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2018 Strength and Hydraulic Conductivity of Cement and By-Product Cementitious Materials Improved Soil
2018 Strength and Hydraulic Conductivity of Cement and By-Product Cementitious Materials Improved Soil
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Samuel Jonah Abbey1, Samson Ngambi2, Adegoke Omotayo Olubanwo3, and Francis Kofi Tetteh4
1
Lecturer in Structural/Geotechnical Engineering, University of South Wales, United Kingdom.
Email: Samuel.abbey@southwales.ac.uk
2
Senior Lecturer in Soil Mechanics and Geotechnics, Coventry University, United Kingdom.
Email: apx290@coventry.ac.uk
3
Lecturer in Structural Engineering and Finite Element, Coventry University, United Kingdom.
Email: aa7878@coventry.ac.uk
4
PhD Candidate Birmingham University, and Senior Geotechnical Engineer, Aspin Group, United Kingdom.
Email: francis.tetteh@aspingroup.com
(* Corresponding author. E-mail: Samuel.abbey@southwales.ac.uk)
Abstract INTRODUCTION
This paper presents an experimental investigation on strength Weak soils are generally regarded as problematic in terms of
and hydraulic conductivity of a fine grained soil mixed with their resistance to shear deformation, hydraulic conductivity,
cement, Pulverised Fly Ash and Ground Granulated Blast Slag. excessive settlement and limited bearing capacity. Deep soil
Strength and permeability are important properties that defines mixing is one technique that has been used to improve these
the engineering behaviour of deep mixing improved soils. properties and enhanced performance, (Abbey et al. 2015; Eyo,
Cement contents of 4%, 8%, 12% and 16% by weight of dry et al., 2017; Terashi, 2009; Abbey et al. 2017, Mousavi and
soil were added using wet soil mixing technique. The Wong 2016). The inclusion of different binder type and cement
percentages of cement were reduced and replaced with PFA, during soil mixing process can generate similar hydration
GGBS and Bentonite at 33.3% and 50% reductions products, (Abdulhussein Saeed, Anuar Kassim, and Nur 2014).
respectively. Unconfined compressive strength (UCS) and The unconfined compressive strength of Portland cement (PC)
permeability tests were conducted on cement, PFA/GGBS and improved soils are usually high making PC the most commonly
Cement/Bentonite mixtures prepared at their respective used binder in soil improvement, (Holm, Terashi, 2003;
optimum moisture content (OMC) and maximum dry density Makusa 2012; Consoli et al. 2015; Oana, 2016, Abbey et al.
(MDD) and cured for different periods. The results show that 2016). Chen, Liu and Lee (2016) examined the variation in
an increase in % of additives causes decrease in porosity and unconfined compressive strength of marine clay, improved
increase in density of cement and cement/PFA stabilised soil with cement during wet deep mixing work at the Marina Bay
and hence, increase in UCS. Except at some optimum values of Financial Centre in Singapore. In their study, the UCS of the
12% and 16% of additives in C+PFA combinations where the improved clay was found to vary from about 700 kPa to about
density of the improved soil decreases at fairly constant 5 MPa. The 28 day UCS of samples improved with cement and
porosity resulting to an increase in UCS. This implies that % of prepared using wet mixing method is always higher than those
additive and the type of additive controls the UCS of improved prepared by dry method, Pakbaz and Farzi (2015). According
soils more than the influence of porosity and density on UCS. to Chen, Liu and Lee (2016), strength distribution in deep
Decrease in porosity of samples improved using mixing improved soils is affected by in-situ soil properties and
C+PFA+GGBS and C+B with increase in % of additives, the chemical reactions between soil and Cementitious
resulted to increase in UCS but however, the reduction in constituent. UCS increases with increase in cement content
density and increase in UCS also shows dominance of % and especially for non-plastic soils (Asturias and Lorenzo 2015,
type of additive on strength over porosity and density. Cement- Abbey et al., 2016, 2017). For applications of soil mixing in
Bentonite and combination of PFA /GGBS with reduced ground water barrier walls, the permeability of the improved
amount of cement were observed to better improved soil, defines the hydraulic conductivity of the barrier walls and
permeability of the soil. This study has also defined the of great importance. Enhancement of permeability of soil
