SUB-ATOMIC PARTICLES, ATOMIC MODELS, (c) helium atoms, which impinged on a metal foil and ◄

ejected electrons
ATOMIC NUMBER, ISOTOPES, ISOBARS AND (d) helium nuclei, which impinged on a metal foil and
ISOTONES got scattered
I. Which of the following is wrong? J 2. The nucleus of an atom can be assumed to be spherical
(a) Cathode rays have constant elm ratio. The radius of the nucleus of mass number A is given b;
113
(b) elm ratio of anode rays is not constant. 1.25 x 10- 13 x A cm. Radius of atom is I A. If the mass
(c) elm ratio of protons is not constant. number is 64, then the fraction of the atomic volume that
(d) elm ratio of P-particles is constant. is occupied by the nucleus is
Heaviest particle is (a) 1.0 x 10- 3 (b) 5.0 >< 10- 5
(c) proton (d) electron. (c) 2.5 >< 10- 2 (d) 1.25 x 10- 13
(a) meson (b) neutron
An a-particle is identical with t 3. Which one of the following constitutes a group of the
(a) proton (b) neutron isoelectronic species?
(c) helium nucleus (d) electron. (a) N 2, 0 2- , NO+, CO (b) c/-,
0 2-, CO, NO
4. The ratio of specific charge of a proton and an a-particle is (c) NO\ ct,
CN- , N2 (d) CW, N2, ot, ct
(d) 1 : 1 8
(a) 2 : 1 (b) I : 2 (c) 1 : 4 14. Atomic radius is of the order of 10- cm and nuclear
13
:-. Nuclear theory of the atom was put forward by radius is of the order of 10- cm. The fraction of atom
(a) Rutherford (b) Aston occupied by nucleus is
(c) Neils Bohr (d) J.J. Thomson. (a) 10-5 (b) 105
(c) 10- 1s (d) none of these.
6. Rutherford's experiment on scattering of a-particles

~
showed for the first time that the atom has 15. The number of electrons, protons and neutrons in a species
(a) electrons (b) protons is 18, 16 and 16 respectively. The appropriate symbol for
( c) nucleus (d) neutrons. the species is
7, Rutherford's scattering experiment is related to the size (a) ?ls2- (b) ?ls (c) t~o 2- (d) t~o-
oftbe
(a) nucleus (b) atom 16. The increasing order (lowest first) from the values of elm
(d) neutron. (charge/mass) for electron (e), proton (p), neutron (n) and
( c) electron
alpha particle (a) is
8. When alpha particles are sent through a thin metal foil (a) e,p, n, a (b) n, p, e, a
most of them go straight through the foil because (c) n, p, a, e (d) n, a,p, e
(a) alpha particles are much heavier than electron
(b) alpha particles are positively charged 17. What is wrong about anode rays?
(c) alpha particles move with high velocity (a) Their elm ratio is constant.
(d) most part of the atom is empty. (b) They are deflected by electrical and magnetic field.
( c) They are produced by ionisation of molecules of the
9. Rutherford's alpha rays scattering experiment eventually residual gas.
led to the conclusion that
( d) They do not originate from the anode.
(a) mass and energy are related
(b) electrons occupy empty space around the nucleus 18. The fundamental particles which are responsible for
(c) neutrons are buried deep in the nucleus keeping nucleons together is
(d) the point of impact with matter can be precisely determined. (a) meson (b) antiproton
( c) positron (d) electron.
10. The triad of nuclei which is isotonic is
(a) 14C 1sN 11F (b) 12C 14N 19p 19. Which of the following has highest ionizing power?
6•7•9 6•7•9
(c) 14C 14N !7F (d) 14C 14N 19F
6 , 7 , 9 (a) a-rays (b) P-rays
6 ' 7 , 9
( c) y-rays ( d) All of these
11. Rutherford's experiment, which established the nuclear
model of the atom, used a beam of 20. An ion with mass nwnber 56 contains three units of positi~e
15
(a) P-particles, which impinged on a metal foil and got charge and 30.4% more neutrons than electrons. The ion
absorbed 3
(a) ~~Ni 3+ (b) ~iFe +
(b) y-rays, which impinged on a metal foil and ejected
electrons (c) ~~Co 3+ (d) ~~Cr
3
+

d
Structure of Atom 37

y given to
21. Nuclides ( 13_.6 eV) from the atom. Thus kinetic energ
(a) have same number of protons emitted electron is
(b) have specific atomic numbers (a) 13.6 eV (b) 20.4 eV
(c) have specific atomic and mass numbers (c) 34.0 eV (d) 6.8 eV
(d) are isotopes. nm (violet) to
J I. Visible spectrum extends from 400
,, 180.isotope of oxygen will have 750 nm (red). Hence frequency ratio is
(a) 4/15 (b) 8/15
(a) I 8 protons
(c) 15/8 (d) none of these.
(b) 9 protons and 9 neutrons
(c) 8 neutrons and 10 protons 32. One of the lines in the spectrum of
atomic hydrogen has
1 of this
(d) IO neutrons and 8 protons. wave number 533.16 cm- • What is the frequency
line?
HR'S
DE VE LO PM EN T LEA DIN G TO BO
11 1
6
(a) 5.623 x I0 s-
1 (b) 1.876 x !0 s-
14 1
FOR
MO DEL OF ATOM, BOHR'S MODEL (d) 1.598 x !0 s·
13 1
(c) 1.598 x !0 s-
M
HYDROGEN ATOM AND TOWARDS QUANTU 33. Calculate the number of photons of
light of wavelength

MECHANICAL MODEL OF THE ATOM 3960 A necessary to provide I J of energy.

