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INSTRUCTIONS

Do not break the seal of the question paper booklet before instructed to do so by the invigilator
In each part of the paper, Section-A contains 7 questions, Section - B contains 2 questions & Section-C contains
10 questions. Total number of pages are 12. Please ensure that the Questions paper you have received contains
ALL THE QUESTIONS in each section and PAGES.
SECTION - A
1. Q.1 to Q.5 has four choices (A), (B), (C), (D) out of which only one is correct & carry 3 marks each. 1 mark will be deducted
for each wrong answer.
2. Q.6 to Q.7 are Reasoning type questions, contains Statement-1 (Assertion) & Statement-2 (Reason). Each Questions has
4 choices (A), (B), (C), (D) out of which only one is correct & carry 3 marks each. 1 mark will be deducted for each wrong
answer.
SECTION - B
1. Q.1 is Matrix match type questions. Column-I contains Three (A,B,C) entries and Column-II contains Four (P,Q,R,S)
entries. Entry of Column-I are to be matched with one or more than one entries of Column-II or vice versa. 2 mark will
be awarded for each part of Column-I. NO NEGATIVE marking for this section.
2. Q.2 is Matrix match type questions. Column-I contains Four (A,B,C,D) entries and Column-II contains Five (P,Q,R,S,T)
entries. Entry of Column-I are to be matched with one or more than one entries of Column-II or vice versa. 2 mark will
be awarded for each part of Column-I. NO NEGATIVE marking for this section.
SECTION - C
1. Q.1 to Q.10 are Integer answer type questions (whose answer are upto 4 digits) & carry 4 marks each. NO NEGATIVE
marking for this section.
NOTE : GENERAL INSTRUCTION FOR FILLING THE OMR ARE GIVEN BELOW.
1. Use only HB pencil or blue/black pen (avoid gel pen) for darkening the bubble.
2. Indicate the correct answer for each question by filling appropriate bubble in your OMR answer sheet.
3. The Answer sheet will be checked through computer hence, the answer of the question must be marked by shading the
circles against the question by dark HB pencil or blue/black pen.
4. While filling the bubbles please be careful about SECTIONS [i.e. Section-A (include single correct, Assertion-Reason),
Section-B(include Matrix Match Type) & Section-C (include integer answer type)].
For example if only 'A' choice is
correct then, the correct method
for filling the bubble is
For example if only 'A & C'
choices are correct then, the
correct method for filling the
bubble is
the wrong method for filling the
bubble are
The answer of the questions in
wrong or any other manner will
be treated as wrong.
For example If Correct match
for (A) is P; for (B) is R, S; for
(C) is Q; for (D) is Q, S, T then
the correct method for filling
the bubble is
Ensure that all columns are filled.
Answers, having blank column will be
treated as incorrect. Insert leading zero(s)
if required :
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
'6' should be
filled as 0006
'86' should be
filled as 0086
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
0 0 0 0 A
1 B 1 1 1
2 C 2 2 2
3 D 3 3 3
4 E 4 4 4
5 F 5 5 5
6 G 6 6
7 H 7 7 7
8 I 8 8 8
9 J 9 9 9
A B C D E
A B C D E
P Q R S T
6
Booklet
0 0 0 0 0
1 1 1 1 1
2 2 2 2 2
3 3 3 3 3
4 4 4 4 4
5 5 5 5 5
6 6 6
7 7 7 7 7
8 8 8 8 8
9 9 9 9 9
6 6
Test Code Batch
10+1
10+2
10+3
Crash
Paper
Paper 1
Paper 2
Roll Number
Name
Test Date D D MMY Y
N AME M I DD
L E N A ME L A S T N A ME
D 1 0 0 1 10+1
1
2 8 3 2 3
F I R S T
394,50 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053 www.motioniitjee.com, email-hr.motioniitjee@gmail.com
TARGET IIT - JEE
MOCK TEST 1
PAPER - 1 Duration : 3 Hours Max. Marks : 225
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
(IVRS No. 0744-2439051/52/53 www. motioniitjee.com , email-hr.motioniitjee@gmail.com
Page 2
SECTION - A
STRAIGHT OBJECTIVE TYPE STRAIGHT OBJECTIVE TYPE STRAIGHT OBJECTIVE TYPE STRAIGHT OBJECTIVE TYPE
Q.1 to Q.5 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct
1.
n
Lim

n
n
n
1 n
n
1 n

+
|

\
| +
is
(A) none zero finite (B) zero (C) negative integer (D) does not exist
2. Values of x satisfying sin
1

