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8-JEEM-2023-JAN-30-SECOND-SHIFT-PAPER
8-JEEM-2023-JAN-30-SECOND-SHIFT-PAPER
8-JEEM-2023-JAN-30-SECOND-SHIFT-PAPER
Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
Important Instructions:
1. The test is of 3 hours duration.
2. This test paper consists of 90 questions. Each subject (PCM) has 30 questions. The
maximum marks are 300.
3. This question paper contains Three Parts. Part-A is Physics, Part-B is Chemistry and
Part-C is Mathematics. Each part has only two sections: Section-A and Section-B.
4. Section – A : Attempt all questions.
6. Section-A (01 – 20) contains 20 multiple choice questions which have only one correct
answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
7. Section-B (1 – 10) contains 10 Numerical based questions. The answer to each question
is rounded off to the nearest integer value. Each question carries +4 marks for correct
answer and –1 mark for wrong answer.
Telegram - https://t.me/pwjeewallah
JEE-MAIN-2023 (30th January-Second Shift)-PCM-2
PART – A (PHYSICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. A vehicle travels 4km with speed of 3km/h and another 4km with speed of 5km/h, then its
average speed is
(A) 3.50 km/h (B) 3.75 km/h
(C) 4.25 km/h (D) 4.00 km/h
Q2. A thin prism P1 with an angle 6 and made of glass of refractive index 1.54 is combined with
another prism P2 made from glass of refractive index 1.72 to produce dispersion without average
deviation. The angle of prism P2 is
(A) 1.3 (B) 4.5
(C) 6 (D) 7.8
Q3. An electron accelerated through a potential difference V1 has a de-Broglie wavelength of . When
V
the potential is changed to V2 , its de-Broglie wavelength increases by 50% . The value of 1 is
V2
equal to
3
(A) 4 (B)
2
9
(C) (D) 3
4
Q4. Match List I with List II:
List-I List-II
A. Attenuation I. Combination of a receiver and transmitter.
B. Transducer II. Process of retrieval of information from the carrier wave at receiver
C. Demodulation III. Converts one form of energy into another
D. Repeater IV. Loss of strength of a signal while propogating through a medium.
Q7. A point source of 100W emits light with 5% efficiency. At a distance of 5m from the source, the
intensity produced by the electric field component is :
1 W 1 W
(A) (B)
10 m2 20 m2
1 W 1 W
(C) (D)
2 m 2 40 m2
Q8. A force is applied to a steel wire ‘A’, rigidly clamped at one end. As a result elongation in the wire
is 0.2mm. If same force is applied to another steel wire ‘B’ of double the length and a diameter
2.4 times that of the wire ‘A’, the elongation in the wire ‘B’ will be (wires having uniform circular
cross sections)
(A) 6.06 102 mm (B) 3.0 102 mm
(C) 6.9 10 2 mm (D) 2.77 102 mm
(A) (B)
A B Y A B Y
0 0 0 0 0 0
0 1 1 0 1 1
1 0 1 1 0 1
1 1 1 1 1 0
(C) (D)
A B Y A B Y
0 0 1 0 0 1
0 1 1 0 1 0
1 0 1 1 0 0
1 1 0 1 1 1
Q10. A flask contains hydrogen and oxygen in the ratio of 2 : 1 by mass at temperature 27 C. The ratio
of average kinetic energy per molecule of hydrogen and oxygen
respectively is :
(A) 4 : 1 (B) 1 : 4
(C) 2 : 1 (D) 1 : 1
JEE-MAIN-2023 (30th January-Second Shift)-PCM-4
Q15. In the given circuit, rms value of current (Irms) through the XL 200 XC 100
resistor R is :
R 100
1
(A) A (B) 2A
2
(C) 2 2 A (D) 20A
Vrms 100 2 V
Q16. A machine gun of mass 10kg fires 20g bullets at the rate of 180 bullets per minute with a speed of
100 ms-1 each. The recoil velocity of gun is
(A) 1.5 m/s (B) 0.6 m/s
(C) 2.5 m/s (D) 0.02 m/s
JEE-MAIN-2023 (30th January-Second Shift)-PCM-5
Q17. An object is allowed to fall from a height R above the earth, where R is the radius of earth. Its
velocity when it strikes the earth’s surface, ignoring air resistance, will be
(A) 2 gR (B) gR
gR
(C) (D) 2 gR
2
3 kg
Q19. Given below two statements : one is labeled as Assertion A and the other is labeled as Reason
R
Assertion A : The nuclear density of nuclides 10 6 56 20 209
5 B, 3 Li, 26Fe, 10 Ne and 83 Bi can be arranged
In the light of the above statements, choose the correct answer from the options given below
(A) A is true but R is false
(B) Both A and R are true but R is NOT the correct explanation of A
(C) Both A and R are true and R is the correct explanation of A
(D) A is false but R is true
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
Q1. In a Young’s double slit experiment, the intensities at two points, for the path differences and
4
( being the wavelength of light used) are I1 and I2 respectively. If I0 denotes the intensity
3
I I
produced by each one of the individual slits, then 1 2 ________.