16
20 (b) 2 x IQ
(a) 2 x !0 18
2J . A photon of wavelength 5000 A strikes a metal surface (c) 2 x !0
15 (d) 2 x I0
energy of
having work function of 2.20 eV. The kinetic 34. The accelerating potential that must
be imparted to a proton
the emitted photoelectron is beam to give it an effective wavelength of 0.05 run is
(a) 4.4 x 10- J
20 (b) 0.425 eV
(wt. of one mole of proton = 1.008 g)
(c) 2.20 eV (a) 0.325 eV (b) 5.205 eV
(d) no electron will be emitted. (c) 52.05 eV (d) 3.25 eV
atom in Lyman
2-L If the shortest wavelength of hydrogen 35. Number of photons emitt
ed in 5 hours by a 50 W sodium
series is x, then longest wave length in Paschen series of
lamp is (Aphoton = 5893 A).
He+ is 2 (b) 4.46 X 10
22
(a) 7.4 X IQ 0 23
9x (b) 36x (c) 36x (d) 59x 24 (d) 5.4 x 10
(a) (c) 2.7 x !0
5 5 7 1
rd is 250 kJ mor •
25. In a hydrogen atom an electron jumps from
3 orbit to 36. Binding energy of electrons in a metal
Ist orbit. What is the energy (in ergs) associated
with the Then threshold frequency of metal is 35 1
38
(a) 3.8 x !0 s-
1 (b) 3.8 x 10 s-
electron before jumping? 12 14 1
(a) -2.417 X w-
12 (b) 2.417 X !0 11
(c) 6.3 x !0 s-
1 (d) 6.3 x IQ s-
12
(c) 2.417 X w- (d) -2.417 X !0
12
wavelength is
37. Electromagnetic radiation with maximum
the ground state
26. Assuming Rydberg constants are equal, (a) ultraviolet (b) radiowave
to
energy of the electron in hydrogen atom is equal (c) X-rays (d) infrared.
state energ y of the electr on in He+
(a) the ground y of orbit
in He+ 38. As we move away from nucleus, the energ
(b) the first excited state energy of the electron 2 (b) increases
ed state energ y of the elect ron in Li + (a) decreases
(c) the first excit 3 d (d) none of these.
Be +. (c) remains unch ange
(d) the ground state energy of the electron in
of 100 mis. The
27. Which of the following is not correct abou
t the product 39. A 0.66 kg ball is moving with a speed
associated wavelength will be (h = 6.6 x34 w-
34
and the principal J s)
of velocity of electron in Bohr's orbit m
or ion? 3 m
(a) 6.6 X 1Q- Z (b) 6.6 X IQ-
quantum number in a hydrogen atom
number. (c) 1.0 X w-
35 (d) 1.0 X w-32 m
(a) It is independent of the principal quantum m
(b) It is independent of the energy of electr on. r to the Bunsen
40. Sodium chloride imparts a yellow colou
(c) It has no dependence of nuclear charge. flame. This can be interpreted due to the
charge.
(d) It varies proportionately with the nuclear
(a) low ionization energy of sodium
number x in yellow vapour
28. The number of photons of light having wave (b) sublimation of metallic sodium to give
velocity tion in
I J of energy source is (Planck's constant = h, (c) emission of excess energy absorbed as a radia
of light= c) the visible region
I
(b) helx (c) -
X
(d) (d) photosensitivity of sodium.
(a) hex hex
he er, the energy
41. With increasing principal quantum numb
29. Frequency of matter wave is equal to adjacent energy levels in H atom
difference between
(a) (K.E. )!2h (b) 2(K.E. )lh (a) decreases (b) increases
(c) (K.E. )lh (d) A (c) remains constant for higher
absorbs 1.50 times (d) decreases for low value of Zand increases
-111 • An electron in H-atom in its ground state value of Z.
its escape
as much energy as the minimum required for
 38
::;:=;. The energy of hydrogen atom in its ground state is
. cc ofnrngnctic -13.6 eV. The energy ~f the level corresponding to the
..S2. Splitting of spectral lines under the mflucn
quantum number n = 5 ts
field is called 1
(a) Stark effect (b) Zeeman cffcc (a) - 0.54 eV (b) - 5.40 eV
th d (c) - 0.68 eV (d) -2.72 eV
(c) Photoelectric effect (d) None of cse.
. s cctrum ofhy rogen
The first emission line in the atomic p 56. The spectrum of He+ is expected to be similar to that of
in the Balmer series appears al (a) H (b) Lt (c) Na (d) He
7R -1
9R - I (b) - cm 57. According to Bohr's theory, the energy required for the
(a) - cm J44
400 SR -I transition of H atom from n = 6 ton= 8 state is
3R - 1 (d) - cm (a) equal to energy required for the transition from
(c) - cm 36
. f th b" f 11 = 5 to n = 7 state
4 d ·us of first orbit, the radtus o n or tt o
•
4-L If r 1s t 11e ra 1 (b) larger than energy required for the transition from
the H-atom will be 2 n = 5 to n =7 state
(a) ,.,,1 (b) ,.,, (c) r/11 (d) ?n .
(c) less than energy required for the transition from
-l:-. If the radius of first Bohr orbit be a0 , then the radius of n = 5 to n = 7 state
third Bohr orbit would be (d) equal to energy for the transition from n = 7 to
(a) 3 x a0 (b) 6 x a0 (c) 9 x a0 (d) 1/9 x a0 . 11 = 9 state.
-16. The electron in an atom 58. An electron is moving in Bohr's fourth orbit. Its de Broglie
(a) moves randomly around the nucleus wavelength is A. What is the circumferenc e of the fourth
(b) has fixed space around the nucleus orbit?
(c) is stationary in various energy levels (a) 2/). (b) 2). (c) 4). (d) 3/)..
( d) moves around its nucleus in definite energy levels.
59. The relationship between energy E, of the radiation with
-l 7. The value of Planck's constant is a wavelength 8000 A and the energy of the radiation with
27 27
(a) 6.6256 x 10- erg s (b) 66.256 x 10- ergs a wavelength 16000 A is
15 23
(c) 6.02 x 10- ergs (d) 3.01 x 10- ergs. (a) £ 1 = 6£2 (b) £ 1 = 2£2
(d) £ 1 = 1/2£2
The radius of hydrogen atom in the ground state is 0.53 A, (c) £ 1 = 4£2
~ 48 the radius of 3 Li 2+ in the similar state is 60. The value of the energy for the first excited state of