2 2
1 x (4x 1)
| |

|
\
= 3 3 cos
1
x is/are
(A)

2
3
(B)
(
(


2
3
, 1
(C)
(
(

0 ,
2
3
(D)
(
(

2
3
, 0
3. The period of the function f(x) = [x] + (

+
n
1
x
+ (

+
n
2
x
+......+
n 1
x
n
(
+
(

nx + 17, n N
(where [
*
] denotes greatest integer function)
(A) 1 (B)
n
1
(C)
n
2
(D) Aperiodic
4. Let h(x) be the piecewise linear function as in figure. If there exist real numbers
, & so that
B
A
h(x).f ''(x) dx f(A) f(B) f(0) = + +

for any twice continuously


(A,0) (B,0)
x
y
y = h(x)
(0,C)
differentiable function f, then the value of ( + + ) is equal to
(A)
A
C 2
(B)
B
C 2
(C) 2
|

\
|
+
B
C
A
C
(D) None of these
5. The greatest integer which is less than or equal to the greatest value of
1
3
0
(x 1)(1 x ) .dx + +

is
(A) 1 (B) 2 (C) 3 (D) 4
PART - I [MATHEMATICS]
MOCK TEST - 1 (P-1) (MATHEMATICS)
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
(IVRS No. 0744-2439051/52/53 www. motioniitjee.com , email-hr.motioniitjee@gmail.com
Page 3
[REASONING TYPE] [REASONING TYPE] [REASONING TYPE] [REASONING TYPE]
Q.6 to Q.7 is Reasoning type question, contains Statement - 1 and Statement-2. Each question
has four choices (A), (B), (C), (D) out of which ONLY ONE is correct
6. Statement1 : If f(x) is continuous on [a, b], then there exists a point c (a, b) such that

b
a
dx ) x ( f = f(c) . (b a)
Statement2 : for a < b, if m & M are, respectively, the smallest & greatest values of f(x)
on [a, b], then m(b a)

b
a
dx ) x ( f (b a)M.
(A) Statement (1) is correct and statement (2) is correct and statement (2) is correct explanation for (1)
(B) Statement (1) is correct and statement (2) is correct and statement (2) is NOT correct
explanation for (1)
(C) Statement (1) is true but (2) is false
(D) Statement (1) is false but (2) is true
7. Statement1 :
n
2
) ! n (
! ) n (
is a natural number for all n N.
Statement2 : Number of ways in which n
2
objects can be distributed among n persons equally is
n
2
) ! n (
! ) n (
.
(A) Statement (1) is correct and statement (2) is correct and statement (2) is correct explanation for (1)
(B) Statement (1) is correct and statement (2) is correct and statement (2) is NOT correct
explanation for (1)
(C) Statement (1) is true but (2) is false
(D) Statement (1) is false but (2) is true
SECTION - B
[MATRIX MATCH TYPE] [MATRIX MATCH TYPE] [MATRIX MATCH TYPE] [MATRIX MATCH TYPE]
Q.1 is "Match the Column" type. Column - I Constains three (i.e. A,B, C) entries and column-II contains Four
(i.e. P,Q,R,S) entries. Entry of column-I are to be matched with ONE OR MORE THAN ONE ENTRIES of column-
II or vice versa.
1. Column I Column II
(A) Let g(x) =
t
Lim
t . ln
tan (x 1/ t)
tan x
| | +
|
\
then
1
4
| g(/8) | equals to (P) 2
(B) Let f(t) =

