Narayana IIT Academy 23-06-24_SR.

IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-45_KEY&SOL

Sec: SR_*CO-SC(MODEL-B) CTM-45 Date: 23-06-24

Time: 3 Hrs JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 1 2 3 3 4 4 2 5 2
6 1 7 3 8 3 9 2 10 3
11 4 12 4 13 2 14 1 15 1
16 1 17 3 18 2 19 4 20 3
21 4 22 1 23 5 24 3 25 2
26 3 27 4 28 9 29 6 30 2

CHEMISTRY
31 A 32 C 33 D 34 D 35 A
36 A 37 B 38 A 39 A 40 A
41 C 42 B 43 A 44 C 45 A
46 A 47 D 48 C 49 C 50 D
51 5 52 6 53 7 54 5 55 3
56 6 57 9 58 5 59 4 60 2

MATHEMATICS
61 A 62 B 63 D 64 A 65 A
66 A 67 B 68 A 69 A 70 C
71 C 72 A 73 C 74 C 75 C
76 A 77 C 78 A 79 B 80 C
81 7 82 9 83 4 84 309 85 3
86 1 87 4 88 2 89 0 90 5

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SOLUTIONS
PHYSICS
 1  1 
1. shift  t1 1    t2  1  
 1   2 

3
2

2

O1
 1   1
 6 1    4 1  
 3 2  2
 2  2  4cm
 New position of O  O '  14  4  18cm
2. Let there is grazing emergence of light before entering into nth layer when i  300 . Form snell’s law
0 sin i  n sin 90
 1 
0 sin 30  0 1  _______ 1
 4n  18 
1 1
 1 n5
2 4n  18
If i  300 , TIR takes place before entering into 5th layer i.e., at the upper surface of 4th layer
3. A  800   2
1 sin i1 sin 45
  C  450 from    2  r1  300
sin C sin r sin r
A  r1  r2  r2  50  r2  C
0

 At second face TIR takes place

  2  180 0  2r2  80 0
4. Here r1  0, 0  r2  A  r2  A
In PQR, 90  2r2  90    1800

2 A   ________ 1
For the section of prism, A      1800

 2  1800    720
2

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R
5. sin C 
Rd

1 R d 3 d
  1     0.5
 Rd R 2 R
6. Here the rays travel from right (0) to the left. Hence it is positive direction
u  9cm  p  0  ,V  ?, R  12cm  P  C 
As the incident and refracted rays are present in medium and air respectively, 1  1.5,  2  1 from
2 1 2  1 1 1.5 1  1.5
  ,    V  4.8cm  P  I 
V u R V  9  12
As ‘V’ is negative, the image is to the right of P i.e., in the medium and it will be virtual as the
refracted rays are in air and image is in the medium
uf
7. For lens  
u f
10  20
  20
10  20
So this position has to be centre of curvature of mirror in order for the ray to retrace its path so
d  40  20  20cm
8. Focal length is the image distance when the object is at infinity on the principal axis
4 3
At P1 ; 1  , 2  , u  ,V  ?, R   R  P1  C1 
3 2
2 1 2  1 3 2 4 3 3 2  4 3
      V  9 R  P1  I1 
V u R V  R
Real image I1 will be formed at 9R distance from P1 . This acts as vertical object to the 2nd spherical
surface. At P2 ; u  9 R  P2  I1  [Here the distance between P1 and P2 is neglected as the lens in thin]
V  ?, 1  3 2, 2  1, R   R  P2  C2 
2 1 2  1 1 3 2 1 3 2 3R
     V   P2  I 2 
V u R V R R 2
3R
Is the distance of final image and it is the focal length
2
R  1
9. For first lens, f1   P1  1
1  1 R

R    2  1
For second lens, f 2   P2 
2  1 R
  2
For system, P  P1  P2  1
R
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10. The given system is the combination of three lenses. First lens is a Plano concave lens. Its focal length
 R1 20
f1    40cm
 g  1 1.5  1

 R2 30
Third one is also Plano concave lens. Its focal length f 3    60cm . Second one is an
 g  1 1.5  1

4
asymmetric biconvex lens of water. R1  20cm, R2  30cm,  
3
1  4  1 1 
   1    f 2  36cm . If f is the focal length of the system,
f 2  3  20 30 
1 1 1 1 1 1 1 1
        f  72cm
f f1 f 2 f 3 f 40 36 60
11. When they are in contact, P  P1  P2  P1  P2  10 _____ 1
When that are at separation P  P1  P2   d  PP
1 2

