
DO NOT attempt to neutralise the acid since exothermic reaction may extend the corrosive injury.
Be careful to avoid further vomit since re-exposure of the mucosa to the acid is harmful. Limit fluids to one or two glasses in an adult.
Charcoal has no place in acid management.
Some authors suggest the use of lavage within 1 hour of ingestion.
SKIN:
Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping.
Deep second-degree burns may benefit from topical silver sulfadiazine.
EYE:
Eye injuries require retraction of the eyelids to ensure thorough irrigation of the conjuctival cul-de-sacs. Irrigation should last at least 20-30 minutes. DO NOT
use neutralising agents or any other additives. Several litres of saline are required.
Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer term use) antibiotic drops, vasoconstrictive agents or artificial tears
may be indicated dependent on the severity of the injury.
Steroid eye drops should only be administered with the approval of a consulting ophthalmologist).
[Ellenhorn and Barceloux: Medical Toxicology]

Water spray or fog.
Foam.

result

Combustible.
Acids may react with metals to produce hydrogen, a highly flammable and explosive gas.
,
,
,

See section 8

See section 12

Minor Spills Clean up all spills immediately.
Major Spills Chemical Class:acidic compounds, organic
Continued...
UNITOR ULTRACIP
SORBENT
TYPE
LAND SPILL - SMALL

cross-linked polymer - particulate 1 shovel shovel R,W,SS


wood fiber - particulate 3 shovel shovel R, W, P, DGC
LAND SPILL - MEDIUM
cross-linked polymer -particulate 1 blower skiploader R, W, SS

cross-linked polymer - pillow 3 throw skiploader R, DGC, RT

polypropylene - mat 3 throw skiploader W, SS, DGC
Legend
R; Not reusable
I: Not incinerable
Moderate hazard.


Fire and explosion
See section 5
protection
Other information Keep containers securely sealed.

Lined metal can, lined metal pail/ can.
Plastic pail.
Polyliner drum.
Suitable container
Metal can or drum
Avoid strong bases.

accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
Continued...
UNITOR ULTRACIP
+ x o x + + +


See section 1.2

DNELs PNECs
Ingredient
INGREDIENT DATA

Not Applicable
Emergency Limits
UNITOR ULTRACIP Not Available Not Available Not Available
citric acid Not Available Not Available
2-ethylhexanol ethoxylate Not Available Not Available

lactic acid Not Available Not Available

citric acid E ≤ 0.01 mg/m³
2-ethylhexanol ethoxylate E ≤ 0.1 ppm
MATERIAL DATA
more.

8.2.1. Appropriate

measures, such as
personal protective
equipment
Continued...
UNITOR ULTRACIP
Safety glasses with unperforated side shields may be used where continuous eye protection is desirable, as in laboratories;
Eye and face protection a danger of splashing, or if the material may be under pressure.
fitted.

Overalls.
Barrier cream.

GLOVE SELECTION INDEX Type AB-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 &
UNITOR ULTRACIP mask) may also be important.

Maximum gas/vapour
NATURAL RUBBER A minimum Half-face Full-Face
NATURAL+NEOPRENE A air p.p.m. (by volume)
factor
NEOPRENE A
AB-AUS /
up to 10 1000 -
NEOPRENE/NATURAL A Class1 P2
NITRILE A AB-AUS /
up to 50 1000 -
Class 1 P2
PVA A
PVC A
up to 100 5000 - AB-2 P2
up to 100 10000 - AB-3 P2
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion 100+ Airline**
Ansell Glove Selection areas of unknown vapour concentrations or oxygen content.
Glove — In order of recommendation
AlphaTec® Solvex® 37-185 the mask is not functioning properly, that the vapour concentration is too
AlphaTec® 38-612 high, or that the mask is not properly fitted. Because of these limitations,
AlphaTec® 58-008
AlphaTec® 58-530B changed after 2 hr of continuous use unless it is determined that the
AlphaTec® 58-530W humidity is less than 75%, in which case, cartridges can be used for 4 hr.
AlphaTec® 58-735
used
AlphaTec® 79-700 76ab-p()
AlphaTec® Solvex® 37-675
DermaShield™ 73-711
MICROFLEX® 63-864
The suggested gloves for use should be confirmed with the glove supplier.

See section 12

Appearance Liquid, colourless to yellow
Continued...
UNITOR ULTRACIP

Physical state Liquid ~1.065 g/cm3 at 20 deg C
1)
octanol / water
Odour threshold Not Available >150 deg C at 760 mm Hg
(°C)
Decomposition
temperature (°C)

point (°C)

boiling range (°C)

or mN/m)
Solubility in water Miscible pH as a solution (1%) 2-3

Nanoform Particle
Characteristics

Not Available

See section 7.2
hazardous reactions
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in a substantial
number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to a chemical insult by first
removing or neutralising the irritant and then repairing the damage. The repair process, which initially evolved to protect
mammalian lungs from foreign matter and antigens, may however, produce further lung damage resulting in the impairment of
Inhaled gas exchange, the primary function of the lungs.
Acidic corrosives produce respiratory tract irritation with coughing, choking and mucous membrane damage. Symptoms of
exposure may include dizziness, headache, nausea and weakness. In more severe exposures, pulmonary oedema may be
evident either immediately or after a latent period of 5-72 hours.
Ingestion of acidic corrosives may produce circumoral burns with a distinct discolouration of the mucous membranes of the
mouth, throat and oesophagus. Immediate pain and difficulties in swallowing and speaking may also be evident. Oedema of the
Ingestion epiglottis may produce respiratory distress and possibly, asphyxia.
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion of low-molecular organic acid solutions may produce spontaneous haemorrhaging, intravascular coagulation,
gastrointestinal damage and oesophageal and pyloric stricture.
Skin Contact Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may heal slowly with
the formation of scar tissue.
Continued...
UNITOR ULTRACIP
One of the mechanisms of skin irritation caused by surfactants is considered to be denaturation of the proteins of skin. It has also
been established that there is a connection between the potential of surfactants to denature protein in vitro and their effect on the
skin. Nonionic surfactants do not carry any net charge and, therefore, they can only form hydrophobic bonds with proteins.
The material produces mild skin irritation; evidence exists, or practical experience predicts, that the material either
produces mild inflammation of the skin in a substantial number of individuals following direct contact, and/or
produces significant, but mild, inflammation when applied to the healthy intact skin of animals (for up to four hours), such
inflammation being present twenty-four hours or more after the end of the exposure period.
Direct eye contact with acid corrosives may produce pain, lachrymation, photophobia and burns. Mild burns of the epithelia
generally recover rapidly and completely. Severe burns produce long-lasting and possible irreversible damage.
after instillation.
Eye Some nonionic surfactants may produce a localised anaesthetic effect on the cornea; this may effectively eliminate the warning
discomfort produced by other substances and lead to corneal injury. Irritant effects range from minimal to severe dependent on
the nature of the surfactant, its concentration and the duration of contact. Pain and corneal damage represent the most severe
manifestation of irritation.
Irritation of the eyes may produce a heavy secretion of tears (lachrymation).
Dilute solutions of low-molecular organic acids cause conjunctival hyperaemia, prompt pain and corneal injury.
Repeated or prolonged exposure to acids may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth
and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.
Gastrointestinal disturbances may also occur.
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and related systemic
Chronic
problems.
Prolonged or repeated skin contact may cause degreasing with drying, cracking and dermatitis following.
TOXICITY IRRITATION
UNITOR ULTRACIP
TOXICITY IRRITATION
citric acid dermal (rat) LD50: >2000 mg/kg[1] Eye (rabbit): 0.75 mg/24h-SEVERE
Oral (Rat) LD50: 3000 mg/kg[2] Skin (rabbit): 500 mg/24h - mild
TOXICITY IRRITATION
2-ethylhexanol ethoxylate
TOXICITY IRRITATION
[1] Eye (rabbit): 0.750 mg SEVERE
Dermal (rabbit) LD50: >2000 mg/kg
lactic acid
Inhalation (Rat) LC50: >7.94 mg/l4h[1] Skin (rabbit): 5 mg/24h SEVERE
Oral (Rat) LD50: 3543 mg/kg[1]
for citric acid (and its inorganic citrate salts)

Based on many experimental data in animals and on human experience, citric acid is of low acute toxicity. The NOAEL for
CITRIC ACID
repeated dose toxicity for rats is 1200 mg/kg/d. The major, reversible (sub)chronic toxic effects seem to be limited to changes in
blood chemistry and metal absorption/excretion kinetics.
2-ETHYLHEXANOL No significant acute toxicological data identified in literature search.

ETHOXYLATE Human beings have regular contact with alcohol ethoxylates through a variety of industrial and consumer products such as
>20 EO is not classified (CESIO 2000)
Continued...
UNITOR ULTRACIP
of humans, the doses were absorbed slowly and incompletely (50% absorbed in 72 hours).
for simple alpha-hydroxy carboxylic acids and their salts:

The US Food and Drug Administration (FDA) received a total of 114 adverse dermatologic experience reports for alpha-hydroxy
acids (AHA)-containing skin care products between 1992 and February 2004, with the maximum number in 1994. The reported
adverse experiences included burning (45), dermatitis or rash (35), swelling (29), pigmentary changes (15), blisters or welts (14),
skin peeling (13), itching (12), irritation or tenderness (8), chemical burns (6), and increased sunburn (3). The frequency of such
LACTIC ACID
reports for skin exfoliating products that contain AHAs has been considerably lower in subsequent years.
UNITOR ULTRACIP & allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of
CITRIC ACID & LACTIC highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic
ACID individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the
irritant.
UNITOR ULTRACIP &
LACTIC ACID
CITRIC ACID & 2- The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
ETHYLHEXANOL This form of dermatitis is often characterised by skin redness (erythema) and swelling epidermis. Histologically there may be
ETHOXYLATE intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis.
2-ETHYLHEXANOL
ETHOXYLATE & LACTIC The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to
ACID irritants may produce conjunctivitis.

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity

UNITOR ULTRACIP Not Not Not

EC50(ECx) 48h Crustacea >50mg/l 2
citric acid EC50 72h Algae or other aquatic plants 990mg/l 2

LC50 96h Fish >100mg/l 2
2-ethylhexanol ethoxylate
Not
EC50(ECx) 48h Crustacea 6.5mg/l
Available
Continued...
UNITOR ULTRACIP
Not
Available
Not
EC50 72h Algae or other aquatic plants 6.5mg/l
Available
Not
EC50 48h Crustacea 6.5mg/l
Available

EC50(ECx) 48h Crustacea 130mg/l 2
EC50 72h Algae or other aquatic plants >2800mg/L 2

lactic acid
Not
Available
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Ecotoxicity:
The tolerance of water organisms towards pH margin and variation is diverse. Recommended pH values for test species listed in OECD guidelines are between
6.0 and almost 9. Acute testing with fish showed 96h-LC50 at about pH 3.5
For Glycol Ethers:
Environmental Fate: Several glycol ethers have been shown to biodegrade however; biodegradation slows as molecular weight increases. No glycol ethers that
have been tested demonstrate marked resistance to biodegradative processes. No glycol ethers that have been tested demonstrate marked resistance to
biodegradative processes.

citric acid LOW LOW
lactic acid LOW LOW

citric acid LOW (LogKOW = -1.64)
lactic acid LOW (LogKOW = -0.72)

Ingredient Mobility
citric acid LOW (Log KOC = 10)
lactic acid HIGH (Log KOC = 1)

P B T

PBT
vPvB
vPvB No


Continued...
UNITOR ULTRACIP

Product / Packaging
disposal
Treat and neutralise at an approved treatment plant.
Labels Required
Marine Pollutant NO

Not Applicable
number

Not Applicable
name

14.5. Environmental
Not Applicable
hazard


Not Applicable
name

class(es)
14.5. Environmental
Not Applicable
hazard

for user

Continued...
UNITOR ULTRACIP

Not Applicable
name


for user

Not Applicable
name

class(es)

14.5. Environmental
Not Applicable
hazard

for user
Not Applicable
Product name Group
2-ethylhexanol ethoxylate Not Available
lactic acid Not Available

2-ethylhexanol ethoxylate Not Available
lactic acid Not Available
citric acid is found on the following regulatory lists
Europe EC Inventory
2-ethylhexanol ethoxylate is found on the following regulatory lists
Not Applicable
lactic acid is found on the following regulatory lists
Europe EC Inventory
Continued...
UNITOR ULTRACIP

Not Applicable




Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (citric acid; 2-ethylhexanol ethoxylate; lactic acid)

China - IECSC Yes

No (2-ethylhexanol ethoxylate)
NLP
Japan - ENCS Yes
Korea - KECI Yes

USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ No (2-ethylhexanol ethoxylate)
Vietnam - NCI Yes
Russia - FBEPH No (2-ethylhexanol ethoxylate)

registration.
CONTACT POINT

SDS Version Summary

Date of
Update
Toxicological information - Acute Health (eye), Toxicological information - Acute Health (inhaled), Toxicological
information - Acute Health (skin), Toxicological information - Acute Health (swallowed), First Aid measures -
1.2 31/08/2021 Advice to Doctor, Toxicological information - Chronic Health, Hazards identification - Classification, Firefighting
measures - Fire Fighter (fire/explosion hazard), Composition / information on ingredients - Ingredients, Exposure
controls / personal protection - Personal Protection (Respirator)
Other information
Continued...
UNITOR ULTRACIP
Continued...
UNITOR ULTRACIP
end of SDS
UNITOR USC
Part Number: 607819 (12 x 1 liter) Issue Date: 29/09/2023

Product name UNITOR USC
Synonyms Pr No: 53985

Other means of
607819 (12 x 1 liter), 607819
identification
Product Category
Consumer
Sectors of Use SU22 Professional uses
Relevant identified uses Cleaning agent for Ultrasonic Cleaners

Central Warehouse
login=wilhelmsen
--------- Norway

Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
Part Number: 607819 (12 x 1 liter) Page 2 of 15 Issue Date: 29/09/2023
UNITOR USC
transport purposes.
regulation (EC) No
H318 - Serious Eye Damage/Eye Irritation Category 1
1272/2008 [CLP] and
amendments [1]
2.2. Label elements
Hazard pictogram(s)
Signal word Danger
Hazard statement(s)
Not Applicable

Not Applicable



Not Applicable

Not Applicable
Material contains Fatty alcohol ethoxylate, Alkylglucoside.
2.3. Other hazards

diethylene glycol
Listed in the Europe Regulation (EC) No 1907/2006 - Annex XVII (Restrictions may apply)
monobutyl ether
3.1.Substances
3.2.Mixtures
Continued...
UNITOR USC
1. CAS No
amendments
4.REACH No
Not Available
1-5 sodium carbonate Not Available
Available
Not Available
1. 160875-66-1* Acute M factor:
Acute Toxicity (Oral) Category 4, Serious
2.Not Available Fatty alcohol Not Available
5-10 Eye Damage/Eye Irritation Category 1; Not Available
3.Not Available ethoxylate Chronic M
H302, H318 [1]
Available
Not Available
1. 161074-93-7* Acute M factor:
1-5 Alkylglucoside Not Available
3.Not Available Category 1; H318 [1] Chronic M
Available
Not Available
2.203-961-6 diethylene glycol Serious Eye Damage/Eye Irritation Not Available
1-5 Not Available
3.603-096-00-8 monobutyl ether * Category 2; H319 [2] Chronic M
Available

Eye Contact
Skin Contact
prevent aspiration.
See Section 11
Continued...
UNITOR USC


result


,
Fire/Explosion Hazard other pyrolysis products typical of burning organic material.