+
t
1
3 / 1 3 3
) x 1 ( x
dx
then
t
Lim
f(t) =
3
2
k
1 k
then k is (Q) 2
1/2
(C) Sum of all possible integral value (s) of m for which the equation (R) 2
1/3
sin x
3
cos x =
m 4
6 m 4

can be valid for some x [0, 2] is (S) 2


1/4
MOCK TEST - 1 (P-1) (MATHEMATICS)
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
(IVRS No. 0744-2439051/52/53 www. motioniitjee.com , email-hr.motioniitjee@gmail.com
Page 4
Q.2 is "Match the Column" type. Column - I Constains four (i.e. A,B, C,D) entries and column-II contains five
(i.e. P,Q,R,S,T) entries. Entry of column-I are to be matched with ONE OR MORE THAN ONE ENTRIES of
column-II or vice versa.
2. Column I Column II
(A) Let f(x) (sin g(x) cos g(x)) + , where is constant of integration (P) y = 2x
is the primitive of sin(ln x). If a =
2 x
lim

f(x) and b = g(e


5
) + g(e
3
) 6,
then point (a, b) lies on the curve (Q) y = x + 1
(B) If the equation sin
1
(x
2
+ x + 1) + cos
1
(x + 1) =
2

has exactly two solution for [a, b), then point (a, b)
lies on the curve (R) y
2
x
2
= 3
(C) Let f(n) =

= = =
n
1 i
i
1 j
j
1 k
1. If a = f(1) and 2b = f(2),
the point (a, b) lies on the curve (S) xy = 0
(D) If a and b are real numbers and 1 + 1 is a root of the equation
x
3
3x
2
bx + a = 0, then point (a, b) lies on the curve (T) y
2
= 4x
SECTION - C
INTEGER ANSWER TYPE INTEGER ANSWER TYPE INTEGER ANSWER TYPE INTEGER ANSWER TYPE
Q.1 to Q.10 are INTEGER ANSWER TYPE Questions. (The answer of each of the questions are upto 4 digits)
1. If & are the roots of the quadratic equation (p
2
3p + 4)x
2
4(2p 1) x + 16 = 0. such that
> 1 > , then number of integral value of p, if its countable otherwise mark zero.
2. For n N, let f
n
(x) = tan
2
x
(1 + sec x) (1 + sec 2x) (1 + sec 4x) ............... (1 + sec 2
n
x) .
If
x 2
) x ( f
lim
3
0 x
= 2
k
then the value of k is
3. Let the image of straight line
2
4 z
5
3 y
3
1 x
=

with plane 2x y + z + 3 = 0 is L & one plane 7x + by


+ cz + d = 0 is such that, it contains the straight Line L and is perpendicular to the plane 2x y +
z + 3 = 0, then b + c + d is
4. For positive integers n, let A
n
=
{ }
1
(n 1) (n 2) ......(n n)
n
+ + + + + , B
n
= {(n + 1)(n + 2)....(n + n)}
1/n
. If
n
n
n
A
Lim
B
=
ae
b
where a, b N and relatively prime then the value of (a + b) is
MOCK TEST - 1 (P-1) (MATHEMATICS)
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
(IVRS No. 0744-2439051/52/53 www. motioniitjee.com , email-hr.motioniitjee@gmail.com
Page 5
5. Let the complex number
1 1
z cos i sin
1000 1000
= + . Find the smallest positive integer n so that z
n
has
an imaginary part which exceeds
1
2
.
6. If the 20
th
term of a H.P. is 1 and the 30
th
term is 1/17, then its largest term is
7. If ABCD is any quadrilateral and P and Q are the midpoints of its diagonal.
If
2 2 2 2 2 2 2
PQ BD AC DA CD BC AB = + + +
, then find the value of .
8. If the polynomial f(x) = 4x
4
ax
3
+ bx
2
cx + 5 where a, b, c R has four positive real zeros r
1
,
r
2
, r
3
and r
4
; such that
1
8
r
5
r
4
r
2
r
4 3 2 1
= + + +
. Then find the value of
4a
19
| |
|
\
9. Let E
1
and E
2
be two Ellipse. The area of the Ellipse E
2
is one - third the area of the quadrilateral
formed by the tangents at the ends of the latus rectum of the ellipse E
3
(E
3
: 5x
2
+ 9y
2
=45). The
eccentricities of E
1
, E
2
and E
3
are equal. E
1
is inscribed in E
2
in such a way that both E
1
and E
2
touch each other at one end of their common major axis. If the length of the major axis of E
1
is
equal to the length of the minor axis of E
2
, then find the area of the ellipse E
2
outside the ellipse E
1
.
10. If the value of the definite integral
n
dx
1 x x
x sin
2
1
0
2
1