r 49
(a) 1.06 A (b) 0.265 A (c) 0.17 A (d) 0.53 A
The third line of the Balmer series, in the emission spectrum
of the hydrogen atom, is due to the transition from the
(a) fourth Bohr orbit to the first Bohr orbit
hydrogen will be
(a) - 13.6 eV
(c) - I.SI eV
(b) - 3.40 eV
(d) -0.85 eV
61 . The most probable radius (in pm) for finding the electron
(b) fifth Bohr orbit to the second Bohr orbit in He+ is
( c) sixth Bohr orbit to the third Bohr orbit (a) 0.0 (b) 52.9 (c) 26.5 (d) 105.8
(d) seventh Bohr orbit to the third Bohr orbit. In hydrogen atom, energy of first excited state is-3.4 eV.
62.
50. The emission spectrum of hydrogen is found to satisfy the Find out the K.E. of the same orbit of hydrogen atom.
expression for the energy change M (in Joules) such that (a) + 3.4 eV (b) + 6.8 eV

E = 2.18X 10-Js(~ -
111
~)J
112 63.
(c) - 13.6 eV (d) + 13.6 eV
2
Ionisation energy of sodium atom is 4. 946 x I 0 kJ m~r •
1

where n 1 = I, 2, 3, ....... and 112 = 2, 3, 4, ....._. . . The wavelength of radiation sufficient to ionise sodium
The spectral lines correspond to Paschen senes if atom is
24
(a) 4 x 10 nm (b) 0.241 nm
(a) 11 1 = I and 112 = 2, 3, 4
(c) 241 nm (d) 400 nm
(b) 11 1 = 3 and 11 2 = 4, 5, 6
d
(c) 111 = I and 112 = 3, 4, 5 64. What is the number of revolutions of an electron in secoo
(d) n 1 = 2 and 11 2 = 3, 4, 5. Bohr's orbit of H-atom in one second? 14
(a) 8.2 X 10 14 (b) 16.4 X 10
51. The energy of the first electron in helium will be 14 4
(a) - 13.6 eV (b) - 54.4 eV (c) 4.1 x 10 (d) 4.1 x 10
(c) - 5.44 eV (d) zero. 65. The ionisation potential of the ground state of hydro~
11
of total kinetic energy atom is 2.17 x 10- ergs per atom. Calculate the ':"av~en hr
52 . In the Bohr's orbit, what is the ratio
of the photon that is emitted when an electron m 3 Bo
and total energy of the electron?
(c) + I (d) ~:.
st
orbit returns to 1 orbit in hydrogen atom. A
(a) - I (b) - 2 2 .
(a) 1370 A(b) 2737 A (c) 1026 A (d) 821
energy of H and Be is
5J . The ratio of the ionisation 66. What is the angular momentum of H-atom or
bital if its
(a) 1 : I (b) I : 3 (c) 1 : 9 (d) I : 16
electron energy is - 3 .4 e V? 34
5-L The radius of second Bohr's orbit is (a) 2.1 x 10-34 Js (b) I.OS x 10- Js
35
(a) 0.053 nm (b) 0.053/4 run (c) 4.2 x 10-34 J s (d) 2.6 x 10- J s
(c) 0.053 x 4 nm (d) 0.053 x 20 run
Structure of Atom 39
2
07. If ionisation energy of H-atom is 13.6 cV, then ionisat
ion 79. Uncertainty in position of an electron (ma'\s = 9.1 x 10- ll g)
4
energy of He + ion is moving with a velocity of 3 x I0 cm/s accurate upto
(a) 13.6 eV (b) 27.2 eV 0.001% will be (Use h/(47t) in uncertainty expression where
27
(c) 6.8 eV (d) 54.4 eV h = 6.626 x I0- erg second)
2+ if (a) 5.76 cm (b) 7.68 cm
68. Calculate the energy of first station ary state of Li (c) 1.93 cm (d) 3.84 cm
1 1
ionisation energy of He + is 19.6 x 10- & J atom- •
is
18
(a) 176.4 x 10- J atom-
1
80. The radiu s of hydro gen atom in the groun d state
2 r state is
18
(b) 4.9 x 10- J atom-
1
0.53 A. The radius of Li + ion in a simila
18 1 (a) 0.53A (b) 1.06A (c) 0.17A (d) 0.265A
(c) 8.7 x 10- J atom-
18 atom- I
(d) 44.1 X 10- J 8 J. What will be the longest wavelength line in Balmer
series
st
61/. If wavelength of J Jine of Balme r series is 6500 A, then of spectrum?
nd (a) 546 nm (b) 656 nm
wavelength of 2 line of Balme r series is
(b) 8775 A (c) 566 nm (d) 556 nm
(a) 4814.8 A
(d) 3250 A = l) is
(c) 180.5 A 82. The Bohr orbit radius for the hydrogen atom (n
, 0. Which energy level of He+ has energy equal to ground approximately 0.530 A. The radius for the first excited
state energy of H-atom? state (n = 2) orbit is (in A)
(b) 2nd (c) 3rd (d) 411i (a) 4.77 (b) 1.06 (c) 0.13 (d) 2.12
(a) Ist
is
83 . The position of both, an electron and a helium atom
1
71. Calculate the energy of H-atom orbital (J atom- ) whose
34 2
10- kg m /sec. known within 1.0 nm. Furthe r the mome ntum of the
angular momentum is 4.2178 x 26 1
electron is known within 5.0 x I0- kg m s- . The minimum
19 19
(a) - 5.45 x 10- (b) - 1.36 x 10-
uncertainty in the measu remen t of the mome ntum of the
19 18
(c) - 87.8 x 10- (d) - 34.88 x 10-
goes helium atom is
72. The radiation is emitte d when a hydro gen atom 1
(a) 8.0 x 10- kg m s- (b) 80 kg m s-
26 1

from a higher energy state to a lower energy state. The 26 1

(c) 50kg ms-
1 (d) 5.0 x l0- kgms -
wavelength of one line in visible region of atomic spectru m
on is
7
of hydrogen is 6.63 x 10- m. Energy difference betwee n 84. The uncer tainty in mome ntum of an electr
5
I x I 0- kg mis. The uncert ainty in its positio n will be
the two states is 34 2
9
(a) 3.0 X 10- l J (b) 1.0 X 10- 18 J (h = 6.62 X I 0- kg m /s)
26
(d) 6.5 10- 7 J (a) 5.27 x 10- m
30 (b) 1.05 x 10- m
(c) 5.0 X 10-IO J X
28
(c) 1.05 x 10- m
28 (d) 5.25 x 10- m
73. If the electron in a hydrogen atom drops from then
=6
d is in which series 85. The de Broglie wavelength of a particle with mass
I g and
to the n = 4 level, the radiation emitte
of lines in the spectrum of atomic hydrogen? velocity I00 mis is 34
35 (b) 6.63 x 10- m
(a) Lyman (b) Balmer (a) 6.63 x 10- m
33 35
(d) Brackett (c) 6.63 x 10- m (d) 6.65 x 10- m
(c) Pasch en
19
th
of 86. For given energy, E = 3.03 x 10- joules corresponding
74. Angular mome ntum of an electron in the n orbit 34 8
hydrogen atom is given by wavelength is (h =6.626 x 10- J sec, c = 3 x 10 m/sec)
(b) 1t/2nh (a) 65.6 nm (b) 6.56 nm
(a) 27tlnh
(d) nh (c) 3.4 nm (d) 656 nm
(c) nhl21t

