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Manzil Legend Batch

(Atomic Structure) Practice Sheet

1. Out of X-rays, infrared rays, visible rays and 9. How many 3d electrons can have spin quantum
microwaves, the largest frequency is of: 1
(1) X-rays (2) IR rays number − ?
2
(3) Visible (4) Microwaves (1) 5 (2) 7
(3) 8 (4) 10
2. The increasing order (lowest first) for the values of
e/m (charge/mass) for electron e , proton (p),
neutron (n) and alpha particle (α) is: 10. The orbital diagram in which the Aufbau principle
(1) e, p, n, α (2) n, p, e, α is violated is:
(3) n, p, α, e (4) n, α, p, e
(1)
3. Which electronic level would allow the hydrogen
atom to absorb a photon but not to emit a photon? (2)
(1) 3s (2) 2p
(3) 2s (4) 1s
(3)
4. How many electrons with l = 2 are there in an atom
having atomic number 54 ? (4)
(1) 3 (2) 10
(3) 14 (4) 20
11. For a d-electron, the orbital angular momentum is:
5. The potential energy of an electron in hydrogen (1) 6(h / 2) (2) 2(h / 2)
atom is – 3.02 eV, its kinetic energy will be:
(3) (h/2) (4) 2(h/2)
(1) 1.51 eV (2) 15.10 eV
(3) 13.6 eV (4) 1.36 eV
12. The wavelength associated with a golf ball
6. The ratio of the energy of a photon of 2000 Å weighing 200 g and moving at a speed of 5 m/h is
wavelength radiation to that of 4000 Å radiation is: of the order:
(1) 1/4 (2) 4 (1) 10–10 m (2) 10–20 m
(3) 1/2 (4) 2 (3) 10–30 m (4) 10–40 m

7. Which of the following does not characterize X- 13. The radius of which of the following orbit is same
rays? as that of the first Bohr’s orbit of hydrogen atom?
(1) The radiation can ionize gases (1) He+ (n = 2) (2) Li2+ (n = 2)
(2) It causes ZnS to fluorescence (3) Li2+ (n = 3) (4) Be3+ (n = 2)
(3) Deflected by electric and magnetic fields
(4) Have wavelengths shorter than ultraviolet rays
14. The kinetic energy of an electron in the second
Bohr orbit of a hydrogen atom is [a0 is Bohr radius]
8. Which one of the following sets of quantum
numbers represents an impossible arrangement? h2 h2
(1) (2)
(1) n = 3; ℓ = 2; mℓ = – 2; ms = 1/2 42 ma 02 162 ma 02
(2) n = 4; ℓ = 0; mℓ = 0; ms = 1/2
h2 h2
(3) n = 3; ℓ = 2; mℓ = – 3; ms = 1/2 (3) (4)
(4) n = 5; ℓ = 3; mℓ = 0; ms = –1/2 322 ma 02 642 ma 02
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15. Which of the following has the same number of s- 23. The atomic masses of ‘He’ and ‘Ne’ are 4 and 20
electrons as the d-electrons in Fe2+? a.mu. respectively. The value of the de Broglie
(1) Li (2) Ca wavelength of ‘He’ gas at – 73°C is “M” times that of
(3) N (4) P the de Broglie wavelength of ‘Ne’ at 727°C ‘M’ is:

16. According to Bohr’s theory, the electronic energy 24. Calculate the wavelength of light required to break
of hydrogen atom in the nth Bohr’s orb it is given the bond between two Cl atoms in Cl2 molecules
−21.76  10−19 [(BE)Cl – Cl = 243 kJ mol–1)
by E n = J . Calculate the longest
n2 (1) 8180 Å (2) 9860 Å
wavelength of light that will be needed to remove (3) 4930 Å (4) 500 Å
an electron from the third Bohr orbit of the He+ ion
25. The number of quanta of radiation of frequency
17. What is the maximum number of electrons that 4.98 × 1014 s–1 required to melt 100 g of ice are
may be present in all the atomic orbitals with (latent heat of melting of ice is 33 joule per g):
principal quantum number 3 and azimuthal (1) 1020 (2) 1022
quantum number 2? (3) 1024 (4) 6.023 ×1021

