/

(TiO 2)
(Semiconductor) N-type

()
(photocatalytic)


(photocatalyst)

(photocatalyst)
2 (photo)
(catalyst)

(the activation energy)

(photocatalyst)

(photocatalyst)

()

(hydroxyl radical)
(hydrogen peroxide)
(superoxide anions)

acetaldehyde, benzene, formaldehyde

21

2
(mechanism of photocatalysis)

(valence band)
(conduction band)

(band gap)
Eg


(aqueous phase)
(photooxidation)
(photo)
Eg


(hole) h+vb

ecb h+vb ecb

(recombination)

(solid-liquid interface)

(acceptor) (reduction)
(donor)

(oxidation)

(strong
oxidation)


(photocatalyst) 2
anatase rutile
anatase rutile 4:1
3:1
30 50 /


(photocatalyst)


(photocatalyst)

(apatite)

3

22

 4
5
Apatite

Ca5(PO4)3(F,Cl,
OH) (hexagonal)

()

- (pH)


(dissolved oxygen) (light
intensity)

()

23




sol-gel

,
(visible light)

Fe3+, Cr3+ V3+

Fujitsu Laboratory LTD. Environment clean-up(purification)technology by photocatalyst titanium apatite. [Online] [cite dated


26 February 2009] Available from Internet:

http://jp.fujitsu.com/group/labs/downloads/en/business/activities/activities-3/fujitsu-labs-envtech-003-en.pdf.
Gillam, E; King, R.M. Gillam. The M.&E. handbook Series: college physics V.2. [n.p.] : Macdonald & Evans Ltd, (1971)


p 215-218.
National Institute of Advanced Industrial Science and Technology (AIST), Apatite/TiO 2 Photocatalyst for air purification


and antibacterial/antimold/antifouling. [Online] [cite dated 26 February 2009] Available from Internet: http://www.aist.go.jp/

aist_e/event/ev20033047/paint.html
. .


, 2549, 6-13.

24