PP
6  P1  P2  0.25  P1 P2   P1  P2  6 1 2
____  2 
4
On solving (1), (2) the values of P1 , P2 are 2 D,8D
1 1 1
 Focal lengths f1   m  50cm; f 2  m  12.5cm
P1 2 8
12. v  u  48cm
v v
m 3
u u
v  3u, u  12cm
v  36cm
1 1 1
 
f v u
f  9cm
13. This is the lens displacement method (conjugate foci method) to determine ‘f’ of a convex lens.

m  2    2  V  2u
V  u  1.8  2u  u  1.8  u  0.6 m V  1.8  0.6  1.2 m
From figure, d  V  u  1.2  0.6  0.6m (distance between the pieces)
L2  d 2 1.82  0.62
For length f    0.4m
4L 4  1.8

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14.

The given lens is equivalent to the combination of a plano convex lens and a plane mirror. If PL and
 1  1
PM represent their powers respectively, the power of system P  2 PL  PM  2    . If the
 fL  fM
1
system behaves as a mirror of focal length f then P  
f
1 2 1 R 
   , here f L  15cm, f M    
f fL fM 2 2
1 2 15
   0  f   cm . The given silvered lens behaves as a concave mirror of focal length
f 15 2
15
cm . Given that u  20cm for this equivalent mirror
2
1 1 1 1 1 1
       V  12cm . As V is ve , the image is formed towards left of
V u f V 20  15 
 
 2
the lens and it is real
15. As all the deviations are in same direction, (clock wise in the figure) their addition gives the net
deviation.

d  d A | d B  dC  d D   i  r   180  2r   180  2r    i  r 
 2  i  r   2 180  2r  ______ 1
sin i sin 45
  2  r  300
sin r sin r
Substituting i, r in (1) we get d  2700
Real depth 4
16. μ= 
App depth 3
4 4
-1
1 3 3
When plane surface is in contact with base=  =  R=25
25 4 -R
8
1 1 1 4  1
=  μ-1     1  f=75 cm
f R f  3  25

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17. for upper half,
R
f1 =
μ-1
lower half
R
f2 =
2  μ-1
for lower f, then for upper 2f
18. For L1 Lens, Image of L1 ,  50cm,L 2 lens will act as virtual object for L 2
virtual object due to U r  25cm=2f 2

then from
u -f
υ2 = 2 2
f 2 -u 2
if u 2  f 2 then
u2  
if L 2 moves towards L1then u 2 >f 2
 u 2 beomes -ve
so initially rays are parallel & then diverging
19. We have
r1 +r2  90....................1
r3  r4  90.................. 2 
r5 +r6  90.................... 3
and
since the emergent ray is parallel to incident ray, we have
r2  90  i.................... 4 

Writing the snell’s equations of refraction, sin i=μ rsinr1

μ1sinr2 =μ 2sinr3
μ 2sinr4  μ 2sinr5
μ 3sinr6  sinr7 and

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Using equation 1 to  4  in the above equation, we get
sin i=μ1sinr1................... 5 
μ1cosr1  μ 2sinr3 ............ 6 
μ 2cosr3  μ 3sinr5 ............ 7 
3 cos r5  cos i.............. 8
 Equation 5    Equation 7    Equation 6    Equation 8
2 2 2 2
0
 sin 2 .i+μ 2 2cos 2 r3 -μ12cos 2 r 1 -μ 52 cos 2 r5 =μ12sin 2 r1 +μ 32sin 2 r 5 -μ 2 2sin 2 r3 -cos 2
Real depth
20. μ=
apparent depth

h-24
object dist U o =
μ
24 h
Image dist Vo = +
μ μ
S=Vo -U o
24 24 48  3
    36cm
μ μ 4
21.
 sin i  sin r
Rd Rd
 
R  d R  d 
2 2
 h2  h2


R  d  R  d
2R 2R
Rd
2 
Rd

22.

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3
20   r1
2
40
r1 
3
r1  r2  A
r2  A  r1
80
r2 
3
3 4
sin r2  sin e
2 3
9
e  r2  30
8
  i  e  A  20  30  40
  10
23.
Hint: power of equivalent mirror
PM1  2 PL  PM
1  3 2  2  1
  1  
f L  4 3   R  4R
1
PL 
4R
2
PM 
R
1 1 2 5
 1  2.  
f 4R R 2R
2R 4R 4R
f1  h2f1  h
5 5 5
Here h  4 then R  5 cm
24.

t t
cos r  y
y cos r
x
sin  i  r  
y
t
x sin i cos r  cos i sin r 
cos r
x  t sin i  cos i tan r 
sin i sin 600
  sin r 
sin r 
1 2 1
sin r  ;cos r  ; tan r 
3 3 2
 1   3 1 1 
 x  6 sin 600  cos 600   6    3 1.7  0.7   3cm
 2  2 2 2
y
25. Object distance from the apparent position of mirror is   y1  y 