I0
Q2. A body of mass 2kg initially at rest. It starts moving unidirectionally under the influence of a
1
source of constant power P. Its displacement in 4s is 2 P m. The value of will be_____.
3
Q3. A stone tied to 180cm long string at its end is making 28 revolutions in horizontal circle in every
1936
minute. The magnitude of acceleration of stone is ms2 . The value of x_______.
x
22
(Take )
7
Q4. In an ac generator, a rectangular coil of 100 turns each having area 14 102 m2 is rotated at 360
rev/min about an axis perpendicular to a uniform magnetic field of magnitude 3.0 T. The
maximum value of the emf produced will be _________V.
22
(Take )
7
x
JEE-MAIN-2023 (30th January-Second Shift)-PCM-7
1
x
2
D
Q8. A faulty thermometer reads 5 C in melting ice and 95 C in steam. The correct temperature on
absolute scale will be ______K when the faulty thermometer reads 41 C.
Q9. The velocity of a particle executing SHM varies with displacement (x) as 42 50 x 2 . The time
x
period of oscillations is s. The value of x is _________.
7
22
(Take )
7
Q10. A radioactive nucleus decays by two different process. The half life of the first process is 5
minutes and that of the second is 30s. The effective half-life of the nucleus is calculated to be
s. The value of is __________.
11
JEE-MAIN-2023 (30th January-Second Shift)-PCM-8
PART – B (CHEMISTRY)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q2. The water quality of a pond was analysed and its BOD was found to be 4. The pond has
(A) Highly polluted water
(B) Slightly polluted water
(C) Very clean water
(D) Water has high amount of fluoride compounds
Q4. Boric acid is solid, whereas BF3 is gas at room temperature because of
(A) Strong ionic bond in Boric acid
(B) Strong covalent bond in BF3
(C) Strong van der Waal’s interaction in Boric acid
(D) Strong hydrogen bond in Boric acid
Q7. Given below are two statements: One is labelled as Assertion A and the other is labelled as
Reason R.
Assertion A: Antihistamines do not affect the secretion of acid in stomach.
Reason R: Antiallergic and antacid drugs work on different receptors.
In the light of the above statements, choose the correct answer from the options given below:
JEE-MAIN-2023 (30th January-Second Shift)-PCM-9
Q8. The correct order of pKa values for the following compounds is:
OH OH OH OH
N NO 2
a b c d
(A) b > d >a >c (B) c > a > d > b
(C) b > a >d > c (D) a > b > c > d
Br Br
NO 2
(X) (Y)
In the above conversion of compound (X) to product (Y), the sequence of reagents to be used
will be:
(A) Br2(aq) (ii) LiAIH4 (iii) H3O+ (B) Br2,Fe (ii) Fe, H+ (iii) LiAlH4
+
(C) Fe, H (ii) Br2(aq) (iii) HNO2 (iv) H3PO2 (D) Fe, H+ (ii) Br2(aq) (iii) HNO2 (iv) CuBr
JEE-MAIN-2023 (30th January-Second Shift)-PCM-10
Q12. Given below are two statements: One is labelled as Assertion A and the other is labelled as
Reason R.