See section 8

See section 12

Moderate hazard.


Safe handling
Fire and explosion
See section 5
protection
Other information

Storage incompatibility Avoid reaction with oxidising agents

accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
Continued...
UNITOR USC
+ x o x + + +


See section 1.2

DNELs PNECs
Ingredient

Inhalation 67.5 mg/m³ (Local, Chronic) 0.11 mg/L (Water (Marine))
diethylene glycol monobutyl
Inhalation 101.2 mg/m³ (Local, Acute) 4.4 mg/kg sediment dw (Sediment (Fresh Water))
ether
Oral 6.25 mg/kg bw/day (Systemic, Chronic) * 0.44 mg/kg sediment dw (Sediment (Marine))
56 mg/kg food (Oral)
INGREDIENT DATA

Indicative Occupational diethylene glycol 2-(2-Butoxyethoxy) 10 ppm / 67.5 101.2 mg/m3 / 15 Not Not
Exposure Limit Values monobutyl ether ethanol mg/m3 ppm Available Available
(IOELVs)

diethylene glycol 10 ppm / 68 Not
factors in the work 2-2(butoksyetoksy)etanol Not Available E
monobutyl ether mg/m3 Available
factors (Norwegian)
Emergency Limits
sodium carbonate 7.6 mg/m3 83 mg/m3 500 mg/m3

30 ppm 33 ppm 200 ppm
ether
sodium carbonate Not Available Not Available

Fatty alcohol ethoxylate Not Available Not Available
Alkylglucoside Not Available Not Available

ether

sodium carbonate E ≤ 0.01 mg/m³
Continued...
UNITOR USC
Fatty alcohol ethoxylate E ≤ 0.1 ppm

MATERIAL DATA
For diethylene glycol monobutyl ether:
CEL TWA: 15.5 ppm, 100 mg/m3
(CEL = Chemwatch Exposure Limit)
In studies involving the inhalation toxicity of diethylene glycol monobutyl ether, exposure for 6 hours daily at 100 mg/m3 had no effect. This concentration is in the
range of the saturated vapour concentration.
Local damage was produced following inhalation of concentrations higher than the saturated vapour concentrations, that is, during inhalation of the aerosol (350
mg/m3).

8.2.1. Appropriate

measures, such as
personal protective
equipment


Overalls.
Barrier cream.

UNITOR USC of protection varies with Type of filter.

NATURAL RUBBER A Protection Factor Respirator Respirator Respirator
NITRILE A A-PAPR-AUS /
up to 10 x ES A-AUS -
Class 1
A-AUS / Class
A: Best Selection up to 50 x ES - -
1
up to 100 x ES - A-2 A-PAPR-2 ^
^ - Full-face

Continued...
UNITOR USC
used

See section 12

Appearance Liquid, clear, green, soluble in water

Physical state Liquid 1.025-1.040
1)
octanol / water
(°C)
Decomposition
pH (as supplied) <11.5 Not Applicable
temperature (°C)
0 Viscosity (cSt) Not Applicable
point (°C)
>100 Molecular weight (g/mol) Not Applicable
boiling range (°C)


or mN/m)

Solubility in water Miscible pH as a solution (1%) 11
Vapour density (Air = 1) Not Applicable VOC g/L 3
Nanoform Particle
Characteristics

Not Available

See section 7.2
hazardous reactions

10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3
Continued...
UNITOR USC
Inhaled removing or neutralising the irritant and then repairing the damage. The repair process, which initially evolved to protect
gas exchange, the primary function of the lungs.
Skin Contact blistering (vesiculation), scaling and thickening of the epidermis.
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial number of individuals
and/or may produce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of
Eye experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to windburn) of the
conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.
Repeated or long-term occupational exposure is likely to produce cumulative health effects involving organs or biochemical
systems.
Chronic
problems.
TOXICITY IRRITATION
UNITOR USC
TOXICITY IRRITATION
dermal (rat) LD50: >2000 mg/kg[2] Eye (rabbit): 100 mg/24h moderate
Oral (Rat) LD50: 2800 mg/kg[2] Eye (rabbit): 100 mg/30s mild
sodium carbonate Eye (rabbit): 50 mg SEVERE
Eye: adverse effect observed (irritating)[1]
Skin (rabbit): 500 mg/24h mild
TOXICITY IRRITATION
Fatty alcohol ethoxylate
TOXICITY IRRITATION
Alkylglucoside
TOXICITY IRRITATION
diethylene glycol [2] Eye (rabbit): 20 mg/24h moderate
Dermal (rabbit) LD50: 4120 mg/kg
monobutyl ether
Oral (Rat) LD50: 5660 mg/kg[2] Eye (rabbit): 5 mg - SEVERE
for sodium carbonate:

Sodium carbonate has no or a low skin irritation potential but it is considered irritating to the eyes. Due to the alkaline properties
an irritation of the respiratory tract is also possible.
No valid animal data are available on repeated dose toxicity studies by oral, dermal, inhalation or by other routes for sodium
SODIUM CARBONATE carbonate. A repeated dose inhalation study, which was not reported in sufficient detail, revealed local effects on the lungs which
could be expected based on the alkaline nature of the compound.
Fatty alcohol ethoxylate Human beings have regular contact with alcohol ethoxylates through a variety of industrial and consumer products such as
Continued...
UNITOR USC
>20 EO is not classified (CESIO 2000)
of humans, the doses were absorbed slowly and incompletely (50% absorbed in 72 hours).
Alkyl glycosides (syn: alkyl polyglucosides, alkyl polyglycosides, APGs) are considered non-irritating to skin, but irritating to eyes
at very high concentrations. A general classification of a 65% C8 alkyl glycoside solution according to the Substance Directive
67/548/EEC is Irritating (Xi) with the risk phrase R41 (Risk of serious damage to the eyes) or R36 (Irritating to the eyes) (Akzo
Nobel 1998).
Acute toxicity:
In single dose dermal studies with caprylyl/capryl glucoside and C10-16 alkyl glucoside (both 50% a.i., n:1.6) in rabbits, the LD50
Alkylglucoside
was greater than the 2000 mg/kg dose administered. In oral studies with the same test substances, none of the mice dosed with
2000 mg/kg caprylyl glucoside and none of the rats dosed with 5000 mg/kg C10-16 alkyl glucoside died
during the study.
Ocular:
In system studies for ocular irritation, the ocular irritation potential of decyl, lauryl, C10-16 alkyl, and coco-glucosides was non to
slightly irritating and of caprylyl/ capryl glucoside was highly irritating.
For diethylene glycol monoalkyl ethers and their acetates:
DIETHYLENE GLYCOL This category includes diethylene glycol ethyl ether (DGEE), diethylene glycol propyl ether (DGPE) diethylene glycol butyl ether
MONOBUTYL ETHER (DGBE) and diethylene glycol hexyl ether (DGHE) and their acetates.
Acute toxicity: There are adequate oral, inhalation and/or dermal toxicity studies on the category members. Oral LD50 values in
rats for all category members are all > 3000 mg/kg bw, with values generally decreasing with increasing molecular weight. Four
to eight hour acute inhalation toxicity studies were conducted for all category members except DGPE in rats at the highest
vapour concentrations achievable.
UNITOR USC & SODIUM
CARBONATE
irritant.
Fatty alcohol ethoxylate &

Alkylglucoside

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity

UNITOR USC Not Not Not
sodium carbonate
Continued...
UNITOR USC
EC50 96h Algae or other aquatic plants 242mg/L 4
156.6-
298.9mg/l

Fatty alcohol ethoxylate Not Not Not

Alkylglucoside Not Not Not

diethylene glycol EC50 48h Crustacea >100mg/l 1

monobutyl ether EC50 72h Algae or other aquatic plants 1101mg/l 2
NOEC(ECx) 96h Algae or other aquatic plants >=100mg/l 1

sodium carbonate LOW LOW

LOW LOW
ether

sodium carbonate LOW (LogKOW = -0.4605)

LOW (BCF = 0.46)
ether

Ingredient Mobility
sodium carbonate HIGH (Log KOC = 1)

LOW (Log KOC = 10)
ether

P B T

PBT
vPvB
vPvB No


Continued...
UNITOR USC

Labels Required
Marine Pollutant NO

Not Applicable
number

Not Applicable
name


14.5. Environmental
Not Applicable
hazard


Not Applicable
name

class(es)

14.5. Environmental
Not Applicable
hazard

for user
Continued...
UNITOR USC

Not Applicable
name


for user

Not Applicable
name

class(es)
14.5. Environmental
Not Applicable
hazard

for user
Not Applicable
Product name Group
Fatty alcohol ethoxylate Not Available
Alkylglucoside Not Available

Not Available
ether

Fatty alcohol ethoxylate Not Available
Alkylglucoside Not Available

Not Available
ether
sodium carbonate is found on the following regulatory lists
Europe EC Inventory
Continued...
UNITOR USC
Fatty alcohol ethoxylate is found on the following regulatory lists
Not Applicable
Alkylglucoside is found on the following regulatory lists

Europe EC Inventory
diethylene glycol monobutyl ether is found on the following regulatory lists

Europe EC Inventory
(Norwegian)

Not Applicable




No (Alkylglucoside)
Non-Industrial Use
Canada - DSL No (Fatty alcohol ethoxylate; Alkylglucoside)

Canada - NDSL No (sodium carbonate; Fatty alcohol ethoxylate; diethylene glycol monobutyl ether)
China - IECSC Yes

No (Fatty alcohol ethoxylate)
NLP
Japan - ENCS Yes
Korea - KECI No (Alkylglucoside)

Philippines - PICCS No (Alkylglucoside)
USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ No (Fatty alcohol ethoxylate; Alkylglucoside)
Vietnam - NCI Yes
Russia - FBEPH No (Fatty alcohol ethoxylate; Alkylglucoside)

registration.

CONTACT POINT

Continued...
UNITOR USC
SDS Version Summary

Date of
Update
Firefighting measures - Fire Fighter (fire/explosion hazard), Firefighting measures - Fire Fighter (fire
9.13 29/09/2023 incompatibility), Composition / information on ingredients - Ingredients, Exposure controls / personal protection -
Personal Protection (Respirator), Handling and storage - Storage (storage incompatibility)
Other information
regulation (EC) No
1272/2008 [CLP] and
amendments
Serious Eye Damage/Eye

Expert judgement
Irritation Category 1, H318
Continued...
UNITOR USC
end of SDS
UNITOR WATER IN OIL REAGENT KIT RELEASER

Product name UNITOR WATER IN OIL REAGENT KIT RELEASER

Other means of
773356, 673350, 673354, 773357, 773359
identification

Central Warehouse
login=wilhelmsen
--------- Norway

Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
transport purposes.
regulation (EC) No
amendments [1]
2.2. Label elements
Hazard statement(s)
Not Applicable
Not Applicable

Not Applicable

Not Applicable

Not Applicable

Not Applicable

Not Applicable
2.3. Other hazards
3.1.Substances
3.2.Mixtures
1. CAS No
Name SCL / M-Factor
4.REACH No
Not Available
1. 68956-68-3
Acute M factor:
2.273-313-5 vegetable
75 Not Classified [1] Not Available Not Available
3.Not Available oils
Chronic M factor:
4.Not Available
Not Available
Continued...

Eye Contact
Inhalation
Ingestion
See Section 11

Foam.

result

Combustible.
,
,
acrolein
,

See section 8

See section 12

Minor Spills
Major Spills Slippery when spilt.

CARE: Absorbent materials wetted with occluded oil must be moistened with water as they may auto-oxidize, become self
heating and ignite.
Some oils slowly oxidise when spread in a film and oil on cloths, mops, absorbents may autoxidise and generate heat, smoulder,
ignite and burn. In the workplace oily rags should be collected and immersed in water.
Moderate hazard.
Continued...



Rags wet / soaked with unsaturated hydrocarbons / drying oils may auto-oxidise; generate heat and, in-time, smoulder and
ignite. This is especially the case where oil-soaked materials are folded, bunched, compressed, or piled together - this allows the
heat to accumulate or even accelerate the reaction
Safe handling Oily cleaning rags should be collected regularly and immersed in water, or spread to dry in safe-place away from direct sunlight
or stored, immersed, in solvents in suitably closed containers.
Fire and explosion

See section 5
protection
Consider storage under inert gas.
Other information
Keep containers securely sealed.

Glass container is suitable for laboratory quantities
Metal can or drum
Suitable container
accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ + + + + + +


See section 1.2

DNELs PNECs
Ingredient
Continued...
INGREDIENT DATA

Not Applicable
Emergency Limits

UNITOR WATER IN OIL
REAGENT KIT RELEASER

vegetable oils Not Available Not Available
MATERIAL DATA

8.2.1. Appropriate Process controls which involve changing the way a job activity or process is done to reduce the risk.
engineering controls Care: Atmospheres in bulk storages and even apparently empty tanks may be hazardous by oxygen depletion. Atmosphere must
be checked before entry.
Requirements of State Authorities concerning conditions for tank entry must be met. Particularly with regard to training of crews
for tank entry; work permits; sampling of atmosphere; provision of rescue harness and protective gear as needed

measures, such as
personal protective
equipment

Chemical goggles.


OTHERWISE:
Other protection
Overalls.
Barrier cream.

UNITOR WATER IN OIL REAGENT KIT RELEASER mask) may also be important.

Maximum gas/vapour
PVC A minimum Half-face Full-Face
air p.p.m. (by volume)
* CPI - Chemwatch Performance Index factor
A: Best Selection A-AUS /
B: Satisfactory; may degrade after 4 hours continuous immersion up to 10 1000 -
Class1
A-AUS /
NOTE: As a series of factors will influence the actual performance of the glove, up to 50 1000 -
Class 1
* Where the glove is to be used on a short term, casual or infrequent basis, up to 50 5000 Airline * -
factors such as "feel" or convenience (e.g. disposability), may dictate a choice up to 100 5000 - A-2
up to 100 10000 - A-3
Continued...
of gloves which might otherwise be unsuitable following long-term or frequent 100+ Airline**

used

See section 12

Appearance Yellow to Amber

1)
octanol / water
(°C)
Decomposition
temperature (°C)

point (°C)

boiling range (°C)


or mN/m)

Nanoform Particle
Characteristics

Not Available

See section 7.2
hazardous reactions
Continued...