75. In a hydrogen atom, if the energy of an electron in the ground 87. When greater numbe r of excited hydrog en atoms reach the
nd
state is -13.6 eV, then that in the 2 excited state is ground state
(a) -1.51 eV (b) -3.4 eV (a) greater number ofline s are found in the Lyman series
(e) - 6.06 eV (d) -13 .6 eV (b) the intensity of lines in the Balme r series increases
en (c) the intensity of lines in the Lyman series increases
76. The wavelength of radiation emitted when in a hydrog (d) both (b) and (c).
atom electrons falls from infinit y to station ary state-I
7 orbit of
88. The veloci ty of the electro n in the first Bohr
1
would be (RH = 1.09 x 10 m- )
8 of the electro n
(a) 91 nm (b) 9.1 x 10-8 nm H-atoms is 2.2 x 10 cm/sec . The veloci ty
2 er= 3) is
(e) 406 nm (d) 192 nm in the third Bohr-o rbit of Li + (atomi c numb
8 8
(a) 19.8 x 10 cm/sec (b) 6.6 x 10 cm/sec
7 en
7. If the speed of electron in Bohr's first orbit of hydrog 8 8
(d) 2.2 x 10 cm/sec
is (c) 4.4 x 10 cm/sec
atom be x, then speed of the electron in 3rd orbit
is
(a) x/9 (b) x/3 (c) 3x (d) 9x 89. The energy required to release l electron from He+
(a) +54.4 eV (b) +13.6 eV
78 en
• !he wave nu~be r of first line of Balmer series of hydrog (c) +27.2 eV (d) cannot be predicted.
is 15200 cm . The wave numbe r of the first Balme r line
s
of Li 2+ ion is 90. Ratio of the energ y of a photo n with wavel ength
(a) 15200 cm- 1 (b) 60800 cm- I 3000 A and 6000 A is
(c) 76000 cm- 1 (c) 2 : I (d) I : 6
(d) 136800 cm- 1 (a) I : 3 (b) I : 2
l) I, If Er, £ft and £ , represe nt s the kinetic energie s of an I ti I . When electro magnet ic radiatio n of wavele ngth 300 nm
1
electro n, alpha particle and a proton respect ively, each fall s on the surface of sodium , electro ns arc emitted with a
moving with same de Broglie wavele ngth then kinetic energy of 1.68 x I Os J mor 1• What is the minimu m
(a) £ C' = £ Cl = E/' (b) E, • > E energy needed to remove an electro n from sodium ?
-ft > Ep
(c) £ ft > £ , > Er (d) Ee> £ , > Ea (a) 6.626 X 10- 19 J (b) 3.99 X )Os J mor 1
1 1
Accord ing to Bohr's theory the angula r momen tum for (c) 3.97 X )Os J mar' (d) 3.81 X 10- 19 J
an electro n of 5th orbit is I 02. A microscope using suitabl e photon s is employ ed to locate
2.5/i Sh 25/i an electro n in an atom within a distanc e ofO. I A. What is
( a) - (b) - (c ) - (d) 611
1t 1t 1t 2rr the uncerta inty involve d in the measur ement of its velocity?
l)J_ The metal which gives photoe lectron s most easily is (a) 6.69 x 10 8 mis (b) 5.79 x 10 6 mis
(a) lithium (b) sodium 8
(c) 7.32 x 10 mis (d) 4.42 x 106 mis
(c) calcium (d) cesium .
I OJ. Which of the followi ng proces ses will be accomp anied by
l)-t. Accord ing to photoe lectric effect, the kinetic energy of absorpt ion of energy ?
the ejected electro ns is directly proport ional to (a) Separa ting an electro n from an electro n
(a) wavele ngth of light
(b) Separa ting a proton from a proton
(b) intensi ty of light
( c) Remov ing an electro n from neutral atom
(c) frequen cy of light
( d) Adding an electro n to a neutral atom
(d) velocit y of inciden t radiatio n.
I 04. The ratio of radii of second and third Bohr orbits of
95. If the thresho ld frequen cy of a metal for photoe lectric
hydrog en atom is
effect is u 0 , then which of the following will not happen ?
(a) If freque ncy of the inciden t radiati on is u , then (a) 2: 3 (b) 3: 2 (e) 4: 9 (d) 9: 4
0
kinetic energy of the electro ns ejected is zero. I 05. The wave numbe r of any spectra l line for an electron ic
(b) If frequen cy of inciden t radiatio n is u, the kinetic transiti on in the spectru m is directly propor tional to
energy of the electro ns ejected will be /m - /rn . (a) the velocit y of the electro ns underg oing transiti on
0
(c) If freque ncy is kept same at u, but intensi ty is (b) the numbe r of electro ns underg oing transiti on
increas ed, the numbe r of electro ns ejected will (c) (n 2 - 11 1) where 11 2 and 11 represe nt the princip al
1
increas e. quantu m numbe rs of higher and lower level
(d) If frequen cy of inciden t radiatio n is further increased,
the numbe r of photoe lectron s ejected will increas e.
(d) ( ~ - ~ )
96. Wave numbe r and frequen cy of yellow radiatio n having 111 112
wavele ngth 5800 A are 106. If electron, hydrogen, helium and neon nuclei are all moving
(a) 1.66 x 10- 8 cm- 1 ; 7.21 x 10 14 s- 1
with the velocit y of light, then the wavele ngths associa ted
(b) 1.92 x 10- 4 cm- 1 ; 5.172 x 10 19 s- 1
with these particle s are in the order
(e) 1.724 x 104 cm- 1 ; 5.172 x 10 14 s- 1
(a) electro n> hydrog en> helium > neon
(d) 2.246 x 104 cm- 1 ; 1.72 x 10 10 s- 1
(b) electro n > helium > hydrog en > neon
97. A 200 g cricke t ball is thrown with a speed of (c) electro n< hydrog en< helium < neon
3.0 x 103 cm sec- 1. What will be its de Broglie wavelength? (d) neon< hydrog en< helium < electro n
(a) 1.1 x 10- 32 cm (b) 2.2 x 10- 32 cm 107. Light of wavele ngth ')... shines on a metal surface with
(c) 0.55 x 10- 32 cm (d) 11.0 x 10- 32 cm intensi ty x and the metal emits y electro ns per second
98 . Emissio n transitions in the Paschen series to orbit n = 3 from of average energy , z. What will happen toy and z if xis
double d?
orbitn can be represented as v = 3.29 x 10 15 (Hz)[~-~}
(3) n
(a) y will be double d and z will becom e half.
(b) y will remain same and z will be double d.
The value of 11 if the transiti on is observ ed at 1285 nm ( c) Bothy and z will be double d.
(wavel ength) is ( d) y will be double d but z will remain same.
(a) 3 · (b) 4 (c) 5 (d) 6 108. The radius of which of the followi ng orbit is same as that
99. Which transiti on in the hydrog en spectru m would have of the Bohr's first orbit of hydrog en atom?
the same wavele ngth as the Balmer transiti on 11 = 4 to (a) He+ (11 = 2) (b) Li 2+ (11 = 2)
n = 2 of He+ spectru m? 2
(c) Li + (n = 3) (d) Be3+ (11 = 2)
(a) 11 = 2 to n = 1 (b) n = 4 to n = 3
( c) n = 5 to n = 3 I 09. The total numbe r of atomic orbitals in fourth energy level
(d) 11 = 3 to 11 = 1
ofan atom is
I 00. What is the maxim um numbe r of emissio n lines when (a) 8 (b) 16 (c) 32 (d) 4
the excited electro n of a H-atom in n = 6, drops to the
110. If radius of Bohr's first orbit of He+ is x the radius of
ground state? Bohr's second orbit of hydrog en, is
(a) 6 (b) 15 '
(c) 30 (d) 12 (a) x (b) 2x (c) 4x (d) 8x
Structure of Atom 41

