Paper Batteries Introduction

Rocket Electric R & D Center

http://www.rocket.co.kr

Paper Battery development Paper Battery

For Cosmetic / DDS
Battery Technologies Battery Technologies
Control of electrochemical reaction Control of electrochemical reaction Optimize Configuration (Composition) Optimize Configuration (Composition) Evaluation technologies Evaluation technologies

For RFID tag

Thin Film Technologies Thin Film Technologies

Printing (Spread) process Printing (Spread) process Sealing Technologies Sealing Technologies

Electrochemistry
Potential Window
1.99V -0.76V NHE 1.23V

Zn

MnO2

Active material theoretical capacity

Positive Material Negative Material MnO2 : 308 mAh/g Zn : 820 mAh/g

Reaction mechanism
Zinc Chloride Type 8MnO2 + 8H2O + ZnCl2 + 4Zn 8MnOOH + ZnCl2 + 4Zn(OH)2

ROCKETs Paper Batteries are..

Totally safe
The batteries contain no toxic chemicals, and cannot explode. They are non-flammable and can therefore be freely shipped, stored and disposed of after use.

Environment-friendly
The materials used in ROCKETs Paper Batteries are environmentally safe according to international standards. The batteries do not contain any heavy metals such as mercury, lead or cadmium, so on.

Thin and flexible

The batteries are made of fluent slurry that can paste thin polymer substrate to create a battery that is film shaped and flexible.

Application field I : Cosmetics

Anti-aging and wrinkles ( Dark spots / Discoloration ( Skin lightening / Whitening ( Firming and lifting ( Moisturizing ( ) ) ) )

Prototype Specification for Cosmetic and DDS

Paper Battery
O. C. V : 1.5 V Thickness : 600 and less

Nominal capacity : 1.5 mAh Operating Voltage : 1.2 V Shelf life : 2 year (80%)

Application pp
Cosmetics Drug Delivery System

Removal effect of wrinkles

Before

After 20 minutes treatment with ION PATCH for anti-aging and wrinkles

Iontophoresis mechanism
Drug (Dr-)
Anionic Drug Chamber Patch Stratum Consume Epidermis Dermis (2mm)
Io n
DrDr Dr- Dr- Dr- Dr-DrDrDr- DrDr-Dr Dr- Dr-

Voltage Source Return Electrode

I on I on Ion -

IonIonIonElectric Field

I on

I on

Subdermal Tissue

Mechanism of Drug (Dr-) Depot Formation

LG Ion Patch (For whitening)

ESTEE LAUDER (For wrinkles)

GEL
(GEL)

Ultra-thin film type battery (Ultra-thin film type battery) y)

GEL
(GEL)

Capacity with various discharge load

1.8 1.5

1.8 1.5

Voltage (V)

1.2 0.9 0.6 0.3 0 0 0.4 0.8 1.2 1.6 Capacity (mAh) 2 2.4

V o lta g e (V )

1.2 0.9 0.6 0.3 0 0 0.4 0.8 1.2 1.6 Capacity (mAh) 2 2.4

1.8 1.5

1.8 1.5

V o lta g e (V )

1.2 0.9 0.6 0.3 0 0 0.4 0.8 1.2 1.6 Capacity (mAh) 2 2.4

V o lta g e (V )

1.2 0.9 0.6 0.3 0 0 0.4 0.8 1.2 1.6 Capacity (mAh) 2 2.4

Electrical & Environmental Performance

4

Specific capacity (m Ah/cm 2 )

3 2 1 0 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4

High Drain Characteristics

Discharge current density(mA/cm 2 )

4

High Temp. Aging Characteristics

Capacity(mAh)

3 2 1

Cells were stored at 45

0 0 5 10 15 20 25 30

Storage period(days)

Dependence of temperature on discharge capacity

1.6 1.4 1.2 Voltage (V) 1.0 0.8 0.6 0.4 0.2 0.0 0 25 50 75 Capacity ratio (%) 100 125 150
60 10 40 0 30 -5 20 -10

Typical series connection method

1.5 V 3.0 V

Discharge : constant resistance 4

3.4

V o lta g e (V )

2.6 1.8 1 0 0.5 1 1.5

Theoretical

Experimental

2.5

Capacity(mAh)

Application field II : RFID Active tag

Chemical system : Zinc/ Manganese dioxide Nominal voltage :1.5 volt Nominal capacity :30mAh @C/30 Max. continuous discharge : C/6 Operating temperature : -20 to 60 Storage temperature : -20 to 30 Dimension : 58mm X 650

Pulse discharge pattern

1.6 1.4 1.2 V o lta g e ( V ) 1.0 0.8 0.6 0.4 0.2 0.0 0 60 120 180 240 Time (min) 300 360 420
100 msec 5 min 5 mA 30 mA

Continuous discharge capacity

Constant current 1mA at 21
1.6 1.4 1.2 V o lta g e(V ) 1.0 0.8 0.6 0.4 0.2 0.0 0 5 10 15 20 25 Capacity(mAh) 30 35 40

Thin Film Battery Market Road Map Thin Film Battery

Cosmetics
Freckles Wrinkles Moisturizing Skin whitening Vitamin Protein Drug Delivery System

Medical

Value added

Toys y
Melody card Toys with melody chip Thin display

I T & BT Field
RFID Smart card Kits for bio

Market formative step

Patents
Domestic

0588089 10-2005-0025608 : 2005-61289 : 12

Abroad The electrode of ultra thin manganese battery and manufacturing method thereof (USA) Application No. 11/106,670 (JAPAN) 2005-136-216 The electrode of ultra thin manganese battery and manufacturing method thereof (CHINA) 200510064794.9

Thank you !