10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

Inhaled Not normally a hazard due to non-volatile nature of product
Fine mists generated from plant/ vegetable (or more rarely from animal) oils may be hazardous. Extreme heating for prolonged
periods, at high temperatures, may generate breakdown products which include acrolein and acrolein-like substances.
Skin Contact using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves
Chronic
UNITOR WATER IN OIL TOXICITY IRRITATION

REAGENT KIT RELEASER Not Available Not Available
TOXICITY IRRITATION
vegetable oils
VEGETABLE OILS Refined grades are edible. No significant acute toxicological data identified in literature search.

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity

UNITOR WATER IN OIL
Not Not Not
REAGENT KIT RELEASER Not Available Not Available
Continued...

vegetable oils Not Not Not
For aliphatic fatty acids and alcohols:

Environmental fate:
Saturated fatty acids are very stable in air, whereas unsaturated (C=C bonds) fatty acids are susceptible to oxidation.
Unsaturation increases the rate of metabolism although the degree of unsaturation and positioning of double bonds is not highly significant.
The available data indicate all fatty acid salt chain lengths up to and including C18 can be metabolised under aerobic conditions and can be considered to be
readily biodegradable
All tests showed that fatty acids and lipids are readily biodegradable
The aliphatic acids are of similar very weak acid strength (approximately pKa 5), i.e., partially dissociate in aqueous solution; the salts of the aliphatic acids are
highly dissociated in water solution such that the anion is the same for homologous salts and acids.
Unsaturated vegetable oils are often used in paints which upon "drying" produce a polymeric network formed of the constituent fatty acids.
During the drying process, a number of compounds are produced that do not contribute to the polymer network. These include unstable hydroperoxide (ROOH)
the major by-product of the reaction of oxygen with unsaturated fatty acids.



Ingredient Mobility

P B T
PBT
vPvB

vPvB No



Continued...
Labels Required
Marine Pollutant NO

Not Applicable
number

Not Applicable
name

14.5. Environmental
Not Applicable
hazard

Not Applicable
name

class(es)

14.5. Environmental
Not Applicable
hazard

for user

Not Applicable
name



for user
Continued...
Not Applicable
name
class(es)

14.5. Environmental
Not Applicable
hazard

for user
Not Applicable
Product name Group

vegetable oils is found on the following regulatory lists

Europe EC Inventory

Not Applicable




Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (vegetable oils)
China - IECSC Yes

Yes
NLP
Japan - ENCS No (vegetable oils)

Korea - KECI Yes
Continued...

USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ Yes
Vietnam - NCI Yes

Russia - FBEPH No (vegetable oils)

registration.
CONTACT POINT
SDS Version Summary

2.3 31/10/2023 Hazards identification - Classification, Name
Other information
end of SDS
UNITOR WATER IN OIL SAFE

Product name UNITOR WATER IN OIL SAFE

Other means of
773357, 673350, 673354, 773356, 773359
identification

Central Warehouse
login=wilhelmsen
--------- Norway

Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
transport purposes.
regulation (EC) No
amendments [1]
2.2. Label elements
Hazard statement(s)
Not Applicable
Not Applicable

Not Applicable

Not Applicable

Not Applicable

Not Applicable

Not Applicable
2.3. Other hazards

3.1.Substances
3.2.Mixtures
1. CAS No
2.EC No % Classification according to regulation (EC) No Nanoform Particle
Name SCL / M-Factor
3.Index No [weight] 1272/2008 [CLP] and amendments Characteristics
4.REACH No
Not Available
1. 7789-78-8
Substances and Mixtures which in Contact with Acute M factor:
2.232-189-2 calcium
4 Water Emit Flammable Gases Category 1; H260 Not Available Not Available
3.001-004-00-5 hydride [2] Chronic M factor:
4.Not Available
Not Available
Continued...

Skin Contact
Inhalation
Ingestion
See Section 11



Non combustible.
Fire/Explosion Hazard Not considered a significant fire risk, however containers may burn.

See section 8

See section 12

Minor Spills Avoid contact with skin and eyes.
Wear impervious gloves and safety goggles.
Minor hazard.
Major Spills Clear area of personnel.

Continued...

Fire and explosion

See section 5
protection

Store in a cool, dry, well-ventilated area.

Contact with water liberates highly flammable gases
None known
accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ + + + + + +


See section 1.2

DNELs PNECs
Ingredient
INGREDIENT DATA
Not Applicable
Emergency Limits

calcium hydride 12 mg/m3 130 mg/m3 790 mg/m3

calcium hydride Not Available Not Available
MATERIAL DATA
Continued...
more.

8.2.1. Appropriate

measures, such as
personal protective
equipment



Eye-wash unit.
Other protection IN CONFINED SPACES:
Non-sparking protective boots
Static-free clothing.
Type -P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)
Required Minimum Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator
P1 - PAPR-P1
up to 10 x ES
Air-line* - -
up to 50 x ES Air-line** P2 PAPR-P2
up to 100 x ES - P3 -
Air-line* -
100+ x ES - Air-line** PAPR-P3
* - Negative pressure demand ** - Continuous flow


See section 12

Appearance White

Physical state Free-flowing Paste 0.87
1)
octanol / water
(°C)
Decomposition
temperature (°C)
point (°C)
boiling range (°C)
Continued...


or mN/m)

Nanoform Particle
Characteristics

Not Available

See section 7.2
hazardous reactions

10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

Inhaled using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable
Skin Contact
Eye
after instillation.
Chronic
UNITOR WATER IN OIL TOXICITY IRRITATION

SAFE Not Available Not Available
TOXICITY IRRITATION
calcium hydride Not Available Eye: adverse effect observed (irritating)[1]
Skin: adverse effect observed (irritating)[1]
Continued...
irritant.
CALCIUM HYDRIDE

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity

UNITOR WATER IN OIL
Not Not Not
SAFE Not Available Not Available

calcium hydride Not Not Not



Ingredient Mobility

P B T
PBT
vPvB
Continued...
vPvB No



Product / Packaging
Consult State Land Waste Management Authority for disposal.
disposal
Bury residue in an authorised landfill.

Labels Required
Marine Pollutant NO

Not Applicable
number

Not Applicable
name

14.5. Environmental
Not Applicable
hazard

Not Applicable
name

class(es)
14.5. Environmental
Not Applicable
hazard
for user

Continued...

Not Applicable
name


for user
Not Applicable
name

class(es)

14.5. Environmental
Not Applicable
hazard

for user
Not Applicable
Product name Group
calcium hydride Not Available

calcium hydride Not Available
calcium hydride is found on the following regulatory lists

Europe EC Inventory

Not Applicable
Continued...



Yes
Non-Industrial Use
Canada - DSL Yes

Canada - NDSL No (calcium hydride)
China - IECSC Yes

Yes
NLP
Japan - ENCS Yes
Korea - KECI Yes

USA - TSCA Yes
Taiwan - TCSI Yes

Mexico - INSQ Yes
Vietnam - NCI Yes
Russia - FBEPH Yes

registration.
CONTACT POINT

H260 In contact with water releases flammable gases which may ignite spontaneously.
Other information
Continued...
end of SDS
UNIVERSAL INDICATOR SOLUTION
Part Number: 777987 (BW Test Kit) Issue Date: 18/08/2022

Product name UNIVERSAL INDICATOR SOLUTION

ALCOHOLS, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) (contains ethanol and methanol); ALCOHOLS, N.O.S.
(vapour pressure at 50 °C more than 110 kPa) (contains ethanol and methanol)

Other means of
777987 (BW Test Kit), 777987
identification
Relevant identified uses reagent - When supplied as part of a kit: The kit may be transported under classification UN3316 CHEMICAL KIT

Central Warehouse
login=wilhelmsen

--------- Norway


Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers
Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
Part Number: 777987 (BW Test Kit) Page 2 of 16 Issue Date: 18/08/2022
purposes.
regulation (EC) No
1272/2008 [CLP] and H225 - Flammable Liquids Category 2
amendments [1]
2.2. Label elements
Hazard pictogram(s)
Signal word Danger
Hazard statement(s)
H225 Highly flammable liquid and vapour.
Not Applicable

Not Applicable

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.

P370+P378 In case of fire: Use alcohol resistant foam or normal protein foam to extinguish.

P403+P235 Store in a well-ventilated place. Keep cool.

Material contains methanol.
2.3. Other hazards

May produce discomfort of the respiratory system and skin*.
ethanol Listed in the Europe Regulation (EC) No 1907/2006 - Annex XVII (Restrictions may apply)
methanol Listed in the Europe Regulation (EC) No 1907/2006 - Annex XVII (Restrictions may apply)
3.1.Substances
Continued...
3.2.Mixtures
1. CAS No
2.EC No % Classification according to regulation (EC) No Nanoform Particle
Name SCL / M-Factor
3.Index No [weight] 1272/2008 [CLP] and amendments Characteristics
4.REACH No
Not Available
1. 64-17-5
Acute M factor: Not
2.200-578-6
>80 ethanol Flammable Liquids Category 2; H225 [2] Available Not Available
3.603-002-00-5
Chronic M factor:
4.Not Available
Not Available
* STOT SE 1;
H370: C ≥ 10 % |
Flammable Liquids Category 2, Acute Toxicity (Oral)
1. 67-56-1 STOT SE 2; H371:
Category 3, Acute Toxicity (Dermal) Category 3, Acute
2.200-659-6 methanol 3 % ≤ C < 10 %
1-5 Toxicity (Inhalation) Category 3, Specific Target Organ Not Available
3.603-001-00-X * Acute M factor: Not
Toxicity - Single Exposure Category 1; H225, H301,
4.Not Available Available
H311, H331, H370 [2] Chronic M factor:
Not Available

Eye Contact
Skin Contact
Ingestion
See Section 11
For acute or short term repeated exposures to ethanol:
Acute ingestion in non-tolerant patients usually responds to supportive care with special attention to prevention of aspiration, replacement of fluid and
correction of nutritional deficiencies (magnesium, thiamine pyridoxine, Vitamins C and K).
Give 50% dextrose (50-100 ml) IV to obtunded patients following blood draw for glucose determination.
Comatose patients should be treated with initial attention to airway, breathing, circulation and drugs of immediate importance (glucose, thiamine).
Decontamination is probably unnecessary more than 1 hour after a single observed ingestion. Cathartics and charcoal may be given but are probably not
effective in single ingestions.
Fructose administration is contra-indicated due to side effects.

Alcohol stable foam.
Continued...
result

Fire Fighting May be violently or explosively reactive.
Wear breathing apparatus plus protective gloves in the event of a fire.
Liquid and vapour are highly flammable.
Severe fire hazard when exposed to heat, flame and/or oxidisers.
Vapour may travel a considerable distance to source of ignition.
,
,

See section 8

See section 12


Major Spills Alert Fire Brigade and tell them location and nature of hazard.
May be violently or explosively reactive.


Safe handling
Fire and explosion
See section 5
protection
Store in original containers in approved flame-proof area.
Other information No smoking, naked lights, heat or ignition sources.
DO NOT store in pits, depression, basement or areas where vapours may be trapped.

Packing as supplied by manufacturer.
Plastic containers may only be used if approved for flammable liquid.
Check that containers are clearly labelled and free from leaks.
Suitable container
For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where a can is to be
used as an inner package, the can must have a screwed enclosure.
For materials with a viscosity of at least 2680 cSt.
Avoid oxidising agents, acids, acid chlorides, acid anhydrides, chloroformates.

Storage incompatibility Avoid strong bases.
*
accordance with
P5a: Flammable Liquids, P5b: Flammable Liquids, P5c: Flammable Liquids
Regulation (EC) No
Qualifying quantity P5a Lower- / Upper-tier requirements: 10 / 50
(tonnes) of dangerous P5b Lower- / Upper-tier requirements: 50 / 200
Continued...
substances as referred to P5c Lower- / Upper-tier requirements: 5 000 / 50 000

application of
+ x + x + + +


See section 1.2

DNELs PNECs
Ingredient

Dermal 343 mg/kg bw/day (Systemic, Chronic)
2.75 mg/L (Water - Intermittent release)
0.79 mg/L (Water (Marine))
Inhalation 1 900 mg/m³ (Local, Acute)
ethanol Dermal 206 mg/kg bw/day (Systemic, Chronic) *
2.9 mg/kg sediment dw (Sediment (Marine))
Oral 87 mg/kg bw/day (Systemic, Chronic) *
580 mg/L (STP)
0.38 g/kg food (Oral)
Dermal 20 mg/kg bw/day (Systemic, Chronic)
Inhalation 130 mg/m³ (Systemic, Acute)
Inhalation 130 mg/m³ (Local, Acute)
Dermal 4 mg/kg bw/day (Systemic, Chronic) *
methanol Not Available
Oral 4 mg/kg bw/day (Systemic, Chronic) *
INGREDIENT DATA

factors in the work ethanol Etanol 500 ppm / 950 mg/m3 Not Available Not Available Not Available
factors (Norwegian)
methanol Methanol 200 ppm / 260 mg/m3 Not Available Not Available Skin
(IOELVs)
factors in the work methanol Metanol 100 ppm / 130 mg/m3 Not Available Not Available HE
factors (Norwegian)
Continued...
Emergency Limits

ethanol Not Available Not Available 15000* ppm
methanol Not Available Not Available Not Available

ethanol 3,300 ppm Not Available
methanol 6,000 ppm Not Available
MATERIAL DATA
For ethanol:
Odour Threshold Value: 49-716 ppm (detection), 101 ppm (recognition)
Eye and respiratory tract irritation do not appear to occur at exposure levels of less than 5000 ppm and the TLV-TWA is thought to provide an adequate margin of
safety against such effects. Experiments in man show that inhalation of 1000 ppm caused slight symptoms of poisoning and 5000 ppm caused strong stupor and
morbid sleepiness. Subjects exposed to 5000 ppm to 10000 ppm experienced smarting of the eyes and nose and coughing.
These exposure guidelines have been derived from a screening level of risk assessment and should not be construed as unequivocally safe limits. ORGS
represent an 8-hour time-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:

ClassOSF Description
Over 90% of exposed individuals are aware by smell that the Exposure Standard (TLV-TWA for example) is being reached, even when distracted by
A 550
working activities
26-
B As "A" for 50-90% of persons being distracted
550
1-26 As "A" for less than 50% of persons being distracted
D 0.18-1 10-50% of persons aware of being tested perceive by smell that the Exposure Standard is being reached
E <0.18 As "D" for less than 10% of persons aware of being tested
For methanol:
Odour Threshold Value: 4.2-5960 ppm (detection), 53.0-8940 ppm (recognition)
NOTE: Detector tubes for methanol, measuring in excess of 50 ppm, are commercially available.
Exposure at or below the recommended TLV-TWA is thought to substantially reduce the significant risk of headache, blurred vision and other ocular and systemic
effects.
Odour Safety Factor (OSF)
OSF=2 (METHANOL)

8.2.1. Appropriate

measures, such as
personal protective
equipment

Hands/feet protection Wear chemical protective gloves, e.g. PVC.

