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Patent Mapping of Oxygen Scavengers Formulation, Application - Group 2 - 120816
Patent Mapping of Oxygen Scavengers Formulation, Application - Group 2 - 120816
Le Tien Dung
Nguyen Thi Nu Duong Thi Hai Hoa
August 17, 2012
OUTLINE
According To Years
Patent Mapping
Oxygen-Scavenger Manufacture Classification of Oxygen Absorbers in Japan Raw materials Commercial applications Formulation
To limit the amount of oxygen available for deteriorative reactions that can lead to reduced functionality of the product
Unspecified (No Assignee of Record) 4% Perfecseal, Inc. 4% General Mills Cereals, LLC 4% Evergreen Packaging Inc. 4% Tenneco Packaging Inc. 6%
PATENT MAPPING
1977 Japanese Oxygen-Scavenger Manufacturers 1978 1979 Mitsubishi Gas Chemical Keplon Oji Kako Toppan 1980 Keplon Tamotsu
Ageless
Freshilizer
Vitalon
Toagosei Chemical Industry Nippon Soda Hakuyo Secule Sansoless Sansocut Modulan Wonderkeep Oxyeater Sequl
PATENT MAPPING
Classification of Oxygen Absorbers in Japan Function Reacant Typical Applications Properties Application Dry; aW < 0.3; tea, nuts Self-working Iron O2 Moisturedependent Pastas Medium aW(aW <0.65); dried beef Absorption Speed 47 days 13 day
3 days at -25C
0.5 day
Catecho
Self-working
PATENT MAPPING
Classification of Oxygen Absorbers in Japan Function O2 & CO2 Reacant Iron and calcium Ascorbic acid O2 & CO2 Organic acid and iron Iron and ethanol on zeolite Typical Applications Properties Application Absorption Speed 38 days 14 days
Self-working Roasted/ground coffee Self-working Moisturedependent Moisturedependent Medium aW(aW >0.3 <0.5); nuts High aW(aW>0.85); cakes High aW(aW>0.85); cakes
O2 & Ethanol
Polymer
polyethylene terephthalate US006083585 polyethylene naphthalate US006083585 Nylon 6 resin US2010/0255231 A1 LLDPE; 1,2-polybutadiene US6287481 B1 EVOH, PVOH, Nylon US6288161 B1 Cellulose, viscose US20040048011
Reactant
cobalt neodecanoate US6287481 B1 iron particulates (4-5um) US2010/0255231 A1 cobalt octoate US6288161 B1 zinc acetate, zinc oxides US6544611 manganese, magnesium US6544611
Additive
Mineral oil US 2010/0255231 A1 Maleic anhydride US6346308 Irgonox 1010 antioxidant US6610215 formaldehyde US20040048011 palladium US20040048011
Photo initiators
OsO4 US6509436 benzophenone masterbatch US6287481 B1
Bulk peanuts
Bakery goods Regenerated collagen sausage casings Several shelf-stable U.S. military ration items NASA (shelf-stable tortillas)
FORMULATION
Formula 1: US 2010/0255231 A1
Components Iron particulates (4-5 um) Sodium bisulfate and sodium chloride composite powder Nylon 6 resin Mineral oil 5 or 20 FreshBlend (oxygen scavenger) Custom Resins Nylene 3411 Surfactan Ratio for weight (%) Function Trade name and Supplier
95 or 80 0.2 wt %
The extruder was set at 2500C for all the heating zones and a die temperature at 2600C
The extruded strands were air cooled. Or optionally water cooled prior to pelletizing.
FORMULATION
Formula 2: US 6682791
Layers A B Thickness 0.5 mils 0.2 mils Component 20% LLDPE*: 80% LDPE** blend
low rate oxygen scavenging material of 9:1 ratio of oxygen scavenging polymer to metal catalyst 20% LLDPE : 80% LDPE blend
low rate oxygen scavenging material of 9:1 ratio of oxygen scavenging polymer to metal catalyst 20% LLDPE : 80% LDPE blend
C
D E
2.5 mils
0.1 mils 0.5 mils
FORMULATION
Formula 3: US 6287481 B1
Components LLDPE 1,2-polybutadiene EPDM rubber 68% 12% 20% Ratio for weight (%) Function The outer layers of the film The inner oxygen scavenging layer The inner oxygen scavenging layer Trade name and Supplier Dowlex 3010, Dow Chemical B830, JSR (Japan Synthetic Rubber) Vistalon 3708, Exxon Exxon
A three-layer oxygen scavenging film was prepared by a flat coextrusion process. The final concentration of cobalt in the scavenging layer of the film was 540 ppm as cobalt metal, and the final concentration of benzophienone was 0 5%
FORMULATION
Formula 4: US 6287481 B1
Components Saran coated PET//EVA/OSL/LLDPE Ethylene/vinyl acetate copolymer layer SBS LDPE EVA 50% 40% 8.54% The OSL layer The OSL layer The OSL layer Ratio for weight (%) 0.48//1.2/0.5 /0.3 mil) Function Trade name and Supplier
Rexene PE1375
Vector8508 from Dexco Chevron PE1017 Quantum
cobalt neodecanoate
benzophenone CaO
0.90%
0.5% 0.050%
Reactant
Photoinitiator The OSL layer
stabilizer
0.01%
CONCLUSION
Oxygen scavengers is active packaging which have two types and mechanisms of action Iron-Based Systems Oxygen Scavenging Polymer Materials. They are mainly used for food and pharmaceutical applications They are the most patented of all active packaging technologies (with at least 50 patents through 1989 and 20 issued from 1990 to 1994) They are important for our life The economics
Health
Environment
REFERENCES
Brody, A. L.; Kline, L. R. and Strupinsky, E. R. Active packaging for food applications. Originally Published by Technomic Published [Online], 2001, 222. Cook, P. 1999. Stealth Scavenging Systems: A Remarkable Breakthrough Technology.Proceedings of OxygenAbsorbers: 2000 and Beyond Conference,
Thank you!
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