394 - Rajeev Gandhi Nagar Kota, Ph. No.

0744-2209671, 93141-87482, 93527-21564

IVRS No. 0744-2439051, 0744-2439052, 0744-2439053 www.motioniitjee.com, email-hr.motioniitjee@gmail.com
1
MOCK TEST - 1
ANSWER KEY WITH SOLUTION
TARGET IIT-JEE
PHYSICS
MATHEMATICS
CHEMISTRY
PAPER - II
SECTION A
1. C 2. B 3. C 4. A 5. A 6. B 7. C
8. C 9. B 10. D 11. C 12. A 13. A
SECTION B
1. (A)T, ; (B)Q ; (C)Q,R,S,T ; (D)R,S
SECTION C
1.

0098 2.

0005 3.

0002 4. 0398 5. 0004 6.

1648 7. 0019
SECTION - A
1. C 2. C 3. B 4. C 5. D 6. D 7. D
8. C 9. A 10. D 11. A 12. A 13. D
SECTION - B
1. AP, BS, CR, DQ
SECTION - C
1. 0008 2. 0011 3. 0001 4. 0000 5. 0006 6. 0005 7. 0006
SECTION - (A)
1. A 2. D 3. C 4. C 5. A 6. D 7. D
8. A 9. D 10. D 11. C 12. D 13. D
SECTION - B
1. A-R,B-S, C-PT, D-Q
SECTION - C
1. 0001 2. 0008 3. 0006 4. 0008 5. 0008 6. 0006 7. 0002
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
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2
SOLUTIONS
MATHEMATICS
SECTION A
1. C
Any point on the line through P(a, 2) is
(a + r cos , 2 + r sin ) & meet the ellipse at A & D
1
4
) sin r 2 (
9
) cos r a (
2 2
=
+
+
+
(4 cos
2
+9 sin
2
) r
2
+4(2a cos + a sin )r+4a
2
= 0
PA
.
PD =
+
2 2
2
sin 9 cos 4
a 4
It cuts the co-ordinate axis at B & C
& PB
.
PC =
cos . sin
a 2
Q PA, PB, PC, PD one in G.P.
so
+
2 2
2
sin a cos 4
a 4
=
cos . sin
a 2
2a sin 2 + 5 cos 2 = 13
1
25 a 4
13
2
+
1 a 6 or a 6
2. B
x = r cos
y = r sin
xdx + ydy = rdr
xdy ydx = r
2
d so

2
r 1
dr
=

d
r = sin( + c)

2 2
y x +
= sin(tan
1
(y/x) + c)
x
2
+ y
2
cos cy sin cx = 0
3. C
Required area =
2
1
|QT ST + TR ST|
=
2
1
) ST QR ( =
2
1
(PR PQ) ST
uuur uuur uuur
=
2
1
) j

2 i

4 ( ) j

4 i

( +
= 7 (square units).
4. A
S
k
=
2
1
.1.k. sin
n 2
k
5. A
m
1
= m
2
z a a b
z a a b

=

....(1)
a
b
O
c
z
m
3
+ m
4
= 0

c o
c o

+
c z
c z

=0 ....(2)
c z =
(zc)
c
c
...(3)
from equation (i)
|
|

\
|

b a
b a
(z a) + z a = ....(4)
from (3) & (4)
) b a (
) b / R a / R (
2 2

(za)+
a
R
2
=
c
R
2

2
c
) c z (
z =
2
c / 1 ab / 1
c / 2 b / 1 a / 1

=
=
=
=
c / R c
b / R b
a / R a
R | a | &
2
2
2
6. B
Using LMVT in [0, 1] to y = f(x)
f (C) =
0 1
) 0 ( f ) 1 ( f

, for some c (0, 1)

) 0 ( f ) 1 ( f e
2
c
=
f(1) 10 =
2
c
e
but
) 1 , 0 ( in e e 1
2
c
< <
1 < f(1) 10 < e
11 < f(1) < 10 + e
A = 11, B = 10 + e, A B = 1 e
7. C
1 4 6
0
4
6
y = 6 / |x + 1|
D(2, 2)
2
y
x
y=x
C(5, 1)
y = 6 x
A(3, 3)
A =