=
+


(where n N) then the value of n is
MOCK TEST - 1 (P-1) (MATHEMATICS)
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
(IVRS No. 0744-2439051/52/53 www. motioniitjee.com , email-hr.motioniitjee@gmail.com
Page 6
PART - II [PHYSICS]
SECTION - A
STRAIGHT OBJECTIVE TYPE STRAIGHT OBJECTIVE TYPE STRAIGHT OBJECTIVE TYPE STRAIGHT OBJECTIVE TYPE
Q.1 to Q.5 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct
1. A steel wire of radius r is stretched horizontally between two clamps located at a distance of 2l from
each other. A weight w is suspended from the midpoint of the wire. If x is the descent of the
midpoint of the wire, then strain in the wire, assuming x small is
(A)
l 2
x
2
(B)
l 5
x
2
(C)
l 3
x
3
(D)
l 9
x
2. Six resistances each of magnitude
3
are connected to form a regular polygon of 6 sides each of
length 2 cm. The combination is placed in a magnetic field B = B
0
e
t
perpendicular to the plane of
the polygon. The induced current in the circuit in ampere, given by
(A)
t
0
e
2
B

(B)
t
0
e
3
B

(C) 2 B
0
e
t
(D) 4 B
0
e
t
3. The potential difference in volts between a and b in the circuit shown here is
(A) 16 V (B) 12 V (C) 10 V (D) 8 V
4. Consider a uniform rod of mass 40 kg and length 8 m, pivoted about a point P, 3 m from one end as
shown in Figure. Few external forces are acting on the rod as shown in Figure. Pick out the correct
statement from the following. (Given, g = 10 m/s
2
).
50N
200N
400N 100N
P
3m 5 m
20N
(A) The rod is in neither translational nor rotational equilibrium.
(B) The rod is in rotational equilibrium only
(C) The magnitude of the force exerted by the rod on the pivot is approximately 503 N.
(D) The rod is in rotational equilibrium about P only.
5. Two masses M
1
and M
2
at an infinite distance apart and initially at rest, start interacting gravitationally.
Their velocity of approach when they are at a distance s apart is
(A) proportional to (M
1
+ M
2
) (B) inversely proportional to s
(C) proportional to (M
1
+ M
2
)
2
(D) proportional to
2
1
s

MOCK TEST - 1 (P-1) (PHYSICS)