111 . In Bohr series of lines of hydrogen spectrum, the third 122. The KE. of electron in He• will be maximum in
11d
line from the red end corresponds to which one of the (a) 3rd orbit (b) 2 orbit
following inter-orbit jumps of the electron for Bohr orbit (c) I st orbit (d) in orbit with 11 = 00 •
th st
in an atom of hydrogen? l 2J. In H-atom, the electron is de-excited from 5 shell to I shell.
(a) 5 ➔ 2 (b) 4 ➔ I (c) 2 ➔ 5 (d) 13 ➔ 2 How many different lines may appear in line spectrum?
112. A photon of radiation of wavelength 4000 A has an energy E. (a) 4 (b) 8 (c) 10 (d) 12
The wavelength of photon of radiation having energy IN. We can say that the energy of the photon of frequency
0.5E will be u is given by E = hu, where h is Planck's constant.
(a) 2000 A (b) sooo A (c) 4000 A (d) 6000 A The momentum of a photon is p = hi!.., where A is the
11 ~- Time taken for an electron to complete one revolution in wavelength of photon. Then we may conclude that
the Bohr orbit of hydrogen atom is velocity of light is equal to
(a) (Elp) 112 (b) Elp (c) Ep (d) (E!p)2
411:2mr 2 nh
(a) (b) 125. The incorrect angular momentum of an electron is
nh 411:2mr
28/z 14/z 14h 35/z
2mnr 2 h (a) 8n (b) ~ (c) ~ (d) 8n
(c) - 2 -, (d)
11 11- 2mnr
11-L An electron moves around the nucleus in a circle of 126. Suggest two transitions in the atomic spectrum of hydrogen
for which the wave number ratio is I 08 : 7.
radius r. Assuming that the uncertainty of the momentum
(a) First Lyman and first Brackett transition
of electron is of the same order as momentum itself, the
(b) First and second Lyman series transition
momentum of the electron would be
(c) First Lyman and first Balmer transition
(a) ..!!..__(b) 2nhr (c) _..!!_ (d) 4nhr (d) First Lyman and first Paschen transition
4nr 2nr
115. The uncertainty in the velocity of a cricket ball of mass 127. A particle A moving with a certain velocity bas a
I00 g, when uncertainty in its position is of the order of de Broglie wavelength of 1 A.If particle B has mass
IA, would be 25% of that of A and velocity 75% of that of A, then the
(a) 2: 5.27 x 10·24 m s- 1 (b) 2: 2.35 x 10-23 m s- 1 de Broglie wavelength of B will be approximately
(c) 2: 3.16 x 10-22 m s· 1 (d) 2: 8.51 x 10-24 m s- 1 (a) I A (b) 5.3 A (c) 3 A (d) 0.2 A

