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Pinch Technology and optimization of

the use of utilities


Maurizio Fermeglia
mauf@dicamp.units.it
www.mose.units.it

Impact of process integration

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Which option requires more capital?

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Energy efficient process can also be more


capital efficient process (saves energy AND
capital)

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Energy efficient design reduces investment


in the utility infrastructure

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Pinch technology basics

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

How do I develop a network which


achieves the target?

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

How can we identify appropriate


process design changes?

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Sustainable Development
Objectives and Process Integration
Social progress which
recognises the needs of
everyone
Effective protection of
the environment
Prudent use of natural
resources
Maintenance of high and
stable levels of
economic growth and
employment

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Process Integration
Introduce
Combined Heat and Power
(CHP)

OR..

Reduce Energy Consumption

Fuel
Crude

POWER
Steam for
Process HEATing

110

Heat
exchanger
network

80
Fuel

Reduce impact on climate change through efficient use


of resources (utilities)
Training Course on:
Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Sustainable Development by Process


Integration

Reduce
Reduce
Environmental
Environmental
Impact
Impact

Improve
Improve
Utility
UtilitySystem
System
Performance
Performance

Energy, Water, Hydrogen Utilities


Training Course on:
Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Sustainable Development by Process


Integration
Reduce
Reduce
Environmental
Environmental
Impact
Impact

Optimise
Optimise
Production
Production
Plan
Plan

Improve
Improve
Utility
UtilitySystem
System
Performance
Performance

Minimise
Minimise
Operating
Operating
Cost
Cost

All
AllAspects
Aspectsof
of
Debottlenecking
Debottlenecking

Capital
CapitalCost
Cost
Avoidance
Avoidance

Energy, Water, Hydrogen


Training Course on:
Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Introduction to Pinch technology


Whenever the design is considered limits exits that
constraints the design

Mechanical constraints
Length and diameter of towers
Diameters of heat exchangers

Thermodynamic constrains
First principles and second principles
Close approach in heat exchanger large surface area
Reflux ratio close to the minimum number of stages grows

When driving force becomes small area becomes large

We say that the design has a PINCH


Applies to heat and mass

In a network (mass or heat) there is a point in which the


driving force is minimum PINCH POINT
A succesful design involves defining where the pinch is
Using the information at the PINCH POINT is named PINCH
TECHNOLOGY
Training Course on:
Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Introduction to Pinch technology


Pinch technology applications

Both heat and mass transfer


New processes
Existing processes for retrofitting

Pinch technology = optimization


For new and existing processes an algorithm is used

Design of heat and mass exchanger network


that consumes the minimum amount of utilities HEN (MEN)
that requires the minimum number of equipments
(exchangers) MUMNE
The solution may not be optimal in the economic sense
it is a starting point close enough to the economic minimum.

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Pinch technology and heat integration


Growing importance of heat integration is driving force
Formalization of heat integration theory pinch technology

Linhoff and Flower


Hohman
Umeda et al.
Douglas
Turton et al (text book)

Different operative configurations of the same process may


result in

Same conditions (composition, temperature, pressure, flow rate)


Different Fixed capital investment
Different cost of utilities
Different Net present value

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

DME reaction: different configurations


No Heat
integration

With heat
integration

Fixed capital investment

$ 346,000

$ 244,600

Cost of utilities

-$ 210,000 /yr

-$ 36,820 /yr

Net present value

-$ 1,636,000

-$ 471,000

Total saving (in the life of the plant) = -471,000 + 1,636,000 =$


1,165,000

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

The MUMNE algorithm


The Minimum Utility steps:

Choose a minimum approach temperature (parametric


optimization)
Construct a temperature interval diagram
Construct a cascade diagram and determine the minimum utility
requirements and the pinch temperatures
Calculate the minimum number of heat exchangers above pinch
Calculate the minimum number of heat exchangers below pinch
Construct the heat exchanger network

The object is to obtain and heat exchanger network

That exchange the minimum energy between the streams and


the utilities
That uses the minimum number of equipment

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Algorithm: initial condition and step 1