Continued...

Employees working with confirmed human carcinogens should be provided with, and be required to wear, clean, full body
protective clothing (smocks, coveralls, or long-sleeved shirt and pants), shoe covers and gloves prior to entering the
regulated area. [AS/NZS ISO 6529:2006 or national equivalent]
Employees engaged in handling operations involving carcinogens should be provided with, and required to wear and use
half-face filter-type respirators with filters for dusts, mists and fumes, or air purifying canisters or cartridges. A respirator
affording higher levels of protection may be substituted.
Prior to each exit from an area containing confirmed human carcinogens, employees should be required to remove and leave
protective clothing and equipment at the point of exit and at the last exit of the day, to place used clothing and equipment in
impervious containers at the point of exit for purposes of decontamination or disposal. The contents of such impervious
Other protection containers must be identified with suitable labels. For maintenance and decontamination activities, authorized employees
entering the area should be provided with and required to wear clean, impervious garments, including gloves, boots and
continuous-air supplied hood.
Overalls.
PVC Apron.
PVC protective suit may be required if exposure severe.
Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as they may
produce static electricity.
For large scale or continuous use wear tight-weave non-static clothing (no metallic fasteners, cuffs or pockets).
Non sparking safety or conductive footwear should be considered.

GLOVE SELECTION INDEX Type AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 &
UNIVERSAL INDICATOR SOLUTION of protection varies with Type of filter.

BUTYL A Protection Factor Respirator Respirator Respirator
PE/EVAL/PE A AX-AUS / AX-PAPR-AUS /

up to 5 x ES -
Class 1 Class 1
NEOPRENE B
up to 25 x ES Air-line* AX-2 AX-PAPR-2
BUTYL/NEOPRENE C
up to 50 x ES - AX-3 -
NAT+NEOPR+NITRILE C
50+ x ES - Air-line** -
NATURAL RUBBER C
NATURAL+NEOPRENE C * - Continuous-flow; ** - Continuous-flow or positive pressure demand

^ - Full-face
NEOPRENE/NATURAL C
NITRILE C hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
NITRILE+PVC C dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury,
PVA C
PVC C
PVDC/PE/PVDC C
SARANEX-23 C The wearer must be warned to leave the contaminated area immediately
SARANEX-23 2-PLY C on detecting any odours through the respirator. The odour may indicate that
TEFLON C
VITON/NEOPRENE C only restricted use of cartridge respirators is considered appropriate.
A: Best Selection
used
Ansell Glove Selection
AlphaTec 02-100
Continued...
AlphaTec® 58-008
AlphaTec® 79-700
MICROFLEX® 63-864
MICROFLEX® Diamond Grip® MF-300

TouchNTuff® 83-500
MICROFLEX® 73-847

See section 12

Appearance Liquid, colourless, miscible with water

1)
octanol / water
(°C)
Decomposition
temperature (°C)

point (°C)

78.3 Molecular weight (g/mol) Not Available
boiling range (°C)
Flammability HIGHLY FLAMMABLE. Oxidising properties Not Available

Upper Explosive Limit (%) 19 Not Available
or mN/m)
Lower Explosive Limit (%) 3.3 Volatile Component (%vol) Not Available
Nanoform Particle
Characteristics

Not Available

See section 7.2
hazardous reactions
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3
Continued...

The most common signs of inhalation overexposure to ethanol, in animals, include ataxia, incoordination and drowsiness for
those surviving narcosis. The narcotic dose for rats, after 2 hours of exposure, is 19260 ppm.
Exposure to aliphatic alcohols with more than 3 carbons may produce central nervous system effects such as headache,
dizziness, drowsiness, muscle weakness, delirium, CNS depression, coma, seizure, and neurobehavioural changes. Symptoms
are more acute with higher alcohols. Respiratory tract involvement may produce irritation of the mucosa, respiratory insufficiency,
Inhaled
respiratory depression secondary to CNS depression, pulmonary oedema, chemical pneumonitis and bronchitis.
The material has NOT been classified by EC Directives or other classification systems as "harmful by inhalation". This is because
of the lack of corroborating animal or human evidence. In the absence of such evidence, care should be taken nevertheless to
ensure exposure is kept to a minimum and that suitable control measures be used, in an occupational setting to control vapours,
fumes and aerosols.
Minor but regular methanol exposures may effect the central nervous system, optic nerves and retinae. Symptoms may be
delayed, with headache, fatigue, nausea, blurring of vision and double vision. Continued or severe exposures may cause
damage to optic nerves, which may become severe with permanent visual impairment even blindness resulting.
Acute effects from inhalation of high concentrations of vapour are pulmonary irritation, including coughing, with nausea; central
nervous system depression - characterised by headache and dizziness, increased reaction time, fatigue and loss of co-ordination
Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be
damaging to the health of the individual.
Ingestion of ethanol (ethyl alcohol, "alcohol") may produce nausea, vomiting, bleeding from the digestive tract, abdominal pain,
and diarrhoea. Effects on the body:
Blood concentration Effects
Mild: impaired vision, co-ordination and

<1.5 g/L
reaction time; emotional instability
Moderate: Slurred speech, confusion,

inco-ordination, emotional instability,
disturbances in perception and senses,
1.5-3.0 g/L possible blackouts, and impaired
objective performance in standardized
Ingestion tests. Possible double vision, flushing,
fast heart rate, sweating and incontinence.
Methanol may produce a burning or painful sensation in the mouth, throat, chest and stomach. This may be accompanied by
nausea, vomiting, headache, dizziness, shortness of breath, weakness, fatigue, leg cramps, restlessness, confusion, drunken
behaviour, visual disturbance, drowsiness, coma and death. Onset of symptoms may be delayed for several hours.
Effects on the nervous system characterise over-exposure to higher aliphatic alcohols. These include headache, muscle
weakness, giddiness, ataxia, (loss of muscle coordination), confusion, delirium and coma. Gastrointestinal effects may include
nausea, vomiting and diarrhoea.
Most liquid alcohols appear to act as primary skin irritants in humans. Significant percutaneous absorption occurs in rabbits but
not apparently in man.
Skin Contact
The material may produce moderate skin irritation; limited evidence or practical experience suggests, that the material either:
produces moderate inflammation of the skin in a substantial number of individuals following direct contact and/or
produces significant, but moderate, inflammation when applied to the healthy intact skin of animals (for up to four hours),
such inflammation being present twenty-four hours or more after the end of the exposure period.
Eye Direct contact of the eye with ethanol may cause immediate stinging and burning with reflex closure of the lid and tearing,
transient injury of the corneal epithelium and hyperaemia of the conjunctiva. Foreign-body type discomfort may persist for up to 2
days but healing is usually spontaneous and complete.
Methanol is a mild to moderate eye irritant. High vapor concentration or liquid contact with eyes causes irritation, tearing, and
burning.
Direct contact of the eye with ethanol may cause immediate stinging and burning with reflex closure of the lid and tearing,
transient injury of the corneal epithelium and hyperaemia of the conjunctiva.
Evidence exists, or practical experience predicts, that the material may cause severe eye irritation in a substantial number of
individuals and/or may produce significant ocular lesions which are present twenty-four hours or more after instillation into the
Continued...
eye(s) of experimental animals. Eye contact may cause significant inflammation with pain. Corneal injury may occur; permanent
impairment of vision may result unless treatment is prompt and adequate.
problems.
On the basis of epidemiological data, the material is regarded as carcinogenic to humans. There is sufficient data to establish a
causal association between human exposure to the material and the development of cancer.
Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
Serious damage (clear functional disturbance or morphological change which may have toxicological significance) is likely to be
caused by repeated or prolonged exposure. As a rule the material produces, or contains a substance which produces severe
lesions. Such damage may become apparent following direct application in subchronic (90 day) toxicity studies or following sub-
acute (28 day) or chronic (two-year) toxicity tests.
There is sufficient evidence to provide a strong presumption that human exposure to the material may result in developmental
toxicity, generally on the basis of:
- clear results in appropriate animal studies where effects have been observed in the absence of marked maternal toxicity, or at
Chronic around the same dose levels as other toxic effects but which are not secondary non-specific consequences of the other toxic
effects.
Long-term exposure to ethanol may result in progressive liver damage with fibrosis or may exacerbate liver injury caused by
other agents.
Repeated ingestion of ethanol by pregnant women may adversely affect the central nervous system of the developing foetus,
producing effects collectively described as foetal alcohol syndrome. These include mental and physical retardation, learning
disturbances, motor and language deficiency, behavioural disorders and reduced head size.
Long-term exposure to methanol vapour, at concentrations exceeding 3000 ppm, may produce cumulative effects characterised
by gastrointestinal disturbances (nausea, vomiting), headache, ringing in the ears, insomnia, trembling, unsteady gait, vertigo,
conjunctivitis and clouded or double vision. Liver and/or kidney injury may also result. Some individuals show severe eye
damage following prolonged exposure to 800 ppm of the vapour.
UNIVERSAL INDICATOR TOXICITY IRRITATION

SOLUTION Not Available Not Available
TOXICITY IRRITATION
Dermal (rabbit) LD50: 17100 mg/kg[1] Eye (rabbit): 500 mg SEVERE
Inhalation (Rat) LC50: 64000 ppm4h[2] Eye (rabbit):100mg/24hr-moderate
ethanol Oral (Rat) LD50: 7060 mg/kg[2] Eye: adverse effect observed (irritating)[1]
Skin (rabbit):20 mg/24hr-moderate

Skin (rabbit):400 mg (open)-mild
TOXICITY IRRITATION
Dermal (rabbit) LD50: 15800 mg/kg[2] Eye (rabbit): 100 mg/24h-moderate
[2] Eye (rabbit): 40 mg-moderate

Inhalation (Rat) LC50: 64000 ppm4h
methanol
Oral (Rat) LD50: 5628 mg/kg[2] Eye: no adverse effect observed (not irritating)[1]
Skin (rabbit): 20 mg/24 h-moderate
UNIVERSAL INDICATOR
SOLUTION
irritant.
ETHANOL & METHANOL This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis. Histologically there may be

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation
Continued...


See Section 11.1
12.1. Toxicity

UNIVERSAL INDICATOR
Not Not Not
SOLUTION Not Available Not Available

LC50 96h Fish 42mg/L 4
EC50(ECx) 96h Algae or other aquatic plants <0.001mg/L 4
ethanol
EC50 96h Algae or other aquatic plants <0.001mg/L 4
EC50 48h Crustacea 2mg/L 4


methanol
14.11-
EC50 96h Algae or other aquatic plants 4
20.623mg/l
For Ethanol:
log Kow: -0.31 to -0.32;
Koc 1: Estimated BCF= 3;
Half-life (hr) air: 144;
Half-life (hr) H2O surface water: 144;
Henry's atm m3 /mol: 6.29E-06;
BOD 5 if unstated: 0.93-1.67,63%
COD: 1.99-2.11,97%;
ThOD : 2.1.
Environmental Fate: Terrestrial - Ethanol quickly biodegrades in soil but may leach into ground water; most is lost by evaporation. Ethanol is expected to have very
high mobility in soil.

ethanol LOW (Half-life = 2.17 days) LOW (Half-life = 5.08 days)
methanol LOW LOW

ethanol LOW (LogKOW = -0.31)
methanol LOW (BCF = 10)

Ingredient Mobility
ethanol HIGH (Log KOC = 1)

Continued...
Ingredient Mobility
methanol HIGH (Log KOC = 1)

P B T
PBT
vPvB
vPvB No



Containers may still present a chemical hazard/ danger when empty.
Return to supplier for reuse/ recycling if possible.
Otherwise:
Product / Packaging
disposal
Dispose of by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or Incineration in a
Labels Required
Marine Pollutant NO

1987
number
14.2. UN proper shipping ALCOHOLS, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) (contains ethanol and methanol); ALCOHOLS, N.O.S.
name (vapour pressure at 50 °C more than 110 kPa) (contains ethanol and methanol)
14.3. Transport hazard Class 3

14.4. Packing group II
14.5. Environmental
Not Applicable
hazard
for user
Classification code F1
Continued...
Hazard Label 3
Special provisions 274 601 640C; 274 601 640D

Limited quantity 1L
Tunnel Restriction Code D/E

Alcohols, n.o.s. * (contains ethanol and methanol)
name
ICAO/IATA Class 3
class(es)
ERG Code 3L

14.5. Environmental
Not Applicable
hazard
Special provisions A3 A180
Cargo Only Maximum Qty / Pack 60 L

for user
Passenger and Cargo Maximum Qty / Pack 5L
Passenger and Cargo Limited Quantity Packing Instructions Y341
Passenger and Cargo Limited Maximum Qty / Pack 1L

ALCOHOLS, N.O.S. (contains ethanol and methanol)
name
14.3. Transport hazard IMDG Class 3

EMS Number F-E , S-D

for user
Limited Quantities 1L

14.2. UN proper shipping ALCOHOLS, N.O.S. (vapour pressure at 50 °C not more than 110 kPa) (contains ethanol and methanol); ALCOHOLS, N.O.S.
name (vapour pressure at 50 °C more than 110 kPa) (contains ethanol and methanol)

3 Not Applicable
class(es)
14.5. Environmental
Not Applicable
hazard
Classification code F1
Special provisions 274; 601; 640C|274; 601; 640D

Limited quantity 1L
for user
Equipment required PP, EX, A
Fire cones number 1
Continued...
Not Applicable
Product name Group
ethanol Not Available

ethanol Not Available

ethanol is found on the following regulatory lists
Europe EC Inventory
(Norwegian)
methanol is found on the following regulatory lists

Europe EC Inventory
(Norwegian)

Not Applicable

Seveso Category P5a, P5b, P5c



Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (ethanol; methanol)
China - IECSC Yes

Yes
NLP
Japan - ENCS Yes
Korea - KECI Yes
Continued...
USA - TSCA Yes
Taiwan - TCSI Yes

Mexico - INSQ Yes
Vietnam - NCI Yes
Russia - FBEPH Yes

registration.
CONTACT POINT

H301 Toxic if swallowed.
H311 Toxic in contact with skin.

