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AP Chapter 16 Acid - Base Equilibria
AP Chapter 16 Acid - Base Equilibria
AP Chapter 16 Acid - Base Equilibria
AP Chapter 16
Brnsted-Lowery
Acids and Bases
Bronsted-Lowery definitions state that
acid-base reactions involve the
transfer of hydronium ions (H+) from
one substance to another.
A hydronium ion is simply a proton
with no surrounding valence
electrons.
Remember acids donate and bases
accept!
Hydronium
ion
Brnsted-Lowery definitions
ACID
Acids
donate
protons
BASE
Bases
accept
protons
Amphoteric
An amphoteric substance is a
substance that can act as either an
acid or a base.
Relative Strengths
of Acids and Bases
Acid-Base Equilibrium
Autoionization of Water
Kc = [H3O+][OH-]
pH Scale
pH = -log[H+]
Neutral solution:
pH = -log(1.0 x 10-7) = -(-7.00) = 7.00
The pH
Scale
The pH Scale
Calculating the pH of a
Basic Solution
Calculate the pH of a basic solution, where the
[OH-] > 1.0 x 10-7 M. Suppose [OH-] = 2.0 x10-3 M.
Calculate the H+ value for this solution.
[H+] =
Kw
[OH-]
1.0 x 10-14
2.0 x 10-3
= 5.0 x 10-12 M
pH and pOH
Measuring pH
pH meter
Acid-base indicators (less precise)
Methyl
orange
Litmus
phenolphthalein
Etc.
Calculating the pH of a
strong acid
pH = -log(0.040) = 1.40
Strong Bases
Common strong bases are the ionic
hydroxides of alkali metals and the
heavy alkaline earth metals.
The cations of these metals have
negligible acidity.
Weak Acids
[H3O+][A-]
[HA]
Polyprotic Acids
Polyprotic acids have more than one
ionizable proton, such as H2SO3.
These acids have acid-dissociation
constants that decrease in magnitude
in the order Ka1>Ka2>Ka3.
Because nearly all the H+(aq) in a
polyprotic solution comes from the
first dissociation, the pH can usually
be estimated using only Ka1.
Weak Bases
Weak bases include NH3, amines and
the anions of weak acids.
Kb = the dissociation constant for the
base.
The relationship between the strength
of an acid and the strength of its
conjugate base is expressed by the
equation Ka x Kb = Kw
Using Kb to Calculate OH
[NH4+][OH-]
= 1.8 x 10-5
[NH3]
Hydrolysis
Acid-base properties of salts can be
attributed to the behavior of their respective
cations and anions.
The reaction with water, with a resulting
change in pH, is called hydrolysis.
Cations of alkali metals and alkaline earth
metals and anions of strong acids dont
hydrolyze.
Salt + water = acid + base
Bond Strength
Strong bonds do not dissociate as
easily as weaker bonds, so they are
less likely to form acidic ions in
solution.
Since HF has such a strong bond due
to the electronegativities, it does not
dissociate readily and is therefore a
weak acid.
Oxyacids
Oxyacids are acids in which OH
groups and possible additional oxygen
atoms are present.
What determines whether it is an acid
or a base?
Generally, as the electronegativity of
the attached element increases, so
will the acidity of the substance.
Oxyacids
Electronegativity
Carboxylic Acids