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Solution Manual for Principles of

Instrumental Analysis, 7th Edition,


Douglas A. Skoog, F. James Holler,
Stanley R. Crouch
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Solution Manual for Principles of Instrumental
Analysis, 7th Edition, Douglas A. Skoog, F. James
Holler, Stanley R. Crouch
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CHAPTER 1

1-1. A transducer is a device that converts chemical or physical information into an electrical

signal or the reverse. The most common input transducers convert chemical or physical

information into a current, voltage, or charge, and the most common output transducers

convert electrical signals into some numerical form.

1-2. The information processor in a visual color measuring system is the human brain.

1-3. The detector in a spectrograph is a photographic film or plate.

1-4. Smoke detectors are of two types: photodetectors and ionization detectors. The

photodetectors consist of a light source, such as a light-emitting diode (LED) and a

photodiode to produce a current proportional to the intensity of light from the LED.

When smoke enters the space between the LED and the photodiode, the photocurrent

decreases, which sets off an alarm. In this case the photodiode is the transducer.

In ionization detectors, which are the typical battery-powered detectors found in homes, a

small radioactive source (usually Americium) ionizes the air between a pair of electrodes.

When smoke enters the space between the electrodes, the conductivity of the ionized air

changes, which causes the alarm to sound. The transducer in this type of smoke detector

is the pair of electrodes and the air between them.

1-5. A data domain is one of the modes in which data may be encoded. Examples of data

domain classes are the analog, digital and time domains. Examples of data domains are

voltage, current, charge, frequency, period, number.

© 2018 Cengage Learning. All Rights Reserved. May not be scanned, copied or duplicated, or posted to a publicly accessible website, in whole or in part.
1

© 2018 Cengage Learning. All Rights Reserved. May not be scanned, copied or duplicated, or posted to a publicly accessible website, in whole or in part.
Principles of Instrumental Analysis, 7th ed. Chapter 1

1-6. Time-domain signals include period, frequency, and pulse width. The information is

encoded in the time relationship of signal fluctuations.

1-7.

Input Transducer Use


Phototube Convert light intensity to an
analog current
Glass electrode Convert electrode potential to a
voltage related to pH
Electron multiplier Convert ion intensity to a
corresponding electric current
Thermal conductivity Converts sample thermal
conductivity to related voltage

1-8. A figure of merit is a number that provides quantitative information about some

performance criterion for an instrument or method.

1-9. Let cs= molar concentration of Cu2+ in standard = 0.0275 M

cx = unknown Cu2+ concentration


Vs = volume of standard = 0.500 mL
Vx = volume of unknown = 25.0 mL
S1 = signal for unknown = 25.2
S2 = signal for unknown plus standard = 45.1
Assuming the signal is proportional to cx and cs , we can write
S1 = Kcx or K = S1/cx
After adding the standard
⎛ V c +V c ⎞
S2 = K ⎜ x x s s ⎟
⎝ Vx +Vs ⎠
Substituting for K and rearranging gives,

© 2018 Cengage Learning. All Rights Reserved. May not be scanned, copied or duplicated, or posted to a publicly accessible website, in whole or in part.
Principles of Instrumental Analysis, 7th ed. Chapter 1

S1V sc s
cx =
S 2 (Vx + Vs ) − S1Vx
25.2 × 0.500 mL × 0.0275 M
cx = = 6.66 × 10−4 M
45.1(0.500 mL + 25.0 mL) − (25.2 25.0 mL)
×

1-10. The results are shown in the spreadsheet below.

(a) Slope, m = 0.0701, intercept, b = 0.0083

(b) From LINEST results, SD slope, sm = 0.0007, SD intercept, sb = 0.0040

(c) 95% CI for slope m is m ± tsm For 95% probability and N – 2 = 4 degrees of freedom, t

= 2.78. 95% CI for m = 0.0701 ± 2.78 × 0.0007 = 0.0701 ± 0.0019 or 0.070 ± 0.002

For intercept, 95% CI = b ± tsb = 0.0083 ± 2.78 × 0.004 = 0.0083 ± 0.011 or 0.08 ± 0.01

(d) cu = 4.87 ± 0.086 mM or 4.87 ± 0.09 mM

© 2018 Cengage Learning. All Rights Reserved. May not be scanned, copied or duplicated, or posted to a publicly accessible website, in whole or in part.
Principles of Instrumental Analysis, 7th ed. 3 Chapter 1

© 2018 Cengage Learning. All Rights Reserved. May not be scanned, copied or duplicated, or posted to a publicly accessible website, in whole or in part.
Principles of Instrumental Analysis, 7th ed. Chapter 1

1-11. The spreadsheet below gives the results

(a) See plot in spreadsheet.