H331 Toxic if inhaled.
H370 Causes damage to organs.
SDS Version Summary

Date of
Update
information - Acute Health (skin), Toxicological information - Acute Health (swallowed), First Aid measures -
Advice to Doctor, Toxicological information - Chronic Health, Hazards identification - Classification, Disposal
considerations - Disposal, Exposure controls / personal protection - Engineering Control, Ecological Information -
2.3 18/08/2022 Environmental, Exposure controls / personal protection - Exposure Standard, First Aid measures - First Aid (eye),
First Aid measures - First Aid (inhaled), First Aid measures - First Aid (skin), Handling and storage - Handling
Procedure, Composition / information on ingredients - Ingredients, Exposure controls / personal protection -
Personal Protection (other), Exposure controls / personal protection - Personal Protection (eye), Exposure
controls / personal protection - Personal Protection (hands/feet)
Other information
Continued...
end of SDS
UNIVERSAL U.V. TRACER FLUID
Part Number: 606268 (250 ml) Issue Date: 18/08/2022

Product name UNIVERSAL U.V. TRACER FLUID

Other means of
606268 (250 ml), 606268
identification
Relevant identified uses Use according to manufacturer's directions.

Central Warehouse
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--------- Norway


Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
Part Number: 606268 (250 ml) Page 2 of 10 Issue Date: 18/08/2022
transport purposes.
regulation (EC) No
[1]
amendments
2.2. Label elements
Hazard statement(s)
Not Applicable
Not Applicable

Not Applicable

Not Applicable

Not Applicable

Not Applicable

Not Applicable
2.3. Other hazards
3.1.Substances
3.2.Mixtures
1. CAS No
2.EC No % Classification according to regulation (EC) SCL / M- Nanoform Particle
Name
3.Index No [weight] No 1272/2008 [CLP] and amendments Factor Characteristics
4.REACH No
Non classified Not
Not Available 100 Not Applicable Not Available
ingredients Applicable

Eye Contact
Continued...

Inhalation
Ingestion
See Section 11

Foam.


Combustible.
Fire/Explosion Hazard Slight fire hazard when exposed to heat or flame.

See section 8

See section 12

Moderate hazard.


Fire and explosion

See section 5
protection
Continued...

Metal can or drum
Suitable container Packaging as recommended by manufacturer.

None known
accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ + + + + + +


See section 1.2

DNELs PNECs
Ingredient
INGREDIENT DATA
Not Applicable
Emergency Limits
UNIVERSAL U.V. TRACER

FLUID

FLUID
MATERIAL DATA

8.2.1. Appropriate
Continued...

measures, such as
personal protective
equipment

Chemical goggles.


OTHERWISE:
Other protection
Overalls.
Barrier cream.

See section 12

Appearance Liquid, yellow, insoluble in water

1)
octanol / water
(°C)
Decomposition
temperature (°C)

< -50 Viscosity (cSt) Not Available
point (°C)

boiling range (°C)
Flash point (°C) >95 Taste Not Available


or mN/m)

Nanoform Particle
Characteristics

Not Available

Continued...
See section 7.2
hazardous reactions
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

Inhaled using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable
Skin Contact The liquid may be miscible with fats or oils and may degrease the skin, producing a skin reaction described as non-allergic
Chronic
UNIVERSAL U.V. TRACER TOXICITY IRRITATION

FLUID Not Available Not Available

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity

Not Not Not
FLUID Not Available Not Available
Continued...


Ingredient Mobility

P B T

PBT
vPvB
vPvB No



Consult State Land Waste Management Authority for disposal.
Bury residue in an authorised landfill.

Labels Required
Marine Pollutant NO

Not Applicable
number

Not Applicable
name

14.5. Environmental
Not Applicable
hazard
for user
Continued...
Hazard Label Not Applicable


Not Applicable
name

class(es)
14.5. Environmental
Not Applicable
hazard

for user

Not Applicable
name



for user

Not Applicable
name

class(es)
14.5. Environmental
Not Applicable
hazard

for user
Continued...
Not Applicable
Product name Group


Not Applicable



Not Available
Non-Industrial Use
Canada - DSL Not Available

Canada - NDSL Not Available
China - IECSC Not Available

Not Available
NLP
Japan - ENCS Not Available
Korea - KECI Not Available

New Zealand - NZIoC Not Available
Philippines - PICCS Not Available
USA - TSCA Not Available
Taiwan - TCSI Not Available

Mexico - INSQ Not Available
Vietnam - NCI Not Available
Russia - FBEPH Not Available

registration.
CONTACT POINT
SDS Version Summary

2.3 18/08/2022 Hazards identification - Classification, Composition / information on ingredients - Ingredients
Continued...
Other information
end of SDS
UNIWASH

Product name UNIWASH
Synonyms Product Part Number: 571745 (25 liter), 659375 (210 liter),
Other means of
571745, 8068-46
identification
Chemical Product
Category
Cleaning agent: This composition meets the criteria for not being harmful to the marine environment according to MARPOL
Relevant identified uses
Annex V and may be discharged into the sea when used to clean cargo holds and external surfaces on ships.

Central Warehouse
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--------- Norway

Registered company name Wilhelmsen IT Services AS

Address PO Box 33 Lysaker Norway NO-1324 Norway
Telephone +47 67 58 40 00
Fax +47 67 58 47 30
Website http://www.wilhelmsen.com/
Email wss.info@wilhelmsen.com

Page 1 continued...
UNIWASH
Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
transport purposes.
regulation (EC) No
1272/2008 [CLP] and H318 - Serious Eye Damage/Eye Irritation Category 1
amendments [1]
2.2. Label elements
Hazard pictogram(s)
Signal word Danger
Hazard statement(s)
Not Applicable

Not Applicable



Not Applicable

Not Applicable
Material contains cocamide diethanolamide., sodium dodecylbenzenesulfonate.
2.3. Other hazards

May produce skin discomfort*.
Continued...
UNIWASH
Possible respiratory and skin sensitizer*.
3.1.Substances
3.2.Mixtures
1. CAS No
Nanoform
2.EC No % Classification according to regulation (EC) SCL / M-
Name Particle
3.Index No [weight] No 1272/2008 [CLP] and amendments Factor
Characteristics
4.REACH No
Not
Available
1. 68891-38-3 Acute M
Skin Corrosion/Irritation Category 2, Hazardous
2.500-234-8 factor: Not
1-5 sodium lauryl ether sulfate to the Aquatic Environment Long-Term Hazard Not Available
3.Not Available Available
Category 3; H315, H412 [1]
factor: Not
Available
Not
Available
1. 68155-07-7* Skin Corrosion/Irritation Category 2, Serious Acute M
2.268-935-9 Eye Damage/Eye Irritation Category 1, factor: Not
1-5 cocamide diethanolamide. Not Available
3.Not Available Hazardous to the Aquatic Environment Long- Available
4.Not Available Term Hazard Category 2; H315, H318, H411 [1] Chronic M
factor: Not
Available
Acute Toxicity (Oral) Category 4, Skin Not
Corrosion/Irritation Category 2, Serious Eye Available
1. 25155-30-0 Damage/Eye Irritation Category 1, Specific Acute M
2.246-680-4 sodium Target Organ Toxicity - Single Exposure factor: Not
1-5 Not Available
3.Not Available dodecylbenzenesulfonate (Respiratory Tract Irritation) Category 3 , Available
4.Not Available Hazardous to the Aquatic Environment Long- Chronic M
Term Hazard Category 1; H302, H315, H318, factor: Not
H335, H410 [1] Available

Eye Contact
Skin Contact
Inhalation

prevent aspiration.
See Section 11
Continued...
UNIWASH



Non combustible.

See section 8

See section 12

Minor Spills
Moderate hazard.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage of concentrated product from entering drains or water course.
Stop leak if safe to do so.
Major Spills
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.
Neutralise/decontaminate residue (see Section 13 for specific agent).
Collect solid residues and seal in labelled drums for disposal.
Wash area and prevent runoff into drains.
After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using.
If contamination of drains or waterways occurs, advise emergency services.


Safe handling
Fire and explosion
See section 5
protection
Other information

Suitable container Polyethylene or polypropylene container.
Packing as recommended by manufacturer.
Continued...
UNIWASH

accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ x o x + + +


See section 1.2

DNELs PNECs
Ingredient
Dermal 0.625 mg/kg bw/day (Systemic, Chronic) 0.052 mg/L (Water (Fresh))
Inhalation 1.102 mg/m³ (Systemic, Chronic) 0.071 mg/L (Water - Intermittent release)
Dermal 132 µg/cm² (Local, Chronic) 0.009 mg/L (Water (Marine))
sodium lauryl ether sulfate Dermal 0.312 mg/kg bw/day (Systemic, Chronic) * 0.2 mg/kg sediment dw (Sediment (Fresh Water))
Dermal 79 µg/cm² (Local, Chronic) * 1 g/L (STP)
7 µg/L (Water (Fresh))
Dermal 0.75 mg/kg bw/day (Systemic, Chronic) 24 µg/L (Water - Intermittent release)
Inhalation 11.5 mg/m³ (Systemic, Chronic) 0.7 µg/L (Water (Marine))
cocamide diethanolamide. Dermal 89.3 µg/kg bw/day (Systemic, Chronic) * 0.23 mg/kg sediment dw (Sediment (Fresh Water))
Inhalation 2.03 mg/m³ (Systemic, Chronic) * 23 µg/kg sediment dw (Sediment (Marine))
Oral 1.17 mg/kg bw/day (Systemic, Chronic) * 32 mg/kg soil dw (Soil)
830 mg/L (STP)

Dermal 1.57 mg/cm² (Local, Chronic)
Inhalation 52 mg/m³ (Systemic, Acute) 0.693 mg/L (Water (Fresh))
Dermal 1.57 mg/cm² (Local, Acute) 0.654 mg/L (Water - Intermittent release)
Inhalation 52 mg/m³ (Local, Acute) 1 mg/L (Water (Marine))
sodium Dermal 28.6 mg/kg bw/day (Systemic, Chronic) * 27.5 mg/kg sediment dw (Sediment (Fresh Water))
dodecylbenzenesulfonate Inhalation 26 mg/m³ (Systemic, Chronic) * 2.75 mg/kg sediment dw (Sediment (Marine))
Dermal 0.787 mg/cm² (Local, Chronic) * 50 mg/L (STP)
Inhalation 26 mg/m³ (Local, Chronic) * 20 mg/kg food (Oral)
Dermal 0.787 mg/cm² (Local, Acute) *
INGREDIENT DATA
Continued...
UNIWASH
Not Applicable
Emergency Limits

sodium
2.1 mg/m3 23 mg/m3 87 mg/m3
sodium lauryl ether sulfate Not Available Not Available

cocamide diethanolamide. Not Available Not Available
sodium
sodium lauryl ether sulfate E ≤ 0.01 mg/m³

cocamide diethanolamide. E ≤ 0.1 ppm
sodium
E ≤ 0.01 mg/m³
MATERIAL DATA
more.

8.2.1. Appropriate

measures, such as
personal protective
equipment


Overalls.
Barrier cream.

See section 12
Continued...
UNIWASH
Appearance Liquid, pale yellow, soluble in water

Physical state Liquid 1.01 - 1.02
1)
octanol / water
(°C)
Decomposition
pH (as supplied) 7-8 Not Available
temperature (°C)
point (°C)

boiling range (°C)


or mN/m)
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) Not Available

Nanoform Particle
Characteristics

Not Available

See section 7.2
hazardous reactions

10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation (as
Inhaled
Skin Contact Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce
Limited evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a
substantial number of individuals following direct contact, and/or produces significant inflammation when applied to the healthy
intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or more after the end of the
exposure period. Skin irritation may also be present after prolonged or repeated exposure; this may result in a form of contact
dermatitis (nonallergic). The dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which may
progress to blistering (vesiculation), scaling and thickening of the epidermis.
Anionic surfactants/ hydrotropes generally produce skin reactions following the removal of natural oils. The skin may appear red
and may become sore. Papular dermatitis may also develop.
Continued...
UNIWASH
Eye
Direct eye contact with some concentrated anionic surfactants/ hydrotropes produces corneal damage, in some cases severe.
Low concentrations may produce immediate discomfort, conjunctival hyperaemia, and oedema of the corneal epithelium. Healing
may take several days.
Chronic
TOXICITY IRRITATION
UNIWASH
TOXICITY IRRITATION
[2]
Oral (Rat) LD50: 1600 mg/kg Eye: adverse effect observed (irritating)[1]
sodium lauryl ether sulfate
Skin (rabbit):25 mg/24 hr moderate
TOXICITY IRRITATION
[2] Not Available
cocamide diethanolamide. dermal (rat) LD50: >2000 mg/kg
[1]
Oral (Rat) LD50: >2000 mg/kg
TOXICITY IRRITATION
[1] Eye (rabbit): 0.25 mg/24hr-SEVERE
dermal (rat) LD50: >2000 mg/kg
Inhalation (Rat) LC50: 0.31 mg/L4h[1] Eye (rabbit): 1% - SEVERE