O
In the light of the above statements, choose the correct answer from the options given below:
(A) Both A and R are true but R is not the correct explanation of A
(B) A is true but R is false
(C) A is false but R is true
(D) Both A and R are true and R is the correct explanation of A
Q13. Bond dissociation energy of “E-H” bond of the “H2E” hydrides of group 16 elements (given below),
follows order.
A. O
B. S
C. Se
D. Te
Choose the correct from the options given below :
(A) A > B >D > C (B) A > B > C > D
(C) D > C > B > A (D) B > A > C > D
Q15. Maximum number of electrons that can be accommodated in shell with n= 4 are:
(A) 16 (B) 72
(C) 32 (D) 50
Q16. KMnO4 oxidises I in acidic and neutral / faintly alkaline solution respectively, to
(A) IO3 & I2 (B) IO3 & IO3
(C) I2 & IO3 (D) I2 &I2
JEE-MAIN-2023 (30th January-Second Shift)-PCM-11
Q17. Decreasing order towards SN1 reaction for the following compounds is:
Cl Cl Cl Cl
NO 2 OMe Cl
a b c d
(A) a > c > d >b (B) b > d > c > a
(C) a > b > c > d (D) d > b > c > a
a b c d
(A) b (B) a
(C) c (D) d
Q20. 1 L, 0.02 M solution of [Co(NH3)5SO4] Br is mixed with 1L, 0.02 M solution of [Co(NH3)5Br]SO4.
The resulting solution is divided into two equal parts (X) and treated with excess of AgNO3
solution and BaCl2 solution respectively as shown below:
1L Solution (X) + AgNO3 solution (excess) Y
1L Solution (X) + BaCl2 solution (excess) Z
The number of moles of Y and Z respectively are
(A) 0.02, 0.01 (B) 0.01, 0.02
(C) 0.01, 0.01 (D) 0.02, 0.02
JEE-MAIN-2023 (30th January-Second Shift)-PCM-12
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
x
Q1. The graph of log vs log p for an adsorption process is a straight line inclined at an angle of 45o
m
with intercept equal to 0.6020. The mass of gas adsorbed per unit mass of adsorbent at the
pressure of 0.4 atm is _______ 101(Nearest integer)
Given: log 2 = 0.3010
Q2. Lead storage battery contains 38% by weight solution of H2SO4. The van’t Hoff factor is 2.67 at
this concentration. The temperature in Kelvin at which the solution in the battery will freezes is
__________(Nearest integer)
Given Kf = 1.8 K kg mol1.
Q3. An organic compound undergoes first order decomposition. If the time taken for the 60%
decomposition is 540s, then the time required for 90% decomposition will be is ________s.
(Nearest integer)
Given: ln 10 = 2.3; log 2 =0.3
Q4. Iron oxide FeO, crystallises in a cubic lattice with a unit cell edge length of 5.0 A . If density of the
FeO in the crystal is 4.0 g cm 3, then the number of FeO units present per unit cell
is______________. (Nearest integer)
Given: Molar mass of Fe and O is 56 and 16g mol1 respectively.
NA = 6.01023 mol1.
Q6. A short peptide on complete hydrolysis produces 3 moles of glycine (G), two moles of leucine (L)
and two moles of valine (V) per mole of peptide. The number of peptide linkages in it are
____________.
E0Y2 |Y 0.36V
2.303RT
0.06V
F
Q9. 1 mole of ideal gas is allowed to expand reversibly and adiabatically from a temperature of 27°C.
The work done is 3 kJ mol1. The final temperature of the gas is _______ K (Nearest integer).
Given CV = 20 J mol1 K1.
Q10. Number of compounds from the following which will not dissolve in cold NaHCO3 and NaOH
solutions but will dissolve in hot NaOH solution is_______.