116. If a proton and an a-particle are accelerated through 128. If the shortest wavelength of H-atom in Lyman series is
the same potential difference, the ratio of de Broglie x. Then longest wavelength in Balmer series of He+ is
wavelengths AP and A0 is 9x 36x x 5x
(a) 2 (b) 1 (c) 2✓ 2 (d) 3
(a) 5 (b) -5 (c) 5 (d) 9
11 7. If the radius offirst orbit ofH-atom is a0, then de Broglie 129. The Vividh Bharati Station of All India Radio, Delhi,
wavelength of electron in 4th orbit is broadcasts on a frequency of 1,368 kHz. Calculate the
(a) 2na0 (b) 16a0 (c) ac/4 (d) 8na 0 wavelength of the electromagnetic radiation emitted by
118. The wave number of last line of Lyman series of hydrogen transmitter. Which part of the electromagnetic spectrum
spectrum is 109674 cm- 1• The wave number of H0 line does it belong to?
in Balmer series of He+ is (a) 21.93 m and radiowave
(a) 438696 cm· 1 (b) 109674 cm- 1 (b) 219 .3 m and radio wave
1 (c) 219.3 m and microwave
(c) 30465 cm· (d) 60930 cm- 1
(d) 219.3mandX-rays
119. The ionization enthalpy of hydrogen atom is
6
1.312 x 10 J mor 1. The energy required to excite the 130. During the ejection of electrons in the presence of light,
electron in the atom from n = 1 to n = 2 is when the frequency of light used, is increased, then
(a) 9.84 x 105 Jmor 1 (b) 8.51 x 105 Jmor 1 (a) KE. of ejected electrons decreases
(c) 6.56 x 105 J mor 1 (d) 7.56 x 105 J mor 1
(b) KE. of ejected electrons increases
120. In an atom, an electron is moving with a speed of {c) threshold frequency increases
600_~s with an accuracy of 0.005%. Certainty with which (d) threshold frequency decreases.
position of the electron can be located is
34 2
(h = 6.6 x 10- kg m s·1, mass of electron em= 9.1 x 10-31 kg) 131. Which diagram best represents the appearance of the line
(a) 1.52 x 10- m 4
(b) 5.10 x 10· 3 m spectrum of atomic hydrogen in the visible region?
(c) 1.92 x 10· 3 m (d) 3.84 x 10· 3 m Increasing wavelength
12 l. Calculate the wavelength (in nanometre) associated with
(a)
a proton moving at 1.0 x 10 3 m s· 1. (Mass of proton I I 111111 I I
27
= 1.67 x 10· _ kg and h = 6.63 x 10-34 J s)
(a) 0.032 (b) 0.40 (c) 2.5 (d) 14.0 (b)
I I 11111
42 (b) 0.229 nm
(a) 0.0289 nm
(d) 289 nm
(rl ] II I I (c) 229 nm