sodium
Oral (Rat) LD50: 438 mg/kg[2] Eye: adverse effect observed (irritating)[1]
Skin (rabbit): 20 mg/24 hr-SEVERE
* [CESIO]
Polyethers, for example, ethoxylated surfactants and polyethylene glycols, are highly susceptible towards air oxidation as
the ether oxygens will stabilize intermediary radicals involved. Investigations of a chemically well-defined alcohol
(pentaethylene glycol mono-n-dodecyl ether) ethoxylate, showed that polyethers form complex mixtures of oxidation
products when exposed to air.
Sensitization studies in guinea pigs revealed that the pure nonoxidized surfactant itself is nonsensitizing but that many of
the investigated oxidation products are sensitizers. Two hydroperoxides were identified in the oxidation mixture, but only
one (16-hydroperoxy-3,6,9,12,15-pentaoxaheptacosan-1-ol ) was stable enough to be isolated.
Alkyl ether sulfates (alcohol or alkyl ethoxysulfates) (AES) (syn: AAASD ,alkyl alcohol alkoxylate sulfates, SLES) are
generally classified according to Comité Européen des Agents de Surface et leurs Intermédiaires Organiques (CESIO) as
SODIUM LAURYL ETHER
Irritant (Xi) with the risk phrases R38 (Irritating to skin) and R36 (Irritating to eyes). An exception has been made for AES
SULFATE
(2-3E0) in a concentration of 70-75% where R36 is substituted with R41 (Risk of serious damage to eyes).
AES are not included in Annex 1 of the list of dangerous substances of Council Directive 67/548/EEC.
In assessing this family the Cosmetic Ingredient Review (CIR) Expert Panel recognized that most of the acute oral toxicity,
dermal irritation and sensitization, subchronic and chronic oral toxicity, reproductive and developmental toxicity,
carcinogenicity, and photosensitization studies have been conducted on ammonium laureth sulfate and sodium laureth
sulfate. Sodium and ammonium laureth sulfate have not evoked adverse responses in any toxicological testing, including
acute oral toxicity, sub-chronic and chronic oral toxicity, reproductive and develop-mental toxicity, carcinogenicity, and
photosensitization studies.
The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants
may produce conjunctivitis.
cocamide diethanolamide. The following information refers to contact allergens as a group and may not be specific to this product.
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The
pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type.
Fatty acid amides (FAA) are ubiquitous in household and commercial environments. The most common of these are based
on coconut oil fatty acids alkanolamides. These are the most widely studied in terms of human exposure.
Fatty acid diethanolamides (C8-C18) are classified by Comite Europeen des Agents de Surface et de leurs Intermediaires
Organiques (CESIO) as Irritating (Xi) with the risk phrases R38 (Irritating to skin) and R41 (Risk of serious damage to
eyes).
Continued...
UNIWASH
For Fatty Nitrogen Derived (FND) Amides (including several high molecular weight alkyl amino acid amides)
The chemicals in the Fatty Nitrogen Derived (FND) Amides of surfactants are similar to the class in general as to
physical/chemical properties, environmental fate and toxicity. Human exposure to these chemicals is substantially
documented.
The Fatty nitrogen-derived amides (FND amides) comprise four categories:
Subcategory I: Substituted Amides
Subcategory II: Fatty Acid Reaction Products with Amino Compounds (Note: Subcategory II chemicals, in many cases,
contain Subcategory I chemicals as major components)
Subcategory III: Imidazole Derivatives
Subcategory IV: FND Amphoterics
Acute Toxicity: The low acute oral toxicity of the FND Amides is well established across all Subcategories by the available
data. The limited acute toxicity of these chemicals is also confirmed by four acute dermal and two acute inhalation studies.
Repeated Dose and Reproductive Toxicity: Two subchronic toxicity studies demonstrating low toxicity are available for
Subcategory I chemicals.
Coconut oil diethanolamine condensate is possibly carcinogenic to humans (IARC Group 2B)
In a study of the dermal application in mice, coconut oil diethanolamine condensate increased the incidence of
hepatocellular carcinoma and hepatocellular adenoma in males and females, and of hepatoblastoma in males. The
incidence of renal tubule adenoma and carcinoma combined was also increased in males. In a study of dermal application
in rats, no increase in tumour incidence was observed.
Tumours of the kidney and hepatoblastoma are rare spontaneous neoplasms in experimental animals.
The amide linkage between diethanolamine and of the fatty acid moiety is resistant to metabolic hydrolysis.
The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure
to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis
(nonallergic). This form of dermatitis is often characterised by skin redness (erythema) and swelling epidermis.
Histologically there may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the
epidermis.
for diethanolamine (DEA):
In animal studies, DEA has low acute toxicity via the oral and dermal routes with moderate skin irritation and severe eye
irritation. In subchronic toxicity testing conducted via the oral route in rats and mice, the main effects observed were
increased organ weights and histopathology of the kidney and/or liver, with the majority of other tissue effects noted only at
relatively high dosages. In subchronic studies conducted via the dermal route, skin irritation was noted as well as systemic
effects similar to those observed in the oral studies.
WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans.
Linear alkylbenzene sulfonates (LAS) are classified as Irritant (Xi) with the risk phrases R38 (Irritating to skin) and R41
(Risk of serious damage to eyes) according to CESIO (CESIO 2000). LAS are not included in Annex 1 of list of dangerous
substances of Council Directive 67/548/EEC.
UNIWASH & SODIUM
Linear alkylbenzene sulfonic acids (LABS) are strong acids (pKa<2) are classified as corrosive (R34)
DODECYLBENZENESULFONATE
Branched materials exhibit comparable toxicity to linear species.
Acute toxicity: The available data indicate minimal to moderate toxicity, with LD50 values ranging from 500 to 2000 mg/kg
body weight (bw).
SODIUM LAURYL ETHER
SULFATE & cocamide No significant acute toxicological data identified in literature search.
diethanolamide.
Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a
cocamide diethanolamide. & non-allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high
SODIUM levels of highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease in
DODECYLBENZENESULFONATE a non-atopic individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documented
exposure to the irritant.

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
Continued...
UNIWASH
12.1. Toxicity

UNIWASH Not Not Not

sodium lauryl ether sulfate
2.43-
4.01mg/l

LC50 96h Fish ~2.4mg/l 2
cocamide diethanolamide. NOEC(ECx) 504h Crustacea ~0.1mg/l 2

EC50 72h Algae or other aquatic plants ~2.1mg/l 2
EC50 48h Crustacea ~3.2mg/l 2

sodium 0.065-
EC50(ECx) 48h Crustacea 4
dodecylbenzenesulfonate 0.085mg/L
EC50 96h Algae or other aquatic plants 0.9mg/L 5
0.065-
0.085mg/L
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
For Surfactants: Kow cannot be easily determined due to hydrophilic/hydrophobic properties of the molecules in surfactants. BCF value: 1-350.
Aquatic Fate: Surfactants tend to accumulate at the interface of the air with water and are not extracted into one or the other liquid phases.
For linear alkylbenzene sulfonic acids (LABS) (and their salts):
Environmental fate:
LABS are generally highly water soluble (miscible) and have a relatively low Kow. The environmental fate data indicate that these chemicals are highly susceptible
to photo-and biodegradation.
LABS are strong acids (pKa <1) that are completely ionised in aqueous solutions.
DO NOTdischarge concentrated product into sewer or waterways.



Ingredient Mobility

P B T
PBT
vPvB
vPvB No
Continued...
UNIWASH



Product / Packaging Where in doubt contact the responsible authority.
Labels Required
Marine Pollutant NO

Not Applicable
number

Not Applicable
name

14.5. Environmental
Not Applicable
hazard




Not Applicable
name

class(es)
14.5. Environmental
Not Applicable
hazard
for user
Continued...
UNIWASH

Not Applicable
name



for user

Not Applicable
name

class(es)
14.5. Environmental
Not Applicable
hazard

for user
Not Applicable
Product name Group
sodium lauryl ether sulfate Not Available
cocamide diethanolamide. Not Available

sodium
Not Available

sodium lauryl ether sulfate Not Available
cocamide diethanolamide. Not Available

sodium
Not Available
Continued...
UNIWASH
sodium lauryl ether sulfate is found on the following regulatory lists
Europe EC Inventory
cocamide diethanolamide. is found on the following regulatory lists

Europe EC Inventory
sodium dodecylbenzenesulfonate is found on the following regulatory lists

Europe EC Inventory

Not Applicable



Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (sodium lauryl ether sulfate; cocamide diethanolamide.; sodium dodecylbenzenesulfonate)
China - IECSC Yes

Yes
NLP
Japan - ENCS Yes
Korea - KECI Yes
New Zealand - NZIoC No (cocamide diethanolamide.)
Philippines - PICCS No (cocamide diethanolamide.)
USA - TSCA Yes
Taiwan - TCSI Yes

Mexico - INSQ No (sodium lauryl ether sulfate; cocamide diethanolamide.)
Vietnam - NCI Yes
Russia - FBEPH Yes

registration.
CONTACT POINT

H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.
Continued...
UNIWASH
Other information
Notes
“This composition meets the criteria for not being harmful to the marine environment according to MARPOL Annex V and may be
discharged into the sea when used to clean cargo holds and external surfaces on ships.”
Continued...
UNIWASH
end of SDS
VACUUM PIPE CLEANER - UNITOR

Product name VACUUM PIPE CLEANER - UNITOR
Synonyms 740498
Other means of
740498, 740498 + 12345
identification
Chemical Product
Category
Relevant identified uses Acid cleaner - Product declaration number offshore: 304539

Central Warehouse
login=wilhelmsen

--------- Norway

Registered company name Wilhelmsen Ships Service AS

Address Willem Barentszstraat 50 Rotterdam 3165AB Netherlands
Telephone +31 4877 777
Fax Not Available
Website http://www.wilhelmsen.com/services/maritime/compan
Email wss.rotterdam@wilhelmsen.com

Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers
Page 1 continued...
Association / Organisation The Netherlands: National Poisons Information Cent CHEMWATCH EMERGENCY RESPONSE (24/7)
Emergency telephone
+ 31 30 274 88 88 +47 23 25 25 84
numbers
Other emergency
+31-10-4877700 +61 3 9573 3188
telephone numbers
transport purposes.
regulation (EC) No
amendments [1]
2.2. Label elements
Hazard statement(s)
Not Applicable
EUH210 Safety data sheet available on request.

Not Applicable

Not Applicable

Not Applicable

Not Applicable

Not Applicable
2.3. Other hazards

May produce discomfort of the eyes*.
3.1.Substances
3.2.Mixtures
Continued...
1. CAS No
Name
4.REACH No
Not Available
Acute M
1. 5329-14-6 Skin Corrosion/Irritation Category 2, Serious Eye
sulfamic Damage/Eye Irritation Category 2, Hazardous to the factor: Not
2.226-218-8
7 Available Not Available
3.016-026-00-0 acid Aquatic Environment Long-Term Hazard Category 3;
Chronic M
4.Not Available [2]
H315, H319, H412 factor: Not
Available
Not Available
Acute M
1. 7732-18-5
factor: Not
2.231-791-2
3.Not Available
80-95 water Not Classified [1] Available Not Available
Chronic M
4.Not Available
factor: Not
Available

See Section 11
For acute or short term repeated exposures to strong acids:
Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially.
Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling
Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise.
Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid on proteins in
specific tissues.
INGESTION:
Immediate dilution (milk or water) within 30 minutes post ingestion is recommended.
DO NOT attempt to neutralise the acid since exothermic reaction may extend the corrosive injury.
Be careful to avoid further vomit since re-exposure of the mucosa to the acid is harmful. Limit fluids to one or two glasses in an adult.
Charcoal has no place in acid management.
Some authors suggest the use of lavage within 1 hour of ingestion.
Continued...
SKIN:
Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping.
Deep second-degree burns may benefit from topical silver sulfadiazine.
EYE:
Eye injuries require retraction of the eyelids to ensure thorough irrigation of the conjuctival cul-de-sacs. Irrigation should last at least 20-30 minutes. DO NOT
use neutralising agents or any other additives. Several litres of saline are required.
Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer term use) antibiotic drops, vasoconstrictive agents or artificial tears
may be indicated dependent on the severity of the injury.
Steroid eye drops should only be administered with the approval of a consulting ophthalmologist).
[Ellenhorn and Barceloux: Medical Toxicology]



Non combustible.
Not considered to be a significant fire risk.
Fire/Explosion Hazard Acids may react with metals to produce hydrogen, a highly flammable and explosive gas.

See section 8

See section 12

Major Spills Chemical Class:acidic compounds, inorganic

SORBENT
TYPE
LAND SPILL - SMALL
foamed glass - pillows 1 throw pitchfork R, P, DGC, RT
expanded mineral - particulate 2 shovel shovel R, I, W, P, DGC

foamed glass - particulate 2 shovel shovel R, W, P, DGC
LAND SPILL - MEDIUM
expanded mineral -particulate 1 blower skiploader R, I, W, P, DGC
foamed glass- particulate 2 blower skiploader R, W, P, DGC

foamed glass - particulate 3 throw skiploader R, W, P, DGC
Legend
R; Not reusable
I: Not incinerable
Continued...
Moderate hazard.


Fire and explosion

See section 5
protection
Other information

Lined metal can, lined metal pail/ can.
Suitable container Plastic pail.
Polyliner drum.
Sulfamic acid:
reacts violently with chlorine, nitric acid, fuming nitric acid, strong bases, chlorine, hypochlorous acid, strong oxidising agents,
sulfides, cyanides or when heated with nitrates, nitrites
is strongly acidic in aqueous solution
hydrolyses to ammonium bisulfate at elevated temperatures
Storage incompatibility is incompatible with alkylene oxides, aliphatic amines, alkanolamines, amides, ammonia, epichlorohydrin, organic
anhydrides, isocyanates, metal nitrates/ nitrites, oxidisers, vinyl acetate, common metals and their alloys, water
Contact with metals may result in the evolution of hydrogen (H2) which can form explosive mixtures in air.
Avoid strong bases.

accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
+ + + + + + +


See section 1.2

DNELs PNECs
Ingredient
sulfamic acid Dermal 10 mg/kg bw/day (Systemic, Chronic) 1.8 mg/L (Water (Fresh))
Inhalation 70.5 mg/m³ (Systemic, Chronic) 0.48 mg/L (Water - Intermittent release)
Dermal 5 mg/kg bw/day (Systemic, Chronic) * 0.18 mg/L (Water (Marine))
Oral 5 mg/kg bw/day (Systemic, Chronic) * 0.84 mg/kg sediment dw (Sediment (Marine))
Continued...
DNELs PNECs
Ingredient
5 mg/kg soil dw (Soil)
20 mg/L (STP)
INGREDIENT DATA
Not Applicable
Emergency Limits
sulfamic acid 9.5 mg/m3 100 mg/m3 630 mg/m3

sulfamic acid Not Available Not Available
water Not Available Not Available
MATERIAL DATA
more.

8.2.1. Appropriate

measures, such as
personal protective
equipment
Safety glasses with unperforated side shields may be used where continuous eye protection is desirable, as in laboratories;
Eye and face protection a danger of splashing, or if the material may be under pressure.
fitted.

Overalls.
Barrier cream.

GLOVE SELECTION INDEX Type -P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 &
VACUUM PIPE CLEANER - UNITOR mask) may also be important.

Maximum gas/vapour
BUTYL A minimum Half-face Full-Face
NEOPRENE A air p.p.m. (by volume)
factor
VITON A
-AUS /
up to 10 1000 -
NATURAL RUBBER C Class1 P2
Continued...
PVA C -AUS / Class

up to 50 1000 -
1 P2
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion up to 100 5000 - -2 P2
C: Poor to Dangerous Choice for other than short term immersion up to 100 10000 - -3 P2
100+ Airline**
* Where the glove is to be used on a short term, casual or infrequent basis, * - Continuous Flow ** - Continuous-flow or positive pressure demand
factors such as "feel" or convenience (e.g. disposability), may dictate a choice A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or
of gloves which might otherwise be unsuitable following long-term or frequent hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
use. A qualified practitioner should be consulted. dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury,
Ansell Glove Selection compounds(below 65 degC)
AlphaTec 02-100
AlphaTec® 38-612
AlphaTec® 58-008
AlphaTec® 58-530B
AlphaTec® 58-530W
AlphaTec® 58-735
AlphaTec® 79-700

See section 12


1)
octanol / water
(°C)
Decomposition
temperature (°C)

>250 Viscosity (cSt) Not Available
point (°C)

boiling range (°C)

or mN/m)
Solubility in water Miscible pH as a solution (20%) 1.1
Nanoform Particle
Characteristics
Continued...