+
3
2
) 1 x / 6 x ( dx + dx
1 x
6
) x 6 (
5
3

\
|
+

=
2
13
6 ln 2 sq. units
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
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3
8. C
In radius of C
1
r =
S

=
3
10
10
5
12
13 13
9. B
k
3
10
= r + r
1
=
3
10
+ r
1
(r
1
is radius of c
2
)
k
3
20
= r
1
....(i)
equation of AC is
5
x
+
12
y
=1
(5,0)
(0,0) (5,0)
(0,k)
(0,12)
(0,10/3) c
1
c
2

r
distance from (0, k) = r
1
k =
5
13
r
1
+ 12
from (i) r
1
=
27
40

r
r
1
=
9
4
(due to symmetry)
radius are in GP with CR 4/9
10. D
sum of the area =
13
180
) 81 / 16 1 (
) 3 / 10 (
2

11. C
12. A
13. A
p = 4
8 + 2 [x] [x]
2
0
([x] 4) ([x]+2) 0
2 [x] 4
y [2, 5)
SECTION B
1. (A)T, ; (B)Q ; (C)Q,R,S,T ; (D)R,S
(A)
! ) 2 x (
e
! x n

l
= 20
! ) 2 x (
! x

= 20
x(x 1) = 20 x
2
x 20 = 0
(x 5)(x + 4) = 0 x = 5
(B) Q 4{x} = x + [x] = x + x {x} ........(1)
5{x} = 2x {x} =
5
x 2
0
5
x 2
< 1 0 x <
2
5
hence [x] = 0, 1, 2
Again from (1) 4x 4[x] = x + [x] 3x = 5[x]
Case-I : If x [0, 1) [x] = 0
3x = 0 x = 0
Case-II : If x [1, 2) [x] = 1
3x = 5 x = 5/3
Case-III : If x (2, 5/2] [x] = 2
3x = 10 x =
3
10
(reject)
number of solutions = 2
Alternatively :
Let x = I + f 4f = I + f + 1 f =
3
21
I = 0, 1 x = 0 & x = 1 +
3
2
=
3
4
(C) Given equation is
x
2
+ 2x(y + g) + y
2
+ 2fy + 4 = 0
2x = 2(y + g) ) 4 fy 2 y ( 4 ) g y ( 4
2 2
+ + +
x = (y + g)
) f g ( y 2 ) 4 g (
2
+
+ 4(g f) = 0 g = f
x = (y + g)
4 g
2

.
g
2
4 g 2 or g 2
(D) If d = 6 ; A = (0, 0); B(6, 0)
Consider a circle with centre A are radius 2(r
1
)
and a circle with centre B and radius 3(r
2
). The
circles will be separated. There will 4 common
tangents at a distance of 2 from A and 3 from B
4 lines |||ly if d = 5; r
1
+ r
2
= 5 3 lines
(0,0)A
(0,2)
(3,0)
B(6,0)
x
y
d=6
Note : |||ly for two intersecting circles
r
2
r
1
< d < r
1
+ r
2
i.e. 1 < d < 5
2 common tangents 2 lines
If d = r
2
r
1
i.e. If d = 1
circles touches internally 1 lines
SECTION C
1. 0098
Let 2
x
= t, then
N
r
= t
6
t
5
t
4
+ t
2
+ t 1
= t
5
(t 1) t
2
(t
2
1) + (t 1)
= (t 1) (t
3
1) (t
2
1)
= (2
x
1) (2
3x
1) (2
2x
1)
Rationalizing given limit :
0 x
Lim

(2
x
1) (2
3x
1) (2
2x
1)
( )
x sin ) 1 x (cos
4 x cos 15

+ +
= 96(log 2)
3
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
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4
2. 0005
f(x) =
4
x
3. 0002
If x = 1 f(y) = (f(1))
y
f(x) = 4
x
so k =
n
Lim
(

