TRNG I HC M A CHT

KHOA DU KH
B MN LC - HA DU

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N TT NGHIP
TI: NGHIN CU X L BN V TRO BAY LM VT LIU HP
PH V NG DNG X L ION Zn2+ TRONG NC THI

Gio vin hng dn:

Sinh vin thc hin: PHAN VN TI

TS. TNG TH THANH HNG

Lp : Lc Ha du A K54

H NI, 6/2014
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NI DUNG
TNH CP THIT CA TI
TNG QUAN
THC NGHIM
KT QU V THO LUN
KT LUN
2

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1. TNH CP THIT CA TI

TNH CP THIT CA TI

Nguyn liu bn
qua x l bng
qu trnh cacbonat
ha.
Vt liu
tng
hp
Tro bay

Nc
nhim
cha ion
Zn2+

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Mi trng
nc sch
hn

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2.

TNG QUAN

GII THIU V BN V TRO BAY

* Thnh phn ha hc pha rn ca bn :
ST
T

Thnh phn

Al2O3

5 - 25

SiO2

1 20

Fe2O3

25 - 60

TiO2

1 - 10

H2O (lin kt)

5 - 15

CaO

2-8

Na2O

1 - 10

Hnh nh Bn th
6

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GII THIU V BN VTRO BAY

* Thnh phn ha hc ca tro bay:
Thnh phn ho hc

SiO2
Al2O3
Fe2O3

40-60
20-30
10-40
5-30
0-5
0-4
0-4
0-3

CaO
MgO
SO3

Na2O
K2O
Than cha chy

0-3

Hnh nh tro bay t nh my ph li

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NGUN GY NHIM KIM LOI TRONG NC THI
Ngun gy nhim kim loi trong nc thi.

Nc thi t cc khu
cng nghip cha
qua x l hoc x l
khng t yu cu

Nc thi
nhim
kim loi
nng

Hnh nh v nhim kim loai nng.

8

Trong cht thi khi khai

thc qung khong sn.

Nc thi t cc thnh ph
ln, trong nng nghip v
giao thng.

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3.

THC NGHIM

X L S B TRO BAY V BN

X l s b tro bay:
Sy kh nhit
1000C trong khong

Tro bay c x
l

12h.

X l s b bn :
Bn
dng bn
thi t

Ly tm vi tc
2400 vng/pht
trong thi gian 15
pht

Mu bn

nghin mn

Ra bng nc
ct nhiu ln
n khi t pH
= 8 8,5

em lc, sy
kh 1050C

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X L S B TRO BAY V BN
* Mt s hnh nh thu c sau qu trnh:

Bn thi t

Bn qua s l
Bn qua x l
bng qu trnh cacbonat
ha phc v cho nguyn
cu.

Bn thi
t

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QU TRNH TNG HP VT LIU HP PHLOGO

* S tng hp vt liu hp ph:
Giai on 1: to
dng ht

Nn thnh
ht nh c
kch thc
t 4 - 4,5
mm v
phi kh

Giai on 2: nung n nh vt liu

cc nhit khc nhau

Nung 950oC

12

Mu VL850

Phn 3
trong 10 pht

Mu VL700

Phn 2

Nung 850oC

Nung 700oC

Thm
0,75g tro
bay

trong 10 pht

Cn 4,25g bn
c x
l bng qu
trnh cacbonat
ha

Phn 1

trong 10 pht

Trn
thnh bt
nho

Mu VL950

QU TRNH TNG HP VT LIU HP PH

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Hnh nh vt liu trc khi x l

Hnh nh vt liu sau khi x l 700oC

Hnh nh vt liu sau khi x l 8500C

Hnh nh vt liu sau khi x l 950oC

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QU TRNH TNG HP VT LIU HP PH

*

S qu trnh hp ph ion Zn2+ ca vt liu

Vt liu (0,2g) VL700, VL850, VL950

Dung dch ZnCl2

Khuy trong thi gian xc nh

Ly tm loi b phn rn

o AAS xc nh nng Zn2+ trong dung dch cn li

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4. KT QU V THO LUN

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Kho st kh nng hp ph ion Zn2+ ca cc vt liu.

Kt qu xc nh hm lng ion Zn2+ trong th nghim nh gi kh nng hp ph ca 3 loi vt liu.