18. Calculate the wave number for the shortest

26. The velocity of electron moving in 3rd orbit of He+
wavelength transition in the Balmer series of
is v. The velocity of electron moving in 2nd orbit of
atomic hydrogen.
Li+2 is:
19. Hα line of Balmer series is 6500 Å. The 9 4
(1) v (2) v
wavelength of H is: 4 9
(1) 4815 Å (2) 4298Å (3) v (4) None of these
(3) 7800 Å (4) 3800 Å
27. The work function of a metal is 4 eV. If light of
20. Graph of incident frequency with stopping frequency 2.3 × 1015 Hz is incident on metal
potential in photoelectric effect is: surface, then:
(1) No photoelectron will be ejected
(1) (2) (2) 2 photoelectron of zero kinetic energy are
ejected
(3) 1 photoelectron of zero kinetic energy is
ejected
(4) 1 photoelectron is ejected, which required the
(3) (4)
stopping potential of 5.52 volt
28. Which of the following graph is correct for 3p?

21. If radius of 2nd orbit is x then de Broglie (1)

wavelength in 4th orbit is given by:
(1) 8 x (2) 2 x
(3) 4 x (4) 6 x (2)

22. The work function () of some metal is listed

below. The number of metals which will show (3)
photoelectric effect when light of 300 nm
wavelength falls on the metal is:
Metal Li Na K Mg Cu Ag Fe Pt W (4)
 2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75
(eV)
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29. Assertion: Principal quantum number of outermost 30. Match the following
electron in Fe is 4. Column-I Column-II
Reason: Last electron is filled in 3d. (orbitals) (Nature and no. of
nodes)
(1) Both assertion and reason are correct, and the
(A) 4d (p) One spherical node
reason is the correct explanation for the z2

assertion (B) 3s (q) One nodal plane

(2) Both assertion and reason are correct, but the (C) 2px (r) Two spherical nodes
reason is not the correct explanation for the (D) 3dxy (s) Two nodal planes
assertion (1) A–(p), B–(r), C–(q), D–(s)
(2) A–(q), B–(p), C–(r), D–(s)
(3) The assertion is true, but the reason is false
(3) A–(r), B–(p), C–(q), D–(s)
(4) The assertion is false, but the reason is true (4) A–(s), B–(p), C–(r), D–(q)
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Answer Key
1. (1) 16. (2055)
2. (4) 17. (10)
3. (4) 18. (27420)
4. (4) 19. (2)
5. (1) 20. (1)
6. (4) 21. (2)
7. (3) 22. (4)
8. (3) 23. (5)
9. (1) 24. (2)
10. (2) 25. (2)
11. (1) 26. (1)
12. (1) 27. (4)
13. (4) 28. (3)
14. (3) 29. (2)
15. (4) 30. (1)
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Hints & Solution

1. (1) 9. (1)
X – rays > visible > infra – red > microwaves 3d 
2. (4) 1
5e − = +
e 0 2 2
for neutron = = 0; α – particle = = 0.5 ;
m 1 4 1
5e − = −
1 1 2
Proton = = 1; electron = = 1837
1 1 / 1837
10. (2)
3. (4) According to Aufbau principle, the orbital of lower
Energy is emitted when electron falls from higher energy (2s) should be fully filled before the filling of
energy level to lower energy level and energy is orbital of higher energy starts.
absorbed when electron moves from lower level to
higher level. 11. (1)
1s is the lowest energy level of electron in an atom. The expression for orbital angular momentum is
 An electron in 1s level of hydrogen can absorb  h 
energy by cannot emit energy. Angular momentum = ( + 1)  
 2 
For d orbital, l = 2
4. (4)
 h   h 
l = 2, i.e., d – orbital Hence, L = 2(2 + 1)   = 6  
Z = 54, 1s2 2s22p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6  2   2 
 Number of electrons in d-orbital = 3d10 + 4d10 =
12. (1)
20e–
According to de-Broglie’s equation
h h
5. (1) = =
P.E. = –3.02 eV p mv
P.E. = 2E [K.E. = –E] Given, h = 6.6  10−34 Js, m = 200  10−3 kg
 P.E. = – 2 K.E. 5
v= m/s
K.E. =
3.02 60  60
2 6.6  10−34
K.E. = 1.51 = −3
= 2.38  10−10 m
200  10  5 / (60  60)
6. (4)
13. (4)
hc
E= ; 1 = 2000Å;  2 = 4000Å n2
 rn = 0.529 Å
E  4000 Z
So 1 = 2 = =2 For hydrogen, n = 1 and Z = 1;  rH = 0.529
E 2 1 2000
For Be3+, n = 2 and Z = 4
0.529  22
7. (3) r =
 Be3+
= 0.529
X-rays ionize gases and cannot get deflected by 4
electric and magnetic fields, wavelength of these
rays is 150 to 0.1 Å. Thus the wavelength of X-rays 14. (3)
is shorter than that of u.v. rays. As per Bohr’s postulate,
nh nh
mvr = so, v =
8. (3) 2 2mr
If l = 2, m  –3, m will vary from –2 to +2 i.e., 1 1  nh 
2