Final image as seen by bird is formed at the same distance u below the mirror.
Distance of image as seen by bird

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 y
S  2  y1  y  
 u
ds  dy dy 1 dy 
Observed velocity V   2 1   
dt  dt dt  dt 
 3 
V  2 0   1   1   y1  cons tan t 
 4 
1
 2 1  3   cm / s
 4 2

As this is +ve, S increases with time. Hence the image appears to be moving downwards.
26. S1  μ-1 A1:S2 =  μ 2 -1 A 2
S1 +S2 =Snot ;but Snot  0  S1   S 2
0.54  4
 1  1 A1   2  1 A2  A2   3
0.72
27. at N1,TIR takes place
1 1
 μ=  2=  c=45°
sinc sinc
r1  15° & r2  15°
r1 =r2  i1 =i 2
As light ray opposite to incident ray deviation=180o
Snot  180
i1 -r1 +180-2c+i 2 -r2 =180

2i=15+180-90-15=180
i=60
n  15=60
n=4
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1 -2 1 -2 2 -4 -10
28. = +  = -  =  F= cm
F fL fm 10 10 10 4
1 1 1 1 1 1 -1 dv 1 du -V 2
+ =  = - .......1  2 =+ 2  Vcm = 2 u cm
v u f v f u v dt u dt u
2
-v
v1 -v m = 2  u o -u m   Vp u o &u m are velocities of image, object & mirror 
u
1 4 3 -1
from 1 =- +  =  v=-10
V 10 10 10
100
from  2 V1   9 1 i   1 i    1iˆ  v1  18i  i  19i
100
Velocity of image=19.m /sec along the +ve x-axis
10+α=19  α=9
1 1 1 1 1 1 v
29. From - = for u=25  = -  V=100  m 25 = =4
v u f v 20 25 u
1 1 1 100 v 100 2
foru=50  = -  v=  m50 = = =
v 20 50 3 u 150 3
m 25 4
= =6
m50 2
3
1 2 1  μ 1
30. =  μ-1 ..............1 and 1 =  -1
f R f  μw  R
f 1 1.5  1  2 f1 1 1 100  1 
   8  1  But P= 1  100  2
f   f f 8f f  8  6.25 
 1.5 
 4  1
 
 3 
CHEMISTRY
31. Conceptual
32. Conceptual
33. MnO2 
KOH / O2
 K 2 MnO4 
Electrolytic oxidation
KMnO4
W X
2
y  MnO 4

z  MnO4
MnO42  acidic medium
 MnO 2  MnO -4
34. Conceptual
35. Conceptual
36. Stability of higher oxidation state increases in transition elements.
37. Conceptual
38. Mischmetall contains lanthanide metal (95%) and iron (5%) and traces of S,C Ca and A
39. Colors of transition metal ion is shown due to d-d transition
Ti 4  3d 0  and Cu 1  3d 10  are colourless
CO 3  3d 5  and Fe 2  3d 6  are coloured ions
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40. (1)Valance shell electron configuration of Mn 2+ is 3d 5 , therefore, has the maximum number of
unpaired electrons equal to 5 and, therefore has maximum magnetic moment.
(2) Valance shell electron configuration of Fe 2+ is 3d 4 , therefore, has maximum number of unpaired
electrons equal to 4.
(3) Valence shell electron configuration of CO 2  is 3d 7 , therefore, has the maximum number of
unpaired electrons equal to 3.
(4) Valance shell electron configuration of Cr 2 is 3d 4 , therefore, has the maximum number of
unpaired electrons equal to 4.
41. Due to lesser difference in energy of (n-1)d and ns electrons so electron are also removed from (n-1)d
sub shell easily.
42. Conceptual
43. When increases unpaired electron, melting point also increase.
44. Al, Cr and Zn oxides are Amphoteric in nature.
d-& f-block Elements final
45. 2CrO42   2 H   Cr2O72  H 2O
Cr2O72  2OH  2CrO42  H 2O

46. K 2Cr2O7  4 NaCl  6 H 2 SO4 

heat
 2 KHSO4  4 NaHSO4  2 CrO2Cl2
chromyl chloride
(oragne red vapoure)

48. As the value of E 0 increases with  +ve  sign oxidsing nature increases so Mn 2 acts as oxidsing agent.
If E 0 value increases with  -ve  sign reducing nature increases so Cr 2 acts as reducing agent.
49. Conceptual
50. Conceptual
51. Conceptual