O O
O H OH
OH O
, , O ,
O O
OH
O
, ,
O
H O H3C CH3
JEE-MAIN-2023 (30th January-Second Shift)-PCM-14
PART – C (MATHEMATICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
dy x 2 3y2
Q3. The solution of the differential equation 2 2 , y 1 0 is
dx 3x y
2xy 2xy
(A) loge x y 2
0 (B) loge x y 2
0
x y x y
xy xy
(C) loge x y 2
0 (D) loge x y 2
0
x y x y
Q4. Let R, a ˆi 2jˆ 3k,
ˆ b ˆi ˆj 2kˆ .
2
If a b a b a b 8iˆ 40ˆj 24kˆ , then a b a b is equal to
(A) 136 (B) 132
(C) 140 (D) 144
Q5. If a plane passes through the points 1, k, 0 , 2,k, 1, 1,1,2 and is parallel to the line
2
x 1 2y 1 z 1 k 1
, then the value of is
1 2 1 k 1k 2
6 13
(A) (B)
13 6
5 17
(C) (D)
17 5
JEE-MAIN-2023 (30th January-Second Shift)-PCM-15
2 2 2
3 1 2 1
Q6. lim 4 2 2 ... 3 is equal to
n n n n n
19
(A) (B) 12
3
(C) 0 (D) 19
(A) a b 2c 1 (B) 2a b c 1
(C) a 2b c 1 (D) 2a b c 1
x3 ax 2 x3
Q9. If the functions f x 2bx and g x ax bx 2 ,a 2b have a common extreme
3 2 3
point, then a 2b 7 is equal to :
(A) 3 (B) 6
3
(C) (D) 4
2
Q10. Let q be the maximum integral value of p in 0, 10 for which the roots of the equation
5
2
x 2 px p 0 are rational. Then the area of the region x, y : 0 y x q ,0 x q is
4
125
(A) 164 (B)
3
(C) 243 (D) 25
Q11. Let A be a point on the x-axis. Common tangents are drawn from A to the curves x 2 y 2 8 and
2
y 2 16x . If one of these tangents touches the two curves at Q and R, then QR is equal to
(A) 76 (B) 81
(C) 72 (D) 64
Q12. The number of ways of selecting two numbers a and b, a 2,4,6,....,100 and
b 1,3,5,....,99 such that 2 is the remainder when a b is divided by 23 is
(A) 268 (B) 108
(C) 54 (D) 186
JEE-MAIN-2023 (30th January-Second Shift)-PCM-16
13 9
Q14.
Let x 8 3 13
and y 7 2 9 . If t denotes the greatest integer t , then
(A) x is even but y is odd (B) x is odd but y is even
(C) x and y are both odd (D) x y is even
Q15. Let S be the set of all values of a1 for which the mean deviation about the mean of 100
consecutive positive integers a1, a 2 , a3 ,....,a100 is 25. Then S is
(A) 99 (B) 9
(C) N (D)
Q20. Let a,b,c 1, a3 , b3 and c 3 be in A.P., and loga b, logc a and logb c be in G.P. If the sum of first 20
a 4b c a 8b c
terms of an A.P., whose first term is and the common difference is is 444 ,
3 10
then abc is equal to:
(A) 343 (B) 216
125 343
(C) (D)
8 8
JEE-MAIN-2023 (30th January-Second Shift)-PCM-18
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
Q1. If the value of real number a > 0 for which x 2 5ax 1 0 and x 2 ax 5 0 have a common
3
real root is then is equal to……
2
Q2. The number of seven digits odd numbers, that can be formed using all the seven digits 1, 2, 2, 2,
3, 3, 5 is…………
to…….
Q4. A bag contains six balls of different colours. Two balls are drawn in succession with replacement.
The probability that both the balls are of the same colour is p. Next four balls are drawn in
succession with replacement and the probability that exactly three balls are of the same colour is
q. If p : q m : n , where m and n are coprime, then m n is equal to……..
1
Q5. If sec 2x 1 dx loge cos2x cos 2x 1 cos x constant, then is equal
to……..
