Petrochemical Technology (TKK-2130)

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13/14 Spring Semester

Petrochemical Technology
(TKK-2130)

Instructor: Rama Oktavian


Email: rama.oktavian86@gmail.com
Office Hr.: M.13-15, Tu. 13-15, W. 13-15, Th. 13-15, F. 09-11

Outlines

1.
1. Polymer
Polymer industry
industry
2.
2.Polymerization
Polymerization process
process
3.
3. Polypropylene
Polypropylene
4.
4. Recent
Recent status
statusand
and technology
technology

Petrochemical industry

Petrochemical industry in Indonesia


Petrochemicals are chemical products derived from petroleum and other
hydrocarbon sources.
Polymers are substances containing a large number of structural units
joined by the same type of linkage. Polymer consists of combination of
monomer

Petrochemical industry

Polymer industry in Indonesia


There are mainly six polymer product comodities

1.
2.
3.
4.
5.
6.

Polyethylene
Polypropylene
Polyvinyl chloride
Polyethylene terephthalate
Polystyrene
Polycarbonate

Polymer industry

Polymer industry in Indonesia


Amoco Mitsui PTA Ind PT
Products: Purified Teraphthalic Acid
Asahimas Chemical PT
Products: polyvinyl chloride
Chandra Asri PT
Products: LLDPE, HDPE, Polypropylene
Dover Chemical PT
Products: Polyvenil Acetate
DOW Chemical Pacific Ltd PT
Products: Polysterene
Mitsubishi Chemical Indonesia PT
Products: PET Resin

Polymer industry

Polymer industry in Indonesia


Pacific Indomas Plastic Ind (PIPI) PT
Products: Polystrene
Polypet Karya Persada PT
Products: Poly Ethilene Terapthalic (PET)
Polyprima Karya Reksa PT
Products: Pure Terepthalic Acid (PTA)
Standar Toyo Polymer PT
Products: PVC Resin Homo Polymer
TITAN Petrokimia Nusantara PT
Products: Polyethylene

Petrochemical industry raw


materials
1. Petroleum
2. Hydrocarbon sources

Polymerization
Polymerization reaction
1. Initiation step
2. Propagation step
3. Termination step

Polymerization
Initiation step
First step reaction due to pressure and heat

H2C

H2C

80 - 90 oC
23 kg/cm

Polymerization
Propagation step
Reaction of free radical with monomer

H
C
H

H
C
H

+ H2 C = H2 C

80 - 90 oC
23 kg/cm

Polymerization
Termination step
Monomer chain aggregation

80 - 90 oC
C

C 23 kg/cm2

Polypropylene
Polypropylene basic
polypropylene is a valuable polymer and is used as plastic for
making pipes, ropes, fibres, etc
It is manufactured by catalytic reaction in a stirred tank reactor, where Ti
and aluminium halides are used as catalysts at a temperature of
60C70C and a pressure of 12 MPa

Polypropylene

Petrochemical products demand in Indonesia

Polypropylene

Petrochemical products demand in Indonesia

Polypropylene supply and demand

Polypropylene

Polypropylene supply and demand

Polypropylene

Polypropylene supply and demand

Polypropylene

Polypropylene supply and demand

Polypropylene

Polypropylene supply and demand

Polypropylene

Polypropylene supply and demand

Polypropylene

Polypropylene

Polypropylene recent status and technology


Methanol-to-Propylene Technology
two reaction steps
1. Methanol dehydration to DME on an aluminium catalyst
2. Transforming DME or methanol into a variety of olefins. The use of ZSM-5
catalyst yields propylene. Propylene will be processed further into
polypropylene

Polypropylene

Polypropylene recent status and technology


Methanol-to-Propylene Technology

Polypropylene

Polypropylene recent status and technology


Propylene Production via Propane Dehydrogenation

Thank You !

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