394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
(IVRS No. 0744-2439051/52/53 www. motioniitjee.com , email-hr.motioniitjee@gmail.com
Page 7
[REASONING TYPE] [REASONING TYPE] [REASONING TYPE] [REASONING TYPE]
Q.6 to Q.7 is Reasoning type question, contains Statement - 1 and Statement-2. Each question
has four choices (A), (B), (C), (D) out of which ONLY ONE is correct
6. Statement - 1 : A body cannot have energy without having momentum but it can have momentum
without having energy
Statement - 2 : Potential energy depends upon configuration whereas kinetic energy depends
upon motion.
(A) Statement (1) is correct and statement (2) is correct and statement (2) is correct explanation for (1)
(B) Statement (1) is correct and statement (2) is correct and statement (2) is NOT correct
explanation for (1)
(C) Statement (1) is true but (2) is false
(D) Statement (1) is false but (2) is true
7. Statement - 1 : When 1 g of water at 100C, is converted to steam at 100C, the internal energy
of the system does not change.
Statement - 2 : From the expression dU = nC
v
dT, if temperature of the system remains constant,
then dU = 0, i.e., internal energy remains constant.
(A) Statement (1) is correct and statement (2) is correct and statement (2) is correct explanation for (1)
(B) Statement (1) is correct and statement (2) is correct and statement (2) is NOT correct
explanation for (1)
(C) Statement (1) is true but (2) is false
(D) Statement (1) is false but (2) is true
SECTION - B
[MATRIX MATCH TYPE] [MATRIX MATCH TYPE] [MATRIX MATCH TYPE] [MATRIX MATCH TYPE]
Q.1 is "Match the Column" type. Column - I Constains three (i.e. A,B, C) entries and column-II contains Four
(i.e. P,Q,R,S) entries. Entry of column-I are to be matched with ONE OR MORE THAN ONE ENTRIES of column-
II or vice versa.
1. In Column I some circuits are given. In all the circuits except in A, switch S remains closed for long
time and then it is opened at t = 0, while for A, the situation is reversed. Column II tells something
about the circuit quantities. Match the items in Column I with those in Column II.
Column I Column II
(A)
L
R
E
S
(P) Induced emf can be greater than E
(B)
L
R
E
S
(Q) Induced emf would be less than E
MOCK TEST - 1 (P-1) (PHYSICS)
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
(IVRS No. 0744-2439051/52/53 www. motioniitjee.com , email-hr.motioniitjee@gmail.com
Page 8
(C)
L
R
E
S
(R) Finally, energy stored in the inductor is
zero
(D)
L
R
E
S
(S) Finally, energy stored in the inductor is
not zero
Q.2 is "Match the Column" type. Column - I Constains four (i.e. A,B, C,D) entries and column-II contains five
(i.e. P,Q,R,S,T) entries. Entry of column-I are to be matched with ONE OR MORE THAN ONE ENTRIES of
column-II or vice versa.
2. The behaviour of a liquid relating to a solid depending on forces of adhesion and cohesion and
gravitational force in tabular form is given below. Now match the items in Column I with those in
Column II.
Column I Column II
(A) Adhesion = cohesion (P) Pressure below the meniscus is lesser than
that above it
(B) Adhesion > cohesion (Q) Pressure belowo the meniscus is same
as that above it
(C) Adhesion < cohesion (R) Pressure below the meniscus is more than
that above it
(D) Radius of the meniscus is more than (S) Insufficient length
the radius of the capillary tube (T) Meniscus is flat
MOCK TEST - 1 (P-1) (PHYSICS)
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
(IVRS No. 0744-2439051/52/53 www. motioniitjee.com , email-hr.motioniitjee@gmail.com
Page 9
SECTION - C
INTEGER ANSWER TYPE INTEGER ANSWER TYPE INTEGER ANSWER TYPE INTEGER ANSWER TYPE
Q.1 to Q.10 are INTEGER ANSWER TYPE Questions. (The answer of each of the questions are upto 4 digits)
1. Two identical balls having like integer charges and placed at a certain distance apart repel each
other with a certain force. They are brought in contact and then moved apart to a distance equal to
half their initial separation. The force of repulsion between them increases 4.5 times in comparison
with the initial value. What is the ratio of the initial charges on the balls ?
2. N cells each of emf e and internal resistance r are arranged in a
ring. Two points including n cells on one side and (N n) cells on
the other side are connected to a capacitor C as shown below.
What is charge on the capacitor C ?
C
n
B
(N n)
A
3. A metal rod of mass 10 gm and length 25 cm is suspended on two springs as shown in Figure below.
The springs are extended by 4 cm. When a 20 ampere current passes through the rod, it rises by 3
cm. Determine the magnetic field assuming acceleration due to gravity to be 10 m/s
2
. Express your
answer in mT.
( )

