VKT sir

Titration:-

A titration is a technique where a solution of known concentration is used to determine the

concentration of an unknown solution. Typically, the titrant (the know solution) is added from a buret
to a known quantity of the analyte (the unknown solution) until the reaction is complete. Knowing the
volume of titrant added allows the determination of the concentration of the unknown. Often, an
indicator is used to usually signal the end of the reaction, the endpoint.

• Titrant: solution of a known concentration, which is added to another solution whose concentration has to be
determined.
• Titrand or analyte: the solution whose concentration has to be determined.

• Equivalence point: point in titration at which the amount of titrant added is just enough to completely
neutralize the analyte solution. At the equivalence point in an acid-base titration, moles of base = moles of
acid and the solution only contains salt and water.
Acid-base titrations are monitored by the change of pH as titration progresses
 VKT sir
Titration : -

Pt
Equivalence :

Acid/Base No
of EpPt
H4 I

Itz20s 2

It POy 3

ItPO2 A

CHLOOH I

Naz Cos 2

zu42 2
 VKT sir
End Pt :
 VKT sir
Titration Base
involving monoprotic Acid and Monohydroxy :

① Titration
of strong
acid with
Strong Base :

0 IM NaOH

O -M 25 m
,

/
H4 + NaOH >
Nat + H

2 .
5 mmde 2 5 nmole
.

HC 25mmoh
0 .
1M 25 m
,

PH =
7 >
-

Equivalence Pt
VKT sir
 VKT sir
& Titration weak Acid
Strong Base
of
with :

o .
Im Naot

0 ·

im
- HA + NaOH > NaA + HLO
2 .

5 mmob 2 Immah
.

HA 2 . 5 mmo

2 5
tom
do = .

=
0 .
1M 25 m/
, 50

PH
+plat 100
7 +
Equivalenc
=
%

Pt
 VKT sir

&

[H+ 103 V
)
JTaxar
+
Butter
=
=

106 = Lax 0
.

ka = 10-5
 VKT sir
Acid
& Titration With
Strong
of
WB :

OIR
, HC
0 IM
,
25 my
BOH + HC ) B4 + HO
-
4 .
5 mmoh 2 . Smal
2 5 mmal
Bolt
.

0 .
/M ,
25 m
90 = M

pH =

-E [phptlopa] =>
[4Pt

9 k =
105 => pHt = 7 -

1[5-topd-top10]
=
5 15.
 VKT sir
Suitable indicator for titration
in the colour
is ,
which have eppt
indicator
.

II
transition range of
⑭ 9 eppt is mid

colour transition
point of
range

pH 5 . - . . .

) EqPt
then it is best

for the
indicator
I

titration .

25 m

V
H4
OED VKT sir
G
B
⑪
,

78 10/
⑧ AspOn = H + HIPOn- pH =
1
0 .
1 0 .
1
9
1(1 2) It Old 0 1C
0 .
0 ..
-

-
- 0
%
= 0
% 0 .
1

ha ,
= k
= = 10ka
,

HePOn- => H + + HPOYL

0 .
1 d 0 .

1 G
kaz
= Y =
Chaz =ha