Gasoline, Diesel, and LPG

Technologies
Kh
lu hunh
(HDS)
Kh Oxy
(HDO)

Kh Nit
(HDN)

Qu trnh
no ha

Hydracking

BO CO TNG HP HA DU

BO CO TNG HP HA DU

TM HIU QU TRNH
HYDRODESULFUR HA
Cn b hng dn:
ThS. L c Duy

Sinh vin thc hin: MSSV:

Hong Th Ngc T B1305173
Nguyn Tn c B1305078
Phm Th Giu B1305081
L Trung Ton B1204352
L Thnh ng B1204269
Nguyn Vn Minh 2102372
Hunh Phng Nhi B1204311
BO CO TNG HP HA DU

NI DUNG BO CO

Gii thiu chung

C ch ca qu trnh
Quy trnh cng ngh

BO CO TNG HP HA DU

GII THIU CHUNG

u im ca phng php x l bng hydro:

- Cht lng sn phm thu c sch hn
- Cc tp cht b x l trit hn.
- Phng php x l bng hydro c th x l
c hu ht cc tp cht v ng thi ci
thin c hiu sut thu hi sn phm

BO CO TNG HP HA DU

GII THIU CHUNG

Qu trnh HDS

Vai tr

ng dng

-Lu hunh: mt ch
tiu nh gi cht
lng du th
- Qu trnh HDS c
dng loi b lu
hunh ra khi kh t
nhin, cc sn phm
du m c tinh ch

-Khng lm mt hot
tnh xc tc trong lc
du
- To sn phm
nguyn nhin liu c
cht lng tt hn
- Gim nhim mi
trng

-Sn xut H2SO4 v

cc sn phm ph
- Sn xut nhin liu
ng c
- Phn on xng
ct trc tip v c
xng t cc qu
trnh th cp

BO CO TNG HP HA DU

C CH PHN NG HDS
1. Phng trnh phn ng tng qut
a. Mercaptanes
R-SH + H2 RH + H2S
b. Sulfur
R2S + 2H2 2RH + H2S
c. Disulfur
(RS)2 + 3H2 2RH + 2H2S
d. Thiophenes
+ 2H2 H2C=CH-CH=CH2 + H2S
+ 3H2

+ H2S
BO CO TNG HP HA DU

C CH PHN NG HDS
2. C ch phn ng ca Hydrodesulfur ha ca Thiophene

BO CO TNG HP HA DU

QUY TRNH CNG NGH

Hydrogen-rich
Recycle gas

Sour gas

30-130 atm
300-400 0C
Distillation
tower

BO CO TNG HP HA DU

THANKS FOR LISTENING

BO CO TNG HP HA DU

BO CO TNG HP HA DU

10

THNH PHN V VAI TR

CHT XC TC
MoS 2
Cht tr xc tc
Lm tng hot tnh
xc tc ln nhiu ln

Co
hoc Ni

Pha hot ng
C tc dng xc tc
b gy lin kt C-S

-Al2O3

Cht mang
Lm tng bn c
hc, bn nhit v gim
thiu kt cho xc tc
B mt tip xc ln
(160-300 m2/g
cu trc xp, gi
tng i r

QU TRNH TNG QUT HDS

Hn hp
nguyn liu

300 400oC
L phn ng

Hon lu H2

30 - 130atm

Ph v lin kt
C-S

Thit b tch H2
v H2S

TP CHT TRONG DU TH
Lu hunh

Nit

Trn 250 hp cht

Mercaptan (RSH)
Sunfur (RSR)
Disulfur (RSSR)
Thiephene
Dn xut Thiophene

DU
TH

Oxy

0.01-1% khi lng

Vng nhit si cao
Dng baz: quinolin,
iso-quinolin, pyridin
Dng trung tnh: pyrol,
indol, carbazol.
Kim loi

Acid, ceton
phenol, ester, ete

BO CO TNG HP HA DU

Ch yu l V, Ni
Hm lng nh: Zn,
Mg, Ti, Cu

13

DU TH

Du th l h d th, lng, nhn c mu bin i

t vng n en ty theo thnh phn v tui ca
du. Tuy nhin c mt s trng hp du th
dng c do cha hm lng parafin rn cao.
Du th l mt hn hp phc tp cc
hydrocacbon v mt s hp cht ca lu hunh,
Nit, Oxy, kim loi

BO CO TNG HP HA DU

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THNH PHN CHNH TRONG

DU TH

Hydro
10-14% KL

Cacbon
83-88% KL
.

Lu hunh
0.05-6% KL
Nit
0.1-2%

Oxy
< 1.5% KL

Lng nh
kim loi: Cu,
Ni, V, Fe, As
.

BO CO TNG HP HA DU

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NHIM V CA
NH MY LC DU

Tip nhn v tn tr du th
Ch bin du th to ra cht nn
Sn xut v kim tra cht lng sn phm. y l
qu trnh pha trn cc cht nn nhm p ng sn
lng theo yu cu v t c tnh cht quy nh cho
mi sn phm. C th kt hp thm ph gia nhm tng
cng tnh nng cho sn phm, mi loi sn phm c
cng thc pha trn ring theo tng hng v tng nh
my.

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CC QU TRNH
TRONG NH MY LC DU

C 4 qu trnh chnh:
Phn tch: gm cc qu trnh vt l ( chng ct,
trch ly) nhm to ra cc phn on c s hp.
Chuyn ha: gm cc phn ng ha hc thay i
cu trc phan t to ra cc phn t mi ph hp vi
yu cu s dng
X l: loi b cc hp cht khng mong mun
Bo v mi trng: gm cc qu trnh x l nc
th, khi thi, kh thi

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CC CH TIU NH GI
CHT LNG CA XNG
Tn ch tiu

Mc gii hn

Hm lng ch, g/l

0.013

Hm lng lu hunh, mg/kg

500

Hm lng benzen, % th tch

2.5

Hm lng Hydrocacbon thm, % th tch 40

Hm lng olefin, % th tch

38

Hm lng Oxy, % khi lng

2.7

18