,

Purpose

.
 Theory

,

 Theory

-
- ( )
- 1 .
 Theory

.

A B A B A B

< > < > < >

1. :
.

2. :
- .
- .

3. : .

,
.
 Theory

(Complex ion)

Fe3+ (aq)+SCN- (aq) Fe(SCN)2+

(aq)
 Theory

Beer

.

A=xlxc

:
l :
c :

 Theory

Fe3+ (aq)+SCN- (aq) Fe(SCN)2+ (aq)

2
[Fe(SCN) ]
K 3
[Fe ][SCN ]

x
K
[Fe3+ ] = a, [SCN-] = b (a x)(b x)
[Fe(SCN)2+] = x

C0 :
CL
C1
L0 : 0 0

C1 : L 1
L1 :
 Chemicals & Apparatus
1. Chemicals
Name Formula M.W m.p () b.p () densit
(g/mol) y
(g/cm3)
Iron () chloride FeCl36H2O 270.3 37 280 1.82
hexahydrate

Ammonium thiocyanate NH4SCN 76.122 149.5 170 1.305

Ammonium chloride NH4Cl 53.49 338 520 1.5274

Potassium thiocyanate KSCN 97.181 173.2 500 1.886

Iron() nitrate nonahydrate Fe(NO3)39H2O 403.999 47.2 125 1.6429

 Chemicals & Apparatus
2. Apparatus
(test tube)

(graduated cylinder) 10mL, 50mL

(dropper)

(test tube rack)

(100mL) (Beaker)

(25 mL) (volumetric flask)

Procedure A.
10 mL + 10 mL +
0.5 M FeCl3 1 M NH4SCN

Total 20 mL

5 mL

reference
0.5 M FeCl3 - 2
1 M NH4SCN - 2

1 M NH4Cl - 10

 Procedure
A.
1)

2 10 mL .

0.5 M FeCl3 , 1 M NH4SCN

, 4 5 mL .

2)

reference

0.5 M FeCl3-2

1 M NH4SCN-2

1 M NH4Cl-10
 Procedure
B.
1) ( 1)
5 1 5 , .

10 mL 0.0002M KSCN 5 mL .

10 mL 0.2M Fe(NO3)3 5 mL 1 .

( SCN- FeSCN2+ : FeSCN2+ 1 )

2) Fe3+ + SCN-

1) Fe(NO3)3 5 . (5ml 25ml . 2

)

5 3, 4, 5 Fe(NO3)3 .
 Procedure
3)

1 ( ) 2
.

1 , 1,2
.

3, 4, 5 .
 Procedure B.
1 (Reference) : 2 : 3 :
0.0002M KSCN 0.0002M KSCN 5mL + 0.0002M KSCN 5mL +
5mL+ Fe(NO3)3 A 5mL Fe(NO3)3 B 5mL
0.2M Fe(NO3)3 5mL

4 : 5 :
0.0002M KSCN 5mL + 0.0002M KSCN 5mL
Fe(NO3)3 C 5mL Fe(NO3)3 D 5mL

0.0002M KSCN Total

1 0.02M Fe(NO3)3 5 mL
( )
2 Fe(NO3)3 A 5 mL

3 5 mL B 5 mL 10 mL
4 C 5 mL

5
D 5 mL
Total
Fe(NO3)3

A 0.2M Fe(NO3)3 5 mL

B A 5 mL
20 mL 25 mL
C B 5 mL

D C 5 mL
 Procedure B.

1,2

.

2,3 , 3,4 , 4,5

.
 Caution

A

ml

Thank you!