Minimum Temperature Approach = Smallest T of two streams
leaving or entering an heat exchanger = 10C
Hot Stream Data
Mass Flow Cp
Temp In
kg/s
kJ/kg/C
C
10.00
2.500
3.000

.8000
.8000
1.000

300.0
150.0
200.0

Temp Out
C
150.0
50.00
50.00

Cumulative Hot Stream Energy Available =


Cold Stream Data
Mass Flow Cp
Temp In
kg/s
kJ/kg/C
C
6.250
10.00
4.000

.8000
.8000
1.000

190.0
90.00
40.00

Temp Out
C
290.0
190.0
190.0

Stream Enthalpy
kW
1200.
200.0
450.0
1850.0

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

400.0
270.0
530.0
kW

Stream Enthalpy
kW
-500.0
-800.0
-600.0

Cumulative Cold Stream Energy Available = -1900.0

Film Heat Transf. Coef


W/m2/C

Film Heat Transf. Coef


W/m2/C
100.0
250.0
80.00

kW

Mexico City - Mexico - September 2006 - slide

Algorithm: construct Temperature interval


diagram (step 2)
Process streams represented by vertical lines
Axes are shifted by the minimum T approach (10C)

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Algorithm: construct a cascade


diagram (1)

Shows the net amount of energy in each interval


diagram
Cascade if there is an excess energy in a T interval
we may cascade it down
Energy cannot be transferred up (II law)
Line is the point at which no more energy can cascade
down
We need to resort to utilities
NOTE: not all problems have a pinch condition: the
algorithm is still valid
Pinch
temperature

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Algorithm: construct a cascade


diagram (2)

Additional heat is transferred to the C interval (yellow line)


Energy is cascaded down through the pinch and rejected to
the cold utility
If heat is transferred across the pinch, the net result will be
that more heat will have to be added from the hot utility and
rejected to the cold utility
To minimize the hot and cold utility requirements,
energy should NOT be transferred across the pinch

Pinch
temperature
Training Course on:
Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Algorithm: minimum n. of exchangers


Above the pinch
Draw boxes representing energy in the hot and cold
process streams and utilities
Transfer energy is indicated by lines (with the amount)
For each line an heat exchanger is required
The problem is split into two sub problems

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Algorithm: minimum n. of exchangers


Below the pinch
Draw boxes representing energy in the hot and cold
process streams and utilities
Transfer energy is indicated by lines (with the amount )
For each line an heat exchanger is required
The problem is not split into sub problems

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Algorithm: minimum n. of exchangers


General relationship

For any sub problem


With or without a pinch
Above or below the pinch

Min. No. of exchangers = No. of hot streams + No. of cold


streams +
No. of utilities 1

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Algorithm: Design the network above the


pinch
Start from the design at the
pinch
To make sure that T min is
not violated, match
streams such that

m c p , IN m c p ,OUT
m c p ,hot m c p ,cold
Note that we consider ONLY
streams present at the
pinch
Each exchanger is
represented by two circles
connected with a line, each
circle represent a side
Training Course on:
Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Algorithm: Design the network above the


pinch
Move away from the pinch
Look at the remaining
streams
Criterion used at pinch not
necessarily holds away
from the pinch
The following constraints
are not violated:

The minimum approach T is


used throughout the design
The number of exchangers
must be that calculated in
step 3
Heat is added form the
coolest possible source

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Algorithm: Design the network below the


pinch
Similar to previous one: start
from the design at the pinch
To make sure that T min is not
violated, match streams such
that

m c p ,hot m c p ,cold

m c p , IN m c p ,OUT

m c p ,hot m c p ,cold
Note that we consider ONLY
streams present at the pinch
Each exchanger is represented
by two circles connected with a
line, each circle represent a side
What happens if the T min is
violated (see figure)

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Algorithm: Design the network below the


pinch
Split stream into
substreams to
meet the T min
criterion

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Algorithm: Design the network below the


pinch
Move away from the pinch
Look at the remaining
streams

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Final result
The final network of
heat exchangers is the
following