functional relationships between hydraulic conductivity and formations is also important in construction of other hydraulic
additive type based on the investigated % of additives and structures such as dams, power houses, tunnels and in a wide
combinations. variety of special cases. Cement - bentonite mixture has been
used in the UK for impermeable cut-off slurry walls (Talfirouz
Keywords: Strength, Permeability, Hydraulic conductivity,
2013) and it has also been used severally in the US to form
Deep Soil Mixing, Improved Soil, Cement, PFA, GGBS,
permeable reactive barriers(PRB) in contaminated soil
Bentonite, fine grained soil
(Bullock 2007). Åhnberg (2003) and Higgins, (2005) observed
that cement-based binders significantly reduces the
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International Journal of Applied Engineering Research ISSN 0973-4562 Volume 13, Number 10 (2018) pp. 8684-8694
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permeability of tested Swedish soil while lime-based binders cement on unconfined compressive strength and hydraulic
produced more rapid result in terms of increase in permeability. conductivity of a fine-grained soil and establish the functional
Yi, Liska and Al-Tabbaa (2013) reported the initial increase in relationship between percentage of additive and hydraulic
permeability upon addition of lime and cement as being due to conductivity.
hydration reaction that takes place when quick lime and the
lime content in cement comes in contact with soil pore water.
This reaction causes flocculation of the clay, forming a coarser MATERIALS
structure than that of the natural soil owing to the formation of
Ca(OH)2 and ion exchange with soil particles (Åhnberg 2003, Model soil and additives
2006). Mousavi and Wong (2016) reported that permeability of The model soil consisted of a silty soil of 24% moisture
cement stabilised clay reduces as cement content increase from content, liquid and plastic limits of 47.8% and 24.3%
8% to 18% and according to EuroSoilStab (2002), the respectively. The untreated model soil has hydraulic
permeability of a soil can increase up to 100 to 1000 times when conductivity of 4.4 x 10-10 under effective stresses of 200kPa
stabilized with binders. Mixture of cement and bentonite has and unconfined compressive strength (UCS) of 145kPa as
also been used to consistently reduce permeability with presented in Table 1.0 The binders considered are cement,
increasing cement content and this combination is commonly GGBS, PFA and cement-bentonite. The hydration of cement in
used in construction of hydraulic impermeable barriers (Takai, the presence of water involves different reactions often
2014) but establishing the percentage of cement and bentonite occurring at the same time and the product of this reaction (C-
required to enhance hydraulic conductivity of a fine grained S-H) gradually bond particles of the improved soil together and
soil would be considered in this paper. According to (Wang et consequently enhances strength. The investigated soil has been
al., (2015), Puppala (2003), Axelsson et al. (2002), treated with cement and inclusion of by-product cementitious
Keramatikerman et al., (2016) and Ali et al. (2013)) use of materials such as GGBS and PFA based on the environmental
cement, lime, PFA and GGBS in soil stabilisation can improve concern on the use of cement. Ground improvement projects,
the strength property of a weak soil. Undoubtedly, cement deep especially in remediation of contaminated sites, soil bentonite
soil mixing has been widely employed in the construction field mixtures have been used to form slurry wall hydraulic barriers
and has effectively reduced soil permeability. But lately, based on the hydrophilic property of bentonite and ability to
problems particularly associated with cost and the absorb organic contents. Cement-bentonite mixtures have been
environments have emerged due to CO2 emission. Therefore, it employed in the UK as impermeable cut-off slurry walls
becomes necessary to investigate into the possible use of by- (Talfirouz 2013) and in the US as permeable reactive barriers
product materials such as PFA and GGBS with reduced amount in contaminated soil (Bullock 2007). The chemical
of cement in deep mixing of weak soils to possibly reduce the compositions and physical properties of the materials used are
environmental impact of cement soil mixing operations. shown in Table 2.0 and Table 3.0 respectively.