Q6. Let a line L pass through the point P 2,3,1 and be parallel to the line
x 3y 2z 2 0 x y 2z . If the distance of L from the point 5,3,8 is , then 3 is equal 2
to……..
Q7. Let A 1, 2, 3, 5, 8, 9 . Then the number of possible functions f : A A such that
f m n f m f n for every m,n A with m n A is equal to………….
Q8. 50th root of a number x is 12 and 50th root of another number y is 18. Then the remainder
obtained on dividing x y by 25 is……..
Q9. Let P a1,b1 and Q a2 ,b2 be two distinct points on a circle with center C
2, 3 . Let O be the
35
origin and OC be perpendicular to both CP and CQ. If the area of the triangle OCP is , then
2
a12 a22 b12 b22 is equal to……….
th
Q10. The 8 common term of the series
S1 3 7 11 15 19 .....,
S2 1 6 11 16 21 ....
is…………
JEE-MAIN-2023 (30th January-Second Shift)-PCM-19
1. B 2. B 3. C 4. A
5. A 6. A 7. D 8. C
9. B 10. D 11. A 12. A
13. C 14. C 15. B 16. B
17. B 18. C 19. D 20. C
SECTION – B
1. 3 2. 4 3. 125 4. 1584
5. 54 6. 12 7. 2 8. 313
9. 88 10. 300
PART – B (CHEMISTRY)
SECTION - A
1. B 2. C 3. D 4. D
5. A 6. A 7. D 8. A
9. C 10. B 11. C 12. C
13. B 14. D 15. C 16. C
17. B 18 C 19. A 20. C
SECTION - B
1. 16 2. 243 3. 1350 4. 4
5. 150 6. 6 7. 3 8. 275
9. 150 10. 3
JEE-MAIN-2023 (30th January-Second Shift)-PCM-20
PART – C (MATHEMATICS)
SECTION - A
1. D 2. A 3. B 4. C
5. B 6. D 7. BD 8. C
9. B 10. C 11. C 12. B
13. C 14. D 15. C 16. D
17. D 18 A 19. B 20. B
SECTION - B
1. 13 2. 240 3. 25 4. 14
5. 1 6. 158 7. 432 8. 23
9. 24 10. 151
JEE-MAIN-2023 (30th January-Second Shift)-PCM-21
I
Sol6. B at centroid 0 sin 1 sin 2 3
4 d
1 2 60 4cm
d 2cm 4 3
c
B
4 10 2
7
3 3
2cm
3
4 2 10 2 2 2
3 3 105 T 2 3
Power P
Sol7. Intensity (I)
Area A
I
100W 0.05 1 W / m2
2 20
4 5 m2
3
Sol10. Average kinetic energy is equal to kT
2
or, KE T
KE H2 1
So or 1: 1
KE O2
1
Sol11. Torque F r kg m2 / s2
Energy kgm2 / s2
Energy density 3
kgm1s2
vol m
P ML1T 2
Pressure gradient kgm 2 s2
x L
-1
Impulse Ft kg m / s or kg m s .
2 m
Sol12. T 2 Time period of spring block system
k
JEE-MAIN-2023 (30th January-Second Shift)-PCM-23
k
m
1
or
m
2kg 2
2
1 1kg 1
Sol13. Both Reason & assertion are two & reason is the correct explanation of assertion.
2
F I2 F 2 0 2I
Sol14. 1 FPQ 0 & 2 FPQ
2 d 2d
2
FPQ : FPQ 1: 4
Vrms Vrms
Sol15. Irms
z 2
R x C xL
2
200 2
100 2 100 2
200 2
100 2
2
Sol16. As Fext = 0
So Pnet 0
or momentum of gun = momentum of bullets
180 20
10 Vgun 100
60 1000
Vgun 0.6m / s
1 1 7 2 3 7 8 18
Sol20. 1.5 0.5
Re q 4 12 3 12 12
12 2 12
Re q
18 3 8 4 A 12/7 B
A B
2
6 8 4
C
6
2 6
1 1
A 3/2 B
8 4 1.6 2.4
A B
C
2 6
12/7 12/7
3/2 3/2
SECTION – B
Sol1. As we know that the phase difference is related to path difference x as :
kx
2
So, 1 .
