Chemistry 210.

002 Spring 2014

MWF 8:00 - 8:50 AM Neckers 240 Instructor: Kevin Smith Phone: 453-6471 Office: Neckers 285 e-mail: ksmith@chem.siu.edu Office Hours: Open door policy or by appointment

Silberberg 3rd Ed.

Textbook, i-clicker response pad, Calculator Required Lecture Materials: Principles of General Chemistry, 3rd ed., Silberberg, McGraw Hill 2013. An i-clicker RF response pad is also required. CONNECT subscription A scientific calculator with log function is required, no cell phones may be used as calculators.

For all students enrolled in the Structured Learning Workshop (CHEM 212), the final grade for both CHEM 210 and CHEM 212 will be based on the total points accumulated from the following sources:

Structured Learning Workshop(CHEM 212) Assigned On-Line Homework Average i>clicker In-Class Response Average Exam Average Final Exam

10% 5% 10% 50% 25%

For Engineering Majors who have been issued an override by the College of Engineering and are not registered for CHEM 212, the final grade for CHEM 210 will be based on the total points accumulated from the following sources (Note: withdrawal from CHEM 212 at any point during the semester will also result in the following grading scheme being utilized):

Assigned On-Line Homework Average i>clicker In-Class Response Average Exam Average Final Exam

5.5% 11.1% 55.6% 27.8%

Grading: Letter grades will be assigned as follows. A 85 100%; B 75 84%; C 65 74%;

D 55 64%;

F 0 54%

Week of 1/13

M Ch 11

W Ch 11-12

F Ch 12

*tentative

1/20
1/27 2/03 2/10 2/17 2/24 3/03 3/10

MLK Day
Ch 13 Ch 14 Ch 16 Ch 16 Ch 17 Exam 2

Ch 12
Ch 13 Ch 14 Ch 16 Ch 16-17 Ch 17 Ch 18 Spring Break

Ch 12
Ch 13 Exam 1 Ch 16 Ch 17 Ch 17 Ch 18

3/17
3/24 3/31 4/07 4/14

Ch 18
Ch 19 Ch 19 Ch 20 Ch 21

Ch 18
Ch 19 Exam 3 Ch 20 Ch 21

Ch 18,19
Ch 19 Ch 20 Ch 21 Ch 23

4/21
4/28 5/05

Ch 23
Review

Ch 23
Review

Exam 4
Review

Final Monday 7:50-9:50AM

Cell Phones Cell phones are considered a classroom disturbance, any cell phone use in the classroom (rings, calls, texting, email) may result in a class wide quiz. A second offense will not be tolerated.

Tardiness Arriving late is considered a classroom disturbance. Excessive tardiness will not be tolerated.

Exams On exam day you will need a pencil (scantrons), calculator (batteries), and a student ID. If you are late, you cant take the exam.

Tips for Success: Read the chapter before class. Foreign language Come to lecture. You are responsible for missed material Review notes. Immediately after class, look over your notes. Fill in details while the topic is fresh. Work problems. Work more problems. Thenwork more problems. Form your own study groups. Exam review sessions. Free tutoring may be available. Make a commitment. Spend 2 hours per credit hour. Ask questions. If you have a question, so do others. Ask in class, during office hours or in lab.

online.siu.edu

Network ID and password

Course selection ?

Use this part of the window to navigate through the different folders

Homework is found under the QUIZZES tab

210 HW Ch11-12 link

i-clicker, +, 2

SIU85*******

http://connect.mcgraw-hill.com/class/k_smith_chem_210_spring_2014

Chapter 11

29

Orbitals?

S
P D F

Valence electrons?

O
Lewis structures?

H2O
Covalent bonds?

Covalent bonds

Hybridization?

Be

Hybridization

p
sp Hybridized

sp

sp

 The two sp hybrid orbitals point in opposite directions. The two unhybridized 2p-orbitals are perpendicular to the sp hybrid orbitals and to each other.

34

Be (Z=4): [He]2s2 + 2Cl (Z=17 ):[Ne]3s23p5 BeCl2

Cl Be

sp-hybridize

Cl

Linear

Hybridized Be: sp

__ __ + 2Cl: . BeCl2 2p 3s 3p

Covalent bonds form from overlap of sp and p orbitals

35

B(Z=5): [He] 2s22p1 + 3F (Z=9 ):[He]2s22p5 BF3

sp2 -hybridize

B F F
Hybridized B atom

Trigonal planar

Isolated B atom

Hybridized B : sp2

__ + 3F: . BF3 2p 2s 2p

Covalent bonds form from overlap of sp2 and p orbitals

36

C (Z=6): [He]

2s22p2 + 4H

(Z=1

):1s1

CH4

H C

sp3 -hybridize

H H

tetrahedral
Covalent bonds form from overlap of sp3 and s orbitals

Hybridized C : sp3

+ 4H: CH4 1s

37

sp3d and sp3d2 Hybridization. VB theory rationalizes the trigonal bipyramid and octahedral arrangements of five and six electron groups by mixing
one 3s-orbital + three 3p-orbitals + one 3d-orbital = five sp3d hybrid orbitals

P(Z=15): [Ne]3s23p3 + 5Cl (Z=17):[Ne]3s23p5 PCl5

Cl Cl P

sp3d-hybridize

Cl Cl

Trigonal bipyramid Cl

Covalent bond forms from overlap of sp3d and p orbitals

Hybridized P : __ __ __ __ + 5Cl: . PCl5 sp3d 3d 3s 3p

38