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Processing Chapter 3 Compression Molding
Processing Chapter 3 Compression Molding
Compression Molding
Introduction
In 1907 Dr. Leo Baekeland achieved a reaction between Phenol, a caustic, crystalline acidic compound and Formaldehyde, a colorless, pungent gas, by heating these ingredients under pressure in a reaction kettle. The resultant, hot liquid when cooled, became a hard brittle solid. It lacked physical strength, but possessed excellent thermal, chemical and electrical insulating properties
Introduction
The hard brittle resin in a pulverized from could be mixed with fillers, reinforcement, colorants, lubricants and catalyst. The end product was a molding compound capable of further processing on heated mills and calendar mills. Thus the first thermosetting molding compound was created.
Introduction
In the following years additional thermoset resin systems were developed to meet the requirements of diverse applications in automotive, communications, construction, transportation, household appliances, business machines, aircraft and aerospace fields.
Thermoset Definition:
A polymeric material which can be formed by the application of heat and pressure, but as a result of chemical reaction permanently crosslinks and cannot be reformed upon further application of heat
Chemical crosslinking must occur for the resultant product to be called a thermoset. Monomeric precursors may or may not be polymeric
Thermoset Families
Allyls Aminos Epoxies Phenolics Polyesters Polyurethanes Silicones Crossed linked thermoplastics
Classifications
General Purpose Average mechanical properties, lower resistance to heat, higher coefficient of expansion, low cost and commodity production.(Phenolics, Aminos and polyesters) Engineering Higher mechanical properties and temperature resistance and more durable. More expensive with moderate production rates. (Epoxies and Polyurethanes)
Classifications
Specialty one or more highly specific and unusual properties. Very expensive and produced in small quantities. (Silicones, Allyls, Crossedlinked Thermoplastics)
General Properties
Thermal and dimensional stability Electrical insulation Chemical resistance High flexural modulus Toughness Surface hardness Moldablilty Cost effectiveness
Phenolics
Introduction
First thermosetting plastic, first synthetic commercially available plastic resin Produced by chemical reaction between phenol (resin) and formaldehyde (curing agent) First made by Dr. Leo Baekeland in 1907 By far the most widely used of all thermosets for molding applications
Chemistry
Phenol Formaldehyde resins are general purpose thermosets formed mainly by the polycondensation reaction between phenol and formaldehyde Resole process, other main process is Novalac Raw Materials
Phenol
Formaldehyde
Phenol
Cumene process for making phenol
Formaldehyde
Formaldehyde is produced by the controlled catalytic oxidation of methanol
Phenolic Reaction
Phenolic resin reaction process
Properties of Phenolics
Physical
Excellent dimensional stability Low water absorption High surface hardness High creep resistance
High compressive strength High modulus, stiffness
Mechanical
Properties of Phenolics
Thermal
Phenolics retain a high percentage of properties at elevated temperatures Low coefficient of thermal expansion Good heat resistance
Properties of Phenolics
Electrical
Chemical Other
Introduction
The process used will be determined by which process can produce the part to appropriate specifications at the most economical rate
Compression Molding
Introduction
Uses a hydraulically operated press Press consists of two heated mold platens, one stationary and one movable Platens have either T slots or tapped holes to fix the mold halves to the platens Tie Rods, usually 4, provide for precise alignment as the press is opened and closed The press open and shut height and the platen temperature are controlled.
Compression Molding
Compression presses are rated by their closing force capacities Can be manual, semiautomatic or fully automatic Preform temperature, molding temperature, molding pressure, molding time and cooling time are the most important design parameters
Cavity depth is very important to achieve the proper molded density
Transfer Molding
Similar to compression molding Four basic types
Pot type transfer molding old technology Plunger transfer molding Automatic Transfer molding Screw transfer molding
Mold design provides a pot into which the compound, heated or unheated, is placed and the press closed The clamping pressure exerted by the press also forces the compound from the pot into a runner system, then into the cavity Was innovative, providing an improved means for certain parts and producing less flash at the parting line