K K

4. A body of density d floats with a part V


1
of its total volume V immersed in one liquid of density d
1
and
with the remainder of volume V
2
immersed in another liquid of density d such that d
1
> d
2
. The ratio of
volumes immersed in liquid 1 to that in liquid 2. [Given: d = 1.8 g/cm
3
, d
1
= 2.1 g/cm
3
and d
2
= 1.2 g/cm
3
].
5. The Poissons ratio for a material is 0.1. If the longitudinal strain of a rod of this material is 1 10
4
,
what is the percentage error in the volume of the rod in power of 10
2
?
6. A choke coil is needed to operate an arc lamp at 160 V (rms) and 50 Hz. The lamp has an effective
resistance of 5 when running at 10A (rms). What is the inductance of the choke coil in powers of
10
2
?
7. A 2 kmol of an ideal diatomic gas is enclosed in a vertical cylinder fitted with a piston and spring as
shown in figure. Initially the spring is compressed by 5 cm and then the electric heater starts
supplying energy to the gas at a constant rate of 100 J/s. Due to conduction through the walls of
the cylinder and radiation of heat, 20 J/s is lost to the surroundings. what is the approximate
increase in temperature of the gas in 5.1 sec in milli kelvin ? (R = 8.3 J/mol/K)
8. A motor cyclist travelling with a speed of 150 m/s between two rows of buildings hears echo after
every 1 second. The distance between the two rows of buildings is about in unit of 10
2
m (given
velocity of sound in air is 340 m/s) is.
9. An artificial satellite is moving in a circular orbit around the earth with a speed equal to half the
magnitude of escape velocity from the earth. If the satellite is stopped in its orbit and allowed to fall
freely onto the earth, find the speed with which it hits the surface of the earth? [g = 10 m/s
2
].
10. In a youngs double slit arrangement, the distance between the slits is 1.5 mm and the distance of
the screen from the slits is 2 m. How many interference maxima will be observed, if the slit is
illuminated with white light? The wavelength range in white light is 420 nm to 690 nm.
MOCK TEST - 1 (P-1) (PHYSICS)
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
(IVRS No. 0744-2439051/52/53 www. motioniitjee.com , email-hr.motioniitjee@gmail.com
Page 10
PART - III [CHEMISTRY]
SECTION - A
STRAIGHT OBJECTIVE TYPE STRAIGHT OBJECTIVE TYPE STRAIGHT OBJECTIVE TYPE STRAIGHT OBJECTIVE TYPE
Q.1 to Q.5 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct
1. Two liquid A & B on mixing form an ideal solution. At certain temperature, the vapour pressure of
the solution containing 3 moles of A & 1 mole of B is 550 mm Hg. But when 4 mole of A & 1 mole of
B are mixed, the V. P. of the solution thus formed 560 mm Hg. The V. P. of pure liquid A is.
(A) 300 mm (B) 600 mm (C) 400 mm (D) 200 mm
2. Which of following compound having plane of symmetry.
(A)
H
OH
H
HO
(B)
H OH
CO H
2
CO H
2
H OH (C)
C = C
H Cl
Cl H
(D) All
3. Which of the following species is having 2 and 2 bonds in their Lewis structure -
(a) SO
4
2
(b) SO
2
(c) H
2
PO
2