14 I. Lines in an atomic emission spectrum of an element arc

(d) ~ I I I I due lo
(a) excitation of electrons from lower energy levels to
a velocity of" m s-1. For ayrot~n
I P. An electron travels with higher levels
. - to have the same de Broglie wavelength, the velocity will (b) energy of electrons
be approximately (c) excited electrons dropping from higher levels to lower
,. (b) 1840 energy levels
(c) 1840 v (d) v
(a) 1840 ,
-,- (d) nuclear charges.
142. The continuum in an atomic spectrum is due to
D). Match the following · - - --- -
- Column-II
--- (a) wave property of an electron
Column-I
.... - - - --- - - -------
- 6.04 eV (b) ionisation of atom
A . Energy of ground state of (i) (c) interaction of anion with an atom
He+ -- (d) instability of the excited state.
- --
B. I Potential energy offirst orbit (ii) -27.2 eV t 43. If the total energy of an electron in a hydrogen atom in
I of H-atom excited state is - 3.4 eV, then the de Broglie wavelength
18
C. Kinetic energy of second (iii) 8.68 x 10- J of the electron is
excited state of He+ (a) 6.6 x 10- 12 m (b) 3 x 10- 10 m
12
(iv) -54.4 eV (c) 6.6 x 10- 10 m (d) 9.3 x 10- m
D. Ionisation potential of He+
144. Which of the following statements is not correct?
(a) A - (i), B - (ii), C - (iii), D - (iv)
(a) All electromagnetic radiations travel with the same
(b) A - (iv), B - (iii), C - (ii), D - (i)
(c) A - (iv), B - (ii), C - (i), D - (iii) velocity.
( d) A - (ii), B - (iii), C - (i), D - (iv) (b) Matter waves generally have velocity less than
nd electromagnetic waves.
U -L Velocity of the electron in 2 orbit of hydrogen is x. What (c) Matter waves are emitted by material particles.
st 2
is the velocity of the electron in I orbit of Li + ion? (d) Electromagnetic waves are associated with electric
2 3 and magnetic fields but matter waves are not.
(a) -x (b) -x (c) 4x (d) 6x
3 2 18 1
135. Ionisation energy of He+ is 19.6 x 10- J atom- • The 145. Uncertainty principle is valid for
2
energy of the first stationary state (n = l) of Li + is (a) proton (b) methane
1
(a) 8.82 x 10- 17 J atom- 1 (b) 4.41 x 10- 16 J atom- (c) both (a) and (b)
1 15 1
(c) 44.1 x 10- 18 J atom- (d) - 2.2 x 10- J atom- (d) l mm sized platinum particles.
136. The energy required to break one mole of Cl-CI bonds in 146. The number of spectral lines that can be possible when
CI2 is 242 kJ mor 1. The longest wavelength oflight capable electrons in the ?1h shell in different hydrogen atoms return
8 1
of breaking a single Cl-Cl bond is (c =3 x 10 m s- and to the 2nd shell is
NA = 6.023 x 1023 mor 1) (a) 12 (b) 15 (c) 14 (d) 10
(a) 495 nm (b) 594 nm (c) 640 run (d) 700 run
147. A hydrogen like species requires 30.7 eV to excite its
137. The first use of quantum theory to explain the structure electron from second orbit to third orbit. The atomic
of atom was made by number of the element is
(a) Heisenberg (b) Bohr (a) 2 (b) 3 (c) 4 (d) 5
