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Cementing Lab. NL 09 Sep 99 - A
Cementing Lab. NL 09 Sep 99 - A
Introduction
Module CF116
09 Sep 99
Laboratory Functions
Execution Stage
2. Chemical Characterisation
Quantitative or qualitative analysis of the slurry
Performance EvaluationSlurries
Governed by the API committee
on Standardisation of Oilwell
Cements (10A & 10B)
downhole conditions
Pressure
Temperature
Performance EvaluationSpacers/Washes
Rheology
Fluid Compatibility
API Spec. 10 contains the procedures for
are investigated.
of Fann 35 readings.
Large difference between test results
indicates incompatibility.
5
Chemical Characterization
Four types of samples are examined
Cement Powder
C3A, C3S, C2S, C4AF and Gypsum
Set Cement
Mix water
Sample
Preparation
Sampling
Sample acquisition
Prior to shipment (batch number)
From rig site
ALWAYS use actual field samples & labelled.
Sampling procedures as per API spec 10B
Section 4
Disposal
Comply with all regulatory requirements
Slurry Design
Slurry Properties
Free Water & Slurry Sedimentation
Water separation from static slurry
Migrates upward, accumulates in pockets
Density
Balance sub-surface pressures
Cement final strength
10
Rheology
Slurry flow modelling
11
Sulfate Resistance
Reaction to magnesium and sodium sulfates;
Stress cracking
Strength Retrogression
Cement Shrinkage occurs at >230F (110C).
Permeability
Lightweight slurries
12
Testing Process
LAB ANALYSIS
REQUEST(LAR)
SLURRY DENSITY
RHEOLOGY
FREE WATER
TEST
FLUID LOSS
TEST
THICKENING TIME
TEST
COMPRESSIVE STRENGTH
TEST
LABORATORY REPORT
13
Laboratory
Procedures
& Equipment
formulation
Designate additives available for slurry design
Request specific performance parameters;
Density
Rheology ( PV, YP & Gel Strength)
Fluid Loss
Thickening Time
Free Water
Compressive Strength
15
Information requested
Summary of results
Conclusions and recommendations
Part 2
Laboratory Tests and Results
Part 3
Appendices as necessary
16
Slurry
Properties
LAR Number
Well Conditions
Slurry
Formulation
17
Sample Calculation
Sample volume for slurry testing is 600 ml
Consider the following slurry composed of;
Class G Neat & 44% water
Material
Class G Cement
Weight
(lbs)
94
Absolute Volume
(gal)
0.0382
Volume
(gal)
3.59
Weight
(gram)
42637.7
Volume
(ml)
13589.6
Water 44%
41.36
0.1202
4.97
18760.6
18813.5
TOTAL
135.36
8.56
61398.3
32403.1
18
Slurry Preparation -
Section 5
Mixed with a high shear mixer (Waring Blender)
Water and Liquid Additives mixed first.
D20 and polymer need to pre-hydrate prior to
sec.
19
20
tube
Free water (ml) measured after 2 hours
21
Section 10
Simulates amount of fluid loss under pressure
against a permeable formation
Use HPHT cell (simulates downhole conditions)
10.7
Testing procedure as per Section 10.11
22
Filtrate Loss
For slurries that dehydrate in less than 30
F 30= 2Qt
5.477
t
23
Rheology -
shear rate
Tested with Viscometer (FANN 35)
Rotational speed (Shear rate)
300 RPM
200 RPM
100 RPM
60 RPM
30 RPM
Rheology
6 RPM and 3 RPM readings omitted.
3 RPM reading is used to determine
Rotational Sleeve
Slurry Cup
25
BOB (Stationary)
26
27
28
Time (min)
0
140
130
120
110
100
90
80
70
60
50
40
30
20
10
0
100
200
deg.F
400
500
Bc
Temp.
Bc
29
300
50
100
API Schedules -
Section 9.5
Pressure and Temperature
schedules derived from field data
schedules available for casing, liner and
squeeze jobs
P-T effect on Thickening Time
continuous exposure to varying P-T profiles
max P-T not necessarily at same point
TOC will be exposed to max P-T while circulating
New Instrumentation & Refine Procedures
API schedules do not cover all factors
dynamic wellbore simulation tool
30
Solution - CemCADE
31
BHCT Prediction
degF ( * 100)
0.5
1.5
3.5
2.5
Formation
Annulus
Casing Fluids
Max
HCT
BHCT
32
conditions
Apparatus;
Curing Bath (ATM pressure & 82 oC)
Curing Chamber (3000 psi & 193 oC)
Procedure.
Measurement Unit
Other methods
33
34
Test Category
Sampling
Slurry Preparation
Summary of Test
Procedures
Slurry Conditioning
Thickening Time
Static Fluid Loss
Compressive Strength
Free Water
Permeability
Rheology
Static Gel Strength
Expansion
Spacer/Wash/Cement
Compatibility
Particle Analysis (Portland
Cement)
Chemical Analysis of Dry Blends
Chemical Analysis of Mix water
35
Equipment
Diverter Flow Sampler
2-Speed Propeller Mixer
Atmospheric Consistometer
Atmospheric and Pressurized
Consistometer
HTHP Fluid Loss Cell
Water/cooling Bath, Curing
Chamber, Hydraulic Press, UCA
250ml graduated glass cylinder
Permeameter
Rotational viscometer
Rotational viscometer
Bar mould, Cylindrical sleeves
Rotational viscometer, Fluid loss
cell, Consistometer, Hydraulic
press
Blaine permeameter
Procedure Reference
ASTM C702, API Spec 10(3) & 10B(4)
API Spec 10(5) & 10B(5)
See relevant sections for Free water,
Fluid loss and Rheology in API Spec 10
& 10B
API Spec 10(8) & 10B(9)
API Spec 10(App F) & 10B(10)
API Spec 10(7) & 10B(7 and 8)
API Spec 10(6 and App M) & 10B(15)
API Spec 10(App G) & 10B(11)
API Spec 10(App H) & 10B(12)
API RP 13B(2) & 10B(12.7)
ASTM C151