Therefore, this study will also focused on the effect of inclusion
of cementitious by-product materials with reduced amount of
CEM I 19.63 0.26 4.71 3.25 0.09 1.17 64.09 0.27 0.73 0.20 2.94 3.22
PFA 52.15 0.87 19.61 7.10 0.07 2.00 4.40 1.06 1.93 0.45 0.54 9.48
GGBS 33.28 0.57 13.12 0.32 0.316 7.74 37.16 0.33 0.474 0.009 2.21 4.42
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SiO2 57.1% Na2O 3.27% Montmorillonite 92% Bulk Density 800–900 kg/m3
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1.000 1.000
0.900 0.900
Void ratio, e
Void ratio, e
0.800 0.800
0.700 0.700
0.600 0.600
0.500 0.500
1 10 100 1000 1 10 100 1000
log p (kPa) log p(kPa)
Unstabilized 3C+3B 4C+4B
Unstabilized 6C 8C 12C 16C
6C+6B 8C+8B
1.000
1.000
0.900
0.900
Void ratio, e
Void ratio,e
0.800
0.800
0.700
0.700
0.600
0.600
0.500
0.500 1 10 100 1000
1 10 100 1000 log p (kPa)
log p (kPa) Unstabilized
2C+2PFA+2GGBS
Unstabilized 3C+3PFA 4C+4PFA 2.667C+2.67PFA+2.67GGBS
4C+4PFA+4GGBS
6C+69FA 8C+8PFA 5.33C+5.33PFA+5.33GGBS
Figure 1.0(a-d): Variation of void ratio of stabilised soils with effective stress
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0.850
0.900
Void ratio, e
Void ratio, e
0.800
0.750 0.800
0.700
0.650 0.700
0.600
0.600
0.550
0.500 0.500
1 10 100 1000 1 10 100 1000
log p(kPa) log p (kPa)
Unstabilized 6C Unstabilized 3C+3PFA
8C 12C 4C+4PFA 6C+6PFA
16C 8C+8PFA
1.000 1.000
Void ratio, e
Void ratio, e
0.900 0.900
0.800 0.800
0.700 0.700
0.600 0.600
0.500 0.500
1 10 100 1000 1 10 100 1000
log p(kPa) log p (kPa)
Unstabilized
2C+2PFA+2GGBS
Unstabilized 3C+3B
2.67C+2.67PFA+2.67GGBS
4C+4PFA+4GGBS 4C+4B 6C+6B
5.33C+5.33PFA+5.33GGBS 8C+8B
Figure 2.0(e-h): Variation of void ratio of stabilised soils with effective stress after 28-days
The results show reduction in void ratio with increase in Effect of porosity and density on UCS
effective stress as expected, due to increase in overburden.
In a study on use of fly ash and GGBS as partial replacement
Irrespective of binder types, void ratio decreases with an
of cement and lime by (Chao, Songyu and Yongfeng 2015), it
increase in % of binder due to bonding effect of additives with
was observed from a microstructural analysis that fly ash
solid soil particles. The inclusion of by-product cementitious
mainly alters the distribution of pore volume of the soil, and
materials increases the volume of solid particles and bonding
produces more hydration compounds as a result of secondary
area. The void ratio of the improved soils decrease as the % of
hydration and pozzolanic reactions. The present study has
binder combinations increases. However, 8% cement-bentonite
investigated other properties of soil improved using
mix shows almost linear and lower variation in void ratio with
combination of this additives with reduced amount of cement.
increasing overburden after 7 and 28days as shown in Figure
The effect of porosity and density on unconfined compressive
1.0(b) and Figure 1.0 (h). This is due to the expansive behaviour
strength (UCS) has been investigated. The results show that an
of bentonite when in contact with water.
increase in % of additives causes decrease in porosity and
increase in density of cement and cement/PFA stabilised soil
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and hence, increase in UCS. Except at higher % of additive of the improved soil. The porosity of samples improved using
(12% and 16% of additives) in C+PFA combinations as shown C+PFA+GGBS and C+B also decreases with increase in % of
in Figure 4.0, where the density of the improved soil decreases additives, resulting to increase in UCS as shown in Figure 3.0,
at fairly constant porosity resulting to increase in UCS. This however, the reduction in density and increase in UCS shown
implies that the % of additive and type of additive controls the in Figure 4.0 again, is due to predominance of % and type of
UCS of improved soils more than the influence of porosity and additive on strength over porosity and density.
