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T I Tri Metric Methods of Analysis
T I Tri Metric Methods of Analysis
ANALYSIS
BASICS OF ANALYTICAL
CHEMISTRY
PROF.DR.ENDANG ASIJATI M.Sc.
Titrimetric Methods
Includes a group of analytical
methods that are based upon
determining the quantity of a
reagent of unknown strength that is
required to react completely with the
analyte.
Titrimetric Methods
Volumetric titrimetry
A type of titrimetry in which the standard
reagent is measured volumetrically.
Gravimetric titrimetri
A type of titrimetry in which the mass of
the standard reagent is measured.
Coulometric titrimetry
A type in which the quantity of charge in
coulombs required to complete a reaction
with the analyte is maesured.
Titration?
A process in which a standard reagent
is added to a solution of an analyte until
the reaction between the analyte and
the reagent is judge to be complete.
Back-titration
A process in which the excess of a standard
solution used to react with an analyte is
determined by titration with a second
standard solution.
End point
Related to the physical sign that
associate with the condition of chemical
equivalence.
The end point is express in range, the
range should address to the equivalence
point.
Standard?
Standard Solution
A primary standard
A secondary standard
Standardization
A process in which concentration of a
volumetric solution is determined by
using it to titrate a known mass of a
primary standard.
PRIMARY STANDARD
HIGH PURITY
ATMOSPHERIC STABILITY
INDEPENDENT OF HUMIDITY
MODEST COST
LARGE MOLAR MASS
ALGEBRAIC RELATIONSHIP
AT THE EQUIVALENCE POINT
Equivalent A = Equivalent B
Mol A = Mol B (if the reaction is 1:1)