Course No: CHE-102 I

Experiment No: 4

Name of the experiment:

QUALITATIVE INORGANIC ANALYSIS
Semi-micro analysis for anions

Date of Performance: 03/11/2009 Date of Submission: 10/11/2009

Name:

RIFAT KHAN

Reg. No: 2008334031 Session: 2008-09 Group: (6)

Semi micro inorganic analysis for anions

Preparation of Na2CO3 prepared soln :

Add to water little amount of of Na2CO3

Saturate
Saturated soln of Na2CO3

Add 0.2 g salt

Heat in water bath for 5 min

Some PPt +some clear soln

Separated the soln

Add distilled water to the ppt ppptresidue

Heat in water bath for 5 min

Add the clear soln to the last one

Now this added soln is prepared for anion test.

Sample 1
Physical analysis :
1) Colour : Blue

2) Physical state : Granulated 3) Solubility : 4) Odour: In cold water No odour.

Inorganic qualitative Chemical analysis for anion of given salt:

Sample - 1 5 drops Na2CO3 prepared soln + water Solution add dil. HCl to acidify(litmus test) + extra 2 drops Acidified soln Solution 2-3 drops of BaCl2 soln White PPt. (BaSO4)

Result : SO42- present . Reaction : SO42- + Ba2+ BaSO4 (white ppt)

White precipitate of barium sulphate, BaSO4, insoluble in warm dilute hydrochloric acid and in dilute nitric acid, but moderately soluble in boiling, concentrated hydrochloric acid.

Sample 2
Physical analysis :
5) Colour : White

6) Physical state : Crystalline solid 7) Solubility : 8) Odour: In cold water No Odour.

Inorganic qualitative Chemical analysis for anion of given salt:

Sample - 2 5 drops Na2CO3 prepared soln + water Solution add dil. H2SO4 to acidify (litmus test) + extra 2 drops Acidified soln Solution 2-3 drops of AgNO3 soln White PPt. (AgCl)

Result : Cl- present . Reaction : Cl- + Ag+ AgCl (white ppt)

Curdy precipitate of silver chloride, AgCl, insoluble in water and in dilute nitric acid, but soluble in dilute ammonia solution, in potassium cyanide (POISON) and in sodium thiosulphate solutions.

AgCI + 2NH3 [Ag(NH3)2]++ Cl[Ag(NH3)2]+ + Cl-+ 2H+ AgCI + 2NH4+

Sample 4
Physical analysis :
9) Colour : Light yellowish

10) Physical state : Crystalline solid 11) Solubility : 12) Odour: In cold water No Odour.

Inorganic qualitative Chemical analysis for anion of given salt:

Sample - 4 5 drops Na2CO3 prepared soln + water Solution add dil. H2SO4 to acidify (litmus test) + extra 2 drops Acidified soln Solution 2-3 drops of AgNO3 soln Yellow, curdy PPt. (AgI)

Result : I- present . Reaction : I- + Ag+ AgI ( Yellow, curdy)

Yellow, curdy precipitate of silver iodide AgI. readily soluble in potassium cyanide and in sodium thiosulphate solutions, very slightly soluble in concentrated ammonia solution, and insoluble in dilute nitric acid.

Sample 6
Physical analysis :
13) Colour : White

14) Physical state : Granulated 15) Solubility : 16) Odour: In cold water No Odour.

Inorganic qualitative Chemical analysis for anion of given salt:

Sample - 6 5 drops Na2CO3 prepared soln + water Solution add dil. H2SO4 to acidify (litmus test) + extra 2 drops Acidified soln Solution 2-3 drops of AgNO3 soln Pale yellow PPt. (AgBr)

Result :

Br- present .

Reaction : Br- + Ag+ AgBr (pale yellow)

Pale-yellow precipitate of silver bromide AgBr, sparingly soluble in dilute, but readily soluble in concentrated ammonia solution. The precipitate is also soluble in potassium cyanide and sodium thiosulphate solutions, but insoluble in dilute nitric acid.

AgBr + 2NH3 [Ag(NH3)2]++ Br[Ag(NH3)2]++ Br-+ 2H+ AgBr + 2NH4+