+ + + +
n 2
n
.........
2
3
2
2
2
1
3 2
S =
2
1
+
2
2
2
+
3
2
3
+...........+
n
2
n
2
S
=
2
2
1
+
3
2
2
+..........+
n
2
1 n
+
1 n
2
n
+
2
S
=
1 n n 3 2
2
n
2
1
.......
2
1
2
1
2
1
+

|
|

\
|
+ + + +
2
S
=
2 / 1 1
2 / 1

= 1 S =
2
4. 0398
P(x) = (x 17) . (x 24) + x 7 = x + 3
(x 17) . (x 24) = 10
product of roots = 398
5. 0004
In ADC
DC
) z y ( sin +
=
sinC
AD
....(1)
In ABD,
x y z
A
B D E C
BD
x sin
=
AD
B sin
....(2)
and from AEC,
EC
z sin
=
AE
C sin
....(3)
and from ABE
BE
) y x ( sin +
=
AE
B sin
....(4)
From equation (1), (2), (3), (4) we get
z sin x sin
) z y ( sin ) y x ( sin + +
=
AE
BE

AD
DE

BD
AD

EC
AE
=
BD
BE

EC
DC
= 2 2 = 4
6. 1648
We have, for q N,
sin (2q /11) i cos (2q/11) = i[cos (2/11)
+ i sin (2/11)]
q
[using De Moivers theorem]
= i
q
where = cos (2/11) + i sin (2/11)
E =

=
(

10
1 q
11
q 2
cos i
11
q 2
sin
=

=
+ + + =
10
1 q
10 2 q
) .... ( i ) i (
= i
1
) 1 (
10


= i
|
|

\
|


1
11
But
11
= [cos (2/11) + isin (2/11)]
11
= cos (2) + isin(2) = 1 + i0 = 1.
Therefore, E = i
|

\
|


1
1
= i.
Thus, S =
= =
+ = +
32
1 p
32
1 p
p 4
) 2 p 3 ( i ) 2 p 3 (
=
2
33 32 3
+ 2 32 = 1648
7. 0019
(i) f(x) =
1 x x
1 x x
2
2
+ +
+
f (x) =
2 2
2
) 1 x x (
) 1 x ( 2
+ +

a = 2
(ii) y
(

3 ,
3
1
b =
3
1
; c = 3
(iii) I =

+ +
+
1 x x
1 x x
2
2
dx
=

+ +
+ +
1 x x
1 x x
2
2
dx

+ +
+
1 x x
1 x 2
2
dx+

+ + 1 x x
dx
2
= x ln (x
2
+ x + 1)+
3
2
tan
1
|
|

\
| +
3
1 x 2
+C
p = 1, f = 1, g =
3
2
, h = 2, k = 3

b
ac
+
gk
h pf
2

= 19
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
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5
PHYSICS
SECTION - (A)
1. A
RMS value of the supply voltage is
2 2
RMS
) 7 . 70 4 . 141 ( ) 7 . 70 ( V + =
= 100 V
100 2 V
peak
= = 141.4 V
2. D
Mass of mixture m = m
1
+ m
2
Volume of mixtgure v = v
1
+ v
2
=
2
2
1
1
m m

density of mixture =
v
m
|

\
|

+
=
2
2
1
1
2 1
m m
m m
If m
1
= m
2
,
2 1
2 1
2 1
2
1 1
2
+

=

=
m = m
1
+ m
2
= v
1

1
+ v
2

2
or v = v
1
+ v
2

2 1
2 2 1 1
v v
v v
v
m
+
+
= =
If v
1
= v
2
= v, then
2
2 1
+
= = arithmetic mean
3. C
Since H
+
is the lightest of all,it will be deflected
most.
Further, radius ratio of the circular paths of
H
+
, He
+
and O
++
vary as
m
q

H
R
+ :
He
R
+ :
O
R
++ =
1 4 16
: :
1 1 2
= 1 : 2 : 2
4. C
For solid sphere A,
= I, where I is moment of inertia and is
angular acceleration.
=
( )
2
0.12
2 I
1.5 0.2
5

=

= 5 rad/s
2
We have =
0
+ t
A
=
0
t, where is
angular deceleration.
Now = 0
t =
0
24
5

= 4.8 s t
A
= 4.8 s
For hollow sphere with I = 2/3MR
2
, similar
calculation yields t
B
= 8 s.
5. A
In an isobaric process, pressure P = con-
stant
specific heat C = C
p
By first law of thermodynamics,
Q = U + PV
( W = PV for isobaric process)