density on UCS. This means that UCS depends more on the %
of additive and the type of additive than on porosity and density
Figure 3.0: Variation of unconfined compressive strength and porosity with % of binder
Figure 4.0: Variation of unconfined compressive strength and density with % of binder
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Hydraulic conductivity changes with binder inclusion drops the degree of saturation of the improved samples below
degree of saturation line of the unimproved soil due to
The coefficient of permeability 𝑘 values obtained from one-
hydration reaction of cement and water, resulting to reduction
dimensional consolidation test showed a bit of scatter as
in hydraulic conductivity. A reduction in % of cement to 3%,
expected however, some important trends were observed. The
2% and 5.33% and inclusion of equal amount of PFA and
results plotted in Figure 5.0 and 6.0 show the variation
PFA+GGBS also reduces the degree of saturation and
hydraulic conductivity with degree of saturation of the
hydraulic conductivity of the improved soil at the early stage of
improved soil materials at different binder percentages after 7
hydration process.
and 28 days. Figure 5.0 shows that the addition of 6% - 16%
Figure 5.0: Variation of hydraulic conductivity and degree of saturation with % of binder
Figure 6.0: Variation of hydraulic conductivity and degree of saturation with % of binder
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The permeability and compressibility of stabilized soil is also additives after 28days due to reduction in porosity of the
expected to vary with curing time due to the continuous binder- improved soils as % of additive increases as shown in Figure
soil reaction that occurs because of cement hydration (Åhnberg 7.0. Soil matrix consists of pores of numerous different sizes,
2003). Figure 7.0 also shows that hydraulic conductivity and the pores-fill performance of these additives differs and this
decreases with reduction in cement content and inclusion of causes the variation in porosity of the improved soil across the
PFA and GGBS contents in the different combinations of different additives and combinations as shown in Figure 7.0.
Figure 7.0: Variation of hydraulic conductivity and porosity with % of binder after 7 and 28 days.
The ease by which water flows through soil is highly dependent From Figure 7.0, it is evident that the inclusion of GGBS and
on porosity and it is evident that reduction in porosity Bentonite causes a smooth reduction in porosity, hence,
accompanied by reduction in hydraulic conductivity of the decrease in permeability due to consistent fineness and particle
improved soil is because of decrease in distances between shape of the GGBS powder, and hence, increase in surface area.
individual soils particles due to bonding. The dependency of Equation 1.0 shows that permeability coefficient is directly
coefficient of hydraulic conductivity of soils on porosity has dependent on porosity and inversely dependent on surface area
been explained using existing empirical relations as shown in of the particles per unit volume of porous matrix (Av), where
Equations 1.0, (Slichter, (1899), Kozeny (1927)). Equations 1.0 the parameter (a) is an empirical term and depends on porosity.
empirically shows the direct proportionality of coefficient of This study has shown that hydraulic conductivity of the
permeability (hydraulic conductivity) on porosity (n) and pore improved soil depends on porosity, % of additives, type and
radius (r). combination of additives as shown in Figure 8.0 and Figure 9.0.
𝑛𝑟 2 n3
𝑘 = = Eq. 1.0
8 aA2
V
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5E-10
Hydraulic Conductivity (m/s)
4.5E-10
4E-10
3.5E-10
3E-10
2.5E-10
2E-10
1.5E-10
1E-10
5E-11
0
0 5 10 15 20
% of additive
The porosity in turn depends on the type and % of additive. determination defines how the functions explain the variability
Therefore, this study has defined the functional relationships of the response data around its mean.
between hydraulic conductivity and additive type based on the
% of additives and combinations considered in this study as
presented in Table 4.0. The values of the coefficients of
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Table 4.0 Functional relationship between hydraulic conductivity and percentage of additive
Mixed soil type
Function
Soil-Cem Soil-Cem/PFA Soil-Cem/PFA/GGBS Soil-Cem/Bentonite
Coefficient of Determination, R2
Linear 0.8285 0.8417 0.9470 0.9297
Exponential 0.8792 0.8942 0.8577 0.9398
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