Vt liu
VL700
VL850
VL950

C0 (mg/l)

m (g/l)
2
2
2

24,7
24,7
24,7

Vi:

qt =

Ct (mg/l)

qt (mg/g)

18,3
20,7
16,3

3,2
2,0
4,2

Co - C t
m

Trong :
qt: l dung lng hp ph ca vt liu ti thi im t (mg/g)
2+ trong dung dch ban u (mg/l)
Co: l nng ion Zn
C
2+ trong dung dch ti thi im t (mg/l)
t: l nng ion Zn
m: l khi lng vt liu hp ph trong 1lt dung dch (g/l)
T bng trn ta suy ra c th di y:

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q (mg/g)
5
4
3
2

q (mg/g)

1
0
VL700
VL850
VL950

th biu th dung lng hp ph ion Zn2+ trn cc vt liu

Nhn vo th, ta thy rng: Trong cc loi vt liu th VL 950 c kh nng hp ph ion km tt nht.
Do ta s chn loi vt liu ny kho st nh hng ca cc yu t tip theo.

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XC NH CU TRC BNG PHNG PHP NHIU

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X TIA RNGHEN (XDR)

Gin nhiu x tia X ca vt liu

cha qua x l

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Gin nhiu x tia X ca vt liu

VL950

C TRNG HNH THI HC CA SEM

Hnh nh SEM vt liu cha qua x l

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Hnh nh SEM ca vt liu qua x l

950oC

NH GI KH NNG HP PH ION Zn2+ CA VT LIU VL950

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nh hng ca nng ion Zn2+n qu trnh hp ph ca vt liu.
STT

C0 (mg/l)

m (g/l)

Ct (mg/l)

qt(mg/l)

5,8

3,36

1,22

12,3

9,28

1,51

16,2

11,52

2,34

20,5

15,38

2,56

24,7

16,4

4,15

30,5

24,1

3,20

35,4

29,54

2,93

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NH GI KH NNG HP PH ION Zn2+ CA VT LIU VL950

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nh hng ca PH n qu trnh hp ph:
pHa

C0(mg/l)

m (g/l)

Ct (mg/l)

qt (mg/g)

24,7

15,7

4,5

24,7

15,5

4,6

24,7

16,1

4,3

24,7

16,5

4,1

24,7

17,7

3,5

24,7

18,7

3,0

24,7

19,5

2,6

24,7

20,2

2,25

24,7

20,7

2,0

10

24,7

21,2

1,75

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Ct(mg/l)

PH

NH GI KH NNG HP PH ION Zn2+ CA VT LIU VL950

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nh hng ca thi gian n qu tnh hp ph:

STT

Thi
gian(pht)

C0 (mg/l)

m (g/l)

Ct (mg/l)

qt (mg/g)

25

24,7

20,1

2,30

60

24,7

18,4

3,15

87

24,7

17,5

3,60

125

24,7

17,2

3,75

150

24,7

16,9

3,90

180

24,7

1,63

4,20

210

24,7

16,16

4,27

240

24.7

16,0

4,35

275

24,7

15,7

4,50

10

300

24,7

15,6

4,55

11

325

24,7

15,6

4,55

12

360

24,7

15,6

4,55

13

390

24,7

15,6

4,55

14

425

24,7

15,6

4,55

22

t(pht)

qt(mg/g)

Co(mg/g)

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5.

KT LUN

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KT LUN

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Qua qu trnh thc hin ti Nghin cu x l bn v tro

bay lm vt liu hp ph v ng dng x l ion Zn2+ trong nc thi,
n thu c nhng kt qu sau y:

to c vt liu hp ph trn c s bn v tro bay.

Tm hiu v xut t l bn v tro bay trong mu vt liu.
Kho st, la chn iu kin nhit nung ph hp to vt liu hp ph ion kim loi trn c s bn v
tro bay.

Trn c s cc phn tch c trng cu trc vt liu (XRD, SEM), nh gi kh nng hp ph ion Zn2+ trn 3
loi vt VL
c chun b
700, VL850 v VL950, la chn c vt liu ph hp nht, l vt liu VL950
vi t l bn : tro bay l 85 : 15.

kho st c cc yu t nh hng n qu trnh hp ph ion km ca vt liu. Cc iu kin ph hp cho

qu trnh hp ph trong phm vi kho st l:

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KT LUN

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Thi gian tip xc ph hp: 300 pht

Nng u ion km ph hp: C0 = 24,7mg/l

pH ban u ca ion km ph hp l: pH = 2
Vt liu hp ph iu ch t bn v tro bay hon ton ph hp vi vic x l ion
2+ trong nc thi.
Zn

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XIN CHN THNH CM N THY C V CC

BN

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