P
U Q
=
V

Q P Q
V Q U

=


U Q
Q
W
Q

P
W
Q
V
Q
=

6. D
At the end of two seconds
the observer is at a distance of 100 1/2 20
4 = 60 m form C.
The source is at a distance of 120 20 2 =
80 m from C.
The situation is as shown in Figure.
80m
(car)S
C
60m
O(observer)
SO =
2 2
SC CO +
= 100 m
From the figure, cos =
80 4
100 5
=
apparent frequency is
f
app
=
s
v
f
v v cos
| |
|

\
=
( )
330
500
330 20 4 / 5
| |
|

\
= 525.5 Hz
7. D
Here angular momentum is conserved.
Hence I
1

1
= I
2

2
or Mr
1
2

1
= Mr
2
2

2
or r
1
v
1
= r
2
v
2
At P
4
, the value of r is minimum and hence
velocity is maximum. Thus kinetic energy is
maximum at P
4
.
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
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6
8. A
The total mechanical energy, E = K + U, where
K is kinetic energy of the particle here if E =
25 J, K = 25 U
For K to be non - negative U < 25 J which is
the case for < x < 5 and 6 < x < .
9. D
If E = 40 J, K = 40 U
This implies U < 40 J for K to be positive.
But from the plot it is clear that minimum
value of U is 35 J.
Hence this is not possible.
10. D
Hence E = 60 J and as the system is iso-
lated, the total mechanical energy remains
conserved.
It is clear from the given variation that U
varies from 35 J to 50 J.
S0 K = E U will be from 10 J to 95 J.
11. C
The equivalent Circuit is as shown in Figure
below.

2 3
3 4 P
Effective capacitance
d
A
3
2
3
C 2
C C 2
C C 2
C
0
1

= =
+

=
12. D
The equivalent circuit is as shown in figure.
2 1
P
4 3
2 3
Q
The effectie capacitance
C =
2
C
+ C =
2
3
C =
d
A
2
3
0

13. D
Energy stored in the system shown in figure
(i) is
2 0 2
l
V
d
A
3
2
2
1
CV
2
1
U
|

\
|
= =
2 0
V
d
A
3
1
|

\
|
=
Energy stored in the system shown in figure
(ii) is
2 0 2
ll
V
d
A
2
3
2
1
CV
2
1
U
|

\
|
= =

2 0
V
d
A
4
3
|

\
|
=

2 0
l ll
V
d
A
12
5
U U
|

\
|
=
SECTION - B
1. A-R,B-S, C-PT, D-Q
SECTION - C
1. 0001
Let A and a be respectively the area of cross
section of the rectangular block and the circular
hole drilled in it.
Then volume of the block = (A a) 10
Weight of the block = (A a) 10 0.9
Weight of liquid displaced = (A a) h 1, where
h is the depth of block below the water level.
Then by the law of floatation, (A a) 10
0.9 = (A a) h 1
h = 9 m.
Therefore, the minimum length of the rope =
10 9 = 1 m
2. 0008
RMS value =
2
E
2
E =
T
2
0
T
0
E dt
dt

= 64 E = 8
3. 0006
X
L
= 2fL = 2 3.14 750 0.1803 = 850
X
C
=
1
2 fC
= 21.2
Impedance Z = ( )
{ }
1/2
2
2
L C
R X X + = 835
Power P
av
= ( )
2 0 0
rms rms rms
I V R R 20 10
I V V 20
2 2 4 835 835
= = =
= 0.0057 W = 6 mW
4. 0008
V
ac
= V
a
V
C
. That is V
a
i
1
R
1
+ i
2
R
2
= V
c
V
a
V
c
= V
ac
= i
1
R
1
i
2
R
2
Substituting the values we find V
ac
= (10e
2t
)
(2) 4 3 = (20e
2t
12)V
V
ac
at t = 0 is 8V
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
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7
5. 0008
At the instant of maximum compression the
mass is momentarily at rest. Hence the entire
energy of the system resides as P.E. in the
compressed spring. Therefore
2 2
1 1
mv kx
2 2
= where v is the velocity of
the mass attached to the spring.
X = 0.1 m
After head-on collision, the striking mass
returns with energy
1
2
mv
2
where v = 0.6 m/s.
So the available energy for oscillation is less
than
1
2
mv
2
. If A is the amplitude of
oscillation, then
1
2
kA
2
=
1
2
mv
2