(c) Planck (d) Einstein.
148. The limiting line in Balmer series will have a frequency of
rd th
138. The ratio ofradius of 3 and 4 Bohr's orbits in hydrogen (a) 6.22 x 10 15 s- 1 (b) 7.22 x 10 14 s- 1
atom is (c) 8.22 x 10 s-14 1
(d) 9.22 x 10 14 s- 1
(a) 3 : 4 (b) 3 : 8 (c) 9 : 16 (d) 8 : 9
149. If the electron falls from n = 5 ton = 4 in the H-atom,
139. For the Paschen series, the values of n 1 and n2 in the then emitted energy is
(a) 0.306 eV (b) 12.09 eV
.
expression, M = Rhc ( - 1 - - 1 ) (c) 1.89 eV (d) 0.65 eV
n2 n2
I 2
(a) n 1 = 1, n2 = 2, 3, 4, .......... . 150. Photoelectric effect is the phenomenon in which
(b) n 1 = 2, n2 = 3, 4, 5, .......... . (a) photons come out of a metal when it is hit by a beam
= 4, 5, 6, ..... ... .. . of electrons
(c) n 1 = 3, n2
(d) n 1 = 4, n2 = 5, 6, 7, ......... .. (b) photons come out of the nucleus of an atom under
the action of an electric field
140. Ionisation energy of lithium atom is 5.2 x 10 2 kJ mor' . (c) electrons come out of a metal with a constant velocity
The wavelength of radiation sufficient to ionise sodium which depends on the frequency and intensity of
atom is incident light wave
 {c) 7. {a) 8. (d) 9. (b) 10. (a)
3. (c) 4. {b) 5. {a) 6.
1. (c) 2. (b) (a) 18. (a) 19. (a) 20. (b)
14. (c) 15. (a) 16. (d) 17.
11 . (d) 12. (d) 13. (c) 29. (c) 30. (d)
25. (a) 26. {b) 27 . (c) 28. (d)
21 . (c) 22. (d) 23. (a) 24. (c) 40. (c)
36. (d) 37 . (b) 38. (b) 39. (c)
31 . (c) 32. (c) 33. (d) 34. {a) 35. (c)
47 . (a) 48. (c) 49. (b) 50. (b)
41 . (a) 42. (b) 43. (d) 44. {a) 45. (c) 46. (d)
57 . (c) 58. (c) 59. (b) 60. (b)
51 . (b) 52. (a) 53. (d) 54. (c) 55. (a) 56. {a)
67 . {d) 68. (d) 69. (a) 70. (b)
61 . (c) 62. (a) 63. (c) 64. {a) 65. (c) . 66. (a)
77. {b) 78. (d) 79. (c) 80. (c)
71 . (b) 72. (a) 73. (d) 74. (c) 75. {a) 76. (a)
87. (c) 88. (d) 89. (a) 90. (c)
81 . (b) 82. (d) 83. (d) 84. {a) 85. (c) 86. (d)
97. (a) 98. (c) 99. (a) 100. (b)
91 . (d) 92. (a) 93. (d) 94. (c) 95. (d) 96. (c)
106. (a) 107. (d) 108. (d) 109. (c) 110. (d)
101 . (d) 102. (b) 103. (c) 104. (c) 105. (d)
115. (a) 116. (c) 117. (d) 118.(d) 119. (a) 120. (c)
111 . (a) 112. (b) 113. (a) 114. (a)
125. (d) 126. (d) 127. (b) 128. (a) 129. (b) 130. (b)
121. (b) 122. (c) 123. (c) 124. (b)
134. (d) 135. (c) 136. (a) 137. (b) 138. (c) 139. (c) 140. (c)
131 . (c) 132 . (a) 133. (c)
141 . (c) 142. (b) 143. (c) 144. (c) 145. (c) 146. (b) 147. (c) 148. (c) 149. (a) 150. (d)
151 . (a) 152. (c) 153. (a) 154. (d) 155. (d) 156. (c) 157. (c) 158. (a) 159. (a) 160. (b)
161 . (b) 162. (c) 163. (b) 164. (c) 165. (a) 166. (a) 167. (b) 168. (d) 169. (c) 170. (a)
171 . (b) 172. (a) 173. (c) 174.(c) 175. (a) 176. (a) 177. (a) 178. (b) 179. (d) 180. (a)
181 . (c) 182. (d) 183. (a) 184. (d) 185. (b) 186. (a) 187. (a) 188. (c) 189. (c) 190. (d)
191 . (c) 192. (d) 193. (c) 194. (c) 195. (b) 196. (b) 197 (d) 198. (a) 199. (d) 200. (b)