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Alcohol Chemistry: Alcoholic Drinks (Ethanol) Solvents Fuels
Alcohol Chemistry: Alcoholic Drinks (Ethanol) Solvents Fuels
Alcohol Chemistry: Alcoholic Drinks (Ethanol) Solvents Fuels
Uses:
Introduction
Draw the FSF and write molecular formulae for: 1. Methanol 2. 2-methylpropan-1-ol 3. 2-methylbutan-2-ol
Naming practice
H H C H H H C H H C H C C H C H H C H H C H H
H O H C HH H C H H
3 - ethyl , 4 - methylheptan - 4 - ol
A homologous series
A family of compounds with the same general formula, similar chemical properties and a graduation in physical properties
Alcohol
H H H C C H H OH
The chemical name for alcohol is ETHANOL: Ethanol is NOT a carbohydrate. Alcoholic drinks are made by fermenting sugar (glucose):
Drink Beer Carbohydrate Barley
% alcohol 3-6
Cider
Wine Whisky Vodka
Apples
Grapes Barley Potatoes
7 10
10 14 35 45 35 - 45
Fermentation
An ENZYME is needed to make this reaction happen - Zymase YEAST (a living organism) contains the enzyme which is needed
Making Ethanol
(C6H10O5)n starch
Enzymes released during germination
C6H12O6 glucose
Enzyme maltase in yeast
C12H22O11
maltose
FERMENTATION
Practical
Burning 5 note
Practical demo
Alcohol Rocket
How much beer contains the equivalent alcohol to one glass of wine? How much beer contains the equivalent alcohol to a single whiskey? Pint for pint, which contains more alcohol, beer or cider? What are the recommended weekly units of drink for men and women? Which organ is chiefly responsible for removing alcohol from the body? List 3 factors which affect how you are affected by alcohol.
How long would it take your body to remove the alcohol consumed by 4 pints of beer? What is the legal driving limit in terms of units of alcohol? If you started drinking at 8pm, and consumed on average 2 pints every hour until 12pm, how long would it take you to be below the legal limit for driving? Explain what causes a hang-over. State 3 long-term effects of excessive alcohol consumption.
Alcoholic Drinks
Drink Beer Cider Carbohydrate Barley Apples % alcohol 3-6 7 10
Wine
Whisky Vodka
Grapes
Barley Potatoes
10 14
35 45 35 - 45
At alcohol concentrations above 15 %, the yeast are poisoned and the enzymes do not work.
Fermentation therefore stops.
Distillation
To produce drinks with a high alcohol concentration, DISTILLATION must be carried out.
Alternative method?
Fermentation is too expensive to produce ethanol on an industrial scale Catalytic hydration of ethene is method used
H3PO4 catalyst 300oC & 70 atmospheres
Ethene + water
Ethanol
C2H4 + H2O
H H H C
C2H5OH
H H H C C H H OH
H
+
C H
OH
Chemistry of dehydration
+
Ethanol Ethene water
H C H C H C H H
H H C H
H C H
H O C H
C H
NAME?
+
H C H H
H O
H H C H C H C H
H C H H
NAME?
Practice
Draw the FSF for the product(s) of hydration of the following alkenes: 3-methylpent-1-ene 2-methylbut-1-ene 2-methylbut-2-ene
Which of the following compounds will produce isomers on dehydration? Hexan-3-ol Heptan-3-ol 2-methylbutan-1-ol