(b) cu = 0.410 µg/mL

(c) S = 3.16Vs + 3.25


bc 3.246 × 2.000 µg/mL
(d) cu = s = = 0.410 µg/mL
mVu 3.164 mL−1 ×5.00 mL

(e) From the spreadsheet sc = 0.002496 or 0.002 µg/mL

4
© 2018 Cengage Learning. All Rights Reserved. May not be scanned, copied or duplicated, or posted to a publicly accessible website, in whole or in part.
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BARCLAY, FLORENCE LOUISA


(CHARLESWORTH) (MRS CHARLES W.
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A strange story of reincarnation. Luke Sparrow is brought up in a


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Putnam

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Pitman 338.1

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Contents: The British corn trade and its units; The corn trade in old
England; The English law on the “cornering” of wheat and other
grain; Two hundred and fifteen years of wheat prices in England; The
corn laws era; The growth and development of the modern corn
trade; The effect of the great war on the corn trade. There are notes
at the close and an index.

[2]
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(HELEN MANCHESTER HUNTINGTON).
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(Eng ed 20–11567)

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*$1.50 Lane 811
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This is the author’s second volume of poems. “Dust of stars” was


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Reviewed by W: S. Braithwaite

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BAROJA Y NESSI, PIO. Youth and egolatry.


(Free lance books) *$1.75 (4) Knopf 868
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BARR, MRS AMELIA EDITH


(HUDDLESTON). Songs in the common chord;
songs for everyone to sing, tuned to the C major
chord of this life; introd. by Joseph C. Lincoln. *$1.50
Appleton 821

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+ Cleveland p85 S ’20 30w

“Once only, in ‘Songs from the journey,’ does Mr Barrett touch


authentic poetry—in the suave and colorful ‘The vase.’ The book is
not distinguished verse.”

− + N Y Call p11 Ag 1 ’20 210w

“Mr Barrett is a poet of great promise, a spirit clear-eyed and


keen.”

+ N Y Times 25:193 Ap 18 ’20 160w

“He has mastered the not too recondite, yet also not too facile,
secret of expressiveness in free verse.” O. W. Firkins

+ Review 3:171 Ag 25 ’20 100w


BARRON, CLARENCE WALKER. World
remaking; or, Peace finance. *$1.75 (4c) Harper
330.9

20–4717

“All history is bound up in the human problems of personal and


national finance—personal and national protection to daily
subsistence.” (Foreword) It is the object of the book to set forth from
the point of view of the financier and the enemy of socialism “the
true relations between the work of capital and the work of hand, and
the relation of both to the labor of brain,” and to show their bearing
on our present-day problems. Some of the articles are: England the
great war loser; England’s weakness and restricted output; Ships and
shipping; The value of the pound sterling; Protection and protected
shipping; Reducing hours and increasing efficiency; The spirit under
British finance and business; The social unrest; Peace “without
victory”; Helpless Russia; Indemnities and signatures; Socialism
versus democracy; Inflation by currency, war bonds, and taxes; Are
we to pay for German intrigue at Panama? Bolshevik danger and the
remedy.

Booklist 16:260 My ’20

“The book is gossipy and readable, and yet is trustworthy, for Mr


Barron had entrée to authorities who talked freely.”

+ N Y Times 25:172 Ap 11 ’20 250w


“There are many little affectations of speech scattered through the
book which some may find irritating. But it is, nevertheless, a good
book and well worth reading.”

+ − Review 2:464 My 1 ’20 220w


R of Rs 61:556 My ’20 60w

BARRUS, CLARA. John Burroughs; boy and


man. il *$3.50 Doubleday

20–20968

“The incidents here related have been told me by Mr Burroughs


himself, and are sanctioned by him. During the midsummer and fall
for many years past I have wandered with him over the fields and
hills and through the woods where he roamed as a boy. In these
rambles he has pointed out the places where the narrated events
occurred. He has explained in detail the curious and interesting ways
and means of long ago—old-time ways which will never come again.
And not only in his youthful haunts, but also during many an evening
by the fireside at The Nest, he has again recounted the childish
recollections, the boyish pastimes, and the youthful dreams recorded
here.” (Preface) After a characterization of the “grown-up boy” and
his forebears the contents are grouped under the headings:
Childhood; Boyhood; Youth; Maturity. There are numerous
illustrations and an index.

“Originally intended as a boys’ life of Burroughs, this is full of the


human, humorous life of the country boy, with the story of the work
and play of the man written in a way to interest readers of any age.”

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