4 2
2 2
& 2 .
3 3
Now resultant intensity is given as
I1 I0 I0 2 I0 I0 cos 1 2I0
& I2 I0 I0 2 I0 I0 cos 2 I0
I1 I2 2I0 I0 3
I0 I0 1
JEE-MAIN-2023 (30th January-Second Shift)-PCM-25
Sol2. P Fv ma v
P dv
v.
m dt
P
dt vdv
m
P v2 2P 1/2
t v t
m 2 m
dx
Also, v
dt
dx 2P 1/2
So,
dt
m
t
2P 1/2
dx
m t dt
2 2P 3/2
x .t
3 m
1 8 3/2 1
x P 4 .42 P
3 2 3
4
Sol6. From the diagram, we can conclude that sides of cuboid is 1m, 2m & 3m along x, y and z-axis.
As we know that
flux E A
2
x 0 0 & x 1m 2 1 . 2 3 12
y 0 0 & y 2m 4 2 1 3 24
& z 0 6 1 2 12 & z 3 6 1 2 12
Total 0 12 0 24 12 12 12
Qenclosed
Also
0
Q
12 Q 120
0
n 12
Sol7. If VB VD 0
or VB VD
Resistance is in Proportion
P R
Q S
6 3 x 1
6 3 x 1
1 2 x
2 x
3 x x 1
2x 2 2x 3x
2x 2 x 0
JEE-MAIN-2023 (30th January-Second Shift)-PCM-27
x 2x 1 0
1
x 0, x
2
1 1
Thus x n2
n 2
Sol9. 4v 2 50 x2
50 x 2
v2
4 4
50 x 2
v
4
1 2
v
2
5 2 x2
v A2 x2
1 2
, Now Time period, T
2
2
T 4
1/ 2
22 x
T 4
7 7
x 88
PART – B (CHEMISTRY)
SECTION – A
Sol1. 4LiNO3
2Li2 O 4NO2 O2
Sol3. (A) Due to large difference in B.pt of CHCl3 & C6H5NH2 these can be separated by simple
distillation.
(B) Due to very small difference in B.pt of C6H14 and C5H12 these can be separated by
fractional distillation.
(C) Mixture of aniline and water can be separated by steam distillation because aniline is
steam volatile and it is insoluble in water.
(D) Generally organic compounds are water insoluble so these can be separated by using
differential extraction technique.
Sol4. In Boric acid strong H-bonding are present therefore it exist as solid.
Sol5. At node 2s 0
r0
2 0
a0
r0 2a0
Sol6.
Cl
H3N Cl
Co
H3N Cl
NH3
Cl Co Cl Bond angle = 90o
Sol7. Antihistamines do not affect the secretion of acid in stomach because antiallergic and aniacid
drugs work on different receptors.
Sol8.
OH OH OH
OH
(a)
N NO 2
- M effect + H effect
+ M effect
(b) (c) (d)
JEE-MAIN-2023 (30th January-Second Shift)-PCM-29
Sol9. In electrolytic refining, the pure metal is used as cathode and impure metal is used as anode.
Na3AlF6 is added during electrolysis of Al2O3 to lower the melting point and increase conductivity.
Sol11.
CH3 CH3
CH3 CH3 CH3
H3PO2
Br2 HNO2
Fe
H+ aq. Br Br
Br Br Br Br
NH2 NH2 N2
NO2
Sol12.
O
Zn - Hg
HCl
HO Cl
If acid sensitive group is present then side reaction can also occurs.
Sol13.
H O H S H Se H Te
Sol14.
2+ 2+ 2+
[Ni(CO)4] [Cu(NH3)4] [Fe(NH3)6] [Fe(H2O)6]
3 2 3 2 2 3
Hybridisation Sp dsp Sp d d sp
NO 2 OMe Cl
-M +M -I
Stability of C b > d > c > a
Sol18.
