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  • Activity (A) : A F/ F Activity Coefficient

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    This document defines activity as the ratio of the fugacity of a component in a real solution to its fugacity in an ideal solution. It also discusses activity coefficients, which measure how much real solutions deviate from ideality, and lists several common equations used to model activity coefficients including Wohl's three suffix, Margules, and Wilson equations. Finally, it lists methods for consistency testing of vapor-liquid equilibrium data such as using the slope of lnγ curves or the Redlich-Kister method.

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    This document defines activity as the ratio of the fugacity of a component in a real solution to its fugacity in an ideal solution. It also discusses activity coefficients, which measure how much real solutions deviate from ideality, and lists several common equations used to model activity coefficients including Wohl's three suffix, Margules, and Wilson equations. Finally, it lists methods for consistency testing of vapor-liquid equilibrium data such as using the slope of lnγ curves or the Redlich-Kister method.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
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    Download as pptx, pdf, or txt
    5 views3 pages

    Activity (A) : A F/ F Activity Coefficient

    Uploaded by

    PRAVIN
    This document defines activity as the ratio of the fugacity of a component in a real solution to its fugacity in an ideal solution. It also discusses activity coefficients, which measure how much real solutions deviate from ideality, and lists several common equations used to model activity coefficients including Wohl's three suffix, Margules, and Wilson equations. Finally, it lists methods for consistency testing of vapor-liquid equilibrium data such as using the slope of lnγ curves or the Redlich-Kister method.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pptx, pdf, or txt
    of 3

    Activity(a):

    It is defined as the fugacity of the existing condition


    to the standard state fugacity

    a=f/ fo
    Activity coefficient :
    It measure the extent to which real solution depart from
    ideality.
    ln=bx
    ln=bx

    Activity coefficient equations

    Wohls three suffix equation


    Margules equation
    Van laar equation
    Wilson equation
    Non random two liquid (NRTL)equation
    Universal quasi chemical (UNIQUAC)equation
    Universal functional activity coefficient (UNIFAC)
    method

    Consistency test for VLE data

    Using slope of ln curves


    Using data at mid point
    Redlich kister method
    Using the coexistence equation
    Using partial pressure data

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