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Bai Dieu Kien Thay Du
Bai Dieu Kien Thay Du
bi:
Cu 1: Dng Excel v gin Ellingham ca cc h: Ag2O, CuO, FeO, ZnO, CCO2,
CCO, COCO2 , SiO2, TiO2, Al2O3, MgO, CaO.
Cu 2: Xc nh bng th y nhit thp nht c th kh ZnO n Zn bng C
Cu 3:Xy dng th Frost cho h Clo t th Latimer
Cu 4:Xy dng th Frost cho h Mn trong mi trng axit (Mn, Mn2+, Mn3+, MnO2,
H2MnO4, HMnO4). T nhn xt bn ca Mn(VI)v Mn(III), s dng tnh ton
chng minh nhn xt .
Bi lm:
Cu 1:Ta c:
G 0 = H 0 T S 0 = 694600 + 201*T
H S0 :O 2= 0, 0; Ag (r=) 0,0; Ag 2O =
(r )
30,57KJ / mol
61140(J / mol )
6114 0 +132,38* T
Lp: CH 19 ho hc
H S0 : O2 =0, 0; Cu( r)
S 0 : O2 = 205, 0; Cur(
=0, 0; CuO( r)
)
=155,
2 KJ / mol
=43, 51 J / molK
2Cu + O2 = 2CuO
0
H 0 =2 HCuO
=2 * ( 155,
2)
0
S 0 =2 SCuO
SO20
2 SCu0
=310,
(4 KJ / mol
)
310400
=(
J / mol
)
=184,
58
( J / molK
)
G 0 = H 0 T S 0 =310400
184+, 58 *T
H S0 :O 2= 0,0; Fe (r=) 0,0; FeO=
(r )
272KJ / mol
S 0 :O 2 =205,0; Fe ( )=
r 27, 29; FeO(=
)r 83,3J / molK
2 Fe +O 2 = 2 FeO
H 0= 2
H 0FeO
= 2*(
272)
=
544 KJ
=
( /mol
S 0 = 2S 0FeO S 0O2 2S 0=
92,98 J ( /molK
Fe
0
G 0 = H 0 T S=
544000 J /mol
(
544000
+
92,98*
T
G 0 = H 0 T S 0 = 1270180 + 208,86*T
HV: Nguyn Th Vn Anh
Lp: CH 19 ho hc
H S0 : O 2= 0,0; Si (r =
0,0; SiO 2(r=) 859, 4KJ / mol
)
S 0 : O 2 = 205,0; Si ( r) = 18,70; SiO 2( =
41,84J / molK
r)
Si + O 2 = SiO 2
H 0 = H 0SiO2= 859, 4 KJ
( /mol= ) 859400 J( /mol
S 0 = S 0SiO2 S O0 2 S 0Si= 181,86J( molK
/
G 0 = H 0 T S 0= 859400
+ 181,86*T
H S0 :O =
0,0; Ti (=
2
r)
0,0; TiO=
2(r )
944KJ / mol
S 0 :O 2 =205,0; Ti ( )=
r 30,72; TiO 2(=) r 50,62J / molK
Ti +O 2= TiO 2
H 0= H 0TiO=
2
944KJ
/ =
( mol
0
S 0= S 0TiO2 S 0O2 S=
Ti
0
G 0= H 0 T
S=
944000(
J mol
/
)
185,1J ( molK
/
944000
+
185,1*
T
Lp: CH 19 ho hc
H S0 : O2 =0, 0; C( r)
S 0 : O2 = 205, 0; Cr(
0,
= 0; CO( K)
=5, 69; COK(
110,
= 52 KJ / mol
)
197,
= 91 J / molK
2C + O2 = 2CO
H 0 =2 HCO0
S 0 =2 SCO0
=2 * ( 110,
52)
221040
=(
J)/ mol
2 SC0 179,
= 44
( J / molK
)
SO20
G 0 = H 0 T S 0
H S0 : O2
=221,
(04 KJ / )mol
221040
=
179, 44 * T
=0, 0; CO( K)
S 0 : O2 = 205, 0; CO
K(
=110,
52; CO2 ( K)
)
393,
= 51 KJ / mol
213,
= 64 J / molK
2CO + O2 = 2CO2
H 0 =2 HCO02
2 HCO0
H 0 =2 * ( 393,
51) 2* ( 110,
52)
S 0 =2 SCO0 2
SO20
2SCO0
565,
= ( 98 KJ /) mol
565980
( = )J / mol
=173,
54
( J / molK)
G 0 = H 0 T S0 565980
=
173,+54 * T
H S0 :O 2= 0,0; C (R=) 0,0; CO 2(=
K)
393,51KJ / mol
393510 J ( /mol
0
S 0 = S 0CO S 0O2 S =
C
2,95J( molK
/
0
G 0 = H 0 T S =
393510
2,95*
T
Lp: CH 19 ho hc
100000
-100000
500
1000
1500
2000
2500
COCO2 Zn-ZnO
3000
Fe-FeO
CCO
-300000
CCO2
-500000
Ti-TiO2
Mg-MgO
Al -Al2O3
-700000
Si-SiO2
-900000