(d) CO
2
4.
N
H
N
H
N
H
(I) (II) (III)
Among these three canonical structures (though more are possible) what would be their relative
contribution into the hybrid:
(A) I > III > II (B) I > II > III (C) III > I > II (D) None
5. The hybridisation of central atom of catioinic part and anionic part of the solid N
2
O
5
molecule are
respectively -
(A) sp
2
and sp
3
(B) sp and sp
2
(C) sp
2
and sp
2
(D) sp
2
and sp
[REASONING TYPE] [REASONING TYPE] [REASONING TYPE] [REASONING TYPE]
Q.6 to Q.7 is Reasoning type question, contains Statement - 1 and Statement-2. Each question
has four choices (A), (B), (C), (D) out of which ONLY ONE is correct
6. Statement-1: The thermodynamic function which determined the spontanity of a process is the
free energy. For process to be spontaneous, the change in free energy must be negative.
Statement-2: The change in free energy is related to the change in enthalpy & change in
entropy. The change in entropy for a process must be always positive if it is spontaneous.
(A) Statement - 1 is true, statement-2 is true and statement-2 is correct explanation for statement-1
(B) Statement -1 is true, statement-2 is true and statement - 2 is NOT the correct explanation for
statement-1
(C) Statement - 1 is true, statement - 2 is false.
(D) Statement - 1 is false, statement - 2 is true.
MOCK TEST - 1 (P-1) (CHEMISTRY)
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
(IVRS No. 0744-2439051/52/53 www. motioniitjee.com , email-hr.motioniitjee@gmail.com
Page 11
7. Statement-1 : Heat of hydrogenation is inversely proportional to stability of isomeric alkene which
give same product after catalytic hydrogenation.
Statement-2 : Higher the stability of alkene greater will be its potential energy.
(A) Statement - 1 is true, statement-2 is true and statement-2 is correct explanation for statement-1
(B) Statement -1 is true, statement-2 is true and statement - 2 is NOT the correct explanation for
statement-1
(C) Statement - 1 is true, statement - 2 is false.
(D) Statement - 1 is false, statement - 2 is true.
SECTION - B
[MATRIX MATCH TYPE] [MATRIX MATCH TYPE] [MATRIX MATCH TYPE] [MATRIX MATCH TYPE]
Q.1 is "Match the Column" type. Column - I Constains three (i.e. A,B, C) entries and column-II contains Four
(i.e. P,Q,R,S) entries. Entry of column-I are to be matched with ONE OR MORE THAN ONE ENTRIES of column-
II or vice versa.
1. Match the column
Column-I Column-II
(A) Addition of HCl can make the (P) CH
3
COONa(aq.)
Buffer solution.
(B) Addition of NaOH can make (Q) NH
3
(aq.)
Buffer solution
(C) Increase solubility when added (R) NH
4
Cl (aq.)
to a saturated solution of CuCO
3
(S) NaHCO
3
(aq.)
Q.2 is "Match the Column" type. Column - I Constains four (i.e. A,B, C,D) entries and column-II contains five
(i.e. P,Q,R,S,T) entries. Entry of column-I are to be matched with ONE OR MORE THAN ONE ENTRIES of
column-II or vice versa.
2. Column-I Column-II
(A) Zn[Fe(CN)
5
NO] (P) Blue colour due to charge transfer
(B) [Fe(H
2
O)
5
NO]SO
4
(Q) d
2
sp
3
hybridisation
(C) Fe
4
[Fe(CN)
6
]
3
(R) paramagnetic compound
(D) K
4
[Fe(CN)
5
O
2
] (S) NO act as positive ligand
(T) Charge transfer metal to metal in complex.
SECTION - C
INTEGER ANSWER TYPE INTEGER ANSWER TYPE INTEGER ANSWER TYPE INTEGER ANSWER TYPE
Q.1 to Q.10 are INTEGER ANSWER TYPE Questions. (The answer of each of the questions are upto 4 digits)
1.
Cl
Cl
2
hv
number of theoritically possible dichloro derivatves (w).
2. Find the ratio of number of lone pairs in N
3

and CO
2
.
MOCK TEST - 1 (P-1) (CHEMISTRY)
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
(IVRS No. 0744-2439051/52/53 www. motioniitjee.com , email-hr.motioniitjee@gmail.com
Page 12
3. A 1.0 g sample containing Fe
3
O
4
and inert impurity was dissolved and treated chemically to reduce
all iron to Fe(II). The final solution required 6 mL of a
29
1
M acidified KMnO
4
solution for complete
oxidation of Fe(II). Hence, percentage of Fe
3
O
4
in the originl sample is.
4. Minimum C atoms required for a alkene to show geometrical isomerims:
5. Find the number of and -bond in the Lewis structure of SO
3

.
6. Air is trapped in a horizontal glass tube by 40 cm mercury column as shown below :
Hg
40 cm
Air
1 atm
If the tube is held vertical keeping the open end up, length of air column shrink to 19 cm. Length in
cm by which the mercury column shifts down is.
7. Sum of stereoisomer in the given compound (a) and (b) are :
Cl Cl
= a (stereoisomer);
Cl
Cl
= b (stereoisomer)
8. The number of furnished permolecule of the complex [Cr(NH
3
)
6
]Cl
3
is/are.
9. A 250 mL flask containing air at 1.0 atm is heated to 100
o
C and then sealed. The flask is cooled to
25
o
C, immersed in water and opened. What valume of water will be drawn back into the flask,
assuming the pressure remains constant ? (Give ans in ml)
10. (i) C OH
CH
3
CH
2
CH
3
H
(W) (major product)
(ii)
(X) PhMgBr (excess)
OH
OH
HO C
O
Sum of number of -hydrogen in (W) + number of moles of PhMgBr consumed (X)
MOCK TEST - 1 (P-1) (CHEMISTRY)

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