Fugacity: It is derived from Latin, expressed as

fleetness or escaping tendency. It is used

to study extensively phase and chemical reaction
equilibrium.
G = RT ln f +

- Is an constant depends on temperature and nature

of gas.
fugacity has same units as pressure for an ideal gas.
Fugacity coefficient () :
Fugacity coefficient is defined as the ratio of fugacity
of component to its pressure.
=f/P

- Is the measure of non ideal behavior of the gas.

Activity(a):
It is defined as the fugacity of the existing condition
to the standard state fugacity
a=f/ fo
Activity coefficient :
It measure the extent to which real solution depart from
ideality.
ln=bx
ln=bx
 Wohls three suffix equation
Margules equation
Van laar equation
Wilson equation
Non random two liquid (NRTL)equation
Universal quasi chemical (UNIQUAC)equation
Universal functional activity coefficient (UNIFAC)
method