NH2 NH2
SECTION – B
x 1
Sol1. log logp logk
m n
1
tan 45o 1 log
x 1
n
m n
logk 0.6020 k 4
x 1
log log k.p n log K
m
1
x x 1
kp n 4 0.4
m m log p
x
1.6 16 101
m
Sol2. Tf iK f m
i 2.67
k f 1.8K kgmol1
moles of solute 38 1000
m
mass of solvent 98 62
2.67 1.8 38 1000
Tf
98 62
JEE-MAIN-2023 (30th January-Second Shift)-PCM-31
Tf 30.05o C
So, freezing point of solution = 27330=243K
1 A 0 10
n n
t1 k 0.4 A 0 540 4
t2 1 A 0 t2 n10
n
k 0.1 A 0
540 n10 n 4
t 2 1350 sec
t2 n4
ZM Z 72
Sol4. d 3
4
NA a 6.0 10 125 10 24
23
Z 4.166 4
Sol7. 2SO2(g) O 2(g) 2SO3(g) ; H 190kJ the yield of SO3 can be increases by
(B) Increasing pressure
(C) Adding more SO2
(D) Adding more O2
Sol10. Ester will not dissolve in cold NaHCO3 and NaOH solution but dissolve in hot NaOH solution.
JEE-MAIN-2023 (30th January-Second Shift)-PCM-32
PART – C (MATHEMATICS)
SECTION – A
Sol1. LHL RHL
lim g h x 1
x 1
lim g h x 1
x 1
lim g 2 x 1
x 1
lim g 2 x 1
x 1
x 1 x 1 x 1 x 1
lim g 2 1 lim g 0 1
x 1 x 1
1 1
Sol2.
c 2a b 3b
take dot product with b
c b 0 3 bb
2
3 b 48
dy xdv
Sol3. y vx , homogeneous equation v
dx dx
dx 3 v
2
dv
3
x v 1
dx dv v 2 dv
x 3 v 13 v 13 c
3dv dv dv dv
nx 3
2 2
3
c
v 1 v 1 v 1 v 1
dv dv dv
nx 4 3
2 2
c
v 1 v 1 v 1
4 2
nx n v 1 c
2 v 1
2
v 1
y 2x 2x 2
nx n 1 2
c
x x y x y
2x x y 2x 2
n x y 2
c
x y
2xy
n x y 2
x y c
y 1 0 c 0
2xy
n x y 2
x y
JEE-MAIN-2023 (30th January-Second Shift)-PCM-33
Sol4.
Use a b c a c b a b c
a b a b a b a b
a b a b a b a b a b
2 2
8iˆ 40ˆj 24kˆ a b a b 0
8 i 5 j 3k 4 9 1 4 a b
ˆ ˆ ˆ 2 2
ˆi 5ˆj 3kˆ a b ˆi 4 3 ˆj 2 3 kˆ 2 2
1
a b 2iˆ ˆj kˆ
a b 3ˆj 5kˆ
2 2
a b a b aa ab ba bb
2
4 a b
4 1 25 9 140
x 1 y 1/ 2 z 1
Sol5. line
1 1 1
Let A 1, k, 0 , B 2, k, 1, C 1, 1, 2
CA 2iˆ k 1 ˆj 2kˆ
CB ˆi k 1 ˆj 3kˆ
1 1 1
line normal 2 k 1 2 0
1 k 1 3
k 5
2
3 n 1 r
Sol6. lim 2 convert to continuous integral
n n n
r 0
1
2
3 2 x dx
0
1
3
2 x
3
3
0
33 23 19
1
Sol7. t r tan1
1 ar ar 1
a ar
tan1 r 1
1 ar ar 1
tan1 ar 1 tan1 ar
Put r 1, 2,.....2021
JEE-MAIN-2023 (30th January-Second Shift)-PCM-34
Sol8.
Direction cosine of vectors cos600 , cos 450 , cos
cos2 cos2 cos2 1
1 1
cos2 1
4 2
1 1
cos2 cos as is acute.