1
2
mv
2
A = 0.08 m.
6. 0006
Maximum number of reflection =
x
| |
|
\
l
, where
x
| |
|
\
l
represents the greatest integer function
and
x = 0.5 tan 30 = 0.5
1
3
0.5m
30
30
x
Maximum number of reflection =
3
1 1 0.5 tan30
2
3
=

l
= 2 3 = 6
7. 0002
f =
180
60
= 3 rev/sec, m = 180 gm
d
dt

= 0.5C/s
Power, P =
dW d
dt dt
=
(JH) = J
dH
dt
= Jms
d
dt

=
4.2 180 0.1 0.5 = 37.8 W
Torque, =
P

=
37.8 37.8
2 f 2 3
=

= 2.005 nm
= 2nm
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
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8
CHEMISTRY
SECTION - A
1. C
SO
2
+ H
2
S 2S + 2H
2
O
0
SO / S
0
Cell
2
E E = 0.14 > 0

0
SO / S
2
E > 0.14
2. C
3. B
S
( anti aromatic if S is in plane with
the ring) (8 e)
4. C
2g H
2
= 1 mole of H
2
A total of 1 mole of gas exerts the same pres-
sure of p given the same volume V and tem-
perature T.
1 g of H
2
=
2
1
mole of H
2
2g of D
2
=
2
1
mole D
2
5. D
6. D

C O
C O
O
O

dimerize

(Antiaro compound
are unstable)
7. D
8. C
(A)
N N
H
H
Pentavalent N X
(B)
N N
H
H
H
Pantavalent NX
(C)
N N H H
9. A
(A) Anti aromatic
(B) Non planar (tube shape)
10. D
(A)
OH
H
(B)
H
H
2
+
+
H
(C)
KH
11. A
12. A
13. D
P
1
= 400 KPa P
2
= 100 KPa
V
1
= 0.2 m
3
V
2
PV
2
= constant
Polytropic process
400 (0.2)
2
= 100 (V
2
)
2
V
2
= 0.4
U = 3 PV + 84
U = 403 = 120 KJ
Change in internal energy = 120 KJ
C
m
= C
v
+
x 1
R

= C
V
+
2 1
R

= C
V
R
q = nC
m
T
U = nC
v
T = 120
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9
120 = C
V

|

\
|

R
V P
R
V P
1 1 2 2
q = nC
m
T = C
m
|
|

\
|
v
C
120
= (C
v
R)
( )
1 1 2 2
1 1 2 2
V P V P
R
V P
R
V P
|

\
|

= 120 (0.4 100 0.2 400 )

= 120 (40 80)
q = 120 + 40 = 80 kJ
If heat tranfer : q = 30 kJ
w = U q
= 120 30 = 150 kJ
SECTION - B
1. (A) P, (B)S, (C)R, (D) Q
(A) Pair A Identical
(B) Pair B Positional isomer
(C) Formed by rotation across C C bond so
conformer
(D) They are geometri cal i somer so
diastereomers
SECTION - C
1. 0008
Assume total O
2
= 100
total ve change = 200
total Fe
2+
= 100
but 4 % are vacant
Only 96 are present
Let x Fe
2+
converted into Fe
3+
(96x) 2 + (x 3) = 200
x = 8
8 Fe
3+
are present for 100 O
2
.
2. 0011
O
O
HO
*
*
*
*
*
*
*
*
*
*
*
3. 0001
4. 0000
In B.C.C. tetrahedral viods are not present.
5. 0006
(i) 1 (ii) 5 ]
CO H
2
CO H
2
O
HO C
O
O
CO H
2
HO C
2
+ CO
2

6. 0005
w = p
ext
(V) = 4.157 kJ
w = P
ext
|
|

\
|

ext
1
ext
2
P
nRT
P
nRT
nR(100) = 4.157 10
3
n =
100 314 . 8
4157

= 5
7. 0006
B B
H H
H H H
H
All terminal H-atoms are in same plane i.e.
total 6-atom are in same plane.