52.
53. MnO4 , CrO42  , Cr2O72 are coloured due to charge transfer theory)
Mn3 , Cu 2 , Fe 2 , Fe3 are coloured due to presence of unpaired electrons
54. TiO, Sc2O3 , Ti2O3 , VO are basic
55.  RhCl  Ph 3 P 3 
56. Second and third triad of 4d and 5d series of group VIII or group, 8, 9 and 10 are collectively called
platinum metals. These are:
4d series : Ru Rh Pd
5d series : Os Ir Pt
57.
4 FeCr2O4  A   8K 2CO3  7O2 
8 K 2CrO4  B   2 Fe2O3  Brown residue   8CO 2

H   H 2SO4 

K 2Cr2O7  C 
Oxidation state of Cr in A=+3 and in B=+6

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58.

59.  La3
, Lu 3  ;  Ce 4  , Yb 2  are colourless
 Sm 3
, Dy 3  yellow colour
 Eu3
, Tb3  pink
60. x can only be 0 or 1, as the general E.C. of actinoids are 5 f 114 6d 01 7 s 2 .
MATHS
61. Using S, S, S, A, I, T the number of six letter words with 3 S’s in (1st, 3rd, 5th places) or (2nd, 4th, 6th
places) = 3  3  6  6  12
62. Using 0, 1, 2, 3, 4, 5 (without repetition of digits) the number of 3 digit numbers, which are (i) ending
with 0  5 P2  20 (ii) ending with 2 or 4 = 2  ( 5 P2  4 P1 )  32
 20 + 32 = 52.
63. If x, y, z are digits in hundred’s, ten’s, unit place respectively then the number of 3 digit numbers xyz
so that (i) x  y  z is 10
C3 (by selecting 3 digits from 0, 1, 2,…., 9), (ii) x  z  y is 10
C3 , (iii)
10
x  y  z is C2
Required = (10 C3  10C3  10C2 )  285 .
64. No. of ways in which
(i) Old man can be arranged in two back seats = 2
(ii) One of the two young men can be arranged in driving seat = 2
(iii) Other young man and 1 lady in remaining 2 seats = 2 P2  2
 Total no. of arrangements = 2  2  2  8
65. No. of ways of arranging
(i) vowels O, I, A, E in 4 odd places = 4
(ii) consonants R, D, N, T in remaining 4 places = 4
k 2 = total no. of arrangements = 4  4  242  k = 24
66. No. of ways of arranging
(i) L, G, B, R in a row = 4  24
(5 P3 )
(ii) A, E, A in 5 gaps between consonants =  30
2
Total no of arrangements = 24 × 30 = 720 = 360  , where   2
67. Total number in three families = 3 + 3 + 4 = 10,
So total arrangement = 10!
Family 1 Family 2 Family 3
3 3 4
Favourable cases
= 3! 3! 3! 4!
Arrangement of 3 families Interval arrangement of families members
 Probability of same family members are together

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Narayana IIT Academy 23-06-24_SR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-45_KEY&SOL
3!3!3!4! 1
=  .
10! 700
68. 4 boys and 2 girls in circle
6!
 5!  2!  5  6! .
4!2!
69. 7 women can be arranged around a circular table in 6! ways
Among these 7 men can sit in7! ways
Hence, number of seating arrangement = 7!  6! .
np 10
70. r   5  I ( )  10C5 (sin 1  )5 (cos1 x)5
pq 2
5
 2 
= 10
C5   sin 1   
 16 4
5
2 
 I ( )  C5  
10

 16 
T3 T
71. | T3 || T4 | , | T5 || T4 |  1, 5 1
T4 T4
T3 2 T5 21x
  , 
T4 x T4 64
T3 2 T 21x
  1 5  1
T4 x T4 64
64
 | x | 2  | x |
21
 64 
n   2,  x  2
 21 
64 64  64   64 
 x  x    , 2    2,  .
21 21  21   21 
6 r
 3  6!  3 
72. Coefficient of x in 1  2x  2  
4
1p 2 x q  2 
 x  p !q ! r ! x 
6! 4
 p  q  r  6  p  2, q  4, r  0  2  240
2!4!
73. Coefficient of x n in the polynomial
( x  2n1C0 )( x  2n1C1 )( x  2n1C2 )...( x  2n1Cn )
Coefficient of x n  2n1C0  2n1C1  .....  2n1Cn
1
=  22 n 1   22 n
2
10 2r 1 1 10 n 1 1 n1
74.  Cr    Cr 1 2r 1 = [ C0  n 1C1  ...  n1Cn ]
r 0 r  1 n  1 r 0 n 1
211  1