It has the minimum n. of


exchangers (8)
Minimum utility
requirement (Qh = 100
kW and Qc = 50 kW)
Using a minimum
approach T = 10

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Heat exchangers design: area and


costs
Up to now, emphasis on the topology of the network
to complete the design, it is necessary to

Estimate the heat transfer area (A= Q / (U Tln F)

And the cost estimate

If heat transfer coefficients are known (including fouling)

Transfer coefficients form literature (Seider Tate, Donahue, )

exchanger area can be calculated (for streams exchangers)


Exchanger DT ln
U
Q
F factor
Area.
C
W/m2/C
kW
m2
1
24.1
129.8
100
0.8
40.0
2
20.0
69.5
300
0.8
270.3
3
47.5
153.8
700
0.8
119.7
4
24.1
80.0
500
0.8
324.6
6
10.0
61.7
100
0.8
202.5
7
17.0
69.5
100
0.8
195.8
TOTAL
1063.0
Exchanger 5 requires an hot utility (steam): T = 76.8 C, U= 76.9 W/m2/C, Area = 16.9 m2
Exchanger 8 requires cooling water: T = 23.2 C, U= 346 W/m2/C, Area = 7.8 m2

TOTAL Area: 1087.7 m2


Training Course on:
Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Effect of the minimum approach


temperature
Calculations must be repeated for different approach T
(step 1)
Problem: step 5 (matching streams and exchanging
energy) cannot be programmed easily
An approximate approach is necessary for investigating
the effect of the approach temperature on the total cost
Based on the Composite temperature enthalpy diagram

Constructed by plotting enthalpy of all streams as a function of T

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Construction of Composite T-H


diagram
Temperatur T C Enthalpy of HOT streams in
Cumulative
e Interval
D

Temperature interval (kW)

Enthalpy of HOT
streams (kW)

50 0

100 (2+3)(100-50) = 250

250

150 (2+3)(150-100) = 250

500

200 (8+3)(200-150) = 50

1050

300 (8)(300-200)

1850

Temperatur
e Interval

T C

= 800

Enthalpy of COLD streams in


Temperature interval (kW)

40 0

90 (4)(90-40)

Cumulative
Enthalpy of COLD
streams (kW)
0

= 200

200

140 (8+4)(140-90) = 600

800

190 (8+4)(190-140) = 600

1400

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Construction of Composite T-H


diagram

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Using the T-H diagram to estimate heat


exchanger area
The working equation is (A= Q / (U Tln F)
Consider a portion of the diagram (figure)

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Results of the heat transfer area


calculations

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Finalize the design


Consider the F factor

By calculating the number of shells in a 1-2 geometry exchanger


The effect of the economy of scale: the cost of two 1-2 S&T in series
is greater than the equivalent 1-2 S&T with the same total area

Calculate the cost of equipments

Knowing the number of shells for each exchanger


Using cost correlations
Applying an economic criteria (such as Equivalent Annual Operating
Cost EAOC)

Approximations

All heat exchangers have the same area over estimation of the
costs
No effect of material of construction (corrections available)
No effect of operating pressure (corrections available)
No multiple utilities (alternative methods)
No streams with phase change (correction available)

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Calculation of the costs for the


network

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Typical relationship for heat transfer area,


utilities and EAOC for a HEN

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Mexico City - Mexico - September 2006 - slide

Mass exchange networks


Exchangers to use energy
more efficiently
Temp Interval Diagram
Cascade diagram pinch
Min n. of eq. above and
below
Composite T exchange diag.
Final T exchange network
Utility: cold and hot source
of energy
Hot and cold
Temperature

Training Course on:


Sustainable Industrial Development: Process Simulation, Analysis, Optimization and Control

Separators to use mass more


efficiently
Composition Interval Diagram
Cascade diagram pinch
Min n. of eq. above and below
Composite mass exchange
diag.
Final mass exchange network
Utility: separation - addition of
solute (from source or to sink)
Rich and lean
Concentration

Mexico City - Mexico - September 2006 - slide

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