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WRD Ot Chemical Clarification Metals Precipitation 445210 7
WRD Ot Chemical Clarification Metals Precipitation 445210 7
Precipitation Methods
Prepared By
Michigan Department of Environmental Quality
Operator Training and Certification Unit
A precipitation reaction is a
reaction in which soluble ions in
separate solutions are mixed
together to form an insoluble
compound that settles out of
solution as a solid. That insoluble
compound is called a precipitate.
Precipitate Formation
soluble
insoluble
Hydroxide Precipitation
Most Soluble Heavy Metals Will Precipitate
When pH is Raised to a Given Point
pH is Raised by Addition of Hydroxide
Cu(NO3)2(aq)
2 NaOH(aq)
Cu(OH) 2(s)
+ 2 NaNO3(aq)
Hydroxide Precipitation
Sodium Hydroxide,
NaOH
Caustic Soda
Calcium Hydroxide,
Ca(OH)2
Hydrated Lime
Sodium Hydroxide
Caustic Soda, Soda Lye
Available in Liquid or Dry Form
Liquid:
Commercial Strength
50 % , 73 % NaOH
Often Stored at 20 %
50 % Crystallizes at 53 Deg. F
Dry:
99.9 % NaOH
Safety
Bag, Drum, or Bulk
Caustic Poison
Dangerous to Handle, Corrosive
Prevent All Body Contact
Protect Eyes
Calcium Hydroxide
Ca(OH)2
Hydrated Lime, Slaked Lime
Available in Dry or Liquid Form
Hydroxide Precipitation
Sodium Hydroxide
VS
Hydrated Lime
Less Expensive
Solids Settle Faster
Higher Sludge Solids Conc
Sludge Easier to Dewater
Takes Longer to Neutralize
More Complicated Feed System
A Lot More Sludge
Process Water
Chemical
Treatment
..
Equalization Tank
Treatment Tank
Treated Water
Back To
Equalization Tank
Clarifier
Filter Press
Sludge Tank
Sludge Bin
Hydroxide Precipitation
From Chart (Book Value)
Minimum Solubility (Best Removal) Value for Some Metals
Cadmium
pH 11.0
Copper
pH 8.1
Chromium
pH 7.5
Nickel
pH 10.8
Zinc
pH 10.1
Hydroxide Precipitation
Need to Determine Optimum pH for Waste
May or May Not be Close to Book Value
Metals Precipitate at Various pH Levels
Depending On:
The Metal Being Precipitated
The Chemistry of the Wastewater
Other Metals Present
Presence of Chelates
Metal Precipitation
Precipitation of more than one metal from the
same solution:
Adjust for Optimum pH for One Metal
(With Lowest Discharge Permit Limit)
Adjust for Compromise pH
Operate in Stages
Adjust pH for Each Metal in Stages
Draw Off Sludge, or Transfer
Supernatant Between Stages
Hydroxide Precipitation
Expected Effluent Quality (mg/L) for Total Metals
Precip +
Settling
Cr
Cu
Ni
Cd
Zn
0.1 to 1.0
0.2 to 1.5
0.5 to 2.5
0.2 to 1.5
0.2 to 1.5
Precip +
Settling +
Filtration
0.05 to 0.5
0.05 to 0.5
0.25 to 1.5
0.05 to 1.0
0.05 to 1.0
NaOH
Mix Tank
Clarifier
Filter
Chelates
Cant Live With em, Cant Do Without em
Chelates
Ca(OH)2
Mix Tank
Cr
Cu
Ni
Cd
Zn
FeS
Mix Tank
OH
Precip +
Settling +
Filtration
0.05 to 0.5
0.05 to 0.5
0.25 to 1.5
0.05 to 1.0
0.05 to 1.0
Clarifier
Filter
OH + S
Precip +
Settling +
Filtration
0.01 to 0.20
0.01 to 0.25
0.05 to 0.50
0.01 to 0.25
0.01 to 0.25
Sodium Dimethyldithiocarbamate
(DTC or SDDC)
Organic sulfur compound
Controls chelated waste streams
Not pH sensitive
any pH above 3
Non amphoteric
Very toxic
Agricultural insecticide
Industrial biocide
Batch Treatment
Usually Preferred for Small Flows
Either a Holding Tank and Reaction Tank,
or Two Reaction Tanks
Reaction Tanks Serve Also as Clarifiers
Allows for Maximum Control of Effluent Quality
Influent Wastewater
Sludge
NaOH
NaOH
Effluent
Effluent
Sludge
Storage
Clarifier
React
Flocculation
pH
Sludge Recirculation
Precipitated Solids Act as Seed Structure for
Forming Precipitate
Batch Treatment
Portion of Settled Sludge Left on Tank Bottom that
Re-suspends When Mixing For New Batch Begins
Sludge Recirculation
Continuous Treatment
Sludge is Recirculated from Sludge Hopper of
Clarifier to the Influent or Reaction Tank
Precipitate at high pH
b.
c.
7. Recirculation of _________________
precipitated sludge may be
beneficial in that it provides seed material
for the precipitation process.
Chemical Clarification
Precipitation Methods
Prepared By
Michigan Department of Environmental Quality
Operator Training and Certification Unit