11
75. S = ( 2  1P0  3  2 P1  4  3 P2 ..... upto 51th terms) + (1! + 2! + 3!.... upto 51th terms)
[ n Pn1  n !]
 S  (2  1! 3  2! 4  3!....  52.51!)  (1! 2! 3!....(51)!)
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= (2! 3! 4!....  52!)  (1! 2! 3! 4! ....  (51)!) = 1! + 52!.
a
76. A  {2,3,5,7,11,13,17,19, 23, 29} and n( A)  10  a, b  A  is a rational number.
b
No. of cases in which a  b is equal to 10
P2  90
a
For a, b  A and a  b then each value of is equal to 1
b
Total no. of rational numbers = 91 and 13x  91  x  7 .
77. Product of m consecutive natural numbers is always divisible by (m!) and from given condition
k
[1, 2,3,...., (n  1)(n)(n  1).....(2n  1)(2n)]  r !
2
k k
 [(2n)!]  r !, where n  2005  (2010!)  r ! and least positive integer k  2
2 2
78.  1     2   2   1  1     2   3   4

 1     2   3   4  2 4

1  5 4
  2 4  2 4  2   2  1  2
1 
22  4
As z  z  1  0  z  , 
2 2
79.

z n  z  n   1 n   1  n
n n

  1  n   n  , if n is a multiple of 3.
n

  1 1  1  0
n

z1  z3 1  i 3
80. 
z2  z3 2


1  i 3 1  3   1  i 3 2

2 1  i 3  2 1  i 3 
4 2


2 1 i 3  1  i 3 
z 2  z3 1  i 3
 
z1  z3 2
 
 cos  i sin
3 3
z 2  z3  z  z3  
  1 and arg  2 
z1  z3 
 1 3 3
z z
Hence, the triangle is an equilateral .
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81. No. of n-digit numbers using only the digits 2, 5, 7 = 3n
900 such numbers are possible if 3n  900
Least value of n is 7.
82. Number of the form xxy  9  9  81
Number of the form xyy  9  9  81
Total no. of numbers = 192
Three digit number abc
Where a  b  c  9 .
83. Letter of the word NALGONDA are A, A, N, N, L, G, O, D
8
P5
No. of ways of remaining A, A, N, N, L in 8 gaps = .
2 2
Then in remaining 3 gaps G, O, D can be arranged in specified order in only 1 way
 8P  P  8765 
P   5  and  4
 4  420  420 
84. MOTHER
1 E
2H
3M
4O
5 R
6 T
So, position of word MOTHER in dictionary
2  5! 2  4! 3  3! 2! 1
= 240 + 48 + 18 + 2 + 1 = 309.
10!
85. ( 2  3 3  6 5)10 general term = ( 2) p ( 3 3)q ( 6 5) r
p !q !r !
 p  0, 2, 4, 6,8,10 , q  0,3, 6,9 , r  0, 6
 p  q  r  10  (4, 0, 6), (4, 6, 0), (10, 0, 0)
86. Each of 10!, 11!, 12!, ….., 49! is a multiple of 100 and hence tens digit of each of them is zero.
required = tens digit of (1! 2! 3! ...  49!)
= tens digit of (1+ 2+ 6 + 24 + 120 + 720 + 5040 + 40320 + 362880)
195 (n  3)!
87. xn  0    195  4(n  3)(n  2) , where n  N
4(n !) (n !)  (n  1)!
This is time for n  1, 2, 3, 4 only
 No. of positive terms of the given sequence is 4.
88. C1 : z   4  3i   2 and C2 : z  z  4  6,z  C
C1 : represents a circle with centre (4, 3) and radius 2 and v represents a ellipse with foci at (0, 0) and
(4, 0) and length of major axis = 6, and length of semi-major axis 2 5 and (4, 2) lies inside the both
C1 and C2 and (4, 3) lies outside the C 2

So, number of intersection points = 2

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89.  z 2  z  0 Let z  x  iy
 x 2  y 2  2ixy  x  iy  0

x 2
 y 2  x   i  2xy  y   0

 x 2  y2  0 and  2x  1 y  0

1 3
If x   then y   and if y = 0 then x = 0, -1
2 2
1 3 1 3
 z  0  0i,  1  0i,  i,  i
2 2 2 2

   R e  z   m  z   0

90.

z  2  2i  1
 z lies inside the circle with centre at 2 + 2i and radius = 1, as shown in figure
6
3iz  6  3i z   3 z  2i
3i
This is distance of z from 2i
Hence for maximum value z = 3 + 2i (Refer figure)
Hence a + b = 5

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