4 2
1 1 1
Equation of plane
2
x 2
2
y 1 z 1 0
2
x 2 2y 2 z 1 0
x 2y z 1
a,b,c lies in it a 2b c 1
5
Sol10. D P2 4 P
4
P 2 5P
P P 5
P 0, 10 , for D to perfect square P can be 0, 9
So, q = 9
9
2
now required area = x 9
0
dx 243
4 R
Sol11. y mx is tangent to x 2 y 2 8 Q
m
4
m
2 2
2
m2 1 m 2 2
1 m
m 1
y x4
JEE-MAIN-2023 (30th January-Second Shift)-PCM-35
13
Sol14. Let x 8 3 13 I f
where I x
0 f 1
13
Let f ' 8 3 13
It will be a fraction
13 13
now I f f ' 8 3 13 8 3 13
I f f ' 2 Natural number
f f ' must be an integer
So, f f ' 0
So, I 2 (Natural number)
Similarly y is an even number
So x y is an even number
Sol16. ax 2 2bx cy 0
y 1, b2 ac
ax2 2 acx c 0
2 c
ax c 0x
a
2
Now, dx 2ex fy 0
c
x ,y 1
a
dc c
2e f 0
a a
d c 2 e ca fa 0
dc 2eb af 0
dc af 2eb
d f 2eb
a c ac
d f 2e d e f
, , AP
a c b a b c
Sol17. PT P 1 I
P P T 1 I
P P 1 I 1 I
1 2
P I 0
P I
n1
use adj A A
Sol19. P Q R
Use p q p q
JEE-MAIN-2023 (30th January-Second Shift)-PCM-37
So, P Q R P Q P R
2
loga logb logc
Sol20. 2b3 a3 c 3 ;
logc loga logb
3 3
logc loga
ca
2b3 2a3
abc
a 4b c
T1 2a ;
3
a 8b c 3a
Common difference =
10 5
20 3a
Sum 444 2 2a 19
2 5
a6
SECTION – B
Sol1. Let common root be ' '
2 1 13a 3
26a 6 4a 13 2a
2 9 9 9
a
2 13 2 2 13
13
6!
Sol2. Pattern .....................1 ways
2!3!
6!
.....................3 ways
3!
6!
.....................5 ways
3!2!
6!
total = 2 240
3!
Sol3. Plot y x2
2
y 1 x
1 1
y 2x x 1 2,4
required region is
1
2
2 2x 2x 2 x 2 dx
0
1
2 x 2 x 3 2
0
1
A 540A 135
4
JEE-MAIN-2023 (30th January-Second Shift)-PCM-38
1 1 1
Sol4. p 6 C1
6 6 6
1 1 1 1
q 6 C2 2! 4
6 6 6 6
4! 1
here pattern is aaab select 6 C2 2! arrange 4 each balls have probability .
3! 6
p 1/ 6 6 6 6 6
q 65 4
p 9
m n 14
q 5
1 cos 2x
Sol5. sec 2x 1 dx dx
cos 2x
2 sin x
dx ; put 2 cos x t ; 2 sin x dx dt
2cos2 x 1
dt
n t t 2 1 c
2
t 1
2
n 2 cos x 2 cos x 1 c
x 2 y 3 z 1
Sol6. Let line be
a b c
It will also satisfy a 3b 2c 0
a b 2c 0
a b c
1 1 1
General pt on line P 2, 3, 1
Direction ratio of PQ 3, , 7
4
PQ line 3 7 0
3
2 2
PQ 3 2 7 3 2 8 58
JEE-MAIN-2023 (30th January-Second Shift)-PCM-39
158
3
3 2 158
Sol7. f m n f m f n
Let m 1, f n f 1 f n
f n f 1 1 0
f 1 1
Let check for m n 3
2
f 9 f 3
So f 3 can be 1,3 f 9 will be decided automatically.
Now total ways = 1 6 2 6 6 1 432
35 1
Sol9. PQ will be diameter OC PC P
2 2
35 5 PC PC 7 O
OP OQ 12 C
So, a12 b12 a22 b22 12 12 24