Not Available

See section 7.2
hazardous reactions

10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

Acidic corrosives produce respiratory tract irritation with coughing, choking and mucous membrane damage. Symptoms of
exposure may include dizziness, headache, nausea and weakness. In more severe exposures, pulmonary oedema may be
Inhaled
evident either immediately or after a latent period of 5-72 hours.
Inhalation of sulfamic acid may cause bloody spit, difficulty breathing, low blood pressure, headache, dizziness, bluish skin
colour and lung congestion.
Not normally a hazard due to non-volatile nature of product
The material has NOT been classified by EC Directives or other classification systems as "harmful by inhalation". This is because
of the lack of corroborating animal or human evidence. In the absence of such evidence, care should be taken nevertheless to
ensure exposure is kept to a minimum and that suitable control measures be used, in an occupational setting to control vapours,
fumes and aerosols.
Ingestion of acidic corrosives may produce circumoral burns with a distinct discolouration of the mucous membranes of the
mouth, throat and oesophagus. Immediate pain and difficulties in swallowing and speaking may also be evident. Oedema of the
epiglottis may produce respiratory distress and possibly, asphyxia.
Ingestion Ingestion of sulfamic acid may cause vomiting, diarrhoea and a drop in blood pressure. Asphyxia may occur from oedema of the
glottis. After initial recovery, onset of fever indicates mediastinitis or peritonitis from perforation of the esophagus or stomach.
Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may heal slowly with
the formation of scar tissue.
Concentrated solutions may cause chemical burns. The effects of sulfamic acid on the skin appear to be limited to the effects of
low pH. Concentrations of greater than 20% of sulfamic acid may injure the skin.
Skin Contact
Direct eye contact with acid corrosives may produce pain, lachrymation, photophobia and burns. Mild burns of the epithelia
generally recover rapidly and completely. Severe burns produce long-lasting and possible irreversible damage.
Eye When applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty-four hours or more
after instillation.
Irritation of the eyes may produce a heavy secretion of tears (lachrymation).
Chronic Repeated or prolonged exposure to acids may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth
and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.
Gastrointestinal disturbances may also occur.
Continued...
problems.
VACUUM PIPE CLEANER - TOXICITY IRRITATION

UNITOR Oral (Rat)LC50: 3160 mg/kg[2] Not Available
TOXICITY IRRITATION
dermal (rat) LD50: >2000 mg/kg[1] Eye (rabbit): 20 mg - moderate
Oral (Rat) LD50: >2000 mg/kg[2] Eye (rabbit): 250 ug/24 h - SEVERE
sulfamic acid Eye: adverse effect observed (irritating)[1]
Skin (human): 4 %/5 days (I)- mild
Skin (rabbit): 500 mg/24 h-SEVERE
TOXICITY IRRITATION
water
Oral (Rat) LD50: >90000 mg/kg[2] Not Available
SULFAMIC ACID The material may produce severe skin irritation after prolonged or repeated exposure, and may produce a contact dermatitis
WATER No significant acute toxicological data identified in literature search.

VACUUM PIPE CLEANER - irritant.
UNITOR & SULFAMIC ACID for acid mists, aerosols, vapours

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity
Continued...

VACUUM PIPE CLEANER -
Fish Pimpephales promelas (Fathead
UNITOR LC50 96 70.3mg/L 8
minnow)

NOEC(ECx) 1560h Fish 0.025mg/l 2
sulfamic acid EC50 72h Algae or other aquatic plants 33.8mg/l 2

EC50 48h Crustacea 71.6mg/l 2
LC50 96h Fish 14.2mg/l 1

water Not Not Not
Harmful to aquatic organisms.

Ecotoxicity:
The tolerance of water organisms towards pH margin and variation is diverse. Recommended pH values for test species listed in OECD guidelines are between
6.0 and almost 9. Acute testing with fish showed 96h-LC50 at about pH 3.5

sulfamic acid HIGH HIGH

water LOW LOW

sulfamic acid LOW (LogKOW = -4.3438)

Ingredient Mobility
sulfamic acid LOW (Log KOC = 6.124)

P B T
PBT
vPvB
vPvB No



Product / Packaging Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable
disposal treatment or disposal facility can be identified.
Treat and neutralise at an approved treatment plant.
Continued...
Labels Required
Marine Pollutant NO

Not Applicable
number

Not Applicable
name

14.5. Environmental
Not Applicable
hazard

Not Applicable
name

class(es)
14.5. Environmental
Not Applicable
hazard

for user

Not Applicable
name



for user
Continued...

Not Applicable
name
class(es)
14.5. Environmental
Not Applicable
hazard

for user
Not Applicable
Product name Group
sulfamic acid Not Available
water Not Available

sulfamic acid Not Available
water Not Available
sulfamic acid is found on the following regulatory lists
Europe EC Inventory
water is found on the following regulatory lists
Europe EC Inventory

Not Applicable


Continued...

Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (sulfamic acid; water)
China - IECSC Yes

Yes
NLP
Japan - ENCS Yes
Korea - KECI Yes
USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ Yes
Vietnam - NCI Yes
Russia - FBEPH Yes

registration.
CONTACT POINT

SDS Version Summary

Date of
Update
information - Acute Health (skin), Toxicological information - Acute Health (swallowed), Hazards identification -
13.37 31/08/2021
Classification, Composition / information on ingredients - Ingredients, Toxicological information - Toxicity and
Irritation (Other)
Other information
Continued...
end of SDS
VACUUM PUMP OIL

Product name VACUUM PUMP OIL
Synonyms 320424,597674
Other means of
320424
identification
Relevant identified uses Use according to manufacturer's directions.

Central Warehouse
login=wilhelmsen

--------- Norway


Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +31-10-4877700 + 31 10 4877700
telephone numbers

Emergency telephone
+47 23 25 25 84
numbers
Other emergency
+61 3 9573 3188
telephone numbers
Page 1 continued...
VACUUM PUMP OIL
transport purposes.
regulation (EC) No
1272/2008 [CLP] and H350 - Carcinogenicity Category 1B
[1]
amendments
2.2. Label elements
Hazard pictogram(s)
Signal word Danger
Hazard statement(s)
H350 May cause cancer.
Not Applicable

Not Applicable

P201 Obtain special instructions before use.

P308+P313 IF exposed or concerned: Get medical advice/ attention.


Material contains paraffinic distillate, heavy, hydrotreated (mild), paraffinic distillate, light, hydrotreated (mild).
2.3. Other hazards

Inhalation and/or ingestion may produce health damage*.
May produce discomfort of the eyes and respiratory tract*.
paraffinic distillate, heavy,

hydrotreated (mild)
paraffinic distillate, light,
hydrotreated (mild)
3.1.Substances
Continued...
VACUUM PUMP OIL
3.2.Mixtures
1. CAS No
Name regulation (EC) No 1272/2008 [CLP] SCL / M-Factor
and amendments
4.REACH No
Not Available
paraffinic distillate,
2.265-157-1 Not Available
<99 heavy, hydrotreated Carcinogenicity Category 1B; H350 [2] Not Available
3.649-467-00-8 Chronic M
(mild)
Available
Not Available
paraffinic distillate,
2.265-158-7 light, hydrotreated Not Available
<99 Carcinogenicity Category 1B; H350 [2] Not Available
3.649-468-00-3 Chronic M
4.Not Available (mild) factor: Not
Available

Eye Contact
Inhalation
prevent aspiration.
Ingestion Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible
aspiration of vomitus.
See Section 11
Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. Mechanical means
should be used if it is considered necessary to evacuate the stomach contents; these include gastric lavage after endotracheal intubation. If spontaneous vomiting
has occurred after ingestion, the patient should be monitored for difficult breathing, as adverse effects of aspiration into the lungs may be delayed up to 48 hours.
For petroleum distillates
· In case of ingestion, gastric lavage with activated charcoal can be used promptly to prevent absorption - decontamination (induced emesis or lavage) is
controversial and should be considered on the merits of each individual case; of course the usual precautions of an endotracheal tube should be considered prior
to lavage, to prevent aspiration.
· Individuals intoxicated by petroleum distillates should be hospitalized immediately, with acute and continuing attention to neurologic and cardiopulmonary
function.
· Positive pressure ventilation may be necessary.
· Acute central nervous system signs and symptoms may result from large ingestions of aspiration-induced hypoxia.
· After the initial episode,individuals should be followed for changes in blood variables and the delayed appearance of pulmonary oedema and chemical
pneumonitis. Such patients should be followed for several days or weeks for delayed effects, including bone marrow toxicity, hepatic and renal impairment
Individuals with chronic pulmonary disease will be more seriously impaired, and recovery from inhalation exposure may be complicated.
· Gastrointestinal symptoms are usually minor and pathological changes of the liver and kidneys are reported to be uncommon in acute intoxications.
· Chlorinated and non-chlorinated hydrocarbons may sensitize the heart to epinephrine and other circulating catecholamines so that arrhythmias may
occur.Careful consideration of this potential adverse effect should precede administration of epinephrine or other cardiac stimulants and the selection of
bronchodilators.
Continued...
VACUUM PUMP OIL
Heavy and persistent skin contamination over many years may lead to dysplastic changes. Pre-existing skin disorders may be aggravated by exposure to this
product.
In general, emesis induction is unnecessary with high viscosity, low volatility products, i.e. most oils and greases.
High pressure accidental injection through the skin should be assessed for possible incision, irrigation and/or debridement.
NOTE: Injuries may not seem serious at first, but within a few hours tissue may become swollen, discoloured and extremely painful with extensive subcutaneous
necrosis. Product may be forced through considerable distances along tissue planes.

Foam.

result

Combustible.
,
,
sulfur oxides (SOx)
,

See section 8

See section 12

Minor Spills
Wear full body protective clothing with breathing apparatus.
Chemical Class: aliphatic hydrocarbons
SORBENT
TYPE
LAND SPILL - SMALL
cross-linked polymer - particulate 1 shovel shovel R, W, SS

treated wood
2 throw pitchfork DGC, RT
fibre- pillow

Continued...
VACUUM PUMP OIL
LAND SPILL - MEDIUM
cross-linked polymer - particulate 1 blower skiploader R,W, SS

cross-linked polymer - pillow 2 throw skiploader R, DGC, RT


polypropylene - mat 4 throw skiploader DGC, RT
Legend
R; Not reusable
I: Not incinerable


The conductivity of this material may make it a static accumulator., A liquid is typically considered nonconductive if its
conductivity is below 100 pS/m and is considered semi-conductive if its conductivity is below 10 000 pS/m., Whether a liquid is
nonconductive or semi-conductive, the precautions are the same., A number of factors, for example liquid temperature, presence
of contaminants, and anti-static additives can greatly influence the conductivity of a liquid.
Safe handling · Electrostatic discharge may be generated during pumping - this may result in fire.
· Ensure electrical continuity by bonding and grounding (earthing) all equipment.
· Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<=1 m/sec until fill pipe submerged
to twice its diameter, then <= 7 m/sec).
Fire and explosion

See section 5
protection

Metal can or drum
Suitable container Packaging as recommended by manufacturer.
· CARE: Water in contact with heated material may cause foaming or a steam explosion with possible severe burns from wide
scattering of hot material. Resultant overflow of containers may result in fire.
· Oil leaks in a pressurized circuit may result in a fine flammable spray (the lower flammability limit for oil mist is reached for a
concentration of about 45 g/m3
· Autoignition temperatures may be significantly lower under particular conditions (slow oxidation on finely divided materials..
accordance with
Not Available
Regulation (EC) No
Qualifying quantity
application of
Continued...
VACUUM PUMP OIL
+ x + o + + +


See section 1.2

DNELs PNECs
Ingredient
Inhalation 5.58 mg/m³ (Local, Chronic) 9.33 mg/kg food (Oral)
hydrotreated (mild)
Inhalation 5.58 mg/m³ (Local, Chronic) 9.33 mg/kg food (Oral)
hydrotreated (mild)
INGREDIENT DATA

paraffinic distillate, heavy, Mineraloljer brukt som Not Not Not
hydrotreated (mild) motorolje Available Available Available
factors (Norwegian)

paraffinic distillate, light, hydrotreated Mineraloljer brukt som Not Not Not
(mild) motorolje Available Available Available
factors (Norwegian)
Emergency Limits

140 mg/m3 1,500 mg/m3 8,900 mg/m3
hydrotreated (mild)
140 mg/m3 1,500 mg/m3 8,900 mg/m3
hydrotreated (mild)

hydrotreated (mild)

hydrotreated (mild)
MATERIAL DATA
Continued...
VACUUM PUMP OIL
more.
Toxicity and Irritation data for petroleum-based mineral oils are related to chemical components and vary as does the composition and source of the original crude.
A small but definite risk of occupational skin cancer occurs in workers exposed to persistent skin contamination by oils over a period of years. This risk has been
attributed to the presence of certain polycyclic aromatic hydrocarbons (PAH) (typified by benz[a]pyrene).
NOTE L: The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3% DMSO extract as measured by IP 346.
European Union (EU) List of harmonised classification and labelling hazardous substances, Table 3.1, Annex VI, Regulation (EC) No 1272/2008 (CLP) - up to the
latest ATP

8.2.1. Appropriate

measures, such as
personal protective
equipment


Hands/feet protection The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be
Employees working with confirmed human carcinogens should be provided with, and be required to wear, clean, full body
protective clothing (smocks, coveralls, or long-sleeved shirt and pants), shoe covers and gloves prior to entering the
regulated area. [AS/NZS ISO 6529:2006 or national equivalent]
Employees engaged in handling operations involving carcinogens should be provided with, and required to wear and use
half-face filter-type respirators with filters for dusts, mists and fumes, or air purifying canisters or cartridges. A respirator
affording higher levels of protection may be substituted.
Prior to each exit from an area containing confirmed human carcinogens, employees should be required to remove and leave
Other protection protective clothing and equipment at the point of exit and at the last exit of the day, to place used clothing and equipment in
impervious containers at the point of exit for purposes of decontamination or disposal. The contents of such impervious
containers must be identified with suitable labels. For maintenance and decontamination activities, authorized employees
entering the area should be provided with and required to wear clean, impervious garments, including gloves, boots and
continuous-air supplied hood.
Overalls.
P.V.C apron.
Barrier cream.
Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)
up to 10 1000 A-AUS / Class1 -

up to 50 1000 - A-AUS / Class 1
up to 100 5000 - A-2
up to 100 10000 - A-3

100+ Airline**

Continued...
VACUUM PUMP OIL


See section 12

Appearance yellow

1)
octanol / water
(°C)
Decomposition
temperature (°C)