possible values of m are –2, –1, 0, +1 and +2 KE = mv2 so, KE = m  

2 2  2mr 
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ao  n2 1  1 1 
Since, r = = RZ2  2 − 2  …..(ii)
z ' 2 5 
So, for 2nd Bohr orbit
1 1 5
a  22 − 2
r= o = 4a o ' 2
3 = 49
1 =2
6500 1 − 1 21
1  22 h 2  h2 2 2
100
KE = m  2 2  = 2 5
2  4 m  (4a o ) 2  322 ma o2 ' 5 100
= 
6500 36 21
15. (4)  ' = 4298.94Å
Fe2+ has 6 d-electrons, P also has 6s – electrons
P – 15 – 1s22s22p63s23p3  ' = 4298Å

16. (2055) 20. (1)

−21.76  10 −19 hn − hn 0 = eVs
En of H = J
n2 v = v0 +
e
Vs
−21.76  10−19 h
 E n of He+ = 2
 Z2 J
n
21. (2)
−21.76 10−19  4
 E3 of He+ = J r2 = x
9
Hence energy equivalent of E3 must be supplied to x 4x
 r1 = and r4 = = 2x
remove the electron 3rd orbit of He+. Wavelength 2 2
corresponding to this energy can be determined by 2r = n
applying the relation.  n = 2  2x [n = 2]
hc 6.625  10−34  3  108  9  = 2x
E= or  =
 21.76  10−19  4
–10
= 2055 × 10 = 2055 Å 22. (4)
hc
Energy associated with incident photon = =
17. (10) 
For n = 3 and l = 2 (i.e., 3d orbital), the values of m 6.6  10−34  3  108
varies from –2 and +2, i.e., –2, –1, 0, +1, +2 and for E= J
300  10−9
each ‘m’ there are 2 values of ‘s’, i.e., +1/2 and –1/2.
 Maximum no. of electrons in all the five d-orbitals 6.6  10−34  3  108
= eV = 4.16 eV
is 10. 300  10−9  1.6  10−19
Photoelectric effect can take place only when Ephoton
18. (27420)
>
The shortest wavelength transition in the Balmer
Thus, number of metals showing photoelectric effect
series corresponds to the transition
n = 2 → n = . Hence, n1 = 2, n2 =  Balmer will be 4 (i.e., Li, Na, K and Mg).
 1 1   1 1 
v = R H  2 − 2  = (109677 cm−1 )  2 − 2  23. (5)
 n1 n 2  2   Since,
= 27419.25 cm–1 h h
= = (since K.E.  T)
mV 2M K.E.
19. (2)
1
1  1 1  
= RZ2  2 − 2  MT
  n1 n 2  For two gases,
1  1 1  He M Ne TNe 20 1000
= RZ2  2 − 2  …..(i) = =  =5
6500 2 3   Ne M He THe 4 200
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24. (2) E = h = 6.67 10−34  2.3 1015

E = 1.5110−18
25. (2)
1.51 10−18
1 g requires 33 J of heat E(eV) =
 100 g = 3300 J 1.6  10−19
En = nhn E(eV) = 9.52
3300 = n × 6.6 × 10–34 × 4.98 × 1014 E > work function
N = 1022 photons Hence photoelectron will eject
1
E = w + mv 2
26. (1) 2
Z E = w + eV
v n = v0 
n 9.52 = 4 + eV
2 eV = 5.52 eV
He + : v n = v0  …. (i) V = 5.52 V
3
3
Li +2 : v n = v 0  …. (ii) 28. (3)
2 For p-orbital, at nucleus surface, 2 is zero.
3
v0 
vn 2 = 33 = 9
= 29. (2)
vn v  2 2 2 4
0
3
9 9 30. (1)
vn = vn = v
4 4

27. (4)
hc
E=


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