Ca-CaO
-1100000
-1300000
Nhit d T
7+
6 4 4 4 4 4 4 4 4 4( ClO73 /Cl42 ) 4 4 4 4 4 4 4 48
+1.20
5+
3+
+1.18
+1.70
1+
+1.63
+1.36
Cl O
Cl O
Cl O
H Cl O
Cl2
Cl
1 4 4 4 4 44 2 4 4 4 4 4 43
E
1 4 4 4 4 4 4 4 4 4 4 4 4 2 4 4 4 4 4( ClO42 /Cl42 ) 4 4 4 4 43
E
( ClO4 /Cl2 )
Bi lm
Lp: CH 19 ho hc
Cl
+
e2C2
l E; =
+
1,36
( Cl /2Cl )
m :
G 1=nE
G1= 4E
F nE
( ClO 2/ HClO)
2E (
( ClO 2/ HClO)
10,06
10,06 F
=
6 F
10,06 F
E( ClO / Cl
=)
/HClO
) Cl
/HClO
) Cl
G1= 4 1,7
F 2 1,63
=
F
6 E( ClO / Cl=
F
)
1,676
10 E( ClO=/
F
Cl )
3
E( ClO =
/Cl )
3
14,78 F
14,78 F
=
10 F
1,478
Lp: CH 19 ho hc
m : G 3 = nE (ClO 2 / ClO F
nE
)
4
F nE
( ClO3 / ClO
2 )
F
4E ( ClO
/ ClO
2 )
F nE (
/ HClO )
G3 = 4 1, 2F 4 1,18F 4 1, 7F
2 1,63=
F
14 E( ClO / Cl
=
F
)
4
19,58 F
=
14 F
2E (
HClO
/
)Cl 2
HClO
/
)Cl 2
19,58
19,58 F
E( ClO / Cl
=)
( ClO
2 / HClO )
1,4
S OXH
(n)
+7
+5
+3
+1
-1
nE
9,8
7,93
5,028
1,63
-1,36
th Frost ca Clo
10
(ClO4)-
(ClO3)-
nE0,V
(ClO2)-
Series1
4
2
Cl2
0
-2
-1 Cl- 0
-2
S OXH
Cu 4:
Lp: CH 19 ho hc
2+
E ( MnO 4 /Mn )
6 4 4 4 4 4 4 4 4 4 4 4 4 4 44
7 4 4 4 4 4 4 4 4 4 4 4 4 4 4 48
E
/ Mn )
6 4 4 4 4 4 4 4 44( MnO
7 24
4 4 4 4 4 4 4 48
+0.56
2
+ 2.27
+ 0.95
+3
+ 1.51
+2
1.18
MnO4
MnO4
MnO2
Mn
1 4
4 4
4 44Mn
2 4
4 4
4 4Mn
43
3+
1 4 4 4 4 4 4 4 4 4 4 44 2 4 4 4 4 4 4( Mn4/Mn4) 4 4 4 43
E
( MnO42/ Mn )
m : G1 = nE
( MnO
4
G1 = 1.
E( MnO
/ MnO24 )
/ MnO24 )
nE
( MnO2
/ MnO
2 )
F 2 E( MnO2
/ MnO
2 )
nE
( MnO
F 1 E( MnO
/ MnO3
/ MnO3
F+ nE
( Mn3 / Mn2
F + 1 E( Mn3 / Mn2
7 E( MnO / Mn ) F = 5, 2 F
4
5, 2 F
= 0, 743
7 F
m: G2 = nE
( MnO2
4
G2 = 2 E( MnO2
4
/ MnO2 )
/ MnO2 )
nE
( MnO
F 1 E( MnO
/ MnO3 )
/ MnO3 )
nE
( Mn3
F 1 E( Mn3
G2 = 4.54
F 0,95 F 1, 51
F 2, 36
+ F
/ Mn2+ )
/ Mn2+ )
nE
F
( Mn2 / Mn0 ) +
F+ 2 E( Mn2 / Mn0 ) +F
4, 64
= F
6 E( MnO2 / Mn ) F = 4, 64 F
4
E( MnO2 / Mn ) =
4
4, 64 F
= 0, 773
6 F
m : G3 = nE
( MnO
G3 = 1 E( MnO
/ MnO3+ )
/ MnO3+ )
F 1 E( Mn3
nE
( Mn3
+
/ Mn2
G3 = 0,
95 F 1,51 F 2,+36 F
/ Mn2
)+
)+
nE
( Mn2
F 2 E( Mn
2
+0
/ Mn
)
+0
/ Mn
)
Mn
/
)
0,1
= F
Lp: CH 19 ho hc
nE
+
( Mn2
F 2+ E( Mn2
G1 = 0,
56 F 4.54
F 0, 95 F 1, 51 2,
F 36F = + 5, 2F
E( MnO / Mn ) =
/M
/ Mn0 )
4 E( MnO / Mn ) F = 0,1F
4
E( MnO2 / Mn ) =
4
0,1F
= 0, 025
4 F
Mn 3+ + 3e Mn; G 4 = n EF = 3E ( Mn3+ / Mn )F
m : G 4=nE
G4= 1E
nE
( Mn 3+/ Mn 2+ )
2E
( Mn 3+/ Mn 2+ )
G4= 1,51F
+
2,36
=F
+2
( Mn
/ Mn0)
+ 2
( Mn
/ Mn0)
0,85F
3E( Mn 3+/ Mn
=)F 0,85 F
0,85 F
=
0,283
3F
Mn 2+ + 2e Mn ;E ( Mn 2+/ Mn
=
1,18
)
E( Mn 3+/ Mn
=)
S OXH
(n)
+7
+6
+4
+3
+2
0
nE
5,2
4,64
0,1
-0,849
-2,36
0
Lp: CH 19 ho hc
5
4
E 0,V
n
3
2
Seri
1
0
-1
-2
-3
MnO2
Mn
0
4
Mn3+
Mn2+
s OXH
(1)
Lp: CH 19 ho hc
2 Mn 3+ + 2 H 2O Mn 2+ + MnO 2 + 4 H+
(2)
Lp: CH 19 ho hc