Not Applicable Viscosity (cSt) Not Available
point (°C)
Not Available Molecular weight (g/mol) Not Applicable
boiling range (°C)
Flash point (°C) >250 Taste Not Available

or mN/m)
Vapour pressure (kPa) <0.01 Gas group Not Available

Solubility in water Immiscible pH as a solution (1%) Not Applicable
Vapour density (Air = 1) Not Available VOC g/L Not Applicable
Nanoform Particle
Characteristics

Not Available

See section 7.2
hazardous reactions
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3

Inhaled The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation (as
Continued...
VACUUM PUMP OIL
Inhalation hazard is increased at higher temperatures.
High inhaled concentrations of mixed hydrocarbons may produce narcosis characterised by nausea, vomiting and
lightheadedness. Inhalation of aerosols may produce severe pulmonary oedema, pneumonitis and pulmonary haemorrhage.
Inhalation of petroleum hydrocarbons consisting substantially of low molecular weight species (typically C2-C12) may produce
irritation of mucous membranes, incoordination, giddiness, nausea, vertigo, confusion, headache, appetite loss, drowsiness,
tremors and anaesthetic stupor.
Central nervous system (CNS) depression may include nonspecific discomfort, symptoms of giddiness, headache, dizziness,
nausea, anaesthetic effects, slowed reaction time, slurred speech and may progress to unconsciousness. Serious poisonings
may result in respiratory depression and may be fatal.
Swallowing of the liquid may cause aspiration of vomit into the lungs with the risk of haemorrhaging, pulmonary oedema,
progressing to chemical pneumonitis; serious consequences may result.
Signs and symptoms of chemical (aspiration) pneumonitis may include coughing, gasping, choking, burning of the mouth, difficult
breathing, and bluish coloured skin (cyanosis).
Ingestion
Ingestion of petroleum hydrocarbons may produce irritation of the pharynx, oesophagus, stomach and small intestine with
oedema and mucosal ulceration resulting; symptoms include a burning sensation in the mouth and throat. Large amounts may
produce narcosis with nausea and vomiting, weakness or dizziness, slow and shallow respiration, swelling of the abdomen,
unconsciousness and convulsions. Myocardial injury may produce arrhythmias, ventricular fibrillation and electrocardiographic
changes.
The liquid may be miscible with fats or oils and may degrease the skin, producing a skin reaction described as non-allergic
Skin Contact The material may accentuate any pre-existing dermatitis condition
Limited evidence exists, or practical experience suggests, that the material may cause eye irritation in a substantial number of
individuals and/or is expected to produce significant ocular lesions which are present twenty-four hours or more after instillation
into the eye(s) of experimental animals. Repeated or prolonged eye contact may cause inflammation characterised by temporary
redness (similar to windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye
Eye
damage/ulceration may occur.
Petroleum hydrocarbons may produce pain after direct contact with the eyes. Slight, but transient disturbances of the corneal
epithelium may also result. The aromatic fraction may produce irritation and lachrymation.
On the basis of epidemiological data, it has been concluded that prolonged inhalation of the material, in an occupational setting,
may produce cancer in humans.
On the basis of epidemiological data, the material is regarded as carcinogenic to humans. There is sufficient data to establish a
causal association between human exposure to the material and the development of cancer.
Principal route of exposure is by skin contact; lesser exposures include inhalation of fumes from hot oils, oil mists or droplets.
Prolonged contact with mineral oils carries with it the risk of skin conditions such as oil folliculitis, eczematous dermatitis,
pigmentation of the face (melanosis) and warts on the sole of the foot (plantar warts). With highly refined mineral oils no
appreciable systemic effects appear to result through skin absorption.
Chronic Repeated or prolonged exposure to mixed hydrocarbons may produce narcosis with dizziness, weakness, irritability,
concentration and/or memory loss, tremor in the fingers and tongue, vertigo, olfactory disorders, constriction of visual field,
paraesthesias of the extremities, weight loss and anaemia and degenerative changes in the liver and kidney. Chronic exposure
by petroleum workers, to the lighter hydrocarbons, has been associated with visual disturbances, damage to the central nervous
system, peripheral neuropathies (including numbness and paraesthesias), psychological and neurophysiological deficits, bone
marrow toxicities (including hypoplasia possibly due to benzene) and hepatic and renal involvement. Chronic dermal exposure to
petroleum hydrocarbons may result in defatting which produces localised dermatoses.
Repeated application of mildly hydrotreated oils (principally paraffinic), to mouse skin, induced skin tumours; no tumours were
induced with severely hydrotreated oils.
TOXICITY IRRITATION
VACUUM PUMP OIL
TOXICITY IRRITATION
[2]
Dermal (rabbit) LD50: >2000 mg/kg Eye: no adverse effect observed (not irritating)[1]
hydrotreated (mild) Inhalation (Rat) LC50: 2.18 mg/l4h[2] Skin: no adverse effect observed (not irritating)[1]
TOXICITY IRRITATION
Dermal (rabbit) LD50: >2000 mg/kg[2] Eye: no adverse effect observed (not irritating)[1]
hydrotreated (mild) Inhalation (Rat) LC50: 2.18 mg/l4h[2] Skin: no adverse effect observed (not irritating)[1]
Continued...
VACUUM PUMP OIL
Studies indicate that normal, branched and cyclic paraffins are absorbed from the mammalian gastrointestinal tract and that the
absorption of n-paraffins is inversely proportional to the carbon chain length,with little absorption above C30. With respect to the
carbon chain lengths likely to be present in mineral oil, n-paraffins may be absorbed to a greater extent that iso- or cyclo-
VACUUM PUMP OIL
paraffins.
The major classes of hydrocarbons have been shown to be well absorbed by the gastrointestinal tract in various species. In
many cases, the hydrophobic hydrocarbons are ingested in association with dietary lipids.
PARAFFINIC DISTILLATE,
LIGHT, HYDROTREATED *Q8 MSDS
(MILD)
The materials included in the Lubricating Base Oils category are related from both process and physical-chemical perspectives;
The potential toxicity of a specific distillate base oil is inversely related to the severity or extent of processing the oil has
undergone, since:
· The adverse effects of these materials are associated with undesirable components, and
· The levels of the undesirable components are inversely related to the degree of processing;
· Distillate base oils receiving the same degree or extent of processing will have similar toxicities;
· The potential toxicity of residual base oils is independent of the degree of processing the oil receives.
· The reproductive and developmental toxicity of the distillate base oils is inversely related to the degree of processing.
The degree of refining influences the carcinogenic potential of the oils. Whereas mild acid / earth refining processes are
VACUUM PUMP OIL &
inadequate to substantially reduce the carcinogenic potential of lubricant base oils, hydrotreatment and / or solvent extraction
methods can yield oils with no carcinogenic potential.
HEAVY, HYDROTREATED
Unrefined and mildly refined distillate base oils contain the highest levels of undesirable components, have the largest variation
(MILD) & PARAFFINIC
of hydrocarbon molecules and have shown the highest potential carcinogenic and mutagenic activities. Highly and severely
DISTILLATE, LIGHT,
refined distillate base oils are produced from unrefined and mildly refined oils by removing or transforming undesirable
HYDROTREATED (MILD)
components.
for Unrefined and Mildly Refined Distillate Base Oils
Acute toxicity: LD50s of >5000 mg/kg (bw) and >2g/kg (bw) for the oral and dermal routes of exposure, respectively, have been
observed in rats dosed with an unrefined light paraffinic distillate The same material was also reported to be “moderately
irritating” to the skin of rabbits. When tested for eye irritation in rabbits, the material produced Draize scores of 3.0 and 4.0
(unwashed/washed eyes) at 24 hours, with the scores returning to zero by 48 hours. The material was reported to be “not
sensitising” when tested in guinea pigs
Repeat dose toxicity: 200, 1000 and 2000 mg/kg (bw)/day of an unrefined base oil has been applied undiluted to the skin of
male and female rabbit..
HEAVY, HYDROTREATED
(MILD) & PARAFFINIC
WARNING: This substance has been classified by the IARC as Group 1: CARCINOGENIC TO HUMANS.
DISTILLATE, LIGHT,
HYDROTREATED (MILD)

Serious Eye
Damage/Irritation
Respiratory or Skin
sensitisation


See Section 11.1
12.1. Toxicity

VACUUM PUMP OIL Not Not Not

hydrotreated (mild)
Continued...
VACUUM PUMP OIL
NOEC(ECx) 504h Crustacea >1mg/l 1

NOEC(ECx) 504h Crustacea >1mg/l 1
hydrotreated (mild)
When spilled this product may act as a typical oil, causing a film, sheen, emulsion or sludge at or beneath the surface of the body of water. The oil film on water
surface may physically affect the aquatic organisms, due to the interruption of the
oxygen transfer between the air and the water
Oils of any kind can cause:
drowning of water-fowl due to lack of buoyancy, loss of insulating capacity of feathers, starvation and vulnerability to predators due to lack of mobility
lethal effects on fish by coating gill surfaces, preventing respiration
asphyxiation of benthic life forms when floating masses become engaged with surface debris and settle on the bottom and
adverse aesthetic effects of fouled shoreline and beaches
In case of accidental releases on the soil, a fine film is formed on the soil, which prevents the plant respiration process and the soil particle saturation. It may
cause deep water infestation.
For petroleum distillates:
Environmental fate:
When petroleum substances are released into the environment, four major fate processes will take place: dissolution in water, volatilization, biodegradation and
adsorption. These processes will cause changes in the composition of these UVCB substances. In the case of spills on land or water surfaces, photodegradation-
another fate process-can also be significant.
Drinking Water Standards: hydrocarbon total: 10 ug/l (UK max.).
For hydrocarbons:
Environmental fate:
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of waters after release in calm sea conditions. This is expected to
evaporate and enter the atmosphere where it will be degraded through reaction with hydroxy radicals.
Some hydrocarbon will become associated with benthic sediments, and it is likely to be spread over a fairly wide area of sea floor.



Ingredient Mobility

P B T
PBT
vPvB
vPvB No


One or more ingredients within this SDS has the potential of causing ozone depletion and/or photochemical ozone creation.
Continued...
VACUUM PUMP OIL

Containers may still present a chemical hazard/ danger when empty.
Return to supplier for reuse/ recycling if possible.
Otherwise:
Product / Packaging
disposal
Labels Required
Marine Pollutant NO

Not Applicable
number

Not Applicable
name

14.5. Environmental
Not Applicable
hazard


Not Applicable
name

class(es)
14.5. Environmental
Not Applicable
hazard

for user
Continued...
VACUUM PUMP OIL

Not Applicable
name


for user

Not Applicable
name

class(es)
14.5. Environmental
Not Applicable
hazard

for user
Not Applicable
Product name Group

Not Available
hydrotreated (mild)

Not Available
hydrotreated (mild)


Not Available
hydrotreated (mild)
Not Available
hydrotreated (mild)
paraffinic distillate, heavy, hydrotreated (mild) is found on the following regulatory lists

EU REACH Regulation (EC) No 1907/2006 - Annex XVII (Appendix 2) Carcinogens: Category 1 B
Continued...
VACUUM PUMP OIL
Europe EC Inventory
(Norwegian)
paraffinic distillate, light, hydrotreated (mild) is found on the following regulatory lists

EU REACH Regulation (EC) No 1907/2006 - Annex XVII (Appendix 2) Carcinogens: Category 1 B
Europe EC Inventory
(Norwegian)

Not Applicable




Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL No (paraffinic distillate, heavy, hydrotreated (mild); paraffinic distillate, light, hydrotreated (mild))
China - IECSC Yes

Yes
NLP
Japan - ENCS Yes
Korea - KECI Yes

USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ No (paraffinic distillate, light, hydrotreated (mild))
Vietnam - NCI Yes
Russia - FBEPH Yes

registration.

CONTACT POINT
Continued...
VACUUM PUMP OIL
SDS Version Summary

Date of
Update
Toxicological information - Chronic Health, Hazards identification - Classification, Disposal considerations -

1.2 09/04/2021 Disposal, Exposure controls / personal protection - Engineering Control, Exposure controls / personal protection
- Personal Protection (other), Accidental release measures - Spills (major)
Other information
Continued...
VACUUM PUMP OIL
end of SDS

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UNICOOL R-449A

Wilhelmsen Ships Service AS

SECTION 1 Identification of the substance / mixture and of the company / undertaking

1.1. Product Identifier

Synonyms 905744; 905748; R-449A

Chemical formula Not Applicable

1.3. Details of the manufacturer or supplier of the safety data sheet

--------Use our Outback portal to obtain our

Telephone +47 67 58 40 00 Not Available +31 10 4877 777

1.4. Emergency telephone number

Association / Organisation CHEMWATCH EMERGENCY RESPONSE (24/7)

SECTION 2 Hazards identification

2.1. Classification of the substance or mixture

2.2. Label elements

Signal word Warning

CLP classification (additional)

Precautionary statement(s) Prevention

Precautionary statement(s) Response

Precautionary statement(s) Storage

Precautionary statement(s) Disposal

Material does not contain any CLP Article 18 substances.

2.3. Other hazards

Cumulative effects may result following exposure*.

May produce discomfort of the respiratory system*.

Limited evidence of a carcinogenic effect*.

Repeated exposure potentially causes skin dryness and cracking*.

Vapours potentially cause drowsiness and dizziness*.

SECTION 3 Composition / information on ingredients

SECTION 4 First aid measures

4.1. Description of first aid measures

Skin Contact If skin contact occurs:

SECTION 5 Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substrate or mixture

5.3. Advice for firefighters

Containers may explode when heated - Ruptured cylinders may rocket

SECTION 6 Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7 Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

X — Must not be stored together

7.3. Specific end use(s)

SECTION 8 Exposure controls / personal protection

8.1. Control parameters

0.1 mg/L (Water (Fresh))

0.1 mg/L (Water (Fresh))

0.1 mg/L (Water (Fresh))

0.142 mg/L (Water (Fresh))

* Values for General Population

Occupational Exposure Limits (OEL)

Source Ingredient Material name TWA STEL Peak Notes

Ingredient TEEL-1 TEEL-2 TEEL-3

1,1,1,2-tetrafluoroethane Not Available Not Available Not Available

2,3,3,3-tetrafluoropropene 2,200 ppm Not Available 1.40E+05 ppm

